JPWO2015163338A1 - Shampoo composition - Google Patents
Shampoo composition Download PDFInfo
- Publication number
- JPWO2015163338A1 JPWO2015163338A1 JP2016514957A JP2016514957A JPWO2015163338A1 JP WO2015163338 A1 JPWO2015163338 A1 JP WO2015163338A1 JP 2016514957 A JP2016514957 A JP 2016514957A JP 2016514957 A JP2016514957 A JP 2016514957A JP WO2015163338 A1 JPWO2015163338 A1 JP WO2015163338A1
- Authority
- JP
- Japan
- Prior art keywords
- mass
- component
- hair
- content
- smoothness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 73
- 239000000203 mixture Substances 0.000 title claims abstract description 70
- -1 polyoxyethylene Polymers 0.000 claims abstract description 43
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 30
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 24
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 24
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 19
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 16
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 12
- 229920002907 Guar gum Polymers 0.000 claims abstract description 11
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims abstract description 11
- 239000000665 guar gum Substances 0.000 claims abstract description 11
- 235000010417 guar gum Nutrition 0.000 claims abstract description 11
- 229960002154 guar gum Drugs 0.000 claims abstract description 11
- 229940070765 laurate Drugs 0.000 claims abstract description 11
- 229940105132 myristate Drugs 0.000 claims abstract description 11
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000001913 cellulose Substances 0.000 claims abstract description 10
- 229920002678 cellulose Polymers 0.000 claims abstract description 10
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 150000008051 alkyl sulfates Chemical class 0.000 claims abstract description 8
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 8
- 210000004209 hair Anatomy 0.000 description 127
- 238000001035 drying Methods 0.000 description 69
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 46
- 229910052757 nitrogen Inorganic materials 0.000 description 23
- 239000006260 foam Substances 0.000 description 18
- 239000003205 fragrance Substances 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- 210000002374 sebum Anatomy 0.000 description 14
- 239000002245 particle Substances 0.000 description 12
- 230000002688 persistence Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
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- 210000004761 scalp Anatomy 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
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- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
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- 239000010410 layer Substances 0.000 description 4
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- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
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- 244000303965 Cyamopsis psoralioides Species 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
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- 229920002125 Sokalan® Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
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- 150000001298 alcohols Chemical class 0.000 description 2
- 235000015107 ale Nutrition 0.000 description 2
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- OPVLOHUACNWTQT-UHFFFAOYSA-N azane;2-dodecoxyethyl hydrogen sulfate Chemical compound N.CCCCCCCCCCCCOCCOS(O)(=O)=O OPVLOHUACNWTQT-UHFFFAOYSA-N 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
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- 239000002738 chelating agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
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- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-N sodium;dodecyl sulfate;hydron Chemical compound [H+].[Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-N 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229960002663 thioctic acid Drugs 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- FGMPLJWBKKVCDB-UHFFFAOYSA-N trans-L-hydroxy-proline Natural products ON1CCCC1C(O)=O FGMPLJWBKKVCDB-UHFFFAOYSA-N 0.000 description 1
- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Chemical group 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 235000019168 vitamin K Nutrition 0.000 description 1
- 239000011712 vitamin K Substances 0.000 description 1
- 150000003721 vitamin K derivatives Chemical class 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 229940046010 vitamin k Drugs 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
Abstract
(A)アニオン性界面活性剤、(B)ラウリン酸ポリグリセリル、及びミリスチン酸ポリグリセリルから選択される少なくとも1種のノニオン性界面活性剤、(C)カチオン性ポリマー、(D)ジメチルポリシロキサン、並びに(E)アミノ変性シリコーンを含有してなり、(A)成分が、(A1)ポリオキシエチレンアルキルエーテル硫酸塩、及び(A2)アルキル硫酸塩を含有し、(A1)成分と(A2)成分との質量比(A1/A2)が1〜7であり、(C)成分が、(C1)カチオン化グアーガム、及び(C2)カチオン化セルロースを含有し、(C1)成分と(C2)成分との質量比(C1/C2)が2〜20であるシャンプー組成物を提供する。(A) anionic surfactant, (B) at least one nonionic surfactant selected from polyglyceryl laurate and polyglyceryl myristate, (C) a cationic polymer, (D) dimethylpolysiloxane, and ( E) containing an amino-modified silicone, wherein the component (A) contains (A1) a polyoxyethylene alkyl ether sulfate and (A2) an alkyl sulfate, and the components (A1) and (A2) The mass ratio (A1 / A2) is 1 to 7, the (C) component contains (C1) cationized guar gum and (C2) cationized cellulose, and the mass of the (C1) component and the (C2) component Provided is a shampoo composition having a ratio (C1 / C2) of 2-20.
Description
本発明は、シャンプー組成物に関する。 The present invention relates to a shampoo composition.
発展途上の東南アジアにおいては、毛髪の洗浄を毎日行わない消費者も数多く存在する。このような消費者のヘアケア習慣に加えて、一年を通じて平均気温が27℃以上、平均湿度は約70%RHと高温多湿の気候が特徴的であり、毛髪がべたつきやすい環境となっている。このため、溜まった皮脂がきちんと落せる洗浄力と泡の持続性を備えながら、すすぎ時の毛髪のなめらかさを有し、高温多湿環境下においても毛髪がべたつかずになめらかであり、やわらかな感触が得られるシャンプーの提供が望まれている。 In developing Southeast Asia, there are many consumers who do not wash their hair every day. In addition to such consumer hair care habits, the average temperature is over 27 ° C. throughout the year, the average humidity is about 70% RH, and the climate is hot and humid, making the hair easy to stick. For this reason, it has a detergency that allows the accumulated sebum to be properly removed and the persistence of foam, while it has a smooth hair when rinsing, and the hair is smooth and non-sticky even in a hot and humid environment. It is desired to provide a shampoo that can provide
従来より、シャンプーの洗浄力を向上させる方法としては、ラウリル硫酸塩、ラウレス硫酸塩等の洗浄力の高いアニオン性界面活性剤の配合量を増やしてヘアワックスの油性成分や皮脂を洗浄させることが行われてきた。しかし、これらの方法では、洗浄力は向上するものの、すすぎ時の毛髪の指通りが極端に悪く、乾燥後の毛髪の感触も好ましいものではなかった。そのため、シャンプーしただけで乾燥後の毛髪の風合いを改善する効果を有するシャンプー組成物の技術が数多く開発され、コンディショニングシャンプーとして市販されている。
このようなコンディショニングシャンプーとしては、例えば、感触付与剤として、カチオン化ポリマー、各種シリコーン化合物、油分、カチオン性界面活性剤等をシャンプー組成物に配合することが提案されている(例えば、特許文献1〜4参照)。Conventionally, as a method for improving the detergency of a shampoo, it is possible to increase the amount of anionic surfactant having a high detergency such as lauryl sulfate and laureth sulfate to wash oil components and sebum of hair wax. Has been done. However, in these methods, although the detergency is improved, the fingering of the hair during rinsing is extremely poor, and the hair feel after drying is not preferable. Therefore, many techniques of shampoo compositions that have the effect of improving the texture of the hair after drying just by shampooing have been developed and are commercially available as conditioning shampoos.
As such a conditioning shampoo, for example, it has been proposed that a cationized polymer, various silicone compounds, an oil component, a cationic surfactant, and the like are blended in a shampoo composition as a touch-imparting agent (for example, Patent Document 1). To 4).
しかしながら、これらの提案の技術では、いずれも、高温多湿環境下においては、毛髪がべたつき、毛髪同士がくっついて重たく感じてしまうことがある。また、コンディショニング剤を配合することにより洗浄力が阻害されてしまい相容れない性質を有しているという課題がある。 However, in any of these proposed technologies, the hair may become sticky and the hairs may stick together and feel heavy under a high temperature and humidity environment. Moreover, there exists a subject that it has the property which a cleaning power will be inhibited by mix | blending a conditioning agent and it has an incompatible property.
したがって、皮脂が多い、高温多湿環境下においても洗浄力及び泡の持続性を担保しつつ、すすぎ時の毛髪のなめらかさが得られると共に、高温多湿環境下での乾燥後の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のやわらかさ、及び高温多湿環境下での乾燥後の毛髪のべたつきのなさを併せ持ち、外観安定性、使用性、及び刺激のなさが良好であるシャンプー組成物の提供が望まれている。 Therefore, while maintaining the detergency and the persistence of foam even in a high-temperature and high-humidity environment with a lot of sebum, the smoothness of the hair when rinsing is obtained, and the smoothness of the hair after drying in a high-temperature and high-humidity environment A shampoo composition that combines the softness of hair after drying in a hot and humid environment and the non-stickiness of hair after drying in a hot and humid environment, and has good appearance stability, usability, and non-irritating properties The provision of
本発明は、従来における前記諸問題を解決し、以下の目的を達成することを課題とする。即ち、本発明は、皮脂が多い、高温多湿環境下においても洗浄力及び泡の持続性を担保しつつ、すすぎ時の毛髪のなめらかさが得られると共に、高温多湿環境下での乾燥後の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のやわらかさ、及び高温多湿環境下での乾燥後の毛髪のべたつきのなさを併せ持ち、外観安定性、使用性及び刺激のなさが良好であるシャンプー組成物を提供することを目的とする。 An object of the present invention is to solve the above-described problems and achieve the following objects. That is, the present invention provides smooth hair when rinsing while ensuring detergency and persistence of foam even in a high-temperature and high-humidity environment with a large amount of sebum, and hair after drying in a high-temperature and high-humidity environment. Smoothness of hair, softness of hair after drying under high temperature and high humidity environment, and non-stickiness of hair after drying under high temperature and high humidity environment. Good appearance stability, usability and no irritation. The object is to provide a shampoo composition.
前記課題を解決するための手段としての本発明のシャンプー組成物は、(A)アニオン性界面活性剤、(B)ラウリン酸ポリグリセリル、及びミリスチン酸ポリグリセリルから選択される少なくとも1種のノニオン性界面活性剤、(C)カチオン性ポリマー、(D)ジメチルポリシロキサン、並びに(E)アミノ変性シリコーンを含有してなり、
前記(A)成分が、(A1)ポリオキシエチレンアルキルエーテル硫酸塩、及び(A2)アルキル硫酸塩を含有し、前記(A1)成分の含有量と前記(A2)成分の含有量との質量比(A1/A2)が1〜7であり、
前記(C)成分が、(C1)カチオン化グアーガム、及び(C2)カチオン化セルロースを含有し、前記(C1)成分の含有量と前記(C2)成分の含有量との質量比(C1/C2)が2〜20である。The shampoo composition of the present invention as a means for solving the above-mentioned problems is at least one nonionic surfactant selected from (A) anionic surfactant, (B) polyglyceryl laurate, and polyglyceryl myristate. An agent, (C) a cationic polymer, (D) dimethylpolysiloxane, and (E) an amino-modified silicone,
The component (A) contains (A1) polyoxyethylene alkyl ether sulfate and (A2) alkyl sulfate, and the mass ratio between the content of the component (A1) and the content of the component (A2) (A1 / A2) is 1-7,
The component (C) contains (C1) cationized guar gum and (C2) cationized cellulose, and the mass ratio (C1 / C2) between the content of the component (C1) and the content of the component (C2) ) Is 2-20.
本発明によると、従来における前記諸問題を解決し、前記目的を達成することができ、皮脂が多い、高温多湿環境下においても洗浄力及び泡の持続性を担保しつつ、すすぎ時の毛髪のなめらかさが得られると共に、高温多湿環境下での乾燥後の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のやわらかさ、及び高温多湿環境下での乾燥後の毛髪のべたつきのなさを併せ持ち、外観安定性、使用性及び刺激のなさが良好であるシャンプー組成物を提供することができる。 According to the present invention, the above-mentioned problems can be solved and the above-mentioned object can be achieved, and there is a lot of sebum, while maintaining the detergency and the persistence of foam even in a high-temperature and high-humidity environment, Provides smoothness and smoothness of hair after drying in a hot and humid environment, softness of hair after drying in a hot and humid environment, and non-stickiness of hair after drying in a hot and humid environment Thus, it is possible to provide a shampoo composition having good appearance stability, usability and no irritation.
(シャンプー組成物)
本発明のシャンプー組成物は、(A)アニオン性界面活性剤、(B)ノニオン性界面活性剤、(C)カチオン性ポリマー、(D)ジメチルポリシロキサン、及び(E)アミノ変性シリコーンを含有してなり、更に必要に応じてその他の成分を含有してなる。(Shampoo composition)
The shampoo composition of the present invention contains (A) an anionic surfactant, (B) a nonionic surfactant, (C) a cationic polymer, (D) dimethylpolysiloxane, and (E) an amino-modified silicone. And further contains other components as necessary.
<(A)アニオン性界面活性剤>
前記アニオン性界面活性剤は、高温多湿環境下においても洗浄力、泡の持続性、及び外観安定性を担保しつつ、また、高温多湿環境下での乾燥後の毛髪のべたつきのなさ、及びすすぎ時に毛髪になめらかな感触を付与し、更に頭皮に刺激を与えない洗浄基剤となる成分である。
前記(A)成分のアニオン性界面活性剤は、(A1)ポリオキシエチレンアルキルエーテル硫酸塩と、(A2)アルキル硫酸塩とを含有する。前記塩としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、ナトリウム、カリウム等のアルカリ金属、アンモニウム、アルカノールアミンなどが挙げられる。<(A) Anionic surfactant>
The anionic surfactant ensures detergency, foam persistence and appearance stability even in a hot and humid environment, and the hair is not sticky and rinsed after drying in a hot and humid environment. It is a component that becomes a cleaning base that sometimes gives a smooth feel to the hair and does not irritate the scalp.
The anionic surfactant of the component (A) contains (A1) polyoxyethylene alkyl ether sulfate and (A2) alkyl sulfate. There is no restriction | limiting in particular as said salt, According to the objective, it can select suitably, For example, alkali metals, such as sodium and potassium, ammonium, an alkanolamine, etc. are mentioned.
前記(A1)のポリオキシエチレンアルキルエーテル硫酸塩としては、下記一般式(A1)で表されるアニオン性界面活性剤が好ましい。
R1O(CH2CH2O)mSO3M1 ・・・ 一般式(A1)
〔ただし、前記一般式(A1)において、R1は、炭素数10〜18のアルキル基を示し、M1は、アルカリ金属、アンモニウム、及びアルカノールアミンのいずれかを示し、mは、平均付加モル数で1〜5の数を示す。〕The polyoxyethylene alkyl ether sulfate (A1) is preferably an anionic surfactant represented by the following general formula (A1).
R 1 O (CH 2 CH 2 O) m SO 3 M 1 ··· general formula (A1)
[In the general formula (A1), R 1 represents an alkyl group having 10 to 18 carbon atoms, M 1 represents any one of an alkali metal, ammonium, and alkanolamine, and m represents an average addition mole. A number from 1 to 5 is shown. ]
前記(A2)成分のアルキル硫酸塩としては、下記一般式(A2)で表されるアニオン性界面活性剤が好ましい。
R2OSO3M2 ・・・ 一般式(A2)
〔ただし、前記一般式(A2)において、R2は、炭素数10〜18のアルキル基を示し、M2は、アルカリ金属、アンモニウム、及びアルカノールアミンのいずれかを示す。〕As the alkyl sulfate salt of the component (A2), an anionic surfactant represented by the following general formula (A2) is preferable.
R 2 OSO 3 M 2 General formula (A2)
[However, the general formula (A2), R 2 represents an alkyl group having 10 to 18 carbon atoms, M 2 represents an alkali metal, ammonium, and one of the alkanolamine. ]
前記シャンプー組成物中での外観安定性と、すすぎ時の毛髪のなめらかさとを両立する観点から、前記一般式(A1)におけるR1及び前記一般式(A2)におけるR2は、炭素数12〜16のアルキル基が好ましい。また、すすぎ時の毛髪になめらかさを付与する点で、前記一般式(A1)におけるmは、2〜3が好ましい。更に、前記一般式(A1)におけるM1又は前記一般式(A2)におけるM2は、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のやわらかさの点から、アンモニウムが特に好ましい。From the viewpoint of achieving both the appearance stability in the shampoo composition and the smoothness of the hair during rinsing, R 1 in the general formula (A1) and R 2 in the general formula (A2) each have 12 to 12 carbon atoms. Sixteen alkyl groups are preferred. Further, m in the general formula (A1) is preferably 2 to 3 in terms of imparting smoothness to the hair at the time of rinsing. Furthermore, M 1 in the general formula (A1) or M 2 in the general formula (A2) is ammonium from the viewpoint of the smoothness of the hair at the time of rinsing and the softness of the hair after drying in a hot and humid environment. Is particularly preferred.
前記(A)成分のアニオン性界面活性剤としては、市販品を用いてもよく、適宜合成したものを用いてもよい。前記市販品としては、前記(A1)のポリオキシエチレンアルキルエーテル硫酸塩として、例えば、Texapon ALES 70(POE(3)ラウリルエーテル硫酸アンモニウム、BASF社製)、シノリンSPE−1250(POE(2)ラウリルエーテル硫酸ナトリウム、新日本理化株式会社製)、エマール20C(POE(3)ラウリルエーテル硫酸ナトリウム、花王株式会社製)などが挙げられる。前記(A2)成分のアルキル硫酸塩として、例えば、Texapon ALS 70(ラウリル硫酸アンモニウム、BASF社製)、Texapon K12(ラウリル硫酸ナトリウム、Cognisジャパン社製)などが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、すすぎ時の毛髪のなめらかさの点から、前記(A1)成分としては、Texapon ALES 70(POE(3)ラウリルエーテル硫酸アンモニウム、BASF社製)、前記(A2)成分としては、Texapon ALS 70(ラウリル硫酸アンモニウム、BASF社製)が好ましい。 As the anionic surfactant of the component (A), a commercially available product may be used, or an appropriately synthesized one may be used. Examples of the commercially available products include (A1) polyoxyethylene alkyl ether sulfates such as Texapon ALES 70 (POE (3) ammonium lauryl ether sulfate, manufactured by BASF), Sinoline SPE-1250 (POE (2) lauryl ether). Sodium sulfate, manufactured by Shin Nippon Rika Co., Ltd.), Emar 20C (POE (3) sodium lauryl ether sulfate, manufactured by Kao Corporation), and the like. Examples of the alkyl sulfate of the component (A2) include Texapon ALS 70 (ammonium lauryl sulfate, manufactured by BASF), Texapon K12 (sodium lauryl sulfate, manufactured by Cognis Japan), and the like. These may be used alone or in combination of two or more. Among these, from the point of the smoothness of the hair at the time of a rinse, as said (A1) component, as Texapon ALES 70 (POE (3) ammonium lauryl ether sulfate, the product made from BASF), as said (A2) component, Texapon ALS 70 (ammonium lauryl sulfate, manufactured by BASF) is preferred.
前記(A)成分が、前記(A1)成分のみの場合、高温多湿環境下での乾燥後の毛髪のべたつきのなさ、及びすすぎ時の毛髪のなめらかさが低下したり、十分な洗浄力を得ることができないことがある。
前記(A)成分が、前記(A2)成分のみの場合、高温多湿環境下での乾燥後の毛髪のべたつきのなさ、及びすすぎ時の毛髪のなめらかさが不十分になることがある。
前記(A1)成分の含有量は、シャンプー組成物全量に対して、3質量%〜24質量%が好ましく、5質量%〜22質量%がより好ましい。前記(A1)成分の含有量が、3質量%未満であると、洗浄力が低下し、すすぎ時の毛髪のなめらかさが低下することがあり、24質量%を超えると、頭皮に刺激が生じたり、粘性が高くなって使用性が悪くなることがある。When the component (A) is only the component (A1), the non-stickiness of the hair after drying in a hot and humid environment and the smoothness of the hair at the time of rinsing are reduced or sufficient detergency is obtained. There are times when you can't.
When the component (A) is only the component (A2), the non-stickiness of the hair after drying in a hot and humid environment and the smoothness of the hair during rinsing may be insufficient.
The content of the component (A1) is preferably 3% by mass to 24% by mass and more preferably 5% by mass to 22% by mass with respect to the total amount of the shampoo composition. When the content of the component (A1) is less than 3% by mass, the detergency may decrease and the smoothness of the hair during rinsing may decrease. When the content exceeds 24% by mass, irritation occurs in the scalp. Or the viscosity may increase and usability may deteriorate.
前記(A2)成分の含有量は、シャンプー組成物全量に対して、1質量%〜15質量%が好ましく、2質量%〜12質量%がより好ましい。前記(A2)成分の含有量が、1質量%未満であると、高温多湿環境下での乾燥後の毛髪のべたつきのなさが低下することがあり、15質量%を超えると、すすぎ時の毛髪のなめらかさが低下することがある。 The content of the component (A2) is preferably 1% by mass to 15% by mass and more preferably 2% by mass to 12% by mass with respect to the total amount of the shampoo composition. When the content of the component (A2) is less than 1% by mass, the non-stickiness of the hair after drying in a hot and humid environment may be reduced. When the content exceeds 15% by mass, the hair at the time of rinsing The smoothness may be reduced.
前記(A)成分の含有量(前記(A1)成分と前記(A2)成分との合計含有量)は、シャンプー組成物全量に対して、泡の持続性、及びすすぎ時の毛髪のなめらかさの点から、5質量%〜30質量%が好ましく、10質量%〜25質量%がより好ましい。前記(A)成分の含有量が、5質量%未満であると、洗浄力が悪くなり、すすぎ時の毛髪のなめらかさが低下することがあり、30質量%を超えると、粘性が高く使用性が悪くなり、頭皮に刺激を与えることがある。 The content of the component (A) (the total content of the component (A1) and the component (A2)) is sufficient for the persistence of the foam and the smoothness of the hair during rinsing with respect to the total amount of the shampoo composition. From the viewpoint, 5% by mass to 30% by mass is preferable, and 10% by mass to 25% by mass is more preferable. When the content of the component (A) is less than 5% by mass, the detergency is deteriorated and the smoothness of the hair at the time of rinsing may be reduced. When the content exceeds 30% by mass, the viscosity is high and the usability is high. May worsen and irritate the scalp.
<質量比(A1/A2)>
前記(A1)成分の含有量と前記(A2)成分の含有量との質量比(A1/A2)は、泡の持続性、すすぎ時の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のべたつきのなさ、及び外観安定性の点から、1〜7であり、1.3〜4が好ましい。前記質量比(A1/A2)が、1未満であると、外観安定性が悪く、すすぎ時の毛髪のなめらかさが低下することがあり、7を超えると、高温多湿環境下での乾燥後の毛髪にべたつきが生じたり、すすぎ時の毛髪のなめらかさが低下することがある。<Mass ratio (A1 / A2)>
The mass ratio (A1 / A2) between the content of the component (A1) and the content of the component (A2) is the persistence of the foam, the smoothness of the hair during rinsing, and the amount after drying in a hot and humid environment. From the point of non-stickiness of hair and appearance stability, it is 1-7, and 1.3-4 are preferable. When the mass ratio (A1 / A2) is less than 1, the appearance stability is poor and the smoothness of the hair at the time of rinsing may be reduced. The hair may become sticky or the smoothness of the hair during rinsing may be reduced.
<(B)ノニオン性界面活性剤>
前記ノニオン性界面活性剤は、皮脂が多い高温多湿環境下における泡の持続性、すすぎ時の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のやわらかさ、高温多湿環境下での乾燥後の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のべたつきのなさを付与するために含有される。
前記(B)成分のノニオン性界面活性剤は、ラウリン酸ポリグリセリル、及びミリスチン酸ポリグリセリルから選択される少なくとも1種であり、グリセリンの平均重合度が6〜10のものが好ましく、グリセリンの平均重合度が10のものがより好ましい。
前記ラウリン酸ポリグリセリルは、モノラウリン酸ポリグリセリル、ラウリン酸デカグリセリル、ラウリン酸デカヘキサグリセリル、モノラウリン酸デカグリセリルなどとも呼ばれる。
前記ミリスチン酸ポリグリセリルは、モノミリスチン酸ポリグリセリル、ミリスチン酸デカグリセリル、ミリスチン酸ヘキサグリセリル、モノミリスチン酸デカグリセリルなどとも呼ばれる。<(B) Nonionic surfactant>
The nonionic surfactant is the persistence of foam in a high-temperature and high-humidity environment rich in sebum, the smoothness of the hair during rinsing, the softness of the hair after drying in a high-temperature and high-humidity environment, and the drying in a high-temperature and high-humidity environment. It is contained in order to impart smoothness of the hair afterwards and non-stickiness of the hair after drying in a hot and humid environment.
The nonionic surfactant of the component (B) is at least one selected from polyglyceryl laurate and polyglyceryl myristate, preferably having an average degree of polymerization of glycerin of 6 to 10, and an average degree of polymerization of glycerin. 10 is more preferable.
The polyglyceryl laurate is also called polyglyceryl monolaurate, decaglyceryl laurate, decahexaglyceryl laurate, decaglyceryl monolaurate, or the like.
The polyglyceryl myristate is also called polyglyceryl monomyristate, decaglyceryl myristate, hexaglyceryl myristate, decaglyceryl monomyristate, and the like.
前記(B)成分のノニオン性界面活性剤としては、市販品を用いてもよく、適宜合成したものを用いてもよい。前記市販品としては、例えば、サンソフトM−12J(ラウリン酸デカグリセリル、太陽化学株式会社製)、サンソフトM−12JW(ラウリン酸デカグリセリル−10、太陽化学株式会社製)、NIKKOL Decaglyn 1−L(ラウリン酸デカグリセリル、日光ケミカルズ株式会社製)、NIKKOL Hexaglyn 1−L(ラウリン酸ヘキサグリセリル、日光ケミカルズ株式会社製)、サンソフトQ−14S(ミリスチン酸デカグリセリル、太陽化学株式会社製)、NIKKOL Decaglyn 1−M(ミリスチン酸デカグリセリル、日光ケミカルズ株式会社製)、NIKKOL Hexaglyn 1−M(ミリスチン酸ヘキサグリセリル、日光ケミカルズ株式会社製)などが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、サンソフトM−12J、サンソフトQ−14Sが好ましい。 As the nonionic surfactant of the component (B), a commercially available product may be used, or an appropriately synthesized one may be used. Examples of the commercially available products include Sunsoft M-12J (decaglyceryl laurate, manufactured by Taiyo Kagaku Co., Ltd.), Sunsoft M-12JW (decaglyceryl laurate-10, manufactured by Taiyo Chemical Co., Ltd.), NIKKOL Decaglyn 1- L (decaglyceryl laurate, manufactured by Nikko Chemicals), NIKKOL Hexaglyn 1-L (hexaglyceryl laurate, manufactured by Nikko Chemicals), Sunsoft Q-14S (decaglyceryl myristate, manufactured by Taiyo Chemical Co., Ltd.), NIKOL Decaglyn 1-M (decaglyceryl myristate, manufactured by Nikko Chemicals Co., Ltd.), NIKKOL Hexaglyn 1-M (hexaglyceryl myristate, manufactured by Nikko Chemicals Co., Ltd.) and the like. These may be used alone or in combination of two or more. Among these, Sunsoft M-12J and Sunsoft Q-14S are preferable.
前記(B)成分のノニオン性界面活性剤の含有量は、シャンプー組成物全量に対して、0.1質量%〜10質量%が好ましく、0.3質量%〜8質量%がより好ましい。前記含有量が、0.1質量%未満であると、皮脂が多い高温多湿環境下において泡の持続性が得られないことがあり、高温多湿環境下での乾燥後の毛髪のやわらかさ、及び高温多湿環境下での乾燥後の毛髪のなめらかさが得られないことがあり、10質量%を超えると、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のべたつきのなさが得られないことがある。 The content of the nonionic surfactant as the component (B) is preferably 0.1% by mass to 10% by mass and more preferably 0.3% by mass to 8% by mass with respect to the total amount of the shampoo composition. When the content is less than 0.1% by mass, the persistence of foam may not be obtained in a hot and humid environment with a lot of sebum, and the softness of hair after drying in a hot and humid environment, and The smoothness of the hair after drying in a hot and humid environment may not be obtained, and if it exceeds 10% by mass, the smoothness of the hair during rinsing and the stickiness of the hair after drying in a hot and humid environment May not be able to be obtained.
<(C)カチオン性ポリマー>
前記カチオン性ポリマーは、すすぎ時の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のやわらかさ、高温多湿環境下での乾燥後の毛髪のなめらかさ、及び良好な使用性を付与するために含有される。
前記(C)成分のカチオン性ポリマーは、(C1)カチオン化グアーガム、及び(C2)カチオン化セルロースを含有する。<(C) Cationic polymer>
The cationic polymer provides smoothness of the hair during rinsing, softness of the hair after drying in a hot and humid environment, smoothness of the hair after drying in a hot and humid environment, and good usability For contain.
The cationic polymer of the component (C) contains (C1) cationized guar gum and (C2) cationized cellulose.
−(C1)カチオン化グアーガム−
前記(C1)成分のカチオン化グアーガムは、グアーヒドロキシプロピルトリモニウムクロリド、塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]グアーガムなどとも呼ばれる。-(C1) Cationized guar gum-
The cationized guar gum of the component (C1) is also called guar hydroxypropyltrimonium chloride, chloride O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum and the like.
前記(C1)成分のカチオン化グアーガムの窒素含量は、すすぎ時の毛髪のなめらかさの点から、1質量%〜1.8質量%が好ましく、1.15質量%〜1.45質量%がより好ましい。
前記窒素含量は、ケルダール法により、前記(C1)成分を硫酸で分解して硫酸アンモニウムとし、そのアンモニアを定量することにより測定することができる。詳細には、「医薬部外品原料規格2006(薬事日報社)」一般試験法 44.窒素定量法を参考に記載された方法により測定できる。
前記(C1)成分としては、市販品を用いてもよく、適宜合成したものを用いてもよい。前記市販品としては、例えば、Jaguar C14S(窒素含量:1.3質量%〜1.7質量%)、Jaguar C−500(窒素含量:1.15質量%〜1.45質量%)等のJaguarシリーズ(Rhodia社製);N−Hance CG14(窒素含量:1.25質量%〜1.55質量%)、N−Hance 3299(窒素含量:1.15質量%〜1.45質量%)、N−Hance CCG45(窒素含量:1.15質量%〜1.45質量%)等のN−Hanceシリーズ(Ashland社製、Aqualon部門);カチナールCG−100S(窒素含量:1.0質量%〜1.7質量%)(東邦化学工業株式会社製);Guarsafe JK140(窒素含量:1.3質量%〜1.7質量%)(JINGKIN CHEMISTRY COMPANY製)などが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のなめらかさの点から、窒素含量が1.15質量%〜1.45質量%であるN−Hance 3299、N−Hance CCG45、Jaguar C−500が特に好ましい。The nitrogen content of the cationized guar gum as the component (C1) is preferably 1% by mass to 1.8% by mass and more preferably 1.15% by mass to 1.45% by mass from the viewpoint of smoothness of the hair during rinsing. preferable.
The nitrogen content can be measured by decomposing the component (C1) with sulfuric acid to give ammonium sulfate and quantifying the ammonia by the Kjeldahl method. For details, refer to “Quasi-drug raw material standard 2006 (Pharmaceutical Daily)” general test method. It can be measured by the method described with reference to the nitrogen determination method.
As said (C1) component, a commercial item may be used and what was synthesize | combined suitably may be used. Examples of the commercially available products include Jaguar C14S (nitrogen content: 1.3% by mass to 1.7% by mass), Jaguar C-500 (nitrogen content: 1.15% by mass to 1.45% by mass), and the like. Series (manufactured by Rhodia); N-Hance CG14 (nitrogen content: 1.25% to 1.55% by mass), N-Hance 3299 (nitrogen content: 1.15% to 1.45% by mass), N -N-Hance series (manufactured by Ashland, Aqualon division) such as Hance CCG45 (nitrogen content: 1.15% by mass to 1.45% by mass); Katchinal CG-100S (nitrogen content: 1.0% by mass to 1.% by mass). 7% by mass) (manufactured by Toho Chemical Co., Ltd.); Guarsafe JK140 (nitrogen content: 1.3% by mass to 1.7% by mass) (JINGKIN CHEMIS) TRY COMPANY) and the like. These may be used alone or in combination of two or more. Among these, N-Hance 3299 having a nitrogen content of 1.15% by mass to 1.45% by mass in terms of the smoothness of the hair at the time of rinsing and the smoothness of the hair after drying in a hot and humid environment. N-Hance CCG45 and Jaguar C-500 are particularly preferable.
前記(C1)成分の含有量は、シャンプー組成物全量に対して、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のなめらかさの点から、0.08質量%〜4質量%が好ましく、0.1質量%〜2.8質量%がより好ましい。前記含有量が、0.08質量%未満であると、すすぎ時の毛髪のなめらかさが低下することがあり、4質量%を超えると、高温多湿環境下での乾燥後の毛髪のやわらかさが低下したり、使用性が悪くなることがある。 The content of the component (C1) is 0.08% by mass to the total amount of the shampoo composition from the viewpoint of the smoothness of the hair when rinsing and the smoothness of the hair after drying in a high-temperature and high-humidity environment. 4 mass% is preferable and 0.1 mass%-2.8 mass% is more preferable. When the content is less than 0.08% by mass, the smoothness of the hair at the time of rinsing may be reduced. When the content exceeds 4% by mass, the softness of the hair after drying in a high-temperature and high-humidity environment may be reduced. It may decrease or usability may deteriorate.
−(C2)カチオン化セルロース−
前記(C2)成分のカチオン化セルロースは、当業界においてPolyquaternium10、塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロースとも呼ばれるトリメチルアンモニウム置換エポキシドと反応させたヒドロキシエチルセルロースの塩である。
前記(C2)成分のカチオン化セルロースの窒素含量は、すすぎ時の毛髪のなめらかさの点から、1.5質量%〜2.2質量%が好ましく、1.7質量%〜2.0質量%がより好ましい。
前記(C2)成分のカチオン化セルロースの窒素含量は、前記(C1)成分のカチオン化グアーガムと同様にして測定することができる。-(C2) cationized cellulose-
The cationized cellulose of the component (C2) is a salt of hydroxyethyl cellulose reacted with a trimethylammonium substituted epoxide also called polyquaternium 10, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride in the industry. is there.
The nitrogen content of the cationized cellulose as the component (C2) is preferably 1.5% by mass to 2.2% by mass, and preferably 1.7% by mass to 2.0% by mass from the viewpoint of smoothness of the hair during rinsing. Is more preferable.
The nitrogen content of the cationized cellulose of the component (C2) can be measured in the same manner as the cationized guar gum of the component (C1).
前記(C2)成分としては、市販品を用いてもよく、適宜合成したものを用いてもよい。前記市販品としては、例えば、ダウ・ケミカル社製の商品名PolymerJRシリーズ(窒素含量:1.5質量%〜2.2質量%)、ダウ・ケミカル社製の商品名PolymerLRシリーズ(窒素含量:0.8質量%〜1.1質量%)、東邦化学工業株式会社製のカチナールHC(窒素含量:1.0質量%〜2.0質量%)、東邦化学工業株式会社製のLCシリーズ(窒素含量:0.5質量%〜1.5質量%)、ライオン株式会社製のレオガードシリーズ(窒素含量:0.6質量%〜2.0質量%)、MIWON社製のMICONIUM PQ10−J−400(窒素含量:1.5質量%〜2.2質量%)などが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、窒素含量1.5質量%〜2.2質量%のものがより好ましく、具体的には、市販品では、Polymer JR400(窒素含量:1.5質量%〜2.2質量%)、レオガードGP(窒素含量:1.6質量%〜2.0質量%)、レオガードKGP(窒素含量:1.6質量%〜2.0質量%)、MICONIUM PQ10−J−400(窒素含量:1.5質量%〜2.2質量%)などが挙げられる。 As said (C2) component, a commercial item may be used and what was synthesize | combined suitably may be used. Examples of the commercially available products include a product name Polymer JR series (nitrogen content: 1.5% by mass to 2.2% by mass) manufactured by Dow Chemical Company, and a product name Polymer LR series (nitrogen content: 0 manufactured by Dow Chemical Company). .8 mass% to 1.1 mass%), Kachinal HC manufactured by Toho Chemical Co., Ltd. (nitrogen content: 1.0 mass% to 2.0 mass%), LC series manufactured by Toho Chemical Industry Co., Ltd. : 0.5% by mass to 1.5% by mass), Lion Guard's Leoguard series (nitrogen content: 0.6% by mass to 2.0% by mass), MIWON's MICONIUM PQ10-J-400 ( Nitrogen content: 1.5% by mass to 2.2% by mass). These may be used alone or in combination of two or more. Among these, those having a nitrogen content of 1.5% by mass to 2.2% by mass are more preferable. Specifically, in the commercial product, Polymer JR400 (nitrogen content: 1.5% by mass to 2.2% by mass) Leogard GP (nitrogen content: 1.6% to 2.0% by mass), Leogard KGP (nitrogen content: 1.6% to 2.0% by mass), MICONIUM PQ10-J-400 (nitrogen content: 1 0.5 mass% to 2.2 mass%).
前記(C2)成分の含有量は、シャンプー組成物全量に対して、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のやわらかさの点から、0.01質量%〜1質量%が好ましく、0.05質量%〜0.7質量%がより好ましい。前記含有量が、0.01質量%未満であると、すすぎ時の毛髪のなめらかさが低下することがあり、1質量%を超えると、高温多湿環境下での乾燥後の毛髪のやわらかさが低下することがある。 The content of the component (C2) is 0.01% by mass to the total amount of the shampoo composition from the viewpoint of the smoothness of the hair at the time of rinsing and the softness of the hair after drying in a hot and humid environment. 1 mass% is preferable and 0.05 mass%-0.7 mass% are more preferable. When the content is less than 0.01% by mass, the smoothness of the hair at the time of rinsing may be reduced. When the content exceeds 1% by mass, the softness of the hair after drying in a high-temperature and high-humidity environment may be reduced. May decrease.
前記(C)成分が、前記(C1)成分のみの場合、高温多湿環境下での乾燥後の毛髪のやわらかさが低下することがあり、また、前記(C2)成分のみの場合、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のなめらかさが低下することがある。
前記(C1)成分と前記(C2)成分とからなる(C)成分の含有量は、シャンプー組成物全量に対して、0.1質量%〜4.8質量%が好ましく、0.2質量%〜3質量%がより好ましい。前記含有量が、0.1質量%未満であると、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のなめらかさが得られないことがあり、4.8質量%を超えると、シャンプー組成物がゲル化して粘度が高くなり使用性が悪くなることがある。When the component (C) is only the component (C1), the softness of the hair after drying in a hot and humid environment may be reduced, and when only the component (C2) is used, The smoothness of the hair and the smoothness of the hair after drying in a hot and humid environment may be reduced.
The content of the component (C) composed of the component (C1) and the component (C2) is preferably 0.1% by mass to 4.8% by mass, and 0.2% by mass with respect to the total amount of the shampoo composition. -3 mass% is more preferable. When the content is less than 0.1% by mass, the smoothness of the hair at the time of rinsing and the smoothness of the hair after drying in a hot and humid environment may not be obtained. If it exceeds 1, the shampoo composition may be gelled to increase the viscosity and deteriorate the usability.
<質量比(C1/C2)>
前記(C1)成分の含有量と前記(C2)成分の含有量との質量比(C1/C2)は、2〜20であり、2.5〜15が好ましい。前記質量比(C1/C2)が、2未満であると、すすぎ時の毛髪のなめらかさが悪くなることがあり、20を超えると、高温多湿環境下での乾燥後の毛髪のなめらかさが悪くなることがある。<Mass ratio (C1 / C2)>
The mass ratio (C1 / C2) between the content of the component (C1) and the content of the component (C2) is 2 to 20, and preferably 2.5 to 15. When the mass ratio (C1 / C2) is less than 2, the smoothness of the hair at the time of rinsing may deteriorate, and when it exceeds 20, the smoothness of the hair after drying in a hot and humid environment is poor. May be.
<(D)ジメチルポリシロキサン>
前記ジメチルポリシロキサンは、皮脂が多い、高温多湿環境下での泡の持続性、すすぎ時の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のべたつきのなさ、良好な使用性、及び外観安定性を付与するために含有される。
前記(D)成分は、ジメチルポリシロキサンであれば特に制限はなく、目的に応じて適宜選択することができ、例えば、トリメチルシリル基末端ジメチルポリシロキサン、シラノール基末端ジメチルポリシロキサンなどが挙げられる。これらの中でも、高温多湿環境下での乾燥後の毛髪のなめらかさを得ることができる点から、トリメチルシリル基末端ジメチルポリシロキサンが好ましい。<(D) Dimethylpolysiloxane>
The dimethylpolysiloxane is rich in sebum, persistence of foam in a hot and humid environment, smoothness of hair during rinsing, smoothness of hair after drying in a hot and humid environment, drying in a hot and humid environment It is contained in order to impart non-stickiness of the later hair, good usability, and appearance stability.
The component (D) is not particularly limited as long as it is dimethylpolysiloxane, and can be appropriately selected according to the purpose. Examples thereof include trimethylsilyl group-terminated dimethylpolysiloxane and silanol group-terminated dimethylpolysiloxane. Among these, trimethylsilyl group-terminated dimethylpolysiloxane is preferable from the viewpoint that smoothness of hair after drying in a hot and humid environment can be obtained.
前記ジメチルポリシロキサンの25℃における動粘度としては、高温多湿環境下での乾燥後の毛髪のなめらかさを付与することができる点から、10,000mm2/s〜30,000,000mm2/sが好ましく、100,000mm2/s〜10,000,000mm2/sがより好ましく、100,000mm2/s〜1,000,000mm2/sが特に好ましい。
前記ジメチルポリシロキサンの25℃における動粘度は、例えば、下記に示す方法により測定することができる。
まず、1g/100mL濃度のジメチルポリシロキサンのトルエン溶液を調製し、下記式(1)により、比粘度ηsp(25℃)を求める。次に、前記比粘度ηspを、下記式(2)に示すHugginsの関係式に代入し、固有粘度〔η〕を求める。前記Huggins定数は、中牟田,日化,77,588,1956に記載のものを用いる。
次に、前記固有粘度〔η〕を下記式(3)に示すA.Kolorlovの式に代入し、分子量Mを求める。最後に、前記分子量Mを下記式(4)に示すA.J.Barryの式に代入し、ジメチルポリシロキサンの動粘度ηを求めることができる。
ηsp=(η/η0)−1・・・式(1)
ηsp=〔η〕+K’〔η〕2・・・式(2)
〔η〕=0.215×10−4M0.65・・・式(3)
logη=1.00+0.0123M0.5・・・式(4)
前記式(1)中、「η0」は、トルエンの粘度を示し、「η」は、溶液の粘度を示す。
前記「η0」及び前記「η」は、化粧品原料基準一般試験法粘度測定法第1法に準拠して測定したものである。The kinematic viscosity at 25 ° C. of the dimethylpolysiloxane, from the viewpoint of capable of imparting smoothness of the hair after drying under high temperature and high humidity environment, 10,000mm 2 / s~30,000,000mm 2 / s more preferably from 100,000mm 2 / s~10,000,000mm 2 / s, 100,000mm 2 / s~1,000,000mm 2 / s is particularly preferred.
The kinematic viscosity at 25 ° C. of the dimethylpolysiloxane can be measured, for example, by the method shown below.
First, a toluene solution of dimethylpolysiloxane having a concentration of 1 g / 100 mL is prepared, and a specific viscosity ηsp (25 ° C.) is obtained by the following formula (1). Next, the specific viscosity [η] is determined by substituting the specific viscosity ηsp into the Huggins relational expression shown in the following formula (2). As the Huggins constant, those described in Nakamuta, Nikka, 77, 588, 1956 are used.
Next, the intrinsic viscosity [η] is represented by the following formula (3). Substituting it into the Kololov equation, the molecular weight M is determined. Finally, the molecular weight M is determined according to A. J. et al. By substituting into the Barry equation, the kinematic viscosity η of dimethylpolysiloxane can be determined.
ηsp = (η / η 0 ) −1 Formula (1)
ηsp = [η] + K ′ [η] 2 Formula (2)
[Η] = 0.215 × 10 −4 M 0.65 (Equation 3)
log η = 1.00 + 0.0123 M 0.5 (4)
In the formula (1), “η 0 ” indicates the viscosity of toluene, and “η” indicates the viscosity of the solution.
The “η 0 ” and the “η” are measured in accordance with the cosmetic raw material standard general test method viscosity measurement method No. 1.
前記(D)成分のジメチルポリシロキサンは、外観安定性の点から、乳化剤で予めエマルション化することが好ましい。前記(D)成分のジメチルポリシロキサンをエマルション化する際の乳化剤や乳化方法としては、特に制限はなく、目的に応じて適宜選択することができる。 The dimethylpolysiloxane as the component (D) is preferably emulsified in advance with an emulsifier from the viewpoint of appearance stability. There is no restriction | limiting in particular as an emulsifier and the emulsification method at the time of emulsifying the dimethylpolysiloxane of the said (D) component, According to the objective, it can select suitably.
前記エマルション中の前記(D)成分のジメチルポリシロキサンの数平均粒径は、すすぎ時の毛髪のなめらかさがよく、乾燥後の毛髪のべたつきのなさの点から、0.5μm〜60μmが好ましく、10μm〜50μmがより好ましく、15μm〜40μmが特に好ましい。
前記数平均粒径が、0.5μm未満であると、高温多湿環境下での乾燥後の毛髪のべたつきが生じてしまうことがあり、60μmを超えると、すすぎ時の毛髪のなめらかさが低下することがある。
ここで、前記数平均粒径は、光学顕微鏡で観察した粒子の像を任意に100ヶ所コンピューターに取り込み、同倍率とした上で、画像処理(例えば、二次元画像解析ソフトウェアWinROOF等)することにより求められる。The number average particle diameter of the dimethylpolysiloxane of the component (D) in the emulsion is good in smoothness of hair at the time of rinsing, and is preferably 0.5 μm to 60 μm from the point of non-stickiness of the hair after drying, 10 micrometers-50 micrometers are more preferable, and 15 micrometers-40 micrometers are especially preferable.
If the number average particle size is less than 0.5 μm, the hair may become sticky after drying in a high-temperature and high-humidity environment, and if it exceeds 60 μm, the smoothness of the hair during rinsing may be reduced. Sometimes.
Here, the number average particle diameter is obtained by arbitrarily capturing images of particles observed with an optical microscope into 100 computers, setting the same magnification, and performing image processing (for example, two-dimensional image analysis software WinROOF). Desired.
前記(D)成分のジメチルポリシロキサンのエマルションとしては、市販品を用いてもよく、適宜合成したものを用いてもよい。前記市販品としては、例えば、BY22−029〔25℃での動粘度:100,000mm2/s、数平均粒径:0.5μm〕(東レ・ダウコーニング株式会社製)、DC−7137〔25℃での動粘度:600,000mm2/s、数平均粒径:35μm〕(ダウコーニング社製);KM−902〔25℃での動粘度:500,000mm2/s、数平均粒径:0.5μm〕(以上、信越化学工業株式会社製);レオフローDMS−55〔25℃での動粘度:100,000mm2/s、数平均粒径:0.5μm〕、レオフローDMS−60〔25℃での動粘度:10,000,000mm2/s:4,000,000mm2/s:1,000mm2/s=15:15:70(質量比)、数平均粒径:0.9μm〕(以上、一方社油脂工業株式会社製);EMU120〔25℃での動粘度:900,000mm2/s、数平均粒径:20μm〕(モメンティブ社製)などが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のべたつきのなさの点から、DC−7137が好ましい。As the emulsion of component (D) dimethylpolysiloxane, commercially available products may be used, or those synthesized as appropriate may be used. Examples of the commercially available product include BY22-029 [kinematic viscosity at 25 ° C .: 100,000 mm 2 / s, number average particle size: 0.5 μm] (manufactured by Toray Dow Corning Co., Ltd.), DC-7137 [25 Kinematic viscosity at 600 ° C .: 600,000 mm 2 / s, number average particle size: 35 μm] (manufactured by Dow Corning); KM-902 [kinematic viscosity at 25 ° C .: 500,000 mm 2 / s, number average particle size: 0.5 μm] (manufactured by Shin-Etsu Chemical Co., Ltd.); Rheoflow DMS-55 [kinematic viscosity at 25 ° C .: 100,000 mm 2 / s, number average particle size: 0.5 μm], Rheoflow DMS-60 [25 kinematic viscosity at ℃: 10,000,000mm 2 / s: 4,000,000mm 2 / s: 1,000mm 2 / s = 15: 15: 70 ( mass ratio), number average particle size: 0.9 .mu.m] (End of the above Industry Co., Ltd.); EMU120 Ltd. [kinematic viscosity at 25 ℃:: 900,000mm 2 / s , a number average particle size of 20μm] (Momentive Corp.). These may be used alone or in combination of two or more. Among these, DC-7137 is preferable from the viewpoint of smoothness of the hair at the time of rinsing and non-stickiness of the hair after drying in a hot and humid environment.
前記(D)成分のジメチルポリシロキサンの含有量は、皮脂が多い高温多湿環境下でも泡の持続性が得られ、すすぎ時の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のべたつきのなさの点から、0.1質量%〜4.8質量%が好ましく、0.5質量%〜3質量%がより好ましい。前記の含有量が、0.1質量%未満であると、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のなめらかさが得られないことがあり、4.8質量%を超えると、高温多湿環境下での乾燥後に毛髪のべたつきが生じたり、皮脂が多い高温多湿環境下で泡の持続性、及び使用性が劣ることがある。 The content of the component (D), dimethylpolysiloxane, provides foam persistence even in a hot and humid environment with a lot of sebum, smoothness of the hair when rinsing, smoothness of the hair after drying in a hot and humid environment From the viewpoint of the non-stickiness of the hair after drying in a hot and humid environment, 0.1% by mass to 4.8% by mass is preferable, and 0.5% by mass to 3% by mass is more preferable. If the content is less than 0.1% by mass, the smoothness of the hair at the time of rinsing and the smoothness of the hair after drying in a hot and humid environment may not be obtained. If it exceeds 50%, the hair may become sticky after drying in a hot and humid environment, or the durability and usability of the foam may be poor in a hot and humid environment with a lot of sebum.
<(E)アミノ変性シリコーン>
前記アミノ変性シリコーンは、皮脂が多い高温多湿環境下における洗浄力、すすぎ時の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のべたつきのなさ、良好な使用性、及び外観安定性を付与するために含有される。
前記(E)成分のアミノ変性シリコーンとしては、例えば、アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体(以下、「アモジメチコン」と称することがある)、アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体(以下、「アミノエチルアミノプロピルメチコン・ジメチコン共重合体」と称することがある)、アミノ変性オルガノポリシロキサン鎖とポリオキシアルキレン鎖とのブロック鎖を有する共重合体(以下、「直鎖アミノポリエーテル変性シリコーン」と称することがある)、アミノプロピルジメチコンなどが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、すすぎ時の毛髪のなめらかさを付与することができる点から、アモジメチコン、直鎖アミノポリエーテル変性シリコーンが好ましい。<(E) Amino-modified silicone>
The amino-modified silicone is a detergency in a high-temperature and high-humidity environment with a lot of sebum, smoothness of hair when rinsed, smoothness of hair after drying in a high-temperature and high-humidity environment, and hair after drying in a high-temperature and high-humidity environment. It is contained for imparting non-stickiness, good usability, and appearance stability.
Examples of the amino-modified silicone of the component (E) include aminoethylaminopropylsiloxane / dimethylsiloxane copolymer (hereinafter sometimes referred to as “amodimethicone”), aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer. A copolymer (hereinafter sometimes referred to as “aminoethylaminopropylmethicone / dimethicone copolymer”), a copolymer having a block chain of an amino-modified organopolysiloxane chain and a polyoxyalkylene chain (hereinafter referred to as “linear amino acid”). And may be referred to as “polyether-modified silicone”), aminopropyl dimethicone, and the like. These may be used alone or in combination of two or more. Among these, amodimethicone and linear amino polyether-modified silicone are preferable from the viewpoint that the smoothness of the hair at the time of rinsing can be imparted.
前記(E)成分のアミノ変性シリコーンは、外観安定性の点から、乳化剤で予めエマルション化することが好ましい。前記(E)成分のアミノ変性シリコーンをエマルション化する際の乳化剤や乳化方法としては、特に制限はなく、目的に応じて適宜選択することができる。 The amino-modified silicone as the component (E) is preferably pre-emulsified with an emulsifier from the viewpoint of appearance stability. There is no restriction | limiting in particular as an emulsifier and the emulsification method at the time of emulsifying the amino modified silicone of the said (E) component, According to the objective, it can select suitably.
前記(E)成分のアミノ変性シリコーンのエマルションとしては、市販品を用いてもよく、適宜合成したものを用いてもよい。前記市販品としては、例えば、SM8904CE、SM8704C、BY22−079、FZ−4671(アモジメチコンエマルション、東レ・ダウコーニング株式会社製)、DC2−8194(ダウコーニング社製)、KF−8004、KF−867S、KF−880(以上、信越化学工業株式会社製)等のアモジメチコン;KF−8005(信越化学工業株式会社製)等のアミノエチルアミノプロピルメチコン・ジメチコン共重合体;SILSTYLE 104(ビスイソブチルPEG−14/アモジメチコン)コポリマー、SILSTYLE 201(ビスイソブチルPEG−14/アモジメチコン)コポリマー、SILSTYLE 401(ビスブチロキシアモジメチコン/PEG−60)コポリマー(以上、東レ・ダウコーニング株式会社製)等の直鎖アミノポリエーテル変性シリコーン;KF−8015、KF−865、KF−8017、KF−8018、KF−8020(信越化学工業株式会社製)等のアミノプロピルジメチコン、などが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、SILSTYLE 401、SM8704Cが好ましい。 As the emulsion of the amino-modified silicone as the component (E), a commercially available product may be used, or an appropriately synthesized product may be used. Examples of the commercially available products include SM8904CE, SM8704C, BY22-079, FZ-4671 (Amodimethicone emulsion, manufactured by Toray Dow Corning), DC2-8194 (manufactured by Dow Corning), KF-8004, and KF-867S. Amodimethicone such as KF-880 (manufactured by Shin-Etsu Chemical Co., Ltd.); aminoethylaminopropyl-methicone / dimethicone copolymer such as KF-8005 (manufactured by Shin-Etsu Chemical Co., Ltd.); SILSTLE 104 (bisisobutyl PEG- 14 / amodimethicone) copolymer, SILSTLE 201 (bisisobutyl PEG-14 / amodimethicone) copolymer, SILSTLE 401 (bisbutoxyoxydimethicone / PEG-60) copolymer (toray, Dow Corning Toray) Linear amino polyether-modified silicone such as KF-8015, KF-865, KF-8017, KF-8018, KF-8020 (manufactured by Shin-Etsu Chemical Co., Ltd.), and the like. . These may be used alone or in combination of two or more. Among these, SILSTLE 401 and SM8704C are preferable.
前記(E)成分のアミノ変性シリコーンの含有量は、シャンプー組成物全量に対して、0.01質量%〜1.5質量%が好ましく、0.1質量%〜1質量%がより好ましい。前記含有量が、0.01質量%未満であると、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のなめらかさが得られないことがあり、1.5質量%を超えると、高温多湿環境下での乾燥後の毛髪にべたつきが生じることがある。 The content of the amino-modified silicone as the component (E) is preferably 0.01% by mass to 1.5% by mass and more preferably 0.1% by mass to 1% by mass with respect to the total amount of the shampoo composition. When the content is less than 0.01% by mass, the smoothness of the hair during rinsing and the smoothness of the hair after drying in a hot and humid environment may not be obtained. If it exceeds 1, the hair after drying in a hot and humid environment may become sticky.
前記(D)成分と前記(E)成分との合計含有量は、高温多湿環境下での乾燥後の毛髪のべたつきを抑える点から、シャンプー組成物全量に対して、0.15質量%〜5質量%が好ましく、0.8質量%〜3.8質量%がより好ましい。前記(D)成分と(E)成分との合計含有量が、0.15質量%未満であると、すすぎ時の毛髪のなめらかさ、及び高温多湿環境下での乾燥後の毛髪のなめらかさが得られないことがあり、5質量%を超えると、皮脂が多い高温多湿環境下において洗浄力が得られず、高温多湿環境下での乾燥後に毛髪がべたつき、使用性が低下することがある。 The total content of the component (D) and the component (E) is 0.15% by mass to 5% with respect to the total amount of the shampoo composition from the viewpoint of suppressing the stickiness of the hair after drying in a hot and humid environment. % By mass is preferable, and 0.8% by mass to 3.8% by mass is more preferable. When the total content of the component (D) and the component (E) is less than 0.15% by mass, the smoothness of the hair at the time of rinsing and the smoothness of the hair after drying in a hot and humid environment When it exceeds 5% by mass, detergency cannot be obtained in a high-temperature and high-humidity environment with a lot of sebum, and the hair may become sticky after drying in a high-temperature and high-humidity environment, resulting in reduced usability.
<その他の成分>
本発明のシャンプー組成物には、前記(A)〜前記(E)成分以外にも通常のシャンプー組成物に用いられているその他の成分を含有することができる。
前記その他の成分としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、油分、アルコール類、保湿剤、増粘剤、防腐剤、酸化防止剤、キレート剤、pH調整剤、紫外線吸収・散乱剤、ビタミン類、アミノ酸類、香料、色素、水などが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。<Other ingredients>
In addition to the components (A) to (E), the shampoo composition of the present invention may contain other components used in ordinary shampoo compositions.
There is no restriction | limiting in particular as said other component, According to the objective, it can select suitably, For example, oil content, alcohol, moisturizer, thickener, antiseptic | preservative, antioxidant, chelating agent, pH adjuster UV absorbers / scatterers, vitamins, amino acids, fragrances, pigments, water and the like. These may be used alone or in combination of two or more.
前記油分としては、例えば、ヒマシ油、オリーブ油、カカオ油、硬化パーム油、椿油、ヤシ油、木ロウ、ホホバ油、グレープシード油、アボガド油等の植物油脂類又はそれらのエステル化合物;ミンク油、卵黄油等の動物油脂類;ミツロウ、鯨ロウ、ラノリン、水添ラノリン、カルナウバロウ、キャンデリラロウ等のロウ類;流動パラフィン、スクワラン、マイクロクリスタリンワックス、セレシンワックス、パラフィンワックス、ワセリン等の炭化水素類;ラウリン酸、ミリスチン酸、ステアリン酸、オレイン酸、イソステアリン酸、ベヘニン酸等の天然及び合成脂肪酸類;グリセロールトリ−2−エチルヘキサン酸エステル、2−エチルヘキシルステアレート、ステアリン酸ブチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、オレイン酸オクチルドデシル、コレステロールオレート等のエステル類などが挙げられる。 Examples of the oil component include castor oil, olive oil, cacao oil, hydrogenated palm oil, coconut oil, coconut oil, tree wax, jojoba oil, grape seed oil, avocado oil and the like, or their ester compounds; mink oil, Animal fats such as egg yolk oil; waxes such as beeswax, whale wax, lanolin, hydrogenated lanolin, carnauba wax, candelilla wax; hydrocarbons such as liquid paraffin, squalane, microcrystalline wax, ceresin wax, paraffin wax, petroleum jelly Natural and synthetic fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid, isostearic acid, behenic acid; glycerol tri-2-ethylhexanoate, 2-ethylhexyl stearate, butyl stearate, isopropyl myristate, Isopropy palmitate , Octyldodecyl myristate, octyldodecyl oleate, and the like esters such as cholesterol oleate.
前記アルコール類としては、例えば、セチルアルコール、オレイルアルコール、ステアリルアルコール、ヘキシルデカノール、オクチルドデカノール、ラウリルアルコール等の天然及び合成高級アルコール類などが挙げられる。 Examples of the alcohols include natural and synthetic higher alcohols such as cetyl alcohol, oleyl alcohol, stearyl alcohol, hexyl decanol, octyl decanol, and lauryl alcohol.
前記保湿剤としては、例えば、1,3−ブタンジオール、イソプレングリコール、1,2−ペンタンジオール、エチレングリコール、プロピレングリコール、ジエチレングリコール、ジプロピレングリコール、ジエチレングリコールモノアルキルエーテル、ポリエチレングリコール(平均分子量が190〜1,650)、ポリプロピレングリコール、ポリエチレングリコール・ポリプロピレングリコール、硬化ヒマシ油(30E.O.)、グリセリン、ジグリセリン、トリグリセリン、ポリグリセリン、ソルビトールなどが挙げられる。 Examples of the humectant include 1,3-butanediol, isoprene glycol, 1,2-pentanediol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, diethylene glycol monoalkyl ether, polyethylene glycol (average molecular weight of 190 to 1,650), polypropylene glycol, polyethylene glycol / polypropylene glycol, hydrogenated castor oil (30EO), glycerin, diglycerin, triglycerin, polyglycerin, sorbitol and the like.
前記増粘剤としては、例えば、アルギン酸ナトリウム、キサンタンガム、珪酸アルミニウム、マルメロ種子抽出物、トラガントガム、デンプン等の天然高分子;メチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、カルボキシメチルセルロース、可溶性デンプン等の半合成高分子;カルボキシビニルポリマー、ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸、メタクリロイルエチルベタイン・メタクリル酸エステル共重合体等の合成高分子化合物などが挙げられる。 Examples of the thickener include natural polymers such as sodium alginate, xanthan gum, aluminum silicate, quince seed extract, tragacanth gum and starch; semi-synthetic polymers such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose and soluble starch. Molecules: Synthetic polymer compounds such as carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, methacryloylethylbetaine / methacrylic acid ester copolymer, and the like.
前記防腐剤としては、例えば、安息香酸塩、ソルビン酸塩、デヒドロ酢酸塩、パラオキシ安息香酸エステル、2,4,4’−トリクロロ−2’−ヒドロキシジフェニルエーテル、3,4,4’−トリクロロカルバニリド、塩化ベンザルコニウム、ヒノキチオール、レゾルシン、メチルクロロイソチアゾリノン・メチルイソチアゾリノン液(商品名:ケーソンCG;ローム・アンド・ハース・ジャパン社製)、サリチル酸、ペンタンジオール、フェノキシエタノール、エタノールなどが挙げられる。 Examples of the preservative include benzoate, sorbate, dehydroacetate, p-hydroxybenzoate, 2,4,4′-trichloro-2′-hydroxydiphenyl ether, 3,4,4′-trichlorocarbani Lido, benzalkonium chloride, hinokitiol, resorcin, methylchloroisothiazolinone / methylisothiazolinone solution (trade name: Caisson CG; manufactured by Rohm and Haas Japan), salicylic acid, pentanediol, phenoxyethanol, ethanol, etc. Can be mentioned.
前記酸化防止剤としては、例えば、ジブチルヒドロキシトルエン、ブチルヒドロキシアニソール、アスコルビン酸などが挙げられる。
前記キレート剤としては、例えば、エデト酸二ナトリウム、エチレンジアミン四酢酸塩、ヘキサメタリン酸塩、グルコン酸などが挙げられる。
前記pH調整剤としては、例えば、水酸化ナトリウム、水酸化カリウム、クエン酸、コハク酸、硫酸、モノエタノールアミン、2−アミノ−2−メチル−1−プロパノール、トリエタノールアミン、アンモニア水、トリイソプロパノールアミン、リン酸、グリコール酸などが挙げられる。
前記紫外線吸収・散乱剤としては、例えば、2−ヒドロキシ−4−メトキシベンゾフェノン、オクチルジメチルパラアミノベンゾエート、エチルヘキシルパラメトキシサイナメート、酸化チタン、カオリン、タルクなどが挙げられる。
前記ビタミン類としては、例えば、ビタミンA、ビタミンB群、ビタミンC、ビタミンD、ビタミンE、ビタミンF、ビタミンK、ビタミンP、ビタミンU、カルニチン、フェルラ酸、γ−オリザノール、α−リポ酸、オロット酸、又はこれらの誘導体などが挙げられる。
前記アミノ酸類としては、例えば、グリシン、アラニン、バリン、ロイシン、イソロイシン、フェニルアラニン、トリプトファン、シスチン、システイン、メチオニン、プロリン、ヒドロキシプロリン、アスパラギン酸、グルタミン酸、アルギニン、ヒスチジン、リジン又はこれらの誘導体などが挙げられる。Examples of the antioxidant include dibutylhydroxytoluene, butylhydroxyanisole, ascorbic acid and the like.
Examples of the chelating agent include disodium edetate, ethylenediaminetetraacetate, hexametaphosphate, and gluconic acid.
Examples of the pH adjuster include sodium hydroxide, potassium hydroxide, citric acid, succinic acid, sulfuric acid, monoethanolamine, 2-amino-2-methyl-1-propanol, triethanolamine, aqueous ammonia, and triisopropanol. Examples include amine, phosphoric acid, and glycolic acid.
Examples of the ultraviolet absorbing / scattering agent include 2-hydroxy-4-methoxybenzophenone, octyldimethylparaaminobenzoate, ethylhexylparamethoxycynamate, titanium oxide, kaolin, and talc.
Examples of the vitamins include vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, vitamin U, carnitine, ferulic acid, γ-oryzanol, α-lipoic acid, Examples include orotic acid and derivatives thereof.
Examples of the amino acids include glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine, and derivatives thereof. It is done.
前記香料及び香料組成物としては、例えば、特開2003−300811号公報の段落[0021]〜[0035]に記載した香料成分、更に特開2003−300811号公報の段落[0050]に記載した香料用溶剤などが挙げられる。前記香料組成物は、前記香料成分、香料用溶剤、香料安定化剤等からなる混合物である。
前記香料用溶剤の香料組成物中における含有量は、0.1質量%〜99質量%が好ましく、0.3質量%〜50質量%がより好ましい。
前記香料安定化剤としては、例えば、ジブチルヒドロキシトルエン、ブチルヒドロキシアニソール、ビタミンE又はその誘導体、カテキン化合物、フラボノイド化合物、ポリフェノール化合物などが挙げられる。これらの中でも、ジブチルヒドロキシトルエンが好ましい。
前記香料安定化剤の香料組成物中における含有量は、0.0001質量%〜10質量%が好ましく、0.001質量%〜5質量%がより好ましい。
前記香料組成物の含有量は、シャンプー組成物全量に対して、0.005質量%〜40質量%が好ましく、0.01質量%〜10質量%がより好ましい。Examples of the fragrance and the fragrance composition include the fragrance components described in paragraphs [0021] to [0035] of JP-A-2003-300121, and further the fragrance described in paragraph [0050] of JP-A-2003-300111. Solvents for use. The fragrance composition is a mixture comprising the fragrance component, a fragrance solvent, a fragrance stabilizer, and the like.
0.1 mass%-99 mass% are preferable, and, as for content in the fragrance | flavor composition of the said fragrance | flavor solvent, 0.3 mass%-50 mass% are more preferable.
Examples of the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E or a derivative thereof, a catechin compound, a flavonoid compound, a polyphenol compound, and the like. Among these, dibutylhydroxytoluene is preferable.
The content of the fragrance stabilizer in the fragrance composition is preferably 0.0001% by mass to 10% by mass, and more preferably 0.001% by mass to 5% by mass.
0.005 mass%-40 mass% are preferable with respect to the shampoo composition whole quantity, and, as for content of the said fragrance | flavor composition, 0.01 mass%-10 mass% are more preferable.
<製造方法>
本発明のシャンプー組成物の製造方法としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、前記(A)成分、前記(B)成分、前記(C)成分、前記(D)成分、及び前記(E)成分、必要に応じて前記その他の成分を添加し、攪拌混合することにより、シャンプー組成物を製造することができる。<Manufacturing method>
There is no restriction | limiting in particular as a manufacturing method of the shampoo composition of this invention, According to the objective, it can select suitably, For example, said (A) component, said (B) component, said (C) component, said ( A shampoo composition can be manufactured by adding D) component, said (E) component, and the said other component as needed, and stirring and mixing.
<pH>
前記シャンプー組成物のpHとしては、特に制限はなく、目的に応じて適宜選択することができるが、25℃で、5〜6が好ましい。
前記pHは、前記シャンプー組成物をpHメーター(HM−30G、東亜ディーケーケー株式会社製)を用いて25℃で測定することができる。
前記シャンプー組成物のpHは、前記pH調整剤を用いて調整することができる。<PH>
There is no restriction | limiting in particular as pH of the said shampoo composition, Although it can select suitably according to the objective, 5-6 are preferable at 25 degreeC.
The pH can be measured at 25 ° C. using a pH meter (HM-30G, manufactured by Toa DKK Corporation) for the shampoo composition.
The pH of the shampoo composition can be adjusted using the pH adjuster.
<容器>
前記シャンプー組成物は、容器に充填して用いることができる。前記容器としては、特に制限なく、目的に応じて適宜選択することができ、例えば、アルミニウムラミネートチューブ、EVALチューブ、アルミニウムチューブ、ガラス蒸着プラスチックチューブ等のチューブ、機械的又は差圧によるディスペンサー容器、スクイーズ容器、ラミネートフィルム容器、スポイト容器、ボトル容器、ポンプ式容器などが挙げられる。
前記ラミネートフィルムの材質としては、例えば、ポリエチレン、ポリエチレンテレフタレート、ポリエステル、二軸延伸ポリプロピレン、無延伸ポリプロピレン、ポリアクリロニトリル、エチレン−酢酸ビニル共重合体等の合成樹脂、紙、アルミニウム蒸着プラスチックなどが挙げられる。また、前記ラミネートフィルムの構造としては、通常2層以上の多層を有しており、強度、柔軟性、耐候性等を考慮し、一般的には2層〜5層が好ましい。
前記ボトルの材質としては、例えば、ポリエチレン、ポリプロピレン、ポリエチレンテレフタレート、ポリスチレン、ポリ塩化ビニル、エチレン−ビニルアルコール樹脂、アクリロニトリル・スチレン樹脂、ABS樹脂、ポリアミド樹脂、又はガラスなどが挙げられる。また、前記容器の構造としては、単層又は2層以上の層構造とすることが好ましい。<Container>
The shampoo composition can be used by filling a container. The container is not particularly limited and can be appropriately selected according to the purpose. For example, aluminum laminate tube, EVAL tube, aluminum tube, glass-deposited plastic tube tube, mechanical or differential pressure dispenser container, squeeze Examples include containers, laminate film containers, dropper containers, bottle containers, and pump-type containers.
Examples of the material of the laminate film include polyethylene, polyethylene terephthalate, polyester, biaxially stretched polypropylene, unstretched polypropylene, polyacrylonitrile, a synthetic resin such as an ethylene-vinyl acetate copolymer, paper, and aluminum vapor-deposited plastic. . Moreover, as a structure of the said laminate film, it has normally two or more layers, and generally 2 layers-5 layers are preferable in consideration of an intensity | strength, a softness | flexibility, a weather resistance, etc.
Examples of the material of the bottle include polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile / styrene resin, ABS resin, polyamide resin, and glass. Further, the structure of the container is preferably a single layer or a layer structure of two or more layers.
<用途>
本発明のシャンプー組成物の用途については、特に制限はなく、目的に応じて適宜選択することができ、例えば、シャンプー、リンスインシャンプー(コンディショニングシャンプー)などが挙げられる。また、一般のシャンプー組成物に限定されるものではなく、フケ防止効果等を訴求した医薬部外品を包含するものである。なお、ヒトの毛髪以外にも、ペット等の動物の毛にも使用することができる。<Application>
There is no restriction | limiting in particular about the use of the shampoo composition of this invention, According to the objective, it can select suitably, For example, a shampoo, rinse-in shampoo (conditioning shampoo) etc. are mentioned. Moreover, it is not limited to a general shampoo composition, but includes quasi-drugs that promote antidandruff effects and the like. In addition to human hair, it can also be used for animal hair such as pets.
以下、本発明の実施例を説明するが、本発明は、これらの実施例に何ら限定されるものではない。なお、以下の実施例及び比較例に記載のシャンプー組成物の含有量は全て純分換算値である。 Examples of the present invention will be described below, but the present invention is not limited to these examples. In addition, all content of the shampoo composition as described in a following example and a comparative example is a pure part conversion value.
(実施例1〜37及び比較例1〜17)
下記表1〜表10に示す組成及び含有量のシャンプー組成物を以下の製造方法に基づいて製造した。(Examples 1-37 and Comparative Examples 1-17)
The shampoo compositions having the compositions and contents shown in Tables 1 to 10 below were produced based on the following production method.
<シャンプー組成物の製造方法>
下記表1〜表10に示す(A)成分、(B)成分、(C)成分、(D)成分、(E)成分、及び共通成分を、下記表1〜表10に示す含有量(純分換算値;質量%)となるように添加し、25℃で30分間攪拌した。ここに、クエン酸を添加してpH(25℃)を5.8に調整することにより、実施例1〜37及び比較例1〜17のシャンプー組成物を得た。なお、pHは、pHメーター(HM−30G、東亜ディーケーケー株式会社製)を用いて25℃で測定した。<Method for producing shampoo composition>
The contents (pure) of (A) component, (B) component, (C) component, (D) component, (E) component, and common component shown in Table 1 to Table 10 below are shown in Table 1 to Table 10 below. (Minute conversion value: mass%), and stirred at 25 ° C. for 30 minutes. The shampoo compositions of Examples 1 to 37 and Comparative Examples 1 to 17 were obtained by adding citric acid thereto and adjusting the pH (25 ° C.) to 5.8. The pH was measured at 25 ° C. using a pH meter (HM-30G, manufactured by Toa DKK Corporation).
得られた各シャンプー組成物について、下記評価方法に基づいて、諸特性を評価した。結果を表1〜表10に併記した。 About each obtained shampoo composition, various characteristics were evaluated based on the following evaluation method. The results are shown in Tables 1 to 10.
<評価方法>
女性専門パネル20名において、高温多湿環境下である温度27℃で湿度70%RHの部屋でじんわり汗をかく程度に運動をした後、十分濡らした毛髪に、各シャンプー組成物6mLを塗布し、十分に泡立てて洗髪後、水道水で温度40℃、流量250mL/3秒間のシャワーで洗い流し、タオルドライ後、自然乾燥させた。
シャンプー洗浄時の評価については、以下のようにして、「使用性」、「泡の持続性」、「洗浄力」、「すすぎ時の毛髪のなめらかさ」の評価を行なった。乾燥後の評価については、以下のようにして、「乾燥後の毛髪のなめらかさ」、「乾燥後の毛髪のやわらかさ」、「乾燥後の毛髪のべたつきのなさ」の評価を行なった。また、洗浄から乾燥までを通して、以下のようにして、「刺激のなさ」を評価した。さらに、以下のようにして、「外観安定性」を評価した。<Evaluation method>
In 20 female professional panelists, after exercising to a level of sweating in a room with a temperature of 27 ° C and a humidity of 70% RH in a hot and humid environment, 6 mL of each shampoo composition was applied to sufficiently wet hair. After sufficiently foaming and washing the hair, it was rinsed with a tap water at a temperature of 40 ° C. and a flow rate of 250 mL / 3 seconds, dried with a towel and then naturally dried.
Regarding the evaluation at the time of shampoo washing, “usability”, “sustainability of foam”, “detergency”, and “smoothness of hair during rinsing” were evaluated as follows. Regarding the evaluation after drying, evaluations of “smoothness of the hair after drying”, “softness of the hair after drying”, and “non-stickiness of the hair after drying” were performed as follows. In addition, from the washing to drying, “no irritation” was evaluated as follows. Furthermore, “appearance stability” was evaluated as follows.
<<使用性>>
各シャンプー組成物の「使用性」について、女性専門パネル20名のうち「使用性が良好」と判断した人数により、下記評価基準に基づき、評価した。ここで、「シャンプー組成物の使用性」とは、ポリエチレンボトル(吉田硝子株式会社製、YP−200K)からの各シャンプー組成物の出しやすさを意味する。
[判断基準]
◎:15名以上が「良好」と判断した
○:11名以上14名以下が「良好」と判断した
△:7名以上10名以下が「良好」と判断した
×:6名以下が「良好」と判断した<< Usability >>
The “usefulness” of each shampoo composition was evaluated based on the following evaluation criteria by the number of women judged as “useful” among the 20 female specialist panels. Here, “usability of shampoo composition” means the ease of taking out each shampoo composition from a polyethylene bottle (Yoshida Glass Co., Ltd., YP-200K).
[Judgment criteria]
◎: 15 or more people judged “good” ○: 11 or more people 14 or less judged “good” Δ: 7 or more people 10 or less judged “good” ×: 6 people or less judged “good” "
<<泡の持続性>>
各シャンプー組成物の「泡の持続性」について、女性専門パネル20名のうち「良好」と判断した人数により、下記評価基準に基づき、評価した。ここで、「泡の持続性が良好」とは、洗い終わりまで一定の泡量を保っていることを意味する。
[判断基準]
◎:15名以上が「良好」と判断した
○:11名以上14名以下が「良好」と判断した
△:7名以上10名以下が「良好」と判断した
×:6名以下が「良好」と判断した<< foam persistence >>
The “sustainability of foam” of each shampoo composition was evaluated based on the following evaluation criteria by the number of women judged as “good” among the 20 female specialized panels. Here, “good foam sustainability” means that a certain amount of foam is maintained until the end of washing.
[Judgment criteria]
◎: 15 or more people judged “good” ○: 11 or more people 14 or less judged “good” Δ: 7 or more people 10 or less judged “good” ×: 6 people or less judged “good” "
<<洗浄力>>
各シャンプー組成物の「洗浄力」について、女性専門パネル20名のうち「良好」と判断した人数により、下記評価基準に基づき評価した。ここで、「洗浄力が良好」とは、頭皮や髪の皮脂が取れて、すっきりした感じであることを意味する。
[判断基準]
◎:15名以上が「良好」と判断した
○:11名以上14名以下が「良好」と判断した
△:7名以上10名以下が「良好」と判断した
×:6名以下が「良好」と判断した<< Detergency >>
The “detergency” of each shampoo composition was evaluated based on the following evaluation criteria by the number of women judged as “good” among the 20 women-specialized panels. Here, “good detergency” means that the scalp and hair sebum is removed and the skin feels clean.
[Judgment criteria]
◎: 15 or more people judged “good” ○: 11 or more people 14 or less judged “good” Δ: 7 or more people 10 or less judged “good” ×: 6 people or less judged “good” "
<<すすぎ時の毛髪のなめらかさ>>
各シャンプー組成物の「すすぎ時の毛髪のなめらかさ」について、女性専門パネル20名のうち「すすぎ時の毛髪のなめらかさが良好」と判断した人数により、下記評価基準に基づき、評価した。
[判断基準]
◎:15名以上が「良好」と判断した
○:11名以上14名以下が「良好」と判断した
△:7名以上10名以下が「良好」と判断した
×:6名以下が「良好」と判断した<< Smoothness of hair during rinsing >>
The “smoothness of hair at the time of rinsing” of each shampoo composition was evaluated based on the following evaluation criteria by the number of female panelists who judged that “the smoothness of the hair at the time of rinsing was good”.
[Judgment criteria]
◎: 15 or more people judged “good” ○: 11 or more people 14 or less judged “good” Δ: 7 or more people 10 or less judged “good” ×: 6 people or less judged “good” "
<<乾燥後の毛髪のなめらかさ>>
各シャンプー組成物の「乾燥後の毛髪のなめらかさ」について、女性専門パネル20名のうち「乾燥後の毛髪のなめらかさが良好」と判断した人数により、下記評価基準に基づき、評価した。
[判断基準]
◎:15名以上が「良好」と判断した
○:11名以上14名以下が「良好」と判断した
△:7名以上10名以下が「良好」と判断した
×:6名以下が「良好」と判断した<< Smoothness of hair after drying >>
The “smoothness of the hair after drying” of each shampoo composition was evaluated based on the following evaluation criteria by the number of female panelists who judged that “the smoothness of the hair after drying” was good.
[Judgment criteria]
◎: 15 or more people judged “good” ○: 11 or more people 14 or less judged “good” Δ: 7 or more people 10 or less judged “good” ×: 6 people or less judged “good” "
<<乾燥後の毛髪のやわらかさ>>
各シャンプー組成物の「乾燥後の毛髪のやわらかさ」について、女性専門パネル20名のうち「乾燥後の毛髪のやわらかさが良好」と判断した人数により、下記評価基準に基づき、評価した。
[判断基準]
◎:15名以上が「良好」と判断した
○:11名以上14名以下が「良好」と判断した
△:7名以上10名以下が「良好」と判断した
×:6名以下が「良好」と判断した<< Softness of hair after drying >>
The “softness of the hair after drying” of each shampoo composition was evaluated based on the following evaluation criteria by the number of women judged as “softness of the hair after drying” among the 20 women-specialized panels.
[Judgment criteria]
◎: 15 or more people judged “good” ○: 11 or more people 14 or less judged “good” Δ: 7 or more people 10 or less judged “good” ×: 6 people or less judged “good” "
<<乾燥後の毛髪のべたつきのなさ>>
各シャンプー組成物の「乾燥後の毛髪のべたつきのなさ」について、女性専門パネル20名のうち「乾燥後の毛髪のべたつきのなさが良好」と判断した人数により、下記評価基準に基づき、評価した。
[判断基準]
◎:15名以上が「良好」と判断した
○:11名以上14名以下が「良好」と判断した
△:7名以上10名以下が「良好」と判断した
×:6名以下が「良好」と判断した<< No stickiness of hair after drying >>
The “non-sticky hair after drying” of each shampoo composition was evaluated based on the following evaluation criteria by the number of female panelists who judged that “non-sticky hair after drying” was “good”. .
[Judgment criteria]
◎: 15 or more people judged “good” ○: 11 or more people 14 or less judged “good” Δ: 7 or more people 10 or less judged “good” ×: 6 people or less judged “good” "
<<刺激のなさ>>
各シャンプー組成物の「刺激のなさ」について、女性専門パネル20名のうち「刺激のなさが良好」と判断した人数により、下記評価基準に基づき、評価した。ここで、「刺激のなさ」とは、各シャンプー組成物による頭皮への刺激(頭皮がひりひりすること)がないことを意味する。
[判断基準]
◎:15名以上が「良好」と判断した
○:11名以上14名以下が「良好」と判断した
△:7名以上10名以下が「良好」と判断した
×:6名以下が「良好」と判断した<< No stimulation >>
The “no irritation” of each shampoo composition was evaluated based on the following evaluation criteria by the number of 20 female specialist panels who judged “no irritation”. Here, “no irritation” means that there is no irritation to the scalp by each shampoo composition (the scalp is tingling).
[Judgment criteria]
◎: 15 or more people judged “good” ○: 11 or more people 14 or less judged “good” Δ: 7 or more people 10 or less judged “good” ×: 6 people or less judged “good” "
<<外観安定性>>
30mL容のガラス製透明容器(日電理化硝子株式会社製、SV−30)に、各シャンプー組成物を30mL詰め、蓋をし、温度50℃で1週間静置した。1週間後の各シャンプー組成物の「外観安定性」について、下記評価基準に基づき、評価した。
[判断基準]
○:シャンプー組成物が分離していない
×:シャンプー組成物が分離している<< Appearance stability >>
A 30 mL glass transparent container (manufactured by Nidec Rika Glass Co., Ltd., SV-30) was packed with 30 mL of each shampoo composition, covered, and allowed to stand at a temperature of 50 ° C. for 1 week. The “appearance stability” of each shampoo composition after one week was evaluated based on the following evaluation criteria.
[Judgment criteria]
○: Shampoo composition is not separated ×: Shampoo composition is separated
なお、実施例1〜37及び比較例1〜17で用いたシャンプー組成物の原料の具体的な内容は、以下の表11に示すとおりである。 In addition, the specific content of the raw material of the shampoo composition used in Examples 1-37 and Comparative Examples 1-17 is as showing in the following Table 11.
*2:ジメチルポリシロキサンB(エマルション)は、以下の方法で調製した。
レオフローDMS−60(一方社油脂工業株式会社製)〔動粘度10,000,000mm2/sの高重合メチルポリシロキサン:動粘度4,000,000mm2/sの高重合メチルポリシロキサン:動粘度1,000mm2/sのメチルポリシロキサン=15:15:70(質量比)〕に、POE(15)セチルエーテル(商品名:NPO−97、ライオンケミカル株式会社製)を乳化剤として水に乳化分散し、シリコーン分は60質量%、数平均粒径は0.9μmに調整したものである。
*POE:ポリオキシエチレン
* 2: Dimethylpolysiloxane B (emulsion) was prepared by the following method.
Rheoflow DMS-60 (manufactured by Yushi Kogyo Co., Ltd.) [Highly polymerized methylpolysiloxane with kinematic viscosity 10,000,000 mm 2 / s: Highly polymerized methylpolysiloxane with kinematic viscosity 4,000,000 mm 2 / s: Kinematic viscosity 1,000 mm 2 / s methylpolysiloxane = 15: 15: 70 (mass ratio)] and emulsified and dispersed in water using POE (15) cetyl ether (trade name: NPO-97, manufactured by Lion Chemical Co., Ltd.) as an emulsifier. The silicone content was adjusted to 60% by mass, and the number average particle size was adjusted to 0.9 μm.
* POE: Polyoxyethylene
本発明のシャンプー組成物は、皮脂が多い、高温多湿環境下においても洗浄力及び泡の持続性を担保しつつ、すすぎ時の毛髪のなめらかさが得られると共に、高温多湿環境下での乾燥後の毛髪のなめらかさ、高温多湿環境下での乾燥後の毛髪のやわらかさ、及び高温多湿環境下での乾燥後の毛髪のべたつきのなさを併せ持ち、外観安定性、使用性及び刺激のなさが良好であるので、例えば、シャンプー、リンスインシャンプー(コンディショニングシャンプー)などに好適に用いられる。 The shampoo composition of the present invention has a smoothness of hair at the time of rinsing while ensuring detergency and sustainability of foam even in a high-temperature and high-humidity environment with a lot of sebum, and after drying under a high-temperature and high-humidity environment It has the smoothness of the hair, the softness of the hair after drying in a hot and humid environment, and the non-stickiness of the hair after drying in a hot and humid environment, and has good appearance stability, usability and no irritation Therefore, for example, it is suitably used for shampoo, rinse-in shampoo (conditioning shampoo) and the like.
本発明の態様としては、例えば、以下のとおりである。
<1> (A)アニオン性界面活性剤、
(B)ラウリン酸ポリグリセリル、及びミリスチン酸ポリグリセリルから選択される少なくとも1種のノニオン性界面活性剤、
(C)カチオン性ポリマー、
(D)ジメチルポリシロキサン、並びに
(E)アミノ変性シリコーンを含有してなり、
前記(A)成分が、(A1)ポリオキシエチレンアルキルエーテル硫酸塩、及び(A2)アルキル硫酸塩を含有し、前記(A1)成分の含有量と前記(A2)成分の含有量との質量比(A1/A2)が1〜7であり、
前記(C)成分が、(C1)カチオン化グアーガム、及び(C2)カチオン化セルロースを含有し、前記(C1)成分の含有量と前記(C2)成分の含有量との質量比(C1/C2)が2〜20であることを特徴とするシャンプー組成物である。
<2> (A)成分の含有量が10質量%〜25質量%であり、
(B)成分の含有量が0.3質量%〜8質量%であり、
(C)成分の含有量が0.2質量%〜3質量%であり、
(D)成分の含有量が0.5質量%〜3質量%であり、
(E)成分の含有量が0.1質量%〜1質量%である前記<1>に記載のシャンプー組成物である。
<3> (A1)成分のポリオキシエチレンアルキルエーテル硫酸塩の含有量が、5質量%〜22質量%であり、
(A2)成分のアルキル硫酸塩の含有量が、2質量%〜12質量%であり、
(C1)成分のカチオン化グアーガムの含有量が、0.1質量%〜2.8質量%であり、
(C2)成分のカチオン化セルロースの含有量が、0.05質量%〜0.7質量%である前記<1>から<2>のいずれかに記載のシャンプー組成物である。As an aspect of this invention, it is as follows, for example.
<1> (A) anionic surfactant,
(B) at least one nonionic surfactant selected from polyglyceryl laurate and polyglyceryl myristate,
(C) a cationic polymer,
(D) comprising dimethylpolysiloxane and (E) amino-modified silicone,
The component (A) contains (A1) polyoxyethylene alkyl ether sulfate and (A2) alkyl sulfate, and the mass ratio between the content of the component (A1) and the content of the component (A2) (A1 / A2) is 1-7,
The component (C) contains (C1) cationized guar gum and (C2) cationized cellulose, and the mass ratio (C1 / C2) between the content of the component (C1) and the content of the component (C2) ) Is a shampoo composition characterized in that it is 2-20.
<2> The content of the component (A) is 10% by mass to 25% by mass,
(B) The content of the component is 0.3 mass% to 8 mass%,
(C) component content is 0.2 mass% to 3 mass%,
(D) component content is 0.5 mass% to 3 mass%,
(E) It is a shampoo composition as described in said <1> whose content of a component is 0.1 mass%-1 mass%.
<3> The content of the polyoxyethylene alkyl ether sulfate as the component (A1) is 5% by mass to 22% by mass,
(A2) The content of the component alkyl sulfate is 2% by mass to 12% by mass,
The content of the cationized guar gum of the component (C1) is 0.1% by mass to 2.8% by mass,
(C2) The shampoo composition according to any one of <1> to <2>, wherein the content of the cationized cellulose as the component is 0.05% by mass to 0.7% by mass.
Claims (3)
(B)ラウリン酸ポリグリセリル、及びミリスチン酸ポリグリセリルから選択される少なくとも1種のノニオン性界面活性剤、
(C)カチオン性ポリマー、
(D)ジメチルポリシロキサン、並びに
(E)アミノ変性シリコーンを含有してなり、
前記(A)成分が、(A1)ポリオキシエチレンアルキルエーテル硫酸塩、及び(A2)アルキル硫酸塩を含有し、前記(A1)成分の含有量と前記(A2)成分の含有量との質量比(A1/A2)が1〜7であり、
前記(C)成分が、(C1)カチオン化グアーガム、及び(C2)カチオン化セルロースを含有し、前記(C1)成分の含有量と前記(C2)成分の含有量との質量比(C1/C2)が2〜20であることを特徴とするシャンプー組成物。(A) an anionic surfactant,
(B) at least one nonionic surfactant selected from polyglyceryl laurate and polyglyceryl myristate,
(C) a cationic polymer,
(D) comprising dimethylpolysiloxane and (E) amino-modified silicone,
The component (A) contains (A1) polyoxyethylene alkyl ether sulfate and (A2) alkyl sulfate, and the mass ratio between the content of the component (A1) and the content of the component (A2) (A1 / A2) is 1-7,
The component (C) contains (C1) cationized guar gum and (C2) cationized cellulose, and the mass ratio (C1 / C2) between the content of the component (C1) and the content of the component (C2) ) Shampoo composition characterized in that it is 2-20.
(B)成分の含有量が0.3質量%〜8質量%であり、
(C)成分の含有量が0.2質量%〜3質量%であり、
(D)成分の含有量が0.5質量%〜3質量%であり、
(E)成分の含有量が0.1質量%〜1質量%である請求項1に記載のシャンプー組成物。(A) Content of a component is 10 mass%-25 mass%,
(B) The content of the component is 0.3 mass% to 8 mass%,
(C) component content is 0.2 mass% to 3 mass%,
(D) component content is 0.5 mass% to 3 mass%,
The shampoo composition according to claim 1, wherein the content of the component (E) is 0.1% by mass to 1% by mass.
(A2)成分のアルキル硫酸塩の含有量が、2質量%〜12質量%であり、
(C1)成分のカチオン化グアーガムの含有量が、0.1質量%〜2.8質量%であり、
(C2)成分のカチオン化セルロースの含有量が、0.05質量%〜0.7質量%である請求項1から2のいずれかに記載のシャンプー組成物。
The content of the polyoxyethylene alkyl ether sulfate as the component (A1) is 5% by mass to 22% by mass,
(A2) The content of the component alkyl sulfate is 2% by mass to 12% by mass,
The content of the cationized guar gum of the component (C1) is 0.1% by mass to 2.8% by mass,
The shampoo composition according to claim 1, wherein the content of the cationized cellulose as the component (C2) is 0.05% by mass to 0.7% by mass.
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JP2003041299A (en) * | 2001-08-01 | 2003-02-13 | Shiseido Co Ltd | Detergent composition |
JP2003292995A (en) * | 2002-03-29 | 2003-10-15 | Shiseido Co Ltd | Cleanser composition |
JP2004018439A (en) * | 2002-06-14 | 2004-01-22 | Kao Corp | Aqueous liquid detergent composition |
JP2006089571A (en) * | 2004-09-22 | 2006-04-06 | Canon Inc | Ink, ink set using the same, inkjet recording method and inkjet recording device |
JP2006182723A (en) * | 2004-12-28 | 2006-07-13 | Kao Corp | Aqueous hair shampoo |
WO2008038496A1 (en) * | 2006-09-26 | 2008-04-03 | Lion Corporation | Shampoo composition |
JP2008081415A (en) * | 2006-09-26 | 2008-04-10 | Lion Corp | Hair cleansing agent composition |
JP6120870B2 (en) * | 2012-11-08 | 2017-04-26 | ライオン株式会社 | Shampoo composition |
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JP2005089571A (en) * | 2003-09-16 | 2005-04-07 | Shiseido Co Ltd | Detergent composition |
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- 2015-04-22 WO PCT/JP2015/062164 patent/WO2015163338A1/en active Application Filing
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Patent Citations (8)
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JP2003041299A (en) * | 2001-08-01 | 2003-02-13 | Shiseido Co Ltd | Detergent composition |
JP2003292995A (en) * | 2002-03-29 | 2003-10-15 | Shiseido Co Ltd | Cleanser composition |
JP2004018439A (en) * | 2002-06-14 | 2004-01-22 | Kao Corp | Aqueous liquid detergent composition |
JP2006089571A (en) * | 2004-09-22 | 2006-04-06 | Canon Inc | Ink, ink set using the same, inkjet recording method and inkjet recording device |
JP2006182723A (en) * | 2004-12-28 | 2006-07-13 | Kao Corp | Aqueous hair shampoo |
WO2008038496A1 (en) * | 2006-09-26 | 2008-04-03 | Lion Corporation | Shampoo composition |
JP2008081415A (en) * | 2006-09-26 | 2008-04-10 | Lion Corp | Hair cleansing agent composition |
JP6120870B2 (en) * | 2012-11-08 | 2017-04-26 | ライオン株式会社 | Shampoo composition |
Non-Patent Citations (1)
Title |
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FRAGRANCE JOURNAL, vol. 30, no. 6, JPN6015029617, 15 June 2002 (2002-06-15), pages 129 - 134, ISSN: 0003594158 * |
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MY184989A (en) | 2021-04-30 |
JP6178001B2 (en) | 2017-08-09 |
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