KR100246141B1 - Composition of wax for vehicle with anticorrosion and cold resistance - Google Patents
Composition of wax for vehicle with anticorrosion and cold resistance Download PDFInfo
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- KR100246141B1 KR100246141B1 KR1019970071810A KR19970071810A KR100246141B1 KR 100246141 B1 KR100246141 B1 KR 100246141B1 KR 1019970071810 A KR1019970071810 A KR 1019970071810A KR 19970071810 A KR19970071810 A KR 19970071810A KR 100246141 B1 KR100246141 B1 KR 100246141B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D157/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
본 발명은 방청 및 내한성을 갖는 왁스 조성물에 관한 것으로서, 더욱 상세하게는 광유(petrolactum)에 희석제, 내한성 첨가제, 방청제 및 충진제 등을 포함하는 방청 및 내한성을 갖는 왁스 조성물에 관한 것이다. 본 발명의 조성물은 내한성 및 내치핑성(chipping resistance)이 우수하여 자동차 바닥용 왁스 등으로 유용하게 사용될 수 있다.The present invention relates to a wax composition having antirust and cold resistance, and more particularly, to a wax composition having antirust and cold resistance including a diluent, a cold resistant additive, a rust preventive agent and a filler in petrolactum. The composition of the present invention is excellent in cold resistance and chipping resistance (chipping resistance) can be usefully used as wax for automobile floors.
Description
본 발명은 방청 및 내한성을 갖는 왁스 조성물에 관한 것으로서, 상세하게는 광유(petrolactum)에 희석제, 내한성 첨가제, 방청제 및 충진제 등을 포함하는 방청 및 내한성을 갖는 왁스 조성물에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wax composition having antirust and cold resistance, and more particularly, to a wax composition having antirust and cold resistance including a diluent, a cold resistant additive, a rust inhibitor, a filler, and the like in petrolactum.
종래의 방청왁스는 아스팔트(asphalt)에 무기 충진제와 나프타 용매 등을 첨가하여 제조하였다. 이러한 방청왁스를 자동차 바닥에 도포하면, 희석제가 증발하여 도막이 건조되어 딱딱한 상태가 된다. 차량 주행시 타이어로 인하여 비산되는 돌 등이 경화된 도막에 부딪히면 도막이 파괴되고, 그 틈새 사이로 부식 생성물들이 침투되어 차체의 바닥면을 부식시키는 원인이 되고 있다. 또한, 겨울철에는 이러한 왁스 도막의 부착력이 약화되어 도막이 탈리되는 문제점이 발생되었다.Conventional rust preventive wax was prepared by adding an inorganic filler and a naphtha solvent to asphalt (asphalt). When such antirust wax is applied to the floor of an automobile, the diluent evaporates and the coating film dries into a hard state. When a vehicle, such as a tire scattered by the tire, hits the hardened coating film, the coating film is broken, and corrosion products penetrate between the gaps, causing the floor surface of the vehicle to corrode. In addition, in winter, the adhesive force of the wax coating is weakened, which causes a problem that the coating is detached.
이에 본 발명자들은 상기한 문제점들을 해결하기 위해 연구를 계속하여 오던중, 저온에서도 불건성인 광유를 주성분으로 하고 여기에 내한성 첨가제, 방청제 및 충진제 등을 포함하는 왁스 조성물을 개발하여 본 발명을 완성하였다.In order to solve the above problems, the inventors of the present invention have completed the present invention by developing a wax composition comprising a mineral oil that is undry at low temperatures as a main component and a cold-resistant additive, a rust inhibitor and a filler.
본 발명의 목적은 방청 및 내한성을 갖는 왁스 조성물을 제공하는 것이다.It is an object of the present invention to provide a wax composition having antirust and cold resistance.
상기와 같은 목적을 달성하기 위하여, 본 발명에서는 주성분인 광유에 피막성능 향상제, 희석제, 내한성 첨가제, 방청제, 아스팔트 및 무기 충진제를 포함하는 왁스 조성물을 제공한다.In order to achieve the above object, the present invention provides a wax composition comprising a film performance improving agent, a diluent, a cold-resistant additive, a rust preventive agent, asphalt, and an inorganic filler in the main oil.
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 발명의 왁스 조성물은 주성분인 광유 25∼35 중량%와 피막성능 향상제로 광유 레진(petroleum resin) 3∼8 중량%, 희석제로 나프타 용매(naphtha solvent) 30∼45 중량%, 내한성 첨가제로 합성 실리콘 오일(synthetic silicon oil) 2∼5 중량%, 방청제로 바륨 디노닐나프탈렌 술포네이트(barium dinonylnaphthalene sulfonate; 이하, "BSN"이라 약칭한다) 0.5∼2.0 중량%, 아스팔트 5∼10 중량% 및 무기 충진제 5∼15 중량%로 구성된다.The wax composition of the present invention comprises 25 to 35% by weight of mineral oil as the main component, 3 to 8% by weight of petroleum resin as a film performance improving agent, 30 to 45% by weight of naphtha solvent as a diluent, and synthetic silicone as a cold-resistant additive. 2 to 5% by weight of synthetic silicon oil, 0.5 to 2.0% by weight of barium dinonylnaphthalene sulfonate (hereinafter abbreviated as "BSN") as antirust agent, 5 to 10% by weight of asphalt and inorganic filler 5 It consists of-15 weight%.
본 발명의 조성물에서 주성분으로 저온특성이 우수한 광유를 사용하는데, 분자량이 500∼1500인 광유를 25∼35 중량% 사용하는 것이 바람직하다.In the composition of the present invention, a mineral oil having excellent low-temperature characteristics is used as a main component, and it is preferable to use a mineral oil having a molecular weight of 500 to 1500 to 25 to 35% by weight.
주성분인 광유의 피막성능을 향상시키기 위하여 본 발명의 조성물에는 광유레진을 사용하는데, 연화점이 100℃ 이하인 광유 레진을 3∼8 중량% 사용하는 것이 바람직하다.In order to improve the film | membrane performance of the mineral oil which is a main component, mineral oil resin is used for the composition of this invention, It is preferable to use 3-8 weight% of mineral oil resin whose softening point is 100 degrees C or less.
본 발명의 왁스 조성물을 도포할 때 작업성을 용이하게 하기 위하여 희석제(diluent)로서 나프타 용매를 30∼45 중량% 사용하는 것이 바람직하다.In order to facilitate workability when applying the wax composition of the present invention, it is preferable to use 30 to 45% by weight of a naphtha solvent as a diluent.
본 발명의 왁스 조성물이 저온에서 경화되었을 때 외부의 충격에 쉽게 부서지는 것을 방지하기 위하여 내한성 첨가제로 합성 실리콘 오일를 사용하는데, 유동점이 -50℃ 이하인 합성 실리콘 오일을 2∼5 중량% 사용하는 것이 바람직하다.In order to prevent the wax composition of the present invention from being easily broken by external impact when cured at low temperature, a synthetic silicone oil is used as a cold-resistant additive, and it is preferable to use 2 to 5% by weight of a synthetic silicone oil having a pour point of -50 ° C or lower. Do.
본 발명의 조성물에 방청성을 향상시키기 위하여 방청제를 첨가하는데, 녹 방지성능을 장기간 유지시킬 수 있는 BSN을 0.5∼2.0 중량% 사용하는 것이 바람직하다.In order to add a rust preventive agent to the composition of the present invention, it is preferable to use 0.5 to 2.0% by weight of a BSN capable of maintaining rust prevention performance for a long time.
본 발명의 조성물을 도포하였을 때 습기나 먼지 등으로 인해 왁스의 본래 색상이 오염되는 것을 방지하고, 도포성능을 향상시키기 위하여 5∼10 중량%의 아스팔트를 첨가하는 것이 바람직하다.When the composition of the present invention is applied, it is preferable to add 5 to 10% by weight of asphalt in order to prevent contamination of the original color of the wax due to moisture or dust, and to improve coating performance.
또한, 상기의 성분에 대하여 점도를 조절하는 증주제로서 무기 충진제를 첨가하는데, 활석 분말 또는 벤톤 분말 등의 충진제를 5∼15 중량% 첨가하는 것이 바람직하다. 이때 충진제의 양이 5 중량% 미만으로 사용하면 제조된 왁스 조성물이 너무 묽어 왁스를 도포시 쉽게 흐르는 문제가 발생된다. 또한 충진제의 양이 15 중량% 이상이면 왁스 조성물의 점도가 너무 커서 도포시 피착면과의 접착성이 약화되어 저온에서 왁스 도막이 쉽게 부서져 탈리되는 현상이 발생된다.Moreover, although an inorganic filler is added as a thickener which adjusts a viscosity with respect to said component, it is preferable to add 5-15 weight% of fillers, such as talc powder or benton powder. At this time, if the amount of the filler is used in less than 5% by weight, the wax composition is too thin, causing a problem of easily flowing when the wax is applied. In addition, if the amount of the filler is 15% by weight or more, the viscosity of the wax composition is so large that the adhesion to the adhered surface is weakened during application, the wax coating film is easily broken and detachment occurs at low temperatures.
이하, 실시예를 통하여 본 발명의 왁스 조성물을 상세히 설명하기로 한다. 단, 하기 실시예는 본 발명을 예시하는 것으로 본 발명의 내용이 실시예에 의해 한정되는 것은 아니다.Hereinafter, the wax composition of the present invention will be described in detail through examples. However, the following examples are illustrative of the present invention, and the contents of the present invention are not limited by the examples.
〈실시예 1 내지 3〉<Examples 1 to 3>
하기 표 1에 기재된 조성비로 따라, 광유에 각종 첨가제를 첨가하여 왁스 조성물을 제조하였다.According to the composition ratios shown in Table 1 below, various additives were added to the mineral oil to prepare a wax composition.
〈비교실시예 1 및 2〉<Comparative Examples 1 and 2>
또한, 상기 실시예의 조성물과 비교하기 위하여 하기 표 2의 조성으로 구성된 왁스 조성물을 실시예와 동일한 방법으로 제조하였다.In addition, a wax composition composed of the composition of Table 2 was prepared in the same manner as in Example to compare with the composition of the above Example.
〈실험예〉 왁스 조성물의 각종 물성 측정Experimental Example Measurement of various physical properties of the wax composition
상기에서 제조된 왁스 조성물을 KS M 2109의 방청유 일반 시험 방법에 따라 유화점을 측정하였으며, 상기의 왁스 조성물을 도포한 시편을 -30℃에서 8시간 방치하여 그때의 저온 부착성을 측정하였고, 염수 분무 및 습윤시의 방청성을 측정하여 하기 표 3에 그 결과를 나타내었다.The emulsification point of the wax composition prepared above was measured according to the general test method of rust-preventive oil of KS M 2109, and the specimen coated with the wax composition was left at -30 ° C. for 8 hours to measure the low temperature adhesion at that time. The rust resistance during spraying and wetting was measured and the results are shown in Table 3 below.
상기에서 살펴본 바와 같이, 본 발명의 왁스 조성물은 저온특성이 우수한 광유를 사용하고, 유동점이 -50℃ 이하인 합성 실리콘 오일을 사용하기 때문에 내한성이 향상되었으며, BSN을 사용하기 때문에 방청성이 향상되어 자동차 바닥용 왁스로 유용하게 사용될 수 있는 우수한 왁스 조성물이다.As described above, the wax composition of the present invention uses mineral oil having excellent low temperature characteristics and synthetic silicone oil having a pour point of -50 ° C. or lower, thereby improving cold resistance, and using BSN to improve corrosion resistance. It is an excellent wax composition that can be usefully used as a wax.
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Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019970071810A KR100246141B1 (en) | 1997-12-22 | 1997-12-22 | Composition of wax for vehicle with anticorrosion and cold resistance |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019970071810A KR100246141B1 (en) | 1997-12-22 | 1997-12-22 | Composition of wax for vehicle with anticorrosion and cold resistance |
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| Publication Number | Publication Date |
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| KR19990052347A KR19990052347A (en) | 1999-07-05 |
| KR100246141B1 true KR100246141B1 (en) | 2000-04-01 |
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| KR1019970071810A KR100246141B1 (en) | 1997-12-22 | 1997-12-22 | Composition of wax for vehicle with anticorrosion and cold resistance |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100820408B1 (en) | 2006-08-09 | 2008-04-10 | 현대자동차주식회사 | The composition for anticorrosion Wax |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101150679B1 (en) * | 2010-03-19 | 2012-05-25 | 현대하이스코 주식회사 | Rust preventive oil with excellent anti oil stain property at high temperature |
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1997
- 1997-12-22 KR KR1019970071810A patent/KR100246141B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100820408B1 (en) | 2006-08-09 | 2008-04-10 | 현대자동차주식회사 | The composition for anticorrosion Wax |
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| KR19990052347A (en) | 1999-07-05 |
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