JP2722222B2 - Hair cosmetics - Google Patents

Hair cosmetics

Info

Publication number
JP2722222B2
JP2722222B2 JP63265076A JP26507688A JP2722222B2 JP 2722222 B2 JP2722222 B2 JP 2722222B2 JP 63265076 A JP63265076 A JP 63265076A JP 26507688 A JP26507688 A JP 26507688A JP 2722222 B2 JP2722222 B2 JP 2722222B2
Authority
JP
Japan
Prior art keywords
hair
molecular weight
silicone
group
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP63265076A
Other languages
Japanese (ja)
Other versions
JPH02111712A (en
Inventor
真伸 龍田
早苗 久保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Priority to JP63265076A priority Critical patent/JP2722222B2/en
Publication of JPH02111712A publication Critical patent/JPH02111712A/en
Application granted granted Critical
Publication of JP2722222B2 publication Critical patent/JP2722222B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine

Description

【発明の詳細な説明】 ［産業上の利用分野］ 本発明は毛髪に対し、優れた光沢を与え、なめらかな
感触を付与し、かつ良好なセット保持力を有する毛髪化
粧料に関するものである。Description: TECHNICAL FIELD The present invention relates to a hair cosmetic which imparts excellent gloss to hair, imparts a smooth feel, and has good set holding power.

［従来の技術］ 従来、毛髪化粧料には毛髪に光沢やなめらかさを与え
る目的でシリコーン油、エステル油、炭化水素油などの
油分を、可溶化、乳化、溶解して用いられている。特に
シリコーン油は、表面張力が低く毛髪へのなじみに優
れ、良い光沢が得られる為、近年多用されている。しか
しながら、シリコーン油に代表される油分では、油分の
もつ限界があり多量に用いたり、消費者が長いあいだ使
用したりすると、頭髪のきしみ感が増したり脂ぎるとい
った欠点があった。又なめらかさを付与する目的でカチ
オン界面活性剤も多用されているが、望ましい光沢を与
えるものではなく、多量に配合すると安定性上も好まし
くないという欠点があった。[Prior art] Conventionally, oil components such as silicone oil, ester oil, and hydrocarbon oil have been used in hair cosmetics by solubilizing, emulsifying, and dissolving them for the purpose of imparting gloss and smoothness to hair. In particular, silicone oils have been widely used in recent years because they have low surface tension, are excellent in conformity to hair, and have good gloss. However, oils represented by silicone oils have the disadvantage that they have a limited oil content, and when used in large quantities or when used by consumers for a long time, the feeling of squeaking of the hair increases and the hair becomes greasy. Also, cationic surfactants are frequently used for the purpose of imparting smoothness, but they do not give desirable gloss and have a drawback that if they are blended in a large amount, stability is not preferable.

また、高分子化合物例えば、ポリビニールピロリドン
系ポリマー、酸性ポリビニルエーテル系ポリマー、酸性
アクリル系ポリマーあるいはカチオン性ポリマー等が配
合されているが、これらは毛髪の固定セット力に優れる
ものの、光沢、なめらかさを満足するものではなかっ
た。又、毛髪を硬化させごわつきを与える欠点があっ
た。In addition, high molecular compounds such as polyvinylpyrrolidone-based polymers, acidic polyvinyl ether-based polymers, acidic acrylic-based polymers or cationic polymers, etc., are compounded, and these have excellent fixing and setting power of hair, but have gloss and smoothness. Was not satisfactory. In addition, there is a disadvantage that the hair is hardened to give stiffness.

［発明が解決しようとする課題］ 本発明者らは、このような事情に鑑み、毛髪に優れた
光沢を与え、なめらかな感触を付与し、頭髪の脂じみが
なく毛髪に塗布しやすく、毛髪に塗布後の乾きが早くか
つ適度なセット力を有する毛髪化粧料を得るべく鋭意研
究した結果、高分子量シリコーンにカチオン化シリコー
ン重合体を加えることが、極めて効果的であることを見
出だし、本発明を完成するに至った。[Problems to be Solved by the Invention] In view of such circumstances, the inventors of the present invention give excellent gloss to hair, give a smooth feel, have no oiliness on the hair, and are easy to apply to hair. As a result of intensive research to obtain a hair cosmetic that dries quickly after application and has an appropriate setting power, it was found that adding a cationized silicone polymer to a high molecular weight silicone was extremely effective. The invention has been completed.

［課題を解決するための手段］ すなわち、本発明は下記一般式［Ｉ］で表わされる高
分子量シリコーンの一種又は二種以上と、カチオン化シ
リコーン重合体の一種又は二種以上とを含有することを
特徴とする毛髪化粧料を提供するものである。[Means for Solving the Problems] That is, the present invention comprises one or more of high molecular weight silicones represented by the following general formula [I] and one or more of cationized silicone polymers. And a hair cosmetic comprising:

（R1はメチル基又は一部がフェニル基を表わし、R2はメ
チル基又は水酸基を表わす。又、ｎは3,000〜20,000の
整数を表わす。） 以下、本発明の構成について説明する。 (R 1 represents a methyl group or a part thereof represents a phenyl group, R 2 represents a methyl group or a hydroxyl group, and n represents an integer of 3,000 to 20,000.) The constitution of the present invention will be described below.

本発明に用いられる高分子量シリコーンは、上記一般
式［Ｉ］で表わされるもので、式中のｎの値が3,000〜2
0,000であり、常温で軟質ゴム状の性状を呈するもので
ある。具体例で示すと、ジメチルポリシロキサン、メチ
ルフェニルポリシロキサン、末端水酸基含有ジメチルポ
リシロキサン、末端水酸基含有メチルフェニルポリシロ
キサン等が挙げられる。The high molecular weight silicone used in the present invention is represented by the above general formula [I], and the value of n in the formula is from 3,000 to 2
0,000 and exhibits soft rubber-like properties at room temperature. Specific examples include dimethylpolysiloxane, methylphenylpolysiloxane, dimethylpolysiloxane having a terminal hydroxyl group, and methylphenylpolysiloxane having a terminal hydroxyl group.

本発明に用いられる高分子量シリコーンの配合量は、
毛髪化粧料全量中の0.1〜25重量％であり、0.1重量％未
満では効果がなく、25重量％を越えると粘度が３万cps
以上となり毛髪に塗布しにくくなる。The compounding amount of the high molecular weight silicone used in the present invention is
It is 0.1-25% by weight of the total amount of hair cosmetics. If it is less than 0.1% by weight, it has no effect. If it exceeds 25% by weight, the viscosity is 30,000 cps.
This makes it difficult to apply to hair.

本発明で用いられるカチオン化シリコーン重合体は、
一般式［II］、［III］で表される。The cationized silicone polymer used in the present invention is
It is represented by general formulas [II] and [III].

（式中、R3は炭素原子１〜18個をもつ１価の炭化水素基
を表し;R4は酸素原子を含み得るC1〜C18アルキレン基又
はアルキレノキシ基を表し、Ｑ はハロゲン化物好まし
くは塩化物イオンであり、ｒは２から20の、好ましくは
２から８の整数を表し、ｓは20から200好ましくは20か
ら50の整数を表す。） （式中、ｐ、ｑは分子量に依存する整数であり、平均分
子量は1000〜8000である。） 本発明で用いられるカチンオン化シリコーン重合体の
市販品としては、「UCAR SILIKONE ALE 56」（UNION CA
RBIDE社製）、「ABIL 9905」（GOLDSCHMIDT社製）等が
挙げられる。 (Where RThreeIs a monovalent hydrocarbon group having 1 to 18 carbon atoms
Represents a C which may include an oxygen atom1~ C18Alkylene group
Represents an alkylenoxy group; Is halide preferred
And r is a chloride ion, and r is 2 to 20, preferably
Represents an integer from 2 to 8, where s is from 20 to 200, preferably 20
Represents an integer of 50. )(Where p and q are integers depending on the molecular weight,
Child size is 1000-8000. ) Of the cation-on silicone polymer used in the present invention
As a commercial product, "UCAR SILIKONE ALE 56" (UNION CA
RBIDE), "ABIL 9905" (GOLDSCHMIDT), etc.
No.

本発明で用いられるカチオン化シリコーン重合体の配
合量は、毛髪化粧料全量中の0.05〜40重量％であるが、
高分子量シリコーンの改質や皮膜性を考慮すると、高分
子量シリコーンに対し、10〜80重量％が好ましい。The compounding amount of the cationized silicone polymer used in the present invention is 0.05 to 40% by weight based on the total amount of the hair cosmetic.
In consideration of the modification of high molecular weight silicone and film properties, the content is preferably 10 to 80% by weight based on high molecular weight silicone.

本発明の高分子量シリコーンを配合する場合、低沸点
鎖状シリコーン油や、低沸点環状シリコーン油や、低沸
点イソパラフィン系炭化水素、炭化水素のフルオルクロ
ル置換体等の揮発性油分に溶解して用いることが好まし
い。When blending the high molecular weight silicone of the present invention, it is used by dissolving in a volatile oil such as a low boiling chain silicone oil, a low boiling cyclic silicone oil, a low boiling isoparaffin hydrocarbon, or a fluorochloro-substituted hydrocarbon. Is preferred.

低沸点鎖状シリコーンは次の一般式で表され、具体例
を挙げれば、ヘキサメチルジシロキサン、オクタメチル
トリシロキサン、デカメチルテトラシロキサン、ヘキサ
デカメチルヘプタシロキサンなどである。The low boiling chain silicone is represented by the following general formula, and specific examples thereof include hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, and hexadecamethylheptasiloxane.

（式中、ｎは０〜５の整数を表す。） 環状シリコーンは次の一般式で表され、具体例を挙げ
れば、オクタメチルシクロテトラシロキサン、デカメチ
ルシクロペンタシロキサン、テトラデカメチルシクロヘ
プタシロキサンなどである。 (In the formula, n represents an integer of 0 to 5.) The cyclic silicone is represented by the following general formula, and specific examples include octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and tetradecamethylcycloheptasiloxane. And so on.

（式中、ｎは３〜７の整数を表す。） 低沸点イソパラフィン系炭化水素としては、常圧にお
ける沸点が60〜260℃の範囲にあるイソパラフィン系炭
化水素を挙げることができ、例えばエクソン社製のアイ
ソパー（登録商標）Ａ、同Ｃ、同Ｄ、同Ｅ、同Ｇ、同
Ｈ、同Ｋ、同Ｌ、同Ｍ、シェル社製のシェルゾール（登
録商標）71、フィリップ社製のソルトロール（登録商
標）100あるいは同130、同220などを挙げることができ
る。 (In the formula, n represents an integer of 3 to 7.) Examples of the low-boiling isoparaffin-based hydrocarbon include an isoparaffin-based hydrocarbon having a boiling point in the range of 60 to 260 ° C at normal pressure. A, C, D, E, G, H, K, L, M, Shell, Solsol (registered trademark) 71 manufactured by Shell, Salt manufactured by Phillip Roll (registered trademark) 100 or 130 and 220.

炭化水素のフルオルクロル置換体としては、トリクロ
ロトリフロロエタンやテトラクロロジフロロエタンなど
を挙げることができる。Examples of fluorochloro-substituted hydrocarbons include trichlorotrifluoroethane and tetrachlorodifluoroethane.

上記低沸点油は任意の一種又は二種以上を用いること
ができ、合計の配合量は高分子量シリコーンに対して１
〜50倍（重量）が好ましい。Any one or more of the above-mentioned low-boiling oils can be used.
~ 50 times (weight) is preferred.

また、上記成分に加えてエタノール、イソプロピルア
ルコール等の低級アルコールを添加してもよい。Further, a lower alcohol such as ethanol or isopropyl alcohol may be added in addition to the above components.

本発明の剤型は任意であり、可溶化系、乳化系、粉末
分散系、油−水の２層系、油−水−粉末の３層系、な
ど、いずれでも構わない。The dosage form of the present invention is arbitrary, and may be any of a solubilizing system, an emulsifying system, a powder dispersion system, an oil-water two-layer system, an oil-water-powder three-layer system, and the like.

乳化系の場合は、高分子量シリコーンを含む油相をノ
ニオン界面活性剤、カチオン界面活性剤、アニオン界面
活性剤あるいはそれらの混合物で乳化して用いるのが一
般的であるが、その際に、あらかじめ界面活性剤と水溶
性多価アルコールとの混合物を調製し、ついで油相と混
合して乳化組成物を得る方法が好ましい。多価アルコー
ルとしては、プロピレングリコール、1,3−ブタンジオ
ール、ジプロピレングリコール、グリセリン、ジグリセ
リン、トリグリセリン等のポリグリセリン、トリメチロ
ールエタン、トリメチロールプロパン、エリスリトー
ル、ペンタエリスリトール、ソルビタン、グルコース、
ソルビトール、マルチトール、シュクロース、ラフィノ
ース、トレハロース、ポリオキシエチレンメチルグルコ
シド、ポリオキシプロピレンメチルグルコシド等が挙げ
られる。乳化組成物の調製に際してはこれらのうち一種
又は二種以上が組み合わされて用いられる。また、油相
を構成する油としては、高分子量シリコーンとともにそ
の他のつぎのような油を併用することができる。すなわ
ち、オリーブ油、ヤシ油、サフラワー油、ヒマシ油、綿
実油などの油脂類、ラノリン、ホホバ油、カルナバロウ
などのロウ類、流動パラフィン、スクワラン、ワセリ
ン、揮発性イソパラフィンなどの炭化水素油、脂肪酸
類、アルコール類、オクタン酸セチル、ミリスチン酸イ
ソプロピルなどのエステル油、ジメチルポリシロキサ
ン、メチルフェニルポリシロキサンなどのシリコーン
油、シリコーン樹脂等の油である。In the case of an emulsion system, it is common to emulsify an oil phase containing a high-molecular-weight silicone with a nonionic surfactant, a cationic surfactant, an anionic surfactant or a mixture thereof. A method is preferred in which a mixture of a surfactant and a water-soluble polyhydric alcohol is prepared and then mixed with an oil phase to obtain an emulsified composition. As polyhydric alcohols, propylene glycol, 1,3-butanediol, dipropylene glycol, glycerin, diglycerin, polyglycerin such as triglycerin, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol, sorbitan, glucose,
Sorbitol, maltitol, sucrose, raffinose, trehalose, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside and the like. When preparing the emulsion composition, one or more of these are used in combination. As the oil constituting the oil phase, the following oils can be used in combination with the high molecular weight silicone. That is, olive oil, palm oil, safflower oil, castor oil, oils such as cottonseed oil, lanolin, jojoba oil, waxes such as carnauba wax, liquid paraffin, squalane, petrolatum, hydrocarbon oils such as volatile isoparaffin, fatty acids, Oils such as alcohols, ester oils such as cetyl octanoate and isopropyl myristate, silicone oils such as dimethylpolysiloxane and methylphenylpolysiloxane, and silicone resins.

上記成分の一般的な配合量は、界面活性剤が毛髪化粧
料全量中の0.5〜10重量％、高分子量シリコーンを含む
油相が20〜80重量％が好ましく、あらかじめ界面活性剤
と水溶性多価アルコールとの混合物を調製して油相と混
合して乳化組成物を得る方法の場合は、界面活性剤が１
〜20重量％、高分子量シリコーンを含む油相が10〜70重
量％、水溶性多価アルコールが化粧料全量中の５〜30重
量％で界面活性剤に対して50〜99重量％程度にするのが
好ましい。Generally, the amount of the above components is preferably 0.5 to 10% by weight of the total amount of the hair cosmetic, and 20 to 80% by weight of the oil phase containing high molecular weight silicone. In the case of a method in which a mixture with a polyhydric alcohol is prepared and mixed with an oil phase to obtain an emulsified composition, the surfactant is 1
20% by weight, oil phase containing high molecular weight silicone 10-70% by weight, water-soluble polyhydric alcohol 5-30% by weight of the total amount of cosmetics, 50-99% by weight of surfactant Is preferred.

本発明の毛髪化粧料には上記の成分に加えて、目的に
応じて本発明の効果を損なわない量的、質的範囲で、防
腐剤、ビタミン、ホルモンなどの薬剤、香料等を添加し
てもよい。To the hair cosmetic of the present invention, in addition to the above-described components, according to the purpose, in a quantitative and qualitative range that does not impair the effects of the present invention, preservatives, vitamins, drugs such as hormones, and fragrances are added. Is also good.

［発明の効果］ 本発明の毛髪化粧料は、整髪固定力に優れ、くし通り
をよくし、毛髪につやを与え、使用性に優れたものであ
る。[Effects of the Invention] The hair cosmetic composition of the present invention is excellent in hair fixability, improves combability, gives gloss to hair, and is excellent in usability.

［実施例］ 次に実施例をあげて本発明をさらに詳細に説明する。
本発明はこれらにより限定されるものではない。配合量
は重量％である。[Examples] Next, the present invention will be described in more detail with reference to examples.
The present invention is not limited by these. The compounding amount is% by weight.

実施例に先立ち、効果試験、評価方法について説明す
る。Prior to the examples, an effect test and an evaluation method will be described.

（１）整髪固定力 毛髪ストランド（4g）に試料2gを塗布し、くしで形を
整え、一時間乾燥後毛髪固定力を評価した。(1) Hair fixing power A 2 g sample was applied to a hair strand (4 g), the shape was adjusted with a comb, and the hair fixing power was evaluated after drying for 1 hour.

○：毛髪固定力が優秀 △：毛髪固定力がやや劣る ×：毛髪固定力が劣る （２）くし通りやすさ 毛髪ストランド（4g）に試料2gを塗布し、くしで形を
整え、一時間乾燥後くし通りやすさを評価した。○: Hair fixing power is excellent △: Hair fixing power is slightly inferior ×: Hair fixing power is inferior (2) Ease of combing Apply 2g of sample to hair strand (4g), fix with comb, and dry for 1 hour Ease of combing was evaluated.

○：なめらか △：ややひっかかる ×：ひっかかる （３）毛髪のつや 試料3gを頭髪の左右に分けて塗布し、くしで形を整え
た後、官能評価した。：: Smooth △: Slightly scratched ×: Slightly scratched (3) Gloss of hair A 3 g sample was applied separately to the left and right sides of the hair, and after shaping the shape with a comb, sensory evaluation was performed.

○：つやがある △：ややつやに劣る ×：つやがない （４）手のべたつき 手のひらに試料1gをとり、30秒間手でこすったあと手
のべたつきを官能評価した。：: glossy △: inferior glossy ×: no glossiness (4) Stickiness of Hand A sample of 1 g was taken on the palm of the hand, and the stickiness of the hand was rubbed with the hand for 30 seconds.

○：全くべたつきがない △：ややべたつきがある ×：かなりのべたつきがある 実施例１ ヘアムース （１）オクタメチルシクロテトラシロキサン 30.0 （２）ジメチルポリシロキサン（R1及びR2はメチル基、
ｎ＝3,000） 3.0 （３）プロピレングリコール 6.0 （４）ポリオキシエチレン（80モル付加）硬化ヒマシ油
エステル 3.0 （５）UCAR SILICONE ALE 56 2.0 （６）エタノール 5.0 （７）イオン交換水 残部 （８）ジメチルエーテル 4.0 （９）ジクロロジフロロメタン 6.0 製法 （１）（２）（５）の溶解物を（３）（４）溶液に添
加し、乳化する。次いで（６）（７）溶液に上記乳化物
を添加、混合する。次いでこの原液を缶に充填後、
（８）（９）の噴射ガスを充填し、フォーム状エアゾー
ルを得た。 ：: no stickiness at all △: slightly sticky ×: considerable stickiness Example 1 Hair Mousse  (1) Octamethylcyclotetrasiloxane 30.0 (2) Dimethylpolysiloxane (R1And RTwoIs a methyl group,
n = 3,000) 3.0 (3) Propylene glycol 6.0 (4) Polyoxyethylene (addition of 80 mol) hydrogenated castor oil
Ester 3.0 (5) UCAR SILICONE ALE 56 2.0 (6) Ethanol 5.0 (7) Deionized water balance (8) Dimethyl ether 4.0 (9) Dichlorodifluoromethane 6.0 Production method (1) (2) (5) 3) (4) Add to the solution
Add and emulsify. Next, the above emulsion is added to the solution (6) or (7).
Add and mix. Then, after filling this stock solution in a can,
(8) Filling with the propellant gas of (9), foam air
I got

比較例１ ヘアムース （１）オクタメチルシクロテトラシロキサン 30.0 （２）プロピレングリコール 6.0 （３）ポリオキシエチレン（80モル付加）硬化ヒマシ油
エステル 3.0 （４）UCAR SILICONE ALE 56 2.0 （５）エタノール 残部 （６）イオン交換水 残部 （７）ジメチルエーテル 4.0 （８）ジクロロジフロロメタン 6.0 製法 （１）（４）を（２）（３）溶液に添加し、乳化す
る。次いで（５）（６）溶液に上記乳化物を添加、混合
する。次いでこの原液を缶に充填後、（７）（８）の噴
射ガスを充填し、フォーム状エアゾールを得た。Comparative Example 1 Hair mousse  (1) Octamethylcyclotetrasiloxane 30.0 (2) Propylene glycol 6.0 (3) Polyoxyethylene (addition of 80 mol) hydrogenated castor oil
Ester 3.0 (4) UCAR SILICONE ALE 56 2.0 (5) Ethanol residue (6) Deionized water residue (7) Dimethyl ether 4.0 (8) Dichlorodifluoromethane 6.0 Production method (1) (4) in (2) (3) solution And emulsify
You. Next, the above emulsion is added to (5) and (6) solutions and mixed.
I do. Next, after filling this undiluted solution into a can, the injection of (7) and (8) was performed.
The propellant was filled to obtain a foam aerosol.

以上、実施例１で得られた本発明品と比較例１で得ら
れた従来品について性状ないし作用効果を第１表に示
す。The properties and effects of the product of the present invention obtained in Example 1 and the conventional product obtained in Comparative Example 1 are shown in Table 1.

第１表から明らかなように本発明の毛髪化粧料は、整
髪固定力、くし通りやすさ及び毛髪のつやに優れ、手の
べたつきのないことがわかる。 As is clear from Table 1, the hair cosmetic composition of the present invention is excellent in hair fixing power, combability, hair shine, and no stickiness of hands.

実施例２ ヘアクリーム （１）デカメチルシクロペンタシロキサン 10.0 （２）ジメチルポリシロキサン（R1及びR2はメチル基、
ｎ＝5,000） 3.0 （３）ジメチルシロキサン 20cps 3.0 （４）トリ−２−エチルヘキサン酸グリセリン 7.0 （５）ワセリン 4.0 （６）ステアリルアルコール 3.0 （７）ソルビタンモノオレート 2.0 （８）ポリオキシエチレン（40モル付加）硬化ヒマシ油
エステル 2.0 （９）グリセリン 6.0 （10）ABIL 9905 2.0 （11）防腐剤 適量 （12）イオン交換水 残部 製法 （１）〜（８）を70℃で撹拌溶解し、（９）〜（12）
を溶解したものの中に加えて乳化し、ヘアクリームを得
た。Example 2 Hair Cream (1) Decamethylcyclopentasiloxane 10.0 (2) Dimethylpolysiloxane (R 1 and R 2 are methyl groups,
n = 5,000) 3.0 (3) Dimethylsiloxane 20 cps 3.0 (4) Glycerin tri-2-ethylhexanoate 7.0 (5) Vaseline 4.0 (6) Stearyl alcohol 3.0 (7) Sorbitan monooleate 2.0 (8) Polyoxyethylene (40 (Mol addition) Hardened castor oil ester 2.0 (9) Glycerin 6.0 (10) ABIL 9905 2.0 (11) Preservatives appropriate amount (12) Ion-exchanged water Remaining production method (1) to (8) are stirred and dissolved at 70 ° C, and (9) ) To (12)
Was added to and dissolved in the mixture to obtain a hair cream.

実施例２は、整髪固定力、くし通りやすさ及び毛髪の
つやに優れ、手のべたつきがなかった。Example 2 was excellent in hair fixing power, combability, and gloss of hair, and was not sticky.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項１】下記一般式［Ｉ］で表される高分子量シリ
コーンの一種または二種以上と、下記一般式［II］およ
び［III］で表されるカチオン化シリコーン重合体の一
種又は二種以上とを含有し、カチオン化シリコーン重合
体の配合量が高分子量シリコーンの配合量に対して10〜
80重量％であることを特徴とする毛髪化粧料。 （R1はメチル基又は一部がフェニル基を表わし、R2はメ
チル基又は水酸基を表わす。又、ｎは3,000〜20,000の
整数を表わす。） （式中、R3は炭素原子１〜18個をもつ１価の炭化水素基
を表し;R4は酸素原子を含み得るC1〜C18アルキレン基又
はアルキレノキシ基を表し、Q-はハロゲン化物好ましく
は塩化物イオンであり、ｒは２から20の、好ましくは２
から８の整数を表し、ｓは20から200、好ましくは20か
ら50の整数を表す。） （式中、ｐ、ｑは分子量に依存する整数であり、平均分
子量は1000〜8000である。）1. One or more of high molecular weight silicones represented by the following general formula [I] and one or two types of cationized silicone polymers represented by the following general formulas [II] and [III] Containing the above, the compounding amount of the cationized silicone polymer is 10 to 10 with respect to the compounding amount of the high molecular weight silicone
A hair cosmetic characterized by being 80% by weight. (R 1 represents a methyl group or a part thereof represents a phenyl group, R 2 represents a methyl group or a hydroxyl group, and n represents an integer of 3,000 to 20,000.) (Wherein, R 3 represents a monovalent hydrocarbon group having 1 to 18 carbon atoms; R 4 represents a C 1 -C 18 alkylene group or an alkylenoxy group which may contain an oxygen atom, and Q − represents a halide. Preferably it is a chloride ion and r is from 2 to 20, preferably 2
And s represents an integer of 20 to 200, preferably 20 to 50. ) (In the formula, p and q are integers depending on the molecular weight, and the average molecular weight is 1000 to 8000.)
JP63265076A 1988-10-20 1988-10-20 Hair cosmetics Expired - Fee Related JP2722222B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63265076A JP2722222B2 (en) 1988-10-20 1988-10-20 Hair cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63265076A JP2722222B2 (en) 1988-10-20 1988-10-20 Hair cosmetics

Publications (2)

Publication Number Publication Date
JPH02111712A JPH02111712A (en) 1990-04-24
JP2722222B2 true JP2722222B2 (en) 1998-03-04

Family

ID=17412265

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63265076A Expired - Fee Related JP2722222B2 (en) 1988-10-20 1988-10-20 Hair cosmetics

Country Status (1)

Country Link
JP (1) JP2722222B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3111923A1 (en) 2015-07-02 2017-01-04 Shin-Etsu Chemical Co., Ltd. Organopolysiloxane and hair cosmetic and method for producing thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5566506A (en) * 1978-11-15 1980-05-20 Lion Corp Cosmetic
JP2537629B2 (en) * 1986-09-03 1996-09-25 株式会社資生堂 Hair cosmetics

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3111923A1 (en) 2015-07-02 2017-01-04 Shin-Etsu Chemical Co., Ltd. Organopolysiloxane and hair cosmetic and method for producing thereof
KR20170004873A (en) 2015-07-02 2017-01-11 신에쓰 가가꾸 고교 가부시끼가이샤 Organopolysiloxane, hair cosmetic and method for manufacturing thereof

Also Published As

Publication number Publication date
JPH02111712A (en) 1990-04-24

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