KR100395932B1 - Skin cosmetic composition - Google Patents
Skin cosmetic composition Download PDFInfo
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- KR100395932B1 KR100395932B1 KR1019970048066A KR19970048066A KR100395932B1 KR 100395932 B1 KR100395932 B1 KR 100395932B1 KR 1019970048066 A KR1019970048066 A KR 1019970048066A KR 19970048066 A KR19970048066 A KR 19970048066A KR 100395932 B1 KR100395932 B1 KR 100395932B1
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- skin
- hydroxy acid
- alpha hydroxy
- mung bean
- acid
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
Abstract
Description
본 발명은 녹두 추출물과 알파히드록시 애씨드(α-Hydroxy Acid)를 동시에 함유하는 피부화장료 조성물에 관한 것으로, 피부노화를 방지하면서도 부작용이 없는 피부미용 화장료 조성물에 관한 것이다.The present invention relates to a skin cosmetic composition containing mung bean extract and alpha hydroxy acid (α-Hydroxy Acid) at the same time, and to a skin cosmetic composition having no side effects while preventing skin aging.
최근 들어 화장품에 사용되는 원료중 피부노화방지 물질로서 가장 각광을 받고 있는 물질이 알파히드록시 애씨드이다. 알파히드록시 애씨드는 피부각질 박리효과, 피부각화증 치유효과, 미백효과(피부색을 밝게 함), 자외선에 의한 자국·반점·얼룩제거효과, 세포활성 촉진효과, 보습효과 및 피부탄력증진효과 등 다양한 피부미용효능을 지니고 있어 전 세계의 화장품 제조회사에서 경쟁적으로 사용하고 있다.Recently, the most widely used substance for preventing skin aging among the raw materials used in cosmetics is alpha hydroxy acid. Alpha hydroxy acid has various skin such as exfoliation effect of skin, keratinization of skin, whitening effect (lightening skin color), removal of marks, spots and stains by ultraviolet rays, promotion of cell activity, moisturizing effect and skin elasticity It has a beauty effect and is used competitively by cosmetics companies around the world.
알파히드록시 애씨드의 사용은 오래 전부터 시작되었다. 고대 이집트인들은 피부를 건강하고 아름답게 유지하기 위하여 신맛이 나는 우유로 목욕을 하였다. 이는 알파히드록시 애씨드의 일종인 우유 속에 함유된 젖산(Lactic acid)이 피부 미용효과를 나타내기 때문이었다. 200여년전 프랑스의 귀족여인들은 묵은 포도주를 얼굴에 발라 깨끗하고 부드러운 피부를 유지하였는데, 묵은 포도주 속에는 주석산(Tartaric acid)이라는 알파히드록시 애씨드가 함유되어있다. 최근에는 미국 템플대학 병원의 피부과 전문의가 임상실험을 통한 알파히드록시 애씨드의 노화방지, 여드름개선, 기미, 주근깨 등 색소침착 예방 및 개선에 관한 미국특허(USP 4105783)를 획득하였고, 이후 이와 관련된 수십 편의 특허가 등록되었다. 알파히드록시 애씨드 중 가장 보편적으로 사용되고 있는 것은 사탕수수에서 얻어지는 글리콜산, 발효우유나 효소반응에 의해 얻어지는 젖산, 사과, 포도, 오렌지, 딸기등에 다량 함유되어 있는 사과산 그리고 포도에서 얻어지는 주석산과 레몬, 오렌지에 다량 함유된 구연산등이 있다.The use of alpha hydroxy acids has been around for a long time. The ancient Egyptians bathed in sour milk to keep their skin healthy and beautiful. This is because lactic acid contained in milk, a kind of alpha hydroxy acid, has a skin cosmetic effect. More than 200 years ago, French aristocrats applied old wine on their faces to keep their skin clean and smooth. The old wine contains an alpha hydroxy acid called tartaric acid. Recently, a dermatologist at Temple University Hospital in the United States acquired US patent (USP 4105783) on the prevention and improvement of pigmentation such as anti-aging, acne improvement, blemishes and freckles of alpha hydroxy acid through clinical trials. A convenience patent has been registered. The most commonly used alpha hydroxy acid is glycolic acid obtained from sugar cane, lactic acid obtained from fermented milk or enzymatic reaction, malic acid contained in large quantities in apple, grape, orange, strawberry, etc. Citric acid is contained in a large amount.
알파히드록시 애씨드는 상기와 같은 뛰어난 피부미용효과를 지니고 있으나 알파히드록시 애씨드를 함유한 화장료가 실제적으로 상기 효과를 발휘하기 위해서는 알파히드록시 애씨드를 고농도(1.0%∼10%)로 함유하거나 강산성(pH 3.5이하)을 유지하여야 한다. 그런데 고농도 혹은 강산성의 알파히드록시 애씨드를 함유한 화장료를 사용할 경우 흉반, 가려움, 따가움, 피부이상 또는 화상등의 피부자극을 유발할 수 있다. 또한, 알파히드록시 애씨드를 사용함으로써 태양광에 대한 민감성이 증가하여 결국에는 광독성과 광과민성등 피부자극이 발생할 수 있다. 그리고 알파히드록시 애씨드를 장기간에 걸쳐 사용할 경우에는 만성 피부자극이 발생할 가능성이 매우 높다. 최근에는 알파히드록시 애씨드의 피부 부작용에 대한 새로운 결과가 제시되고 있다(Cosmetic & Toiletries 112(2). 14. 1997).Alpha hydroxy acid has the excellent skin beauty effect as described above, but the cosmetics containing alpha hydroxy acid contain alpha hydroxy acid at high concentration (1.0% to 10%) or have strong acidity ( pH 3.5 or below) should be maintained. However, using cosmetics containing high concentrations or strong acidic alpha hydroxy acid can cause skin irritation such as thorax, itching, itching, skin abnormalities or burns. In addition, the use of alpha hydroxy acid may increase the sensitivity to sunlight, and eventually skin irritation such as phototoxicity and photosensitivity may occur. And long-term use of alpha hydroxy acid is very likely to cause chronic skin irritation. Recently, new results have been proposed for the skin side effects of alphahydroxy acids (Cosmetic & Toiletries 112 (2). 14. 1997).
이에 본 발명자들은 알파히드록시 애씨드외에 녹두 추출물을 동시에 함유하는 화장료를 제공함으로써, 화장료에의 배합시 변색등의 안정성 문제를 해결하고 알파히드록시 애씨드의 피부미용효과를 그대로 유지하면서 피부자극등 부작용을 방지할 수 있는 피부미용 화장료 조성물을 개발함으로써 본 발명을 완성하였다.Therefore, the present inventors provide a cosmetic containing both mung bean extract in addition to the alpha hydroxy acid, to solve the stability problems such as discoloration when blending in the cosmetics, while maintaining the skin beauty effect of the alpha hydroxy acid while maintaining side effects such as skin irritation The present invention was completed by developing a cosmetic composition for skin care that can be prevented.
즉, 본발명의 목적은 녹두 추출물과 알파히드록시 애씨드를 동시에 함유함으로써, 피부자극등 부작용이 없는 피부노화방지 효과가 개선된 피부미용 화장료 조성물을 제공하는데 있다.That is, an object of the present invention is to provide a cosmetic composition for improving skin anti-aging effect by containing both mung bean extract and alpha hydroxy acid at the same time, there is no side effect such as skin irritation.
본 발명에 따른 피부미용 화장료 조성물은 기초 화장료에 녹두 추출물을 0.01∼50.0중량%, 바람직하게는 0.1∼10.0중량%와 알파히드록시 애씨드를 건조잔분량으로 0.01∼20.0중량%, 바람직하게는 0.1∼10.0중량%의 양을 함유하는 것을 특징으로 한다.The cosmetic composition for skin care according to the present invention is 0.01 to 50.0% by weight, preferably 0.1 to 10.0% by weight, and 0.1 to 10.0% by weight, and alpha hydroxy acid as a dry residue in the base cosmetic, 0.01 to 20.0% by weight, preferably 0.1 to It is characterized by containing an amount of 10.0% by weight.
본 발명에서 사용되는 녹두 추출물은 거피한 녹두로부터통상적인 추출 방법에의하여 추출한 것이다. 녹두(Phaseolus aureus, Phaseolus radiatus; Mung Bean)는 한방에서 해독제로 사용되어 왔을 뿐만 아니라 동의보감에서는 녹두 분을 얼굴에 발랐을 때 피부미용효과를 얻을 수 있다고 알려져 왔다. 본 발명자들은 한국 특허출원 제 94-29258 호에서 녹두의 피부미용효과를 나타내는 활성성분을 분리 동정하여 비텍신(Vitexin)과 이소비텍신(Isovitexin)임을 밝혔으며, 이 성분들이 항산화 효과와 항 염증 효과를 가지고 있음을 개시하였다. 본 발명에 사용되는 녹두 추출물은 통상적인 추출방법에 의해 제조하였다.Mung bean extract used in the present invention is extracted from the peeled mung bean by a conventional extraction method . Mung Bean ( Phase Molbean ) has been used as an antidote in oriental medicine, and it is known that Dongbobom can get skin beauty effect when Mung bean is applied to face. The present inventors have identified and identified the active ingredient showing the skin-cosmetic effect of mung bean in Korean Patent Application No. 94-29258, which are Vitexin and Isovitexin, and these ingredients have antioxidant and anti-inflammatory effects. It is disclosed that it has. Mung bean extract used in the present invention was prepared by a conventional extraction method.
본 발명에 사용되는 알파히드록시 애씨드로는 모과, 사탕수수, 사탕무우, 월귤나무, 사과나무, 포도나무, 오렌지, 레몬등의 식물에서 추출되는 복합 식물산 또는 복합 과일산, 우유나 와인의 발효에 의해 얻어지는 천연산, 화학 합성방법에 의해 만들어지는 산등이 있다.The alpha hydroxy acid used in the present invention is used for fermentation of complex vegetable acids or complex fruit acids extracted from plants such as Chinese quince, sugar cane, sugar beet, bilberry, apple tree, vine, orange, lemon, milk or wine. Natural acids obtained, and acids produced by chemical synthesis methods.
본 발명에 따른 녹두 추출물과 알파히드록시 애씨드를 동시에 함유한 피부미용 화장료 조성물은 함유된 녹두 추출물에 의해 알파히드록시 애씨드의 피부자극등의 부작용이 완화되고, 알파히드록시 애씨드의 피부 보습효과, 피부 탄력증진효과, 주름개선효과등이 유지되는 한편, 녹두 추출물 자체의 피부미용 효과가 더해지므로써, 피부자극등의 부작용이 없으면서도 뛰어난 피부미용효과를 주는 우수한 제품이다.The cosmetic composition for skin care containing both mung bean extract and alpha hydroxy acid according to the present invention is alleviated side effects such as skin irritation of alpha hydroxy acid by the mung bean extract contained, the skin moisturizing effect of alpha hydroxy acid, skin The elasticity enhancing effect, wrinkle improvement effect, etc. are maintained, while the skin beauty effect of the mung bean extract itself is added, and it is an excellent product that gives excellent skin beauty effect without side effects such as skin irritation.
본 발명에 따른 화장료에는 유연 화장수, 수렴 화장수, 영양 화장수, 영양 크림, 마사지 크림, 에센스, 아이 크림, 아이 에센스, 클렌징 크림, 클렌징 폼, 클렌징 워터, 팩, 파우더, 보디 로션, 보디 크림, 보디 오일, 보디 에센스등이 있다.Cosmetics according to the present invention include a flexible lotion, astringent lotion, nutrition lotion, nutrition cream, massage cream, essence, eye cream, eye essence, cleansing cream, cleansing foam, cleansing water, pack, powder, body lotion, body cream, body oil And body essences.
이하 처방예 및 실험예를 들어 본 발명을 상세히 설명하나, 본 발명이 이에 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to prescription examples and experimental examples, but the present invention is not limited thereto.
처방예 1 : 유연화장수Prescription Example 1: Flexible Cosmetics
처방예 2 : 영양화장수Prescription Example 2: Nutritional Cosmetics
처방예 3 : 영양 크림Prescription Example 3: Nutrition Cream
처방예 4 : 에센스Prescription Example 4: Essence
처방예 5 : 맛사지 크림Prescription 5: massage cream
처방예 6 : 팩Prescription Example 6: Pack
처방예 7 및 8: 영양크림Prescription 7 and 8: Nutritional Cream
실시예 1, 2, 3 및 비교예 1, 2, 3Examples 1, 2, 3 and Comparative Examples 1, 2, 3
본 발명에 따라 녹두추출물과 알파히드록시 애씨드를 포함한 복합물을 각각 실시예 1, 2, 3으로 하고 알파히드록시 애씨드만을 사용한 것을 비교예 1, 2, 3으로 하였다. 알파히드록시 애씨드는 L-젖산, 글리콜산, 레몬, 사탕무우 및 사탕수수 추출물인 복합 과일산을 사용하였다. 실시예 1, 2, 3 및 비교예 1, 2, 3 의 조성은 표 1 에 나타내었다.According to the present invention, composites containing mung bean extract and alpha hydroxy acid were used as Examples 1, 2 and 3, respectively, and those using only alpha hydroxy acid were used as Comparative Examples 1, 2 and 3. Alphahydroxy acid used complex fruit acid, L-lactic acid, glycolic acid, lemon, beet and sugarcane extract. The compositions of Examples 1, 2 and 3 and Comparative Examples 1, 2 and 3 are shown in Table 1.
비교예 4 및 5Comparative Examples 4 and 5
처방예 7 및 8과 같은 조성이나 녹두 추출물을 첨가하지 않은 것을 각각 비교예 4 및 5로 하였다.The same compositions as in Formulations 7 and 8 and no green bean extracts were added to Comparative Examples 4 and 5, respectively.
실험예 1 : 세포독성실험Experimental Example 1: Cytotoxicity Test
사람피부세포(Fibroblast. ATCC A431)를 포도당 4.5g/l, 10% 혈청, 1% 항생제가 함유된 DMEM 배지에 접종하여 5% CO2조건하에서 37℃에서 24시간 배양하였다. 이 때 접종한 세포의 수는 1× 104이었다. 배양 후, 각 배양 웰에 실험시료를 처리하였다. 실험시료는 실시예 1, 2, 3 및 비교예 1, 2, 3의 것을 사용하였다. 실험시료를 각각 처리한 후 이를 다시 24시간 배양하였다. 살린-포스페이트 완충용액(PBS)에 MTT를 5mg/mL의 농도로 용해시킨 용액을 10μL 씩 첨가한 후, 37℃에서 4시간 반응시켰다. 웰의 내용물을 완전히 버린 후 MTT 용해용액인 10% 트리톤 엑스-100(Triton X-100)을 함유한 산 처리 이소프로판올(0.1N HCl)을 웰당 100μL 씩 첨가하여 20분간 교반한 후 ELISA 측정기로 570nm에서 흡광도를 측정하였다. 그 결과는 표 2 에 나타내었다.Human skin cells (Fibroblast. ATCC A431) were inoculated in DMEM medium containing 4.5 g / l glucose, 10% serum, and 1% antibiotic and incubated for 24 hours at 37 ° C. under 5% CO 2 conditions. The number of cells inoculated at this time was 1 × 10 4 . After incubation, the experimental sample was treated in each culture well. Experimental samples were used in Examples 1, 2, 3 and Comparative Examples 1, 2, 3. Each of the experimental samples was treated and then incubated again for 24 hours. 10 μL of a solution in which MTT was dissolved at a concentration of 5 mg / mL was added to the saline-phosphate buffer (PBS), followed by reaction at 37 ° C. for 4 hours. After completely discarding the contents of the well, acid-treated isopropanol (0.1 N HCl) containing 10% Triton X-100, MTT solution, was added at 100 μL per well and stirred for 20 minutes, followed by ELISA measurement at 570 nm. Absorbance was measured. The results are shown in Table 2.
실험결과는 표 2 에 나타낸 바와 같이, 알파히드록시 애씨드만 처리한 경우에는 강한 세포독성을 나타내었으나, 녹두 추출물을 동시에 첨가한 경우에는 알파히드록시 애씨드의 세포독성이 현저하게 줄었음을 알 수 있다.As shown in Table 2, the results showed strong cytotoxicity when only alphahydroxy acid was treated, but the cytotoxicity of alphahydroxy acid was significantly reduced when mungbean extract was added simultaneously. .
실험예 2 : 피부자극실험Experimental Example 2: Skin Stimulation Experiment
폐쇄 첩포 시험 방법으로 건강한 남녀 20명의 실험 대상자 양팔 하박부에 처방예 7 ,8 및 비교예 4, 5 의 실험제품을 각각 24시간 부착한 후 제거하여 피부자극을 체크하였다. 실험결과는 표 3 에 나타내었다.As a closed patch test method, 20 healthy males and females were attached to the lower arms of the underarms for 24 hours, and the test products of Formulation Examples 7 and 8 and Comparative Examples 4 and 5 were removed for 24 hours, and skin irritation was checked. The experimental results are shown in Table 3.
피부자극 판정기준Skin irritation criteria
표 4 에 나타낸 바와 같이, 본 발명품인 녹두 추출물과 알파히드록시 애씨드를 동시에 함유한 제품이 알파히드록시 애씨드 단독 함유제품보다 피부자극이 현저하게 적음을 알 수 있다.As shown in Table 4, it can be seen that the product containing both mung bean extract and alpha hydroxy acid of the present invention is significantly less skin irritation than the product containing alpha hydroxy acid alone.
실험예 3 : 피부탄력효과Experimental Example 3 Skin Elasticity Effect
온도 24∼26℃, 습도 40%로 일정하게 유지되는 항온 항습실에서 건강한 남성 40명을 무작위로 20명씩 2개 그룹으로 나눈 후 각 그룹을 대상으로 실험예 2와 동일한 실험 제품을 두가지 씩 피검자의 왼쪽과 오른쪽 얼굴에 나누어 발라 3 개월 사용후 피부탄력 측정기인 큐토메타 SEM 575(Cutometer SEM 575)를 이용하여 피부 탄력도를 측정하여 평균값을 비교하였다. 그 결과를 표 4 에 나타내었다.In a constant temperature and humidity room maintained at a constant temperature of 24 to 26 ° C and a humidity of 40%, 40 healthy men were randomly divided into two groups of 20 people. After applying for 3 months, the skin elasticity was measured using cutometer SEM 575 (Cutometer SEM 575). The results are shown in Table 4.
표 4에 나타낸 바와 같이, 본 발명품이 알파히드록시 애씨드 단독 함유제품보다 피부탄력 효과가 우수함을 알 수 있다.As shown in Table 4, it can be seen that the present invention has an excellent skin elasticity effect than the product containing alpha hydroxy acid alone.
실험예 4: 피부 보습효과Experimental Example 4: Skin Moisturizing Effect
24∼26℃, 40% 습도로 일정하게 유지되는 항응 항습실에서 건강한 남성 40명을 무작위로 20명씩 2개 그룹으로 나눈 후, 각 그룹을 대상으로 실험예 2와 동일한 실험제품을 두가지 씩 피검자의 왼쪽과 오른쪽 얼굴에 나누어 발라 4시간 사용 후 피부수분 측정기인 코르오메타 CM 820(Corneometer CM 820)을 이용하여 측정하였다. 실험결과는 표 5 에 나타내었다.In an anti-humidity room kept constant at 24 to 26 ° C and 40% humidity, 40 healthy males were randomly divided into two groups of 20 people, and two groups of the same experimental product as in Experiment 2 were used for each group. After 4 hours of application, the skin was measured using a coromeometer CM 820 (Corneometer CM 820). The experimental results are shown in Table 5.
표 5에서 나타낸 바와 같이, 본 발명품이 알파히드록시 애씨드 단독 함유제품보다 피부 보습효과가 우수함을 알 수 있다.As shown in Table 5, it can be seen that the present invention has an excellent skin moisturizing effect than the product containing alpha hydroxy acid alone.
실험예 5 : 피부주름 개선효과Experimental Example 5: Skin wrinkle improvement effect
건강한 남성 40명을 무작위로 20명씩 2개 그룹으로 나눈 후, 각 그룹을 대상으로 실험예 2와 동일한 실험제품을 두가지씩 피검자의 왼쪽과 오른쪽 얼굴에 나누어 발라 3개월 사용 후 피부 리플리카(replica)를 만들어 스킨 비지오메타 SV 400(Skin visiometer SV400)을 이용하여 피부주름을 분석하여 주름 개선효과를 Ra(주름평균길이), Rz(주름골간의 평균거리)값으로 비교하였다. 실험결과는 표 6 에 나타내었다.After 40 healthy males were randomly divided into 2 groups of 20 people, two groups of the same test product as in Experiment 2 were applied to the left and right faces of the subjects. Skin wrinkles were analyzed using Skin Visiometer SV400 and wrinkle improvement effect was compared with Ra (mean wrinkle length) and Rz (mean distance between wrinkles). The experimental results are shown in Table 6.
표 6에 나타낸 바와 같이, 본 발명품이 알파히드록시 애씨드 단독함유 제품보다 피부 주름 개선효과가 우수함을 알 수 있다.As shown in Table 6, it can be seen that the present invention has a skin wrinkle improvement effect is superior to the product containing alpha hydroxy acid alone.
상기 실험결과에서 보여진 바와 같이 본 발명에 따라 알파히드록시 애씨드외에 녹두 추출물을 동시에 함유한 화장료는 알파히드록시 애씨드를 단독으로 사용할때의 피부자극등의 부작용을 억제할 뿐만 아니라, 녹두 추출물의 피부미용 효과가 더해져서 알파히드록시 애씨드를 단독으로 사용할때보다, 피부주름 개선, 피부 탄력 증진등의 효과가 우수함을 알 수 있다. 그러므로 본 발명은 피부노화를 방지하면서도 부작용이 없는 우수한 피부미용 화장료 조성물을 제공한다.As shown in the above experimental results, cosmetics containing mung bean extract in addition to alpha hydroxy acid according to the present invention not only suppress side effects such as skin irritation when using alpha hydroxy acid alone, and skin beauty of mung bean extract In addition to the effect, it can be seen that the effect of improving skin wrinkles, enhancing skin elasticity, etc., is superior to using alpha hydroxy acid alone. Therefore, the present invention provides an excellent skin care cosmetic composition that prevents skin aging but does not have side effects.
Claims (3)
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| KR1019970048066A KR100395932B1 (en) | 1997-09-22 | 1997-09-22 | Skin cosmetic composition |
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| KR1019970048066A KR100395932B1 (en) | 1997-09-22 | 1997-09-22 | Skin cosmetic composition |
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| KR20030042527A (en) * | 2001-11-23 | 2003-06-02 | 주식회사 코리아나화장품 | Cosmetic Compositions Comprising Extract from Mung-bean for Abirritating Skin |
| WO2004080432A1 (en) * | 2003-03-10 | 2004-09-23 | Songwoo Kim | Composition for lip cosmetics |
| KR20060093164A (en) * | 2005-02-21 | 2006-08-24 | 주식회사 엘지생활건강 | Anti-wrinkle cosmetic composition |
| KR100858630B1 (en) * | 2007-04-27 | 2008-09-17 | 주식회사 코리아나화장품 | Cosmetic composition for screening uv rays and preventing photo-aging comprising mung bean extract as active ingredients |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940018077A (en) * | 1993-01-19 | 1994-08-16 | 한동근 | Cosmetics |
| KR960000191A (en) * | 1994-06-01 | 1996-01-25 | 한동근 | Cosmetic Compositions Containing Alpha-hydroxy Acids |
| JPH0977628A (en) * | 1995-09-14 | 1997-03-25 | Sunstar Inc | Skin cosmetic material composition |
| KR0161333B1 (en) * | 1995-10-27 | 1998-12-01 | 유상옥 | Cosmetic composition comprising extracts of mung bean(phaseolus aureus) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940018077A (en) * | 1993-01-19 | 1994-08-16 | 한동근 | Cosmetics |
| KR960000191A (en) * | 1994-06-01 | 1996-01-25 | 한동근 | Cosmetic Compositions Containing Alpha-hydroxy Acids |
| JPH0977628A (en) * | 1995-09-14 | 1997-03-25 | Sunstar Inc | Skin cosmetic material composition |
| KR0161333B1 (en) * | 1995-10-27 | 1998-12-01 | 유상옥 | Cosmetic composition comprising extracts of mung bean(phaseolus aureus) |
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