JPWO2019138271A5 - - Google Patents
Download PDFInfo
- Publication number
- JPWO2019138271A5 JPWO2019138271A5 JP2020537615A JP2020537615A JPWO2019138271A5 JP WO2019138271 A5 JPWO2019138271 A5 JP WO2019138271A5 JP 2020537615 A JP2020537615 A JP 2020537615A JP 2020537615 A JP2020537615 A JP 2020537615A JP WO2019138271 A5 JPWO2019138271 A5 JP WO2019138271A5
- Authority
- JP
- Japan
- Prior art keywords
- nanocomposite
- ultra
- sheets
- transition metal
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002114 nanocomposite Substances 0.000 claims description 188
- 239000000463 material Substances 0.000 claims description 172
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 80
- 239000000203 mixture Substances 0.000 claims description 71
- 229910021389 graphene Inorganic materials 0.000 claims description 70
- 238000000034 method Methods 0.000 claims description 59
- 229910052582 BN Inorganic materials 0.000 claims description 50
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 50
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 50
- 229910001416 lithium ion Inorganic materials 0.000 claims description 50
- 239000002105 nanoparticle Substances 0.000 claims description 48
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 33
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 29
- 239000011593 sulfur Substances 0.000 claims description 26
- 229910052717 sulfur Inorganic materials 0.000 claims description 26
- 239000002904 solvent Substances 0.000 claims description 24
- 229910021524 transition metal nanoparticle Inorganic materials 0.000 claims description 23
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 claims description 21
- 239000011230 binding agent Substances 0.000 claims description 20
- 239000002482 conductive additive Substances 0.000 claims description 19
- 150000003839 salts Chemical class 0.000 claims description 16
- 239000003792 electrolyte Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 14
- 239000003575 carbonaceous material Substances 0.000 claims description 10
- 150000004770 chalcogenides Chemical class 0.000 claims description 9
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 9
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 150000004767 nitrides Chemical class 0.000 claims description 9
- 229910052596 spinel Inorganic materials 0.000 claims description 8
- 239000011029 spinel Substances 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 7
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 239000002086 nanomaterial Substances 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 72
- 239000007772 electrode material Substances 0.000 description 19
- 239000010405 anode material Substances 0.000 description 17
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 15
- 239000012530 fluid Substances 0.000 description 15
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 14
- -1 MoS2 Chemical class 0.000 description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 238000010586 diagram Methods 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 229910052744 lithium Inorganic materials 0.000 description 10
- 229910052961 molybdenite Inorganic materials 0.000 description 9
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 9
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 9
- 238000000696 nitrogen adsorption--desorption isotherm Methods 0.000 description 9
- 239000003960 organic solvent Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 125000004429 atom Chemical group 0.000 description 8
- 238000005119 centrifugation Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000001878 scanning electron micrograph Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 239000003129 oil well Substances 0.000 description 7
- 239000012286 potassium permanganate Substances 0.000 description 7
- 238000004626 scanning electron microscopy Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 description 6
- 239000002019 doping agent Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000004580 weight loss Effects 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 229910003092 TiS2 Inorganic materials 0.000 description 5
- 229910003090 WSe2 Inorganic materials 0.000 description 5
- 238000013019 agitation Methods 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 229910003002 lithium salt Inorganic materials 0.000 description 5
- 159000000002 lithium salts Chemical class 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000002411 thermogravimetry Methods 0.000 description 5
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 230000001351 cycling effect Effects 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000004098 selected area electron diffraction Methods 0.000 description 4
- 239000012265 solid product Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000001757 thermogravimetry curve Methods 0.000 description 4
- 238000003828 vacuum filtration Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229910016001 MoSe Inorganic materials 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 3
- 238000001069 Raman spectroscopy Methods 0.000 description 3
- 238000001237 Raman spectrum Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000010406 cathode material Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 239000011889 copper foil Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000005553 drilling Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- ZBYYWKJVSFHYJL-UHFFFAOYSA-L cobalt(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Co+2].CC([O-])=O.CC([O-])=O ZBYYWKJVSFHYJL-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000000350 glycoloyl group Chemical group O=C([*])C([H])([H])O[H] 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 150000003463 sulfur Chemical class 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 208000032953 Device battery issue Diseases 0.000 description 1
- 208000033999 Device damage Diseases 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000445 field-emission scanning electron microscopy Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 238000002065 inelastic X-ray scattering Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000037427 ion transport Effects 0.000 description 1
- 230000033001 locomotion Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000001314 profilometry Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/866,113 | 2018-01-09 | ||
| US15/866,113 US10424782B2 (en) | 2018-01-09 | 2018-01-09 | Nanocomposite electrode materials for use in high temperature and high pressure rechargeable batteries |
| PCT/IB2018/056449 WO2019138271A1 (en) | 2018-01-09 | 2018-08-24 | Nanocomposite electrode materials for use in high temperature and high pressure rechargeable batteries |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| JP2021509761A JP2021509761A (ja) | 2021-04-01 |
| JP2021509761A5 JP2021509761A5 (https=) | 2022-12-05 |
| JPWO2019138271A5 true JPWO2019138271A5 (https=) | 2022-12-05 |
| JP7239591B2 JP7239591B2 (ja) | 2023-03-14 |
Family
ID=63638186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020537615A Active JP7239591B2 (ja) | 2018-01-09 | 2018-08-24 | 高温および高圧の再充電可能な電池で使用するためのナノコンポジット電極材料 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US10424782B2 (https=) |
| EP (1) | EP3738160B1 (https=) |
| JP (1) | JP7239591B2 (https=) |
| CA (1) | CA3087837A1 (https=) |
| TW (1) | TW201937790A (https=) |
| WO (1) | WO2019138271A1 (https=) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11239466B2 (en) | 2018-01-09 | 2022-02-01 | Saudi Arabian Oil Company | Nanocomposite cathode materials for use in batteries |
| US10424782B2 (en) | 2018-01-09 | 2019-09-24 | Saudi Arabian Oil Company | Nanocomposite electrode materials for use in high temperature and high pressure rechargeable batteries |
| US11830735B2 (en) * | 2018-10-03 | 2023-11-28 | Northwestern University | Two-dimensional semiconductor based printable optoelectronic inks, fabricating methods and applications of same |
| CN114342026A (zh) | 2019-07-09 | 2022-04-12 | 沙特阿拉伯石油公司 | 制造用于高温电化学储能装置的纳米复合材料的方法 |
| CN113054129A (zh) * | 2019-12-28 | 2021-06-29 | Tcl集团股份有限公司 | 复合材料及其制备方法、导电电极和发光二极管 |
| DE102020128628A1 (de) * | 2020-05-28 | 2021-12-02 | Taiwan Semiconductor Manufacturing Co. Ltd. | Halbleiterbauelement mit zweidimensionalen materialien |
| US11688605B2 (en) | 2020-05-28 | 2023-06-27 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device with two-dimensional materials |
| CN112002889B (zh) * | 2020-09-09 | 2022-11-11 | 肇庆市华师大光电产业研究院 | 一种锂硫电池正极材料及其制备方法 |
| CN112186152A (zh) * | 2020-09-21 | 2021-01-05 | 天元军融(辽宁)化工研究所新材料孵化器股份有限公司 | 一种吸收太赫兹波为电池补充电量的方法和电池 |
| US20220238860A1 (en) * | 2021-01-22 | 2022-07-28 | Saudi Arabian Oil Company | Nanocomposite and method of making catalyst for high loading and utilization of sulfur at elevated temperatures |
| CN115101719B (zh) * | 2022-05-27 | 2023-06-23 | 长虹三杰新能源有限公司 | 一种柔性电极材料的制备方法及应用 |
| JP2024048027A (ja) * | 2022-09-27 | 2024-04-08 | 株式会社Abri | リチウム硫黄電池用正極及びリチウム硫黄電池 |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2636932C (en) | 2006-01-12 | 2014-03-25 | The Board Of Trustees Of The University Of Arkansas | Nanoparticle compositions and methods for making and using the same |
| US9705136B2 (en) | 2008-02-25 | 2017-07-11 | Traverse Technologies Corp. | High capacity energy storage |
| US9362549B2 (en) | 2011-12-21 | 2016-06-07 | Cpt Ip Holdings, Llc | Lithium-ion battery anode including core-shell heterostructure of silicon coated vertically aligned carbon nanofibers |
| WO2009134707A2 (en) | 2008-04-27 | 2009-11-05 | Board Of Regents, The University Of Texas System | Ultracapacitors and methods of making and using |
| US20100218801A1 (en) | 2008-07-08 | 2010-09-02 | Chien-Min Sung | Graphene and Hexagonal Boron Nitride Planes and Associated Methods |
| US9117568B2 (en) | 2009-04-03 | 2015-08-25 | Vorbeck Materials Corp. | Polymer compositions containing carbonaceous fillers |
| EP2414286A4 (en) | 2009-04-03 | 2014-10-29 | Vorbeck Materials Corp | POLYMER COMPOSITIONS WITH GRAPHIDE FOILS AND GRAPHITE |
| WO2011028804A2 (en) | 2009-09-02 | 2011-03-10 | Ut-Battelle, Llc | Sulfur-carbon nanocomposites and their application as cathode materials in lithium-sulfur batteries |
| WO2012047316A1 (en) | 2010-05-21 | 2012-04-12 | Ada Technologies, Inc. | High performance carbon nano-tube composites for electrochemical energy storage devices |
| US9577243B2 (en) | 2010-05-28 | 2017-02-21 | Sion Power Corporation | Use of expanded graphite in lithium/sulphur batteries |
| WO2012006657A1 (en) | 2010-07-14 | 2012-01-19 | Monash University | Material and applications therefor |
| CN104094457B (zh) | 2011-09-30 | 2017-06-23 | 加州大学校务委员会 | 在高性能锂/硫电池中作为硫固定剂的氧化石墨烯 |
| EP2578539B1 (en) | 2011-10-06 | 2014-08-27 | Karlsruher Institut für Technologie | Carbon encapsulated metal oxide nanocomposite, method for its preparation and its use in Li-ion batteries |
| US9029228B2 (en) | 2011-10-19 | 2015-05-12 | SunEdision Semiconductor Limited (UEN201334164H) | Direct and sequential formation of monolayers of boron nitride and graphene on substrates |
| US8790814B2 (en) | 2012-02-16 | 2014-07-29 | Nanotek Instruments, Inc. | Inorganic nano sheet-enabled lithium-exchanging surface-mediated cells |
| CN103094552B (zh) | 2012-10-12 | 2016-08-03 | 合肥国轩高科动力能源有限公司 | 一种5V锂离子电池正极材料LiNi0.5-x Mn1.5MxO4的表面包覆方法 |
| KR102100925B1 (ko) | 2013-03-22 | 2020-04-14 | 삼성전자주식회사 | 기판 구조체, 상기 기판 구조체를 형성하는 방법, 및 이를 구비하는 전기소자 |
| US8557916B1 (en) | 2013-04-30 | 2013-10-15 | Alfaisal University | Composition and method of making nanocomposite containing graphene sheets |
| US9368831B2 (en) | 2013-06-10 | 2016-06-14 | Nanotek Instruments, Inc. | Lithium secondary batteries containing non-flammable quasi-solid electrolyte |
| US9203084B2 (en) | 2013-08-08 | 2015-12-01 | Nanotek Instrurments, Inc. | Cathode active material-coated discrete graphene sheets for lithium batteries and process for producing same |
| KR101466310B1 (ko) * | 2013-09-09 | 2014-11-27 | 아주대학교산학협력단 | 금속산화물-그래핀 나노복합체의 제조방법 및 금속산화물-그래핀 나노복합체를 이용한 전극 제조방법 |
| CN104649700B (zh) | 2013-11-18 | 2017-02-15 | 苏州东南佳新材料股份有限公司 | 一种受电弓碳滑板及其制造方法 |
| CN105244476A (zh) * | 2014-06-11 | 2016-01-13 | 中国科学院苏州纳米技术与纳米仿生研究所 | 氮掺杂石墨烯包覆纳米硫正极复合材料、其制法及应用 |
| WO2016138385A1 (en) * | 2015-02-26 | 2016-09-01 | Board Of Regents, The University Of Texas System | Two-dimensional nanosheets and methods of making and use thereof |
| JP2016189320A (ja) * | 2015-03-27 | 2016-11-04 | Tdk株式会社 | リチウムイオン二次電池用正極活物質、リチウムイオン二次電池用正極およびこれを用いたリチウムイオン二次電池 |
| US9780379B2 (en) | 2015-05-21 | 2017-10-03 | Nanotek Instruments, Inc. | Alkali metal secondary battery containing a carbon matrix- or carbon matrix composite-based dendrite intercepting layer |
| US10665863B2 (en) | 2015-08-21 | 2020-05-26 | Nec Corporation | Additives for fast chargeable lithium ion batteries |
| US10361460B2 (en) | 2015-10-02 | 2019-07-23 | Nanotek Instruments, Inc. | Process for producing lithium batteries having an ultra-high energy density |
| CN108352511B (zh) | 2015-11-13 | 2021-11-19 | 纳诺格拉夫公司 | 用于锂离子电化学电池中的石墨烯包封电活性材料 |
| US10971717B2 (en) | 2015-11-19 | 2021-04-06 | Tdk Corporation | Positive electrode active material, positive electrode, and lithium ion secondary battery |
| US10193144B2 (en) | 2015-12-17 | 2019-01-29 | Uchicago Argonne, Llc | High capacity lithium ion batteries having oxides, peroxides, or superoxides as cathode active material |
| US10008723B1 (en) | 2016-05-17 | 2018-06-26 | Nanotek Instruments, Inc. | Chemical-free production of graphene-wrapped electrode active material particles for battery applications |
| US9899672B2 (en) | 2016-05-17 | 2018-02-20 | Nanotek Instruments, Inc. | Chemical-free production of graphene-encapsulated electrode active material particles for battery applications |
| CN106398179B (zh) | 2016-09-07 | 2018-03-06 | 中国科学院重庆绿色智能技术研究院 | 一种多组分石墨烯/聚氨酯弹性体复合材料的制备方法 |
| US10008747B1 (en) | 2016-12-28 | 2018-06-26 | Nanotek Instruments, Inc. | Process for producing flexible and shape-conformal rope-shape alkali metal batteries |
| CN106654232B (zh) * | 2017-01-20 | 2019-04-12 | 北京航空航天大学 | 一种二次金属锂电池负极用层状复合物的制备方法 |
| US10840502B2 (en) * | 2017-02-24 | 2020-11-17 | Global Graphene Group, Inc. | Polymer binder for lithium battery and method of manufacturing |
| US10896784B2 (en) * | 2017-03-31 | 2021-01-19 | Global Graphene Group, Inc. | Direct microwave production of graphene |
| US11515519B2 (en) * | 2017-10-17 | 2022-11-29 | VoltaXplore Inc | Graphene-polymer porous scaffold for stable lithium-sulfur batteries |
| CN108034256A (zh) | 2017-12-01 | 2018-05-15 | 青岛德通纳米技术有限公司 | 一种高导热低比重锂电池防爆硅胶垫片及其制备方法 |
| US11239466B2 (en) | 2018-01-09 | 2022-02-01 | Saudi Arabian Oil Company | Nanocomposite cathode materials for use in batteries |
| US10424782B2 (en) | 2018-01-09 | 2019-09-24 | Saudi Arabian Oil Company | Nanocomposite electrode materials for use in high temperature and high pressure rechargeable batteries |
| CN109182856B (zh) | 2018-08-18 | 2019-09-17 | 山东大学 | 一种AlN与MgB2颗粒增强镁基复合材料及其制备方法 |
| CN109762518B (zh) | 2019-02-19 | 2021-11-09 | 军事科学院系统工程研究院军需工程技术研究所 | 一种三维多孔石墨烯/氮化硼复合材料及其制备方法 |
| CN114342026A (zh) | 2019-07-09 | 2022-04-12 | 沙特阿拉伯石油公司 | 制造用于高温电化学储能装置的纳米复合材料的方法 |
-
2018
- 2018-01-09 US US15/866,113 patent/US10424782B2/en active Active
- 2018-08-24 EP EP18772901.7A patent/EP3738160B1/en active Active
- 2018-08-24 WO PCT/IB2018/056449 patent/WO2019138271A1/en not_active Ceased
- 2018-08-24 CA CA3087837A patent/CA3087837A1/en active Pending
- 2018-08-24 JP JP2020537615A patent/JP7239591B2/ja active Active
- 2018-09-06 TW TW107131222A patent/TW201937790A/zh unknown
-
2019
- 2019-02-07 US US16/270,010 patent/US11658286B2/en active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP7239591B2 (ja) | 高温および高圧の再充電可能な電池で使用するためのナノコンポジット電極材料 | |
| Yu et al. | High-performance Ti-doped O3-type Na [Tix (Ni0. 6Co0. 2Mn0. 2) 1-x] O2 cathodes for practical sodium-ion batteries | |
| Ding et al. | Enhanced rate performance and cycling stability of a CoCO 3–polypyrrole composite for lithium ion battery anodes | |
| TWI870428B (zh) | 用於高溫電化學能量儲存裝置之奈米複合物的製造方法 | |
| WO2018208660A1 (en) | Rolled alkali metal batteries and production process | |
| Zhang et al. | Microwave-assisted and large-scale synthesis of SnO 2/carbon-nanotube hybrids with high lithium storage capacity | |
| WO2017105572A2 (en) | Process for producing lithium batteries having an ultra-high energy density | |
| WO2017034656A1 (en) | Rechargeable lithium batteries having an ultra-high volumetric energy density and required production process | |
| Yao et al. | Enhanced rate and cycling performance of FeCO3/graphene composite for high energy Li ion battery anodes | |
| Liu et al. | Microstructure and superior electrochemical activity of Cu3P/reduced graphene oxide composite for an anode in lithium-ion batteries | |
| JPWO2019138271A5 (https=) | ||
| Wu et al. | Exploring structural stability mechanism of TiO2 encapsulated in 3D flower-like SnS2 anode for lithium ion batteries | |
| Ma et al. | Construction of conductive network in hematite for lithium, sodium and potassium storage | |
| Kanimozhi et al. | A synergic effect of N-Graphene wrapped α-Fe2O3 nanofacets prepared by Microwave-assisted solvothermal method for Lithium-ion battery | |
| Cheekati et al. | The impacts of graphene nanosheets and manganese valency on lithium storage characteristics in graphene/manganese oxide hybrid anode | |
| Fernando | Graphene derivatives for Li-ion batteries | |
| US20220238860A1 (en) | Nanocomposite and method of making catalyst for high loading and utilization of sulfur at elevated temperatures | |
| Dou et al. | High-surface-area-Fe2O3/carbon nanocomposite: one-step synthesis and its highly reversible and enhanced high-rate lithium storage properties | |
| Moradkhani et al. | Cobalt-Free High-Entropy Oxide ((Vcrnimnzn) 3o4) as a High-Performance Anode Material for Li-Ion Batteries | |
| Lu | Transition-metal oxides, sulphide and sulphur composites for lithium batteries |