JPWO2020202131A5 - - Google Patents
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- Publication number
- JPWO2020202131A5 JPWO2020202131A5 JP2021556704A JP2021556704A JPWO2020202131A5 JP WO2020202131 A5 JPWO2020202131 A5 JP WO2020202131A5 JP 2021556704 A JP2021556704 A JP 2021556704A JP 2021556704 A JP2021556704 A JP 2021556704A JP WO2020202131 A5 JPWO2020202131 A5 JP WO2020202131A5
- Authority
- JP
- Japan
- Prior art keywords
- organic cation
- donor
- solvent medium
- organic
- molar ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 150000002892 organic cations Chemical class 0.000 claims 11
- 238000000034 method Methods 0.000 claims 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 9
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 6
- 239000002904 solvent Substances 0.000 claims 6
- 235000019253 formic acid Nutrition 0.000 claims 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- 150000003839 salts Chemical class 0.000 claims 4
- 125000001424 substituent group Chemical group 0.000 claims 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- -1 alkylammonium cations Chemical class 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 3
- 239000011541 reaction mixture Substances 0.000 claims 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims 2
- QHJPGANWSLEMTI-UHFFFAOYSA-N aminomethylideneazanium;iodide Chemical compound I.NC=N QHJPGANWSLEMTI-UHFFFAOYSA-N 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
- 238000011065 in-situ storage Methods 0.000 claims 2
- LLWRXQXPJMPHLR-UHFFFAOYSA-N methylazanium;iodide Chemical compound [I-].[NH3+]C LLWRXQXPJMPHLR-UHFFFAOYSA-N 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- HBZSVMFYMAOGRS-UHFFFAOYSA-N octylazanium;iodide Chemical compound [I-].CCCCCCCC[NH3+] HBZSVMFYMAOGRS-UHFFFAOYSA-N 0.000 claims 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- XPOLVIIHTDKJRY-UHFFFAOYSA-N acetic acid;methanimidamide Chemical compound NC=N.CC(O)=O XPOLVIIHTDKJRY-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 claims 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims 1
- 230000026045 iodination Effects 0.000 claims 1
- 238000006192 iodination reaction Methods 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 230000002194 synthesizing effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL429454A PL429454A1 (pl) | 2019-04-02 | 2019-04-02 | Sposób otrzymywania jodków organicznych, kompozycja perowskitotwórcza z jodkiem organicznym otrzymanym tym sposobem oraz ogniwo fotowoltaiczne z warstwą perowskitową wytworzoną z tej kompozycji |
| PLP.429454 | 2019-04-02 | ||
| PCT/IB2020/055167 WO2020202131A1 (en) | 2019-04-02 | 2020-06-01 | A method for synthesis of organic iodides, a perovskite-forming composition comprising an organic iodide and a photovoltaic cell with a perovskite layer obtained therefrom |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| JP2022528315A JP2022528315A (ja) | 2022-06-10 |
| JPWO2020202131A5 true JPWO2020202131A5 (https=) | 2023-02-20 |
| JP2022528315A5 JP2022528315A5 (https=) | 2023-02-20 |
| JP7634148B2 JP7634148B2 (ja) | 2025-02-21 |
Family
ID=71401812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021556704A Active JP7634148B2 (ja) | 2019-04-02 | 2020-06-01 | 有機ヨウ化物の合成のための方法、有機ヨウ化物を含むペロブスカイト形成組成物、およびそれから得られるペロブスカイト層を有する光電池 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US12202783B2 (https=) |
| EP (1) | EP3719001B1 (https=) |
| JP (1) | JP7634148B2 (https=) |
| KR (1) | KR102815316B1 (https=) |
| CN (1) | CN114096511B (https=) |
| ES (1) | ES2966640T3 (https=) |
| PL (2) | PL429454A1 (https=) |
| WO (1) | WO2020202131A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4249468B1 (en) | 2022-03-21 | 2025-05-07 | Solaveni GmbH | A method for synthesis of halide salts |
| CN115872902A (zh) * | 2022-12-09 | 2023-03-31 | 湖南铱太科技有限公司 | 一种甲脒氢碘酸盐的绿色提纯方法 |
| CN118684584A (zh) * | 2023-03-22 | 2024-09-24 | 宁德时代新能源科技股份有限公司 | 有机化合物、钙钛矿前驱体溶液、钙钛矿薄膜、钙钛矿电池和用电装置 |
| CN116986992B (zh) * | 2023-08-01 | 2025-07-04 | 西湖大学 | 二维锡基钙钛矿的可控制备方法及其在光泵浦中的应用 |
| KR20250116468A (ko) * | 2024-01-25 | 2025-08-01 | 한화솔루션 주식회사 | 페로브스카이트 용액 및 이를 이용하는 페로브스카이트 박막 형성 방법 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006151700A (ja) * | 2004-11-25 | 2006-06-15 | Toshiba Corp | 水素生成物質の製造方法及びその装置 |
| WO2012173676A1 (en) | 2011-06-17 | 2012-12-20 | Precursor Energetics, Inc. | Solution-based processes for solar cells |
| CN103906786B (zh) * | 2011-10-04 | 2017-06-09 | 巴斯夫欧洲公司 | 基于苯并二酮的聚合物 |
| MX2014008171A (es) * | 2012-01-03 | 2014-10-06 | Saudi Basic Ind Corp | Metodo para preparar di-organo-dialcoxisilanos. |
| PL230302B1 (pl) * | 2012-02-27 | 2018-10-31 | Apeiron Synthesis Spolka Z Ograniczona Odpowiedzialnoscia | Katalizatory metatezy zawierające grupy oniowe |
| GB201208793D0 (en) * | 2012-05-18 | 2012-07-04 | Isis Innovation | Optoelectronic device |
| ES2707296T3 (es) * | 2012-09-18 | 2019-04-03 | Univ Oxford Innovation Ltd | Dispositivo optoelectrónico |
| KR20150082473A (ko) * | 2012-11-07 | 2015-07-15 | 바스프 에스이 | 나프토디온 기재 중합체 |
| EP3227394B1 (en) * | 2014-12-03 | 2019-07-03 | Saule Sp. z o.o. | A film-forming compostion and a method for manufacturnig a photoactive film |
| JP6330064B1 (ja) * | 2017-01-10 | 2018-05-23 | 伊勢化学工業株式会社 | ヨウ化水素酸の製造方法及びヨウ化金属水溶液の製造方法 |
| CN107337607B (zh) * | 2017-07-14 | 2019-02-05 | 北京理工大学 | 一种甲基碘化铵的制备方法 |
-
2019
- 2019-04-02 PL PL429454A patent/PL429454A1/pl unknown
-
2020
- 2020-05-29 PL PL20177469.2T patent/PL3719001T3/pl unknown
- 2020-05-29 EP EP20177469.2A patent/EP3719001B1/en active Active
- 2020-05-29 ES ES20177469T patent/ES2966640T3/es active Active
- 2020-06-01 CN CN202080026905.XA patent/CN114096511B/zh active Active
- 2020-06-01 WO PCT/IB2020/055167 patent/WO2020202131A1/en not_active Ceased
- 2020-06-01 KR KR1020217035679A patent/KR102815316B1/ko active Active
- 2020-06-01 JP JP2021556704A patent/JP7634148B2/ja active Active
- 2020-06-01 US US17/601,065 patent/US12202783B2/en active Active
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