JPWO2020070836A1 - 樹脂組成物、ラップフィルム及びラップフィルム収容体 - Google Patents
樹脂組成物、ラップフィルム及びラップフィルム収容体 Download PDFInfo
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
Abstract
Description
移動相:テトラヒドロフラン
検出器:示差屈折計
流速:1.0mL/分
カラム温度:20℃
注入量:500μL
ポリオレフィン系樹脂としては、ポリエチレン系樹脂等が挙げられ、ポリエチレン系樹脂は、低密度ポリエチレン、線状低密度ポリエチレン、線状超低密度ポリエチレン、中密度ポリエチレン、高密度ポリエチレン、エチレン等をモノマー単位とする共重合体であってよい。具体的には、ポリエチレン系樹脂は、エチレンと、プロピレン、1−ブテン、1−ペンテン、1−ヘキセン、4−メチル−1−ペンテン、1−ヘプテン、1−オクテン等の炭素数3〜10のα−オレフィン、酢酸ビニル、プロピオン酸ビニル等のビニルエステル、アクリル酸メチル、アクリル酸エチル、メタクリル酸メチル、メタクリル酸エチル等の不飽和カルボン酸エステル;共役ジエン、非共役ジエン等の不飽和化合物;などから選ばれる1種又は2種以上との共重合体であってよい。ポリエチレン系樹脂におけるエチレン単位の含有量は、モノマー単位全量基準で50質量%以上であってよい。
まず、グリセロール−3−リン酸を不飽和脂肪酸でアシル化し、得られた生成物を脱リン酸することによりジアシルグリセロールを合成する。その後、ジアセチルグリセロールをエポキシ化し、得られた生成物をジカルボン酸と反応させて脱水する。
添加剤A:下記式(5)で表される化合物(Di(2-acetate,3-epoxyoleate)glyceryl adipate)
添加剤B1:アセチル化モノグリセライド(理研ビタミン株式会社製、「PL−012」)
添加剤B2:アジピン酸ジオクチル(新日本理化株式会社製、「サンソサイザーDOA」)
添加剤B3:エポキシ化大豆油(三和合成化学株式会社製、「ケミサイザーSE−100」)
添加剤B4:グリセリン脂肪酸エステル(理研ビタミン株式会社製、「XO−100」)
添加剤B5:Ca/Zn系安定剤(株式会社ADEKA製、「SC−308E」)
得られた各樹脂組成物60gをラボプラストミル(株式会社東洋精機製作所製、「4C150−01」)に取り付けたローラミキサR60型に投入し、210℃、60rpmで混練することで、樹脂組成物の動的熱安定性を評価した。動的熱安定性時間は、定常トルクの数値から150%のトルク値に達するまでの時間とした。動的熱安定性時間が長いほど、熱安定性に優れているといえる。結果を表1,2に示す。
Tダイ押出機にて、各樹脂組成物を樹脂温度200℃で押出してラップフィルムの成形を行い、得られたラップフィルムの外観を観察することで製膜性を評価した。評価基準は、以下のとおりである。なお、評価がA又はBであれば、製膜性に優れているといえる。結果を表1,2に示す。
A:ほぼ均一の厚みのラップフィルムが得られ、24時間の押出でヤケが発生しなかった。
B:ラップフィルムの厚みにわずかにむらが見られ、24時間の押出でヤケが発生した。
C:ラップフィルムの厚みむらが激しく、8時間の押出でヤケが発生した。
一定面積の試料をラップフィルムから切り取り、その表面積1cm2当たり2mLのヘプタン溶液に25℃の温度で1時間浸漬し、溶液を蒸発乾固させ、その重量を測定することでフィルムからヘプタン溶液への移行量を求めた。当該移行量が少ないほど、添加剤の溶出量を抑制できるといえる。結果を表1,2に示す。
Claims (28)
- 前記化合物の分子量が500以上である、請求項1に記載の樹脂組成物。
- 前記化合物の分子量が5000以下である、請求項1〜3のいずれか一項に記載の樹脂組成物。
- 前記式(3)におけるm1及びm2が1である、請求項5に記載の樹脂組成物。
- 前記式(3)におけるn1及びn2が0である、請求項5又は6に記載の樹脂組成物。
- 前記式(3)におけるR2及びR5が炭素数5〜9のアルキレン基である、請求項5〜7のいずれか一項に記載の樹脂組成物。
- 前記式(3)におけるR2及びR5がヘプチレン基である、請求項5〜8のいずれか一項に記載の樹脂組成物。
- 前記式(3)におけるR6及びR9が炭素数6〜10のアルキル基である、請求項5〜9のいずれか一項に記載の樹脂組成物。
- 前記式(3)におけるR6及びR9がオクチル基である、請求項5〜10のいずれか一項に記載の樹脂組成物。
- 前記式(3)におけるR7及びR8が炭素数1〜4のアルキル基である、請求項5〜11のいずれか一項に記載の樹脂組成物。
- 前記式(3)におけるR7及びR8がメチル基である、請求項5〜12のいずれか一項に記載の樹脂組成物。
- 前記式(3)におけるR1が炭素数2〜6のアルキレン基である、請求項5〜13のいずれか一項に記載の樹脂組成物。
- 前記式(3)におけるR1がブチレン基である、請求項5〜14のいずれか一項に記載の樹脂組成物。
- アセチル化モノグリセライドを更に含有する、請求項1〜16のいずれか一項に記載の樹脂組成物。
- 多価カルボン酸エステルを更に含有する、請求項1〜17のいずれか一項に記載の樹脂組成物。
- 前記多価カルボン酸エステルがヒドロキシ多価カルボン酸エステルを含む、請求項18に記載の樹脂組成物。
- 前記ヒドロキシ多価カルボン酸エステルがアセチル化クエン酸トリアルキルエステルを含む、請求項19に記載の樹脂組成物。
- 前記多価カルボン酸エステルがシクロヘキサンジカルボン酸ジアルキルエステルを含む、請求項18〜20のいずれか一項に記載の樹脂組成物。
- エポキシ化植物油を更に含有する、請求項1〜21のいずれか一項に記載の樹脂組成物。
- 前記エポキシ化植物油がエポキシ化大豆油を含む、請求項22に記載の樹脂組成物。
- 前記エポキシ化植物油がエポキシ化亜麻仁油を含む、請求項22又は23に記載の樹脂組成物。
- 請求項1〜25のいずれか一項に記載の樹脂組成物からなる層を備える、ラップフィルム。
- 食品の包装に用いられる、請求項26に記載のラップフィルム。
- 巻芯と、
前記巻芯に巻回された、請求項26又は27に記載のラップフィルムと、
前記巻芯及び前記フィルムを収容する箱体と、を備えるラップフィルム収容体。
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プラスチック・機能性高分子材料事典, vol. 初版第1刷, JPN6022047883, 20 February 2004 (2004-02-20), pages 900頁, ISSN: 0004920740 * |
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