JPWO2011099501A1 - Curable composition, cured product and method of using curable composition - Google Patents

Abstract

The present invention contains (A) a silane compound copolymer having a specific repeating unit, (B) an epoxy compound, and (C) an alicyclic acid anhydride having a carboxyl group and other alicyclic acid anhydrides. A curable composition containing a curing agent (A): [(B) + (C)] = 100: 20 to 100: 60 (mass ratio), a cured product obtained by curing the composition, In addition, the present invention relates to a method of using the composition as an adhesive for an optical element fixing material and an encapsulant for an optical element fixing material. ADVANTAGE OF THE INVENTION According to this invention, the curable composition which is excellent in heat resistance and transparency over a long period of time, and can obtain the hardened | cured material which has high adhesive force even at high temperature is provided.

Description

  The present invention relates to a curable composition from which a cured product having excellent transparency and heat resistance and high adhesive strength is obtained, a cured product obtained by curing the composition, and an optical element fixing material using the composition. The present invention relates to a method for use as an adhesive for optical devices or a sealant for optical element fixing materials.

Until now, the curable composition has been improved in various ways depending on the application, and has been widely used industrially as a raw material, an adhesive, a coating agent, and the like for optical parts and molded articles. For example, a curable composition that forms a cured product having excellent transparency is used as a raw material or a coating agent for optical parts, and a curable composition that forms a cured product having high adhesive strength is used as an adhesive or a coating agent. It is often used preferably.
In recent years, curable compositions have also been used as compositions for optical element fixing materials, such as adhesives for optical element fixing materials and sealing agents for optical element fixing materials, when producing optical element sealing bodies. It is coming.

  Examples of the optical element include various lasers such as a semiconductor laser (LD), light emitting elements such as a light emitting diode (LED), a light receiving element, a composite optical element, and an optical integrated circuit. In recent years, blue and white light optical elements having a shorter peak emission wavelength have been developed and widely used. Such a light emitting element with a short peak wavelength of light emission has been dramatically increased in brightness, and accordingly, the amount of heat generated by the optical element tends to be further increased.

  However, with the recent increase in brightness of optical elements, the cured product of the composition for optical element fixing materials is exposed to higher energy light and higher temperature heat generated from the optical element for a long time, and deteriorates and cracks. The problem of generating or peeling occurred.

In order to solve this problem, Patent Documents 1 to 3 propose a composition for an optical element fixing material containing a polysilsesquioxane compound as a main component.
However, even if it is a cured product of the composition for optical element fixing materials mainly composed of the polysilsesquioxane compound described in Patent Documents 1 to 3, heat resistance and transparency are maintained while maintaining sufficient adhesive force. It was sometimes difficult to get.

Moreover, as a composition used for optical element sealing, Patent Document 4 proposes an epoxy resin composition using an alicyclic epoxy resin, and Patent Document 5 proposes an epoxy resin composition containing a polythiol compound. ing.
However, even when these compositions are used, there is a case where sufficient light deterioration resistance accompanying a change with time cannot be satisfied or the adhesive force is lowered.
Therefore, development of a curable composition that is superior in heat resistance and transparency and that can provide a cured product having high adhesive force is eagerly desired.

JP 2004-359933 A JP 2005-263869 A JP 2006-328231 A JP 7-309927 A JP 2009-001752 A

  The present invention has been made in view of the situation of such prior art, and is a curable composition that is excellent in heat resistance and transparency, and that can obtain a cured product having high adhesive strength, and curing the composition. It is an object of the present invention to provide a cured product and a method of using the composition as an adhesive for optical element fixing materials or an encapsulant for optical element fixing materials.

  As a result of intensive studies to solve the above problems, the present inventors have obtained (A) a specific silane compound copolymer, (B) an epoxy compound, and (C) an alicyclic acid anhydride having a carboxyl group, A cured product of a composition containing other alicyclic acid anhydrides has been found to be a cured product having high adhesive strength even at high temperatures while maintaining excellent transparency and heat resistance over a long period of time. The invention has been completed.

Thus, according to the first aspect of the present invention, the following curable compositions [1] to [8] are provided.
[1] (A) In the molecule, the following formulas (i), (ii) and (iii)

[Wherein R ¹ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, X ⁰ represents a halogen atom, a cyano group or a group represented by the formula: OG (wherein G represents a protecting group for a hydroxyl group) D) represents a single bond or a linking group. R ² represents an alkyl group having 1 to 20 carbon atoms or a phenyl group which may have a substituent. ]
(I) and (ii), (i) and (iii), (ii) and (iii), or (i), (ii) and (iii) having repeating units A silane compound copolymer having a weight average molecular weight of 1,000 to 30,000, (B) an epoxy compound, and (C) an alicyclic acid anhydride having a carboxyl group and other alicyclic acid anhydrides. The curing agent containing the product is (A): [(B) + (C)] = 100: 20 to 100: 60 in a mass ratio of (A) to [(B) + (C)]. A curable composition to contain.

[2] The abundance of a group represented by the formula: R ¹ —CH (X ⁰ ) —D— ([R ¹ —CH (X ⁰ ) —D]) Is a silane compound copolymer of [R ¹ —CH (X ⁰ ) —D]: [R ² ] = 55: 45 to 25:75 in a molar ratio of the abundance of R ² and R ² ([R ² ]). [1] The curable composition according to [1].

[3] (A ′) Formula (1): R ¹ —CH (X ⁰ ) —D—Si (OR ³ ) _p (X ¹ ) _3-p
[Wherein R ¹ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, X ⁰ represents a halogen atom, a cyano group or a group represented by the formula: OG (wherein G represents a protecting group for a hydroxyl group) D) represents a single bond or a linking group. R ³ represents an alkyl group having 1 to 6 carbon atoms, X ¹ represents a halogen atom, and p represents an integer of 0 to 3. ]
And at least one of the silane compounds (1) represented by formula (2): R ² Si (OR ⁴ ) _q (X ² ) _3-q
(In the formula, R ² represents an alkyl group having 1 to 20 carbon atoms or an optionally substituted phenyl group, R ⁴ represents an alkyl group having 1 to 6 carbon atoms, and X ² represents a halogen atom. Q represents an integer of 0 to 3.)
A silane compound copolymer having a weight average molecular weight of 1,000 to 30,000, obtained by condensing a mixture of silane compounds containing at least one of the silane compounds (2) represented by: (B) an epoxy compound, And (C) a curing agent containing an alicyclic acid anhydride having a carboxyl group and another alicyclic acid anhydride in a mass ratio of (A ′) and [(B) + (C)] ( A ′): [(B) + (C)] = 100: 20 to 100: 60 The curable composition to be contained.

[4] The silane compound copolymer of (A ′) described above has a molar ratio of silane compound (1) and silane compound (2): [silane compound (1)]: [silane compound (2)] = The curable composition according to [3], which is a silane compound copolymer obtained by condensation at a ratio of 55:45 to 25:75.

[5] The mass ratio of the curing agent (C) is (an alicyclic acid anhydride having a carboxyl group): (other alicyclic acid anhydride) = 50: 50 to 10:90 [1. ] Or the curable composition as described in [3].

[6] The curable composition according to [1] or [3], further comprising an antioxidant.
[7] The curable composition according to [6], wherein the antioxidant is a phosphorus-based antioxidant.
[8] The curable composition according to [1] or [3], which is a composition for an optical element fixing material.

According to the second aspect of the present invention, the following [9] and [10] cured products are provided.
[9] A cured product obtained by curing the curable composition according to [1] or [3].
[10] The cured product according to [9], which is an optical element fixing material.

According to the third aspect of the present invention, there is provided a method of using the curable composition of the present invention of the following [11] and [12].
[11] A method of using the curable composition according to [1] or [3] as an adhesive for an optical element fixing material.
[12] A method of using the curable composition according to [1] or [3] as a sealant for an optical element fixing material.

According to the curable composition of the present invention, even when irradiated with high energy light or in a high temperature state, it does not color and does not deteriorate transparency, and has excellent transparency over a long period of time. In addition, a cured product having a high adhesive force even at a high temperature can be obtained.
The curable composition of the present invention can be used when forming an optical element fixing material, and particularly preferably used as an optical element fixing material adhesive and an optical element fixing material sealing agent. it can.

Hereinafter, the present invention will be described in detail by dividing it into 1) a curable composition, 2) a cured product, and 3) a method of using the curable composition.
1) Curable composition The curable composition of the present invention comprises:
(A) In the molecule, the following formulas (i), (ii) and (iii)

(I) and (ii), (i) and (iii), (ii) and (iii), or (i), (ii) and (iii) having repeating units A silane compound copolymer having a weight average molecular weight of 1,000 to 30,000, (B) an epoxy compound, and (C) an alicyclic acid anhydride having a carboxyl group and other alicyclic acid anhydrides. The curing agent containing the product is (A): [(B) + (C)] = 100: 20 to 100: 60 in a mass ratio of (A) to [(B) + (C)]. It is characterized by containing.

(A) Silane compound copolymer The curable composition of the present invention comprises (i) and (i) of the repeating units represented by the formulas (i), (ii) and (iii) as the component (A). having a repeating unit of ii), (i) and (iii), (ii) and (iii), or (i), (ii) and (iii), and having a weight average molecular weight of 1,000 to 30,000 A silane compound copolymer (hereinafter sometimes referred to as “silane compound copolymer (A)”).
The silane compound copolymer (A) may have one type of repeating unit represented by (i), (ii), or (iii), or may have two or more types.

In formulas (i) to (iii), R ¹ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and is preferably a hydrogen atom.
Examples of the alkyl group having 1 to 6 carbon atoms represented by R ¹ include methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, t-butyl group, i-butyl group, s- A butyl group, n-pentyl group, n-hexyl group, etc. are mentioned.

X ⁰ represents a halogen atom such as a fluorine atom, a chlorine atom, a bromine atom or an iodine atom; a cyano group; or a group represented by the formula: OG.

  G represents a hydroxyl-protecting group. There is no restriction | limiting in particular as a hydroxyl-protecting group, The well-known protecting group known as a hydroxyl-protecting group is mentioned. For example, acyl protecting groups; silyl protecting groups such as trimethylsilyl group, triethylsilyl group, t-butyldimethylsilyl group, t-butyldiphenylsilyl group; methoxymethyl group, methoxyethoxymethyl group, 1-ethoxyethyl group An acetal type protective group such as tetrahydropyran-2-yl group or tetrahydrofuran-2-yl group; an alkoxycarbonyl type protective group such as t-butoxycarbonyl group; a methyl group, an ethyl group, a t-butyl group or an octyl group , Ether-based protecting groups such as allyl group, triphenylmethyl group, benzyl group, p-methoxybenzyl group, fluorenyl group, trityl group and benzhydryl group; Among these, as G, an acyl-type protecting group is preferable.

Specifically, the acyl-based protecting group is a group represented by the formula: —C (═O) R ⁵ . In the formula, R ⁵ represents carbon such as methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, i-butyl group, s-butyl group, t-butyl group, and n-pentyl group. An alkyl group of 1 to 6; or a phenyl group which may have a substituent.

Examples of the substituent of the phenyl group which may have a substituent represented by R ⁵ include methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, s-butyl group, i -Alkyl groups such as butyl, t-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl and i-octyl; halogen atoms such as fluorine, chlorine and bromine An alkoxy group such as a methoxy group or an ethoxy group;

Among these, as X ^{0, since} it is easy to obtain and a cured product having high adhesive strength is obtained, a chlorine atom, a group represented by the formula: OG ′ (wherein G ′ is an acyl group) And a group selected from a cyano group, a group selected from a chlorine atom, an acetoxy group and a cyano group is more preferable, and an acetoxy group is particularly preferable.

D represents a single bond or a linking group.
Examples of the linking group include a divalent organic group that may have a substituent. 1-20 are preferable and, as for carbon number of the said organic group, 1-10 are more preferable.
Examples of the divalent organic group that may have a substituent include an alkylene group that may have a substituent, an alkenylene group that may have a substituent, and a substituent. An alkynylene group which may have a substituent, an arylene group which may have a substituent, an arylene group which may have a substituent (an alkylene group, an alkenylene group or an alkynylene group) and an arylene group which may have a substituent; And a divalent group consisting of the above-mentioned combinations.

As the alkylene group of the alkylene group which may have a substituent, a methylene group, an ethylene group, a propylene group, a trimethylene group, a tetramethylene group, a pentamethylene group, a hexamethylene group, or the like, preferably 1 to 20 carbon atoms, Examples include an alkylene group having 1 to 10 carbon atoms.
The alkenylene group of the alkenylene group which may have a substituent is an alkenylene group having 2 to 20 carbon atoms such as a vinylene group, propenylene group, butenylene group or pentenylene group, preferably an alkenylene group having 2 to 10 carbon atoms. Is mentioned.
Examples of the alkynylene group which may have a substituent include alkynylene groups having 2 to 20 carbon atoms such as ethynylene group and propynylene group, preferably alkynylene groups having 2 to 10 carbon atoms.
As the arylene group of the arylene group which may have a substituent, an arylene group having 6 to 20 carbon atoms such as an o-phenylene group, an m-phenylene group, a p-phenylene group, or a 2,6-naphthylene group, preferably Includes an arylene group having 6 to 10 carbon atoms.

  Examples of the substituent for the alkylene group, alkenylene group, and alkynylene group include a halogen atom such as a fluorine atom and a chlorine atom; an alkoxy group such as a methoxy group and an ethoxy group; an alkylthio group such as a methylthio group and an ethylthio group; a methoxycarbonyl group; An alkoxycarbonyl group such as an ethoxycarbonyl group; and the like.

Examples of the substituent for the arylene group include: a cyano group; a nitro group; a halogen atom such as a fluorine atom, a chlorine atom and a bromine atom; an alkyl group such as a methyl group and an ethyl group; an alkoxy group such as a methoxy group and an ethoxy group; And alkylthio groups such as ethylthio group; and the like.
These substituents may be bonded at arbitrary positions in groups such as an alkylene group, an alkenylene group, an alkynylene group, and an arylene group, and a plurality of them may be bonded in the same or different manner.

  The divalent group consisting of a combination of an optionally substituted (alkylene group, alkenylene group, or alkynylene group) and an optionally substituted arylene group has the above substituents. And a group in which at least one kind of (alkylene group, alkenylene group, or alkynylene group) which may be present and at least one kind of arylene group which may have the substituent are bonded in series. Specific examples include groups represented by the following formula.

  Among these, D is preferably an alkylene group having 1 to 10 carbon atoms, more preferably an alkylene group having 1 to 6 carbon atoms, and a methylene group or an ethylene group, because a cured product having high adhesive strength is obtained. Particularly preferred.

In formulas (ii) to (iii), R ² represents an alkyl group having 1 to 20 carbon atoms or an optionally substituted phenyl group.
Examples of the alkyl group having 1 to 20 carbon atoms represented by R ² include methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, s-butyl group, i-butyl group, t- A butyl group, n-pentyl group, n-hexyl group, n-octyl group, i-octyl group, n-nonyl group, n-decyl group, n-dodecyl group and the like can be mentioned.

Examples of the substituent of the phenyl group which may have a substituent represented by R ² include methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, s-butyl group, i -Alkyl groups such as butyl group, t-butyl group, n-pentyl group, n-hexyl group, n-heptyl group, n-octyl group and i-octyl group; alkoxy groups such as methoxy group and ethoxy group; fluorine atom And halogen atoms such as chlorine atom.

Specific examples of the phenyl group optionally having a substituent represented by R ² include a phenyl group, a 2-chlorophenyl group, a 4-methylphenyl group, a 3-ethylphenyl group, and a 2,4-dimethylphenyl group. , 2-methoxyphenyl group and the like.

In the silane compound copolymer (A), the amount of the group represented by the formula: R ¹ —CH (X ⁰ ) —D— ([R ¹ —CH (X ⁰ ) —D]) and R ² The molar ratio of the abundance ([R ² ]) is preferably [R ¹ —CH (X ⁰ ) —D]: [R ² ] = 55: 45 to 25:75. By being in the said range, since the obtained hardened | cured material is excellent in transparency and adhesiveness, and is excellent in heat resistance, even after it sets | places on high temperature, the fall of these characteristics is suppressed.
The abundance of the group represented by the formula: R ¹ —CH (X ⁰ ) —D— and R ² can be quantified by measuring the NMR spectrum of the silane compound copolymer (A), for example.

  The unit structure arrangement of the silane compound copolymer (A) is not particularly limited, and examples thereof include a random copolymer, a block copolymer, a graft copolymer, and an alternating copolymer. A random copolymer is particularly preferable. .

  The weight average molecular weight (Mw) of the silane compound copolymer (A) is in the range of 1,000 to 30,000, preferably in the range of 1,500 to 6,000. By being in the said range, the hardened | cured material which is excellent in the handleability of a composition, and excellent in adhesiveness and heat resistance is obtained. A weight average molecular weight (Mw) can be calculated | required as a standard polystyrene conversion value by the gel permeation chromatography (GPC) which uses tetrahydrofuran (THF) as a solvent, for example.

  The molecular weight distribution (Mw / Mn) of the silane compound copolymer (A) is not particularly limited, but is usually 1.0 to 3.0, preferably 1.1 to 2.0. By being in the said range, the hardened | cured material which is excellent in adhesiveness and heat resistance is obtained.

  A silane compound copolymer (A) can be used individually by 1 type or in combination of 2 or more types.

The silane compound copolymer (A) is a ladder-type polysilsesquioxane compound.
The fact that the silane compound copolymer has a ladder structure can be confirmed, for example, by performing infrared absorption spectrum measurement, X-ray diffraction measurement, and NMR measurement of the reaction product.

In the curable composition of the present invention, the silane compound copolymer (A) as the component (A) has the formula (1): R ¹ —CH (X ⁰ ) —D—Si (OR ³ ) _p (X ¹ ) _3-p
At least one of silane compounds (1) represented by:
Equation _{^{(2): R 2 Si (}} OR 4) q (X 2) 3-q
A silane compound copolymer having a weight average molecular weight of 1,000 to 30,000 obtained by condensing a mixture of silane compounds containing at least one of the silane compounds (2) represented by Polymer (A ′) ”), and the silane compound copolymer (A) is preferably a silane compound copolymer (A ′).

[Silane compound (1)]
Silane compound (1) has the formula ^(1): R 1 -CH (X 0) is _{^{-D-Si (OR 3) p}} (X 1) a compound represented by _3-p. By using the silane compound (1), it is possible to obtain a silane compound copolymer having excellent transparency and adhesion even after curing.
That's right.

In the formula ^(1), specific examples of R 1, ^{X 0} and D is a silane compound copolymer in ^(A), those exemplified as R 1, ^{X 0} and D.

R ³ is methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, s-butyl group, i-butyl group, t-butyl group, n-pentyl group, n-hexyl group, etc. Represents an alkyl group having 1 to 6 carbon atoms.
X ¹ represents a halogen atom such as a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom.
p represents an integer of 0 to 3.
When p is 2 or more, the ORs ³ may be the same or different. When (3-p) is 2 or more, X ¹ may be the same or different.

Specific examples of the silane compound (1) include chloromethyltrimethoxysilane, bromomethyltriethoxysilane, 2-chloroethyltripropoxysilane, 2-bromoethyltributoxysilane, 3-chloropropyltrimethoxysilane, and 3-chloro. Propyltriethoxysilane, 3-chloropropyltripropoxysilane, 3-chloropropyltributoxysilane, 3-bromopropyltrimethoxysilane, 3-bromopropyltriethoxysilane, 3-bromopropyltripropoxysilane, 3-bromopropyltri Butoxysilane, 3-fluoropropyltrimethoxysilane, 3-fluoropropyltriethoxysilane, 3-fluoropropyltripropoxysilane, 3-fluoropropyltributoxysilane, 3-iodopropylto Methoxysilane, 2-chloroethyltrimethoxysilane, 3-chloropropyltriethoxysilane, 4-chlorobutyltripropoxysilane, 5-chloropentyltripropoxysilane, 2-chloropropyltrimethoxysilane, 3-chloro-3-acetyl Propyltrimethoxysilane, 3-chloro-3-methoxycarbonylpropyltrimethoxysilane, o- (2-chloroethyl) phenyltripropoxysilane, m- (2-chloroethyl) phenyltrimethoxysilane, p- (2-chloroethyl) phenyl Trialkoxysilane compounds in which X ⁰ is a halogen atom, such as triethoxysilane and p- (2-fluoroethyl) phenyltrimethoxysilane;

Chloromethyltrichlorosilane, bromomethylbromodimethoxysilane, 2-chloroethyldichloromethoxysilane, 2-bromoethyldichloroethoxysilane, 3-chloropropyltrichlorosilane, 3-chloropropyltribromosilane, 3-chloropropyldichloromethoxysilane, 3-chloropropyldichloroethoxysilane, 3-chloropropylchlorodimethoxysilane, 3-chloropropylchlorodiethoxysilane, 3-bromopropyldichloroethoxysilane, 3-bromopropyltribromosilane, 3-bromopropyltrichlorosilane, 3- Bromopropylchlorodimethoxysilane, 3-fluoropropyltrichlorosilane, 3-fluoropropylchlorodimethoxysilane, 3-fluoropropyldichloromethoxysilane 3-fluoropropylchlorodiethoxysilane, 3-iodopropyltrichlorosilane, 4-chlorobutylchlorodiethoxysilane, 3-chloro-n-butylchlorodiethoxysilane, 3-chloro-3-acetylpropyldichloroethoxysilane, Halogenosilane compounds wherein X ⁰ is a halogen atom, such as 3-chloro-3-methoxycarbonylpropyltribromosilane;

Cyanomethyltrimethoxysilane, cyanomethyltriethoxysilane, 1-cyanoethyltrimethoxysilane, 2-cyanoethyltrimethoxysilane, 2-cyanoethyltriethoxysilane, 2-cyanoethyltripropoxysilane, 3-cyanopropyltrimethoxysilane, 3- Cyanopropyltriethoxysilane, 3-cyanopropyltripropoxysilane, 3-cyanopropyltributoxysilane, 4-cyanobutyltrimethoxysilane, 5-cyanopentyltrimethoxysilane, 2-cyanopropyltrimethoxysilane, 2- (cyano Methoxy) ethyltrimethoxysilane, 2- (2-cyanoethoxy) ethyltrimethoxysilane, o- (cyanomethyl) phenyltripropoxysilane, m- (cyanomethyl) phenyltrimethoxy Run, p-(cyanomethyl) phenyl triethoxysilane, p-(2-cyanoethyl) trialkoxysilane compounds are such phenyltrimethoxysilane, X ⁰ is a cyano group;

Cyanomethyltrichlorosilane, cyanomethylbromodimethoxysilane, 2-cyanoethyldichloromethoxysilane, 2-cyanoethyldichloroethoxysilane, 3-cyanopropyltrichlorosilane, 3-cyanopropyltribromosilane, 3-cyanopropyldichloromethoxysilane, 3- Cyanopropyldichloroethoxysilane, 3-cyanopropylchlorodimethoxysilane, 3-cyanopropylchlorodiethoxysilane, 4-cyanobutylchlorodiethoxysilane, 3-cyano-n-butylchlorodiethoxysilane, 2- (2-cyano Ethoxy) ethyltrichlorosilane, 2- (2-cyanoethoxy) ethylbromodiethoxysilane, 2- (2-cyanoethoxy) ethyldichloropropoxysilane, o- (2-cyanoethyl) pheny Trichlorosilane, m-(2-cyanoethyl) phenylmethoxy dibromo silane, p-(2-cyanoethyl) phenyl dimethoxy chlorosilane, p-(2-cyanoethyl) and phenyl tribromosilane silane, halosilane compound ^{X 0} is a cyano group Kind;

3-acetoxypropyltrimethoxysilane, 3-acetoxypropyltriethoxysilane, 3-acetoxypropyltripropoxysilane, 3-acetoxypropyltributoxysilane, 3-propionyloxypropyltrimethoxysilane, 3-propionyloxypropyltriethoxysilane, 3-benzoyloxypropyltrimethoxysilane, 3-benzoyloxypropyltriethoxysilane, 3-benzoyloxypropyltripropoxysilane, 3-benzoyloxypropyltributoxysilane, 2-trimethylsilyloxyethyltrimethoxysilane, 3-triethylsilyloxy Propyltriethoxysilane, 3- (2-tetrahydropyranyloxy) propyltripropoxysilane, 3- (2-tetrahydrofurani Oxy) propyltributoxysilane, 3-methoxymethyloxypropyltrimethoxysilane, 3-methoxyethoxymethyloxypropyltriethoxysilane, 3- (1-ethoxyethyloxy) propyltripropoxysilane, 3- (t-butoxycarbonyloxy) ) X ⁰ is a group represented by the above formula: OG, such as propyltrimethoxysilane, 3-t-butoxypropyltrimethoxysilane, 3-benzyloxypropyltriethoxysilane, 3-triphenylmethoxypropyltriethoxysilane, etc. Certain trialkoxysilane compounds;

3-acetoxypropyltrichlorosilane, 3-acetoxypropyltribromosilane, 3-acetoxypropyldichloromethoxysilane, 3-acetoxypropyldichloroethoxysilane, 3-acetoxypropylchlorodimethoxysilane, 3-acetoxypropylchlorodiethoxysilane, 3- Benzoyloxypropyltrichlorosilane, 3-trimethylsilyloxypropylchlorodimethoxysilane, 3-triethylsilyloxypropyldichloromethoxysilane, 3- (2-tetrahydropyranyloxy) propylchlorodiethoxysilane, 3- (2-tetrahydrofuranyloxy) Propyldichloroethoxysilane, 3-methoxymethyloxypropyltribromosilane, 3-methoxyethoxymethyloxypropyltrichloro Lan, 3- (1-ethoxyethyloxy) propylchlorodimethoxysilane, 3-t-butoxycarbonyloxypropyldichloromethoxysilane, 3-t-butoxypropylchlorodiethoxysilane, 3-triphenylmethoxypropyldichloroethoxysilane, 3 -Halogenosilane compounds such as benzyloxypropyltribromosilane, where X ⁰ is a group represented by the formula: OG;
These silane compounds (1) can be used singly or in combination of two or more.

Among these, as the silane compound (1), a cured product having better adhesiveness is obtained, so trialkoxysilane compounds in which X ⁰ is a halogen atom, trialkoxysilane in which X ⁰ is a cyano group Compounds, or trialkoxysilane compounds in which X ⁰ is a group represented by the formula: OG are preferred, trialkoxysilane compounds having a 3-chloropropyl group, trialkoxysilane compounds having a 3-acetoxypropyl group More preferred are trialkoxysilane compounds having a 2-cyanoethyl group, or trialkoxysilane compounds having a 3-cyanopropyl group.

[Silane compound (2)]
Silane compounds (2) have the formula _{^{(2): R 2 Si (}} OR 4) q (X 2) is a compound represented by _3-q.
In the formula (2), specific examples of R ² include those exemplified as R ² in the silane compound copolymer (A).

R ⁴ represents the same alkyl group having 1 to 6 carbon atoms as R ³ .
X ² represents the same halogen atom as X ¹ .
q represents an integer of 0 to 3.
When q is 2 or more, OR ⁴ may be the same or different. When (3-q) is 2 or more, X ² may be the same or different.

Specific examples of the silane compound (2) include methyltrimethoxysilane, methyltriethoxysilane, ethyltrimethoxysilane, ethyltriethoxysilane, n-propyltrimethoxysilane, n-butyltriethoxysilane, i-butyltrimethoxy. Alkyltrialkoxysilane compounds such as silane, n-pentyltriethoxysilane, n-hexyltrimethoxysilane, i-octyltriethoxysilane, dodecyltrimethoxysilane, methyldimethoxyethoxysilane, methyldiethoxymethoxysilane;
Alkylhalogenoalkoxysilane compounds such as methylchlorodimethoxysilane, methyldichloromethoxysilane, methylchlorodiethoxysilane, ethylchlorodimethoxysilane, ethyldichloromethoxysilane, n-propylchlorodimethoxysilane, n-propyldichloromethoxysilane;
Alkyltrihalogenosilane compounds such as methyltrichlorosilane, methyltribromosilane, ethyltrichlorosilane, ethyltribromosilane, n-propyltrichlorosilane;

Has substituents such as phenyltrimethoxysilane, 4-methoxyphenyltrimethoxysilane, 2-chlorophenyltrimethoxysilane, phenyltriethoxysilane, 2-methoxyphenyltriethoxysilane, phenyldimethoxyethoxysilane, phenyldiethoxymethoxysilane Optionally phenyltrialkoxysilane compounds;
Phenylhalogenoalkoxysilane compounds which may have a substituent such as phenylchlorodimethoxysilane, phenyldichloromethoxysilane, phenylchloromethoxyethoxysilane, phenylchlorodiethoxysilane, phenyldichloroethoxysilane;
And phenyltrihalogenosilane compounds which may have a substituent such as phenyltrichlorosilane, phenyltribromosilane, 4-methoxyphenyltrichlorosilane, 2-chlorophenyltrichlorosilane, and 2-ethoxyphenyltrichlorosilane.
These silane compounds (2) can be used singly or in combination of two or more.

[A mixture of silane compounds]
Even if the mixture of the silane compound (1) and the silane compound (2) is used as the mixture of the silane compound used for producing the silane compound copolymer (A ′), the object of the present invention is further inhibited. Although it may be a mixture containing other silane compounds as long as it is not, a mixture comprising the silane compound (1) and the silane compound (2) is preferred.

  The use ratio of the silane compound (1) and the silane compound (2) is preferably a molar ratio of [silane compound (1)]: [silane compound (2)] = 55:45 to 25:75.

  The method for condensing the mixture of the silane compounds is not particularly limited, but the silane compound (1), the silane compound (2), and other silane compounds as required are dissolved in a solvent, and a predetermined amount of catalyst is added. And a method of stirring at a predetermined temperature.

The catalyst used may be either an acid catalyst or a base catalyst.
Examples of the acid catalyst include inorganic acids such as hydrochloric acid, sulfuric acid, nitric acid, and phosphoric acid; organic acids such as methanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid, acetic acid, and trifluoroacetic acid; It is done.

  Base catalysts include trimethylamine, triethylamine, lithium diisopropylamide, lithium bis (trimethylsilyl) amide, pyridine, 1,8-diazabicyclo [5.4.0] -7-undecene, aniline, picoline, 1,4-diazabicyclo [2 2.2] Organic bases such as octane and imidazole; Organic salt hydroxides such as tetramethylammonium hydroxide and tetraethylammonium hydroxide; Metals such as sodium methoxide, sodium ethoxide, sodium t-butoxide and potassium t-butoxide Alcoholates; Metal hydrides such as sodium hydride and calcium hydride; Metal hydroxides such as sodium hydroxide, potassium hydroxide and calcium hydroxide; Metal carbonates such as sodium carbonate, potassium carbonate and magnesium carbonate; Hydrogen carbonate And the like are; thorium, metal hydrogen carbonates such as potassium hydrogen carbonate.

  Among these, as a catalyst to be used, an acid catalyst is preferable and an inorganic acid is more preferable.

  The usage-amount of a catalyst is 0.1 mol%-10 mol% normally with respect to the total molar amount of a silane compound, Preferably it is the range of 1 mol%-5 mol%.

  The solvent to be used can be appropriately selected according to the type of the silane compound. For example, water; aromatic hydrocarbons such as benzene, toluene and xylene; esters such as methyl acetate, ethyl acetate, propyl acetate and methyl propionate; ketones such as acetone, methyl ethyl ketone, methyl i-butyl ketone and cyclohexanone; methyl And alcohols such as alcohol, ethyl alcohol, n-propyl alcohol, i-propyl alcohol, n-butyl alcohol, i-butyl alcohol, s-butyl alcohol and t-butyl alcohol. These solvents can be used alone or in combination of two or more.

  Among these, water, aromatic hydrocarbons, and a mixed solvent thereof are preferable, and a mixed solvent of water and toluene is particularly preferable. When water and toluene are used, the ratio of water to toluene (volume ratio) is preferably 1: 9 to 9: 1, more preferably 7: 3 to 3: 7.

  The amount of the solvent used is such that the total molar amount of the silane compound is usually 0.1 mol to 10 mol, preferably 0.5 mol to 10 mol per liter of the solvent.

  The temperature at which the silane compound is condensed (reacted) is usually in the temperature range from 0 ° C. to the boiling point of the solvent used, preferably in the range of 20 ° C. to 100 ° C. If the reaction temperature is too low, the progress of the condensation reaction may be insufficient. On the other hand, if the reaction temperature is too high, it is difficult to suppress gelation. The reaction is usually completed in 30 minutes to 20 hours.

  After completion of the reaction, when an acid catalyst is used, an alkaline aqueous solution such as sodium hydrogen carbonate is added to the reaction solution. When a base catalyst is used, the reaction solution is added with an acid such as hydrochloric acid. Summing is performed, and the salt generated at that time is removed by filtration or washing with water, etc., and the desired silane compound copolymer can be obtained.

(B) Epoxy Compound The curable composition of the present invention contains an epoxy compound (hereinafter sometimes referred to as “epoxy compound (B)”) as the component (B).
Since the curable composition of this invention contains an epoxy compound (B), the hardened | cured material excellent in heat resistance can be obtained.

  The epoxy compound (B) may be any compound having an epoxy group in the molecule, but a compound having two or more epoxy groups is preferable.

  Examples of the epoxy compound having two or more epoxy groups include glycidyl ethers of phenols such as bisphenol A, bisphenol F, resorcinol, phenol novolac, and cresol novolac; glycidyl ethers of alcohols such as butanediol, polyethylene glycol, and polypropylene glycol; Glycidyl esters of carboxylic acids such as acids, isophthalic acid and tetrahydrophthalic acid; so-called alicyclics in which an epoxy is introduced by oxidizing the double bond of a compound containing an alicyclic structure having a carbon-carbon double bond Formula epoxy compounds;

Bisphenol A type epoxy resin, bisphenol F type epoxy resin, bisphenol S type epoxy resin, alicyclic epoxy resin, cresol novolac type epoxy resin, phenol novolac type epoxy resin, biphenyl type epoxy resin, glycidylamine type epoxy resin, glycidyl ester type Epoxy resin, hydantoin type epoxy resin, acrylic acid modified epoxy resin (epoxy acrylate), phosphorus-containing epoxy resin, stilbene type epoxy resin, hydroquinone type epoxy resin, naphthalene skeleton type epoxy resin, tetraphenylolethane type epoxy resin, DPP -N-pentylphthalate) type epoxy resin, trishydroxyphenylmethane type epoxy resin, dicyclopentadienephenol type epoxy resin, silicon-containing epoxy Resin, diglycidyl ether of bisphenol A ethylene oxide adduct, diglycidyl ether of bisphenol A propylene oxide adduct, cyclohexanedimethanol diglycidyl ether, polyglycidyl ether of aliphatic polyhydric alcohol, polyglycidyl ester of polybasic acid, and These halides (brominated epoxy resins and the like) and epoxy resins such as nuclear hydrogenated materials;
These can be used individually by 1 type or in combination of 2 or more types.

  Among these, it is preferable to use an alicyclic epoxy compound from the viewpoint of obtaining a cured product having high adhesive force even at a high temperature. Examples of the alicyclic epoxy compound include 3,4-epoxycyclohexanecarboxylic acid 3,4-epoxycyclohexylmethyl, vinylcyclohexene diepoxide, which are represented by the following formula (a), having two or more epoxy rings in the molecule. Can be mentioned. Among these, 3,4-epoxycyclohexanecarboxylate 3,4-epoxycyclohexylmethyl is particularly preferable.

(C) Curing Agent The curable composition of the present invention comprises a curing agent (hereinafter referred to as “curing agent”) containing, as component (C), an alicyclic acid anhydride having a carboxyl group and other alicyclic acid anhydrides. (C) ").
Since the curable composition of this invention contains a hardening | curing agent (C), the hardened | cured material excellent in heat resistance can be obtained.

The alicyclic acid anhydride having a carboxyl group is an alicyclic acid anhydride substituted with at least one carboxyl group.
Specific examples of the alicyclic acid anhydride include polyazeline acid anhydride, 3-methyl-1,2,3,6-tetrahydrophthalic anhydride, 4-methyl-1,2,3,6-tetrahydrophthalic anhydride. Acid, tetrahydrophthalic anhydride, 3-methyl-hexahydrophthalic anhydride, 4-methyl-hexahydrophthalic anhydride, hexahydrophthalic anhydride, methyl nadic anhydride, 5-norbornene-2,3-dicarboxylic anhydride, norbornane Examples include 2,3-dicarboxylic acid anhydride, methyl-5-norbornene-2,3-dicarboxylic acid anhydride, methyl-norbornane-2,3-dicarboxylic acid anhydride, and the like.
The carboxyl group may be substituted at any position of the alicyclic structure of the alicyclic acid anhydride, and the position of substitution and the number of carboxyl groups to be substituted are not particularly limited.

Of these, cyclohexane-1,2,4-tricarboxylic acid-1,2 anhydride and cyclohexane-1,2,3-tricarboxylic acid-1,2 anhydride, in which a carboxyl group is substituted for hexahydrophthalic anhydride, are preferred. Cyclohexane-1,2,4-tricarboxylic acid-1,2 anhydride is particularly preferable. This compound may exist as a stereoisomer, but may be any isomer.
The alicyclic acid anhydride having a carboxyl group can be used alone or in combination of two or more.

Other alicyclic acid anhydrides are alicyclic acid anhydrides having no carboxyl group. Examples of the other alicyclic acid anhydrides include those exemplified as the alicyclic acid anhydride of the alicyclic acid anhydride having a carboxyl group. Of these, 3-methyl-hexahydrophthalic anhydride and 4-methyl-hexahydrophthalic anhydride are preferable, and 4-methyl-hexahydrophthalic anhydride is particularly preferable.
Other alicyclic acid anhydrides can be used singly or in combination of two or more.

  In the curing agent (C), the proportion of the alicyclic acid anhydride having a carboxyl group and the other alicyclic acid anhydride is such that the alicyclic acid anhydride having a carboxyl group and the other alicyclic acid anhydride are used. It is preferable that (alicyclic acid anhydride having a carboxyl group): (other alicyclic acid anhydride) = 50: 50 to 10:90.

  In the curable composition of the present invention, the components (A), (B), and (C) are mixed in a mass ratio of (A) and [(B) + (C)] (A): [( B) + (C)] = 100: 20 to 100: 60, and the components (A ′), (B), and (C) are used as (A ′) and [(B) + (C) ] In a mass ratio of (A ′): [(B) + (C)] = 100: 20 to 100: 60. When the ratio of (B) + (C) is less than 20, sufficient adhesive strength cannot be obtained, and when it is more than 60, the compatibility with the component (A) or the component (A ′) is deteriorated and excellent transparency. Sex cannot be obtained.

  Furthermore, the use ratio of the components (B) and (C) is, by mass ratio, preferably (B) :( C) = 4: 6 to 6: 4, particularly preferably 5: 5.

  By using each component in such a ratio, it is possible to obtain a curable composition capable of obtaining a cured product having excellent transparency and heat resistance over a long period of time and having a high adhesive force even at high temperatures.

The curable composition of the present invention preferably further contains an antioxidant in addition to the above components to prevent oxidative deterioration during heating.
Examples of the antioxidant include phosphorus-based antioxidants, phenol-based antioxidants, sulfur-based antioxidants, and the like. Among these, phosphorus-based antioxidants are preferable.

  Phosphorus antioxidants include triphenyl phosphite, diphenylisodecyl phosphite, phenyl diisodecyl phosphite, tris (nonylphenyl) phosphite, diisodecylpentaerythritol phosphite, tris (2,4-di-t-butylphenyl) ) Phosphite, cyclic neopentanetetraylbis (octadecyl) phosphite, cyclic neopentanetetraylbis (2,4-di-t-butylphenyl) phosphite, cyclic neopentanetetraylbis (2,4 -Di-t-butyl-4-methylphenyl) phosphite, bis [2-t-butyl-6-methyl-4- {2- (octadecyloxycarbonyl) ethyl} phenyl] hydrogen phosphite, etc. 9,10-dihydro- -Oxa-10-phosphaphenanthrene-10-oxide, 10- (3,5-di-t-butyl-4-hydroxybenzyl) -9,10-dihydro-9-oxa-10-phosphaphenanthrene-10- And oxaphosphaphenanthrene oxides such as 10-decyloxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide.

  Examples of phenolic antioxidants include 2,6-di-t-butyl-p-cresol, dibutylhydroxytoluene, butylated hydroxyanisole, 2,6-di-t-butyl-p-ethylphenol, stearyl-β- Monophenols such as (3,5-di-t-butyl-4-hydroxyphenyl) propionate; 2,2′-methylenebis (4-methyl-6-t-butylphenol), 2,2′-methylenebis (4- Ethyl-6-tert-butylphenol), 4,4′-thiobis (3-methyl-6-tert-butylphenol), 4,4′-butylidenebis (3-methyl-6-tert-butylphenol), 3,9-bis [1,1-dimethyl-2- {β- (3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy} ethyl] 2,4,8, Bisphenols such as 10-tetraoxaspiro [5,5] undecane; 1,1,3-tris (2-methyl-4-hydroxy-5-tert-butylphenyl) butane, 1,3,5-trimethyl-2 , 4,6-tris (3,5-di-t-butyl-4-hydroxybenzyl) benzene, tetrakis- [methylene-3- (3 ′, 5′-di-t-butyl-4′-hydroxyphenyl) Propionate] methane, bis [3,3′-bis- (4′-hydroxy-3′-t-butylphenyl) butyric acid] glycol ester, 1,3,5-tris (3 ′, 5′-di-) t-butyl-4′-hydroxybenzyl) -S-triazine-2,4,6- (1H, 3H, 5H) trione, polymer phenols such as tocophenol;

  Examples of the sulfur-based antioxidant include dilauryl-3,3'-thiodipropionate, dimyristyl-3,3'-thiodipropionate, distearyl-3,3'-thiodipropionate, and the like.

These antioxidants can be used alone or in combination of two or more.
Preferably the usage-amount of antioxidant is 0.01-10 mass parts with respect to 100 mass parts of silane compound copolymers (A) or (A ').

The curable composition of the present invention may further contain other components as long as the object of the present invention is not impaired.
Examples of other components include ultraviolet absorbers, light stabilizers, and diluents.

The ultraviolet absorber is added for the purpose of improving the light resistance of the resulting cured product.
Examples of the ultraviolet absorber include salicylic acids such as phenyl salicylate, pt-butylphenyl salicylate, p-octylphenyl salicylate; 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4 -Octoxybenzophenone, 2-hydroxy-4-dodecyloxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2-hydroxy-4-methoxy- Benzophenones such as 5-sulfobenzophenone; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 2- (2′-hydroxy-5′-t-butylphenyl) benzotriazole, 2- (2 ′ -Hydroxy-3 ', 5'-di-t -Butylphenyl) benzotriazole, 2- (2'-hydroxy-3'-t-butyl-5'-methylphenyl) -5-chlorobenzotriazole, 2- (2'-hydroxy-3 ', 5'-di -T-butylphenyl) -5-chlorobenzotriazole, 2- (2'-hydroxy-3 ', 5'-di-t-amylphenyl) benzotriazole, 2-{(2'-hydroxy-3', 3 Benzotriazoles such as '', 4 '', 5 '', 6 ''-tetrahydrophthalimidomethyl) -5'-methylphenyl} benzotriazole; bis (2,2,6,6-tetramethyl-4-piperidyl ) Sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) [{3,5-bis (1 , 1-Dimethyl Chill) -4-hydroxyphenyl} methyl] butyl hindered amines, such as malonate; and the like.

These ultraviolet absorbers can be used alone or in combination of two or more.
Preferably the usage-amount of a ultraviolet absorber is 0.01-10 mass parts with respect to 100 mass parts of silane compound copolymers (A) or (A ').

The light stabilizer is added for the purpose of improving the light resistance of the resulting cured product.
Examples of the light stabilizer include poly [{6- (1,1,3,3, -tetramethylbutyl) amino-1,3,5-triazine-2,4-diyl} {(2,2,6 , 6-tetramethyl-4-piperidine) imino} hexamethylene {(2,2,6,6-tetramethyl-4-piperidine) imino}] and the like.

These light stabilizers can be used alone or in combination of two or more.
The amount of the light stabilizer used is preferably 0.01 to 10 parts by mass with respect to 100 parts by mass of the silane compound copolymer (A) or (A ′).

A diluent is added in order to adjust the viscosity of the curable composition.
Examples of the diluent include glycerin diglycidyl ether, butanediol diglycidyl ether, diglycidyl aniline, neopentyl glycol glycidyl ether, cyclohexane dimethanol diglycidyl ether, alkylene diglycidyl ether, polyglycol diglycidyl ether, and polypropylene glycol diglycidyl ether. Examples include ether, trimethylolpropane triglycidyl ether, glycerin triglycidyl ether, 4-vinylcyclohexene monoxide, vinylcyclohexene dioxide, methylated vinylcyclohexene dioxide, and the like.
These diluents can be used singly or in combination of two or more.

  The curable composition of the present invention is, for example, known by blending the above components (A) or (A ′), (B), (C), and, optionally, an antioxidant and other components in a predetermined ratio. It can be obtained by mixing and defoaming by the above method.

According to the curable composition of the present invention obtained as described above, even when irradiated with high energy light or in a high temperature state, it is not colored and the transparency is not lowered, and it is long-term. It is possible to obtain a cured product having excellent transparency and high adhesive strength.
Therefore, the curable composition of the present invention is suitably used as a raw material for optical parts and molded articles, an adhesive, a coating agent, and the like. In particular, since the problem relating to deterioration of the optical element fixing material accompanying the increase in luminance of the optical element can be solved, the curable composition of the present invention can be suitably used as a composition for optical element fixing material. it can.

2) Cured product The second of the present invention is a cured product obtained by curing the curable composition of the present invention.
Heat curing is mentioned as a method of hardening the curable composition of this invention. The heating temperature for curing is usually 100 to 200 ° C., and the heating time is usually 10 minutes to 20 hours, preferably 30 minutes to 10 hours.

The cured product of the present invention has excellent transparency over a long period of time, even when irradiated with high energy light or in a high temperature state, without being colored and having a reduced transparency, and High adhesive strength.
Therefore, the hardened | cured material of this invention is used suitably as an optical component, a molded object, an adhesive layer, a coating layer, etc. In particular, since the problem relating to the deterioration of the optical element fixing material accompanying the increase in luminance of the optical element can be solved, the cured product of the present invention can be suitably used as the optical element fixing material.

It can be confirmed that the cured product of the present invention has a high adhesive force, for example, by measuring the adhesive force as follows. That is, the curable composition is applied to the mirror surface of the silicon chip, and the coated surface is placed on the adherend and pressure-bonded, and then heated and cured. This is left for 30 seconds on a measurement stage of a bond tester heated in advance to a predetermined temperature (for example, 23 ° C.), and in a horizontal direction (shear direction) with respect to the adhesion surface from a position 50 μm high from the adherend. Stress is applied and the adhesion between the test piece and the adherend is measured.
The adhesive strength of the cured product is preferably 110 N / 2 mm □ or more at 23 ° C.

  It can be confirmed that the cured product is excellent in transparency by measuring light transmittance. The light transmittance of the cured product is preferably 80% or more, more preferably 85% or more, with light having a wavelength of 450 nm.

  It can be confirmed that the cured product has excellent heat resistance over a long period of time because the change in transparency is small even after the cured product has been placed at a high temperature for a long time. The transparency is preferably such that the transmittance at a wavelength of 450 nm is 80% or more of the initial transmittance after being placed at 150 ° C. for 300 hours.

3) Method of using curable composition The third of the present invention is a method of using the curable composition of the present invention as an adhesive for optical element fixing materials or an encapsulant for optical element fixing materials.
Examples of optical elements include light emitting elements such as LEDs and LDs, light receiving elements, composite optical elements, and optical integrated circuits.

<Adhesive for optical element fixing material>
The curable composition of this invention can be used conveniently as an adhesive agent for optical element fixing materials.

  As a method of using the curable composition of the present invention as an adhesive for an optical element fixing material, the composition is applied to one or both adhesive surfaces of a material to be bonded (such as an optical element and its substrate). After the pressure bonding, there is a method in which the material to be bonded is firmly bonded by heat curing.

  Main substrate materials for bonding optical elements include glass such as soda lime glass and heat-resistant hard glass; ceramics; iron, copper, aluminum, gold, silver, platinum, chromium, titanium, and alloys of these metals , Metals such as stainless steel (SUS302, SUS304, SUS304L, SUS309, etc.); polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, ethylene-vinyl acetate copolymer, polystyrene, polycarbonate, polymethylpentene, polysulfone, polyetheretherketone , Synthetic resins such as polyethersulfone, polyphenylene sulfide, polyetherimide, polyimide, polyamide, acrylic resin, norbornene resin, cycloolefin resin, glass epoxy resin, etc.

  The heating temperature at the time of heat curing is usually 100 to 200 ° C., although it depends on the curable composition used. The heating time is usually 10 minutes to 20 hours, preferably 30 minutes to 10 hours.

<Sealant for optical element fixing material>
The curable composition of this invention can be used suitably as a sealing agent of an optical element sealing body.

As a method of using the curable composition of the present invention as a sealant for an optical element fixing material, for example, after molding the composition into a desired shape to obtain a molded body containing the optical element, the process itself And the like, and the like.
The method for molding the curable composition of the present invention into a desired shape is not particularly limited, and a known molding method such as a normal transfer molding method or a casting method can be employed.

  Although the heating temperature at the time of heat-curing depends on the curable composition to be used, it is usually 100 to 200 ° C. The heating time is usually 10 minutes to 20 hours, preferably 30 minutes to 10 hours.

  Since the obtained optical element sealing body uses the curable composition of the present invention, an optical element having a short peak wavelength of 400 to 490 nm, such as white or blue light emitting LED, is used. Also, it is excellent in transparency and heat resistance that does not deteriorate due to heat or light.

  EXAMPLES Next, although an Example and a comparative example demonstrate this invention further in detail, this invention is not limited to the following Example.

(Weight average molecular weight measurement)
The weight average molecular weight (Mw) of the silane compound copolymer obtained in the production example was a standard polystyrene conversion value, and was measured with the following apparatus and conditions.
Device name: HLC-8220GPC, manufactured by Tosoh Corporation Column: TSKgelGMHXL, TSKgelGMHXL and TSKgel2000HXL sequentially connected Solvent: tetrahydrofuran Injection amount: 80 μl
Measurement temperature: 40 ° C
Flow rate: 1 ml / min Detector: Differential refractometer

(Measurement of IR spectrum)
The IR spectrum of the silane compound copolymer obtained in Production Example was measured using the following apparatus.
Fourier transform infrared spectrophotometer (Spectrum 100, manufactured by PerkinElmer)

(Production Example 1)
In a 300 ml eggplant-shaped flask, 16.7 g (84 mmol) of phenyltrimethoxysilane (manufactured by Tokyo Chemical Industry Co., Ltd.) as the silane compound (2) and 3-acetoxypropyltrimethoxysilane (manufactured by Amax Co.) as the silane compound (1) After charging 8.0 g (36 mmol), 120 ml of toluene as a solvent and 60 ml of distilled water, 0.15 g (1.5 mmol) of phosphoric acid (manufactured by Kanto Chemical Co., Inc.) was added as a catalyst while stirring, and further at room temperature for 16 hours. Stirring was continued.

  After completion of the reaction, 100 ml of ethyl acetate was added to the reaction mixture and neutralized with a saturated aqueous sodium hydrogen carbonate solution. After standing still for a while, water was removed, and the organic layer was washed twice with distilled water and then dried over anhydrous magnesium sulfate. After the magnesium sulfate was filtered off, the filtrate was concentrated to 50 ml with an evaporator, dropped into a large amount of n-hexane to cause reprecipitation, and the precipitate was separated by decantation. The obtained precipitate was dissolved and recovered in methyl ethyl ketone (MEK), and the solvent was distilled off under reduced pressure with an evaporator, followed by vacuum drying to obtain 14.7 g of a silane compound copolymer (A1).

The weight average molecular weight (Mw) of the silane compound copolymer (A1) was 2,500, and the molecular weight distribution (Mw / Mn) was 1.53.
In addition, IR spectrum data of the silane compound copolymer (A1) is shown below.
Si—Ph: 699 cm ⁻¹ , 741 cm ⁻¹ , Si—O: 1132 cm ⁻¹ , —CO: 1738 cm ⁻¹

(Production Example 2)
In Production Example 1, the same procedure as in Production Example 1 except that the amount of phenyltrimethoxysilane used was 14.3 g (72 mmol) and the amount of 3-acetoxypropyltrimethoxysilane used was 10.7 g (48 mmol). 15.9 g of silane compound copolymer (A2) was obtained.

The weight average molecular weight (Mw) of the silane compound copolymer (A2) was 2,600, and the molecular weight distribution (Mw / Mn) was 1.51.
In addition, IR spectrum data of the silane compound copolymer (A2) is shown below.
Si—Ph: 699 cm ⁻¹ , 741 cm ⁻¹ , Si—O: 1132 cm ⁻¹ , —CO: 1738 cm ⁻¹

(Production Example 3)
In Production Example 1, the same procedure as in Production Example 1 except that the amount of phenyltrimethoxysilane used was 11.9 g (60 mmol) and the amount of 3-acetoxypropyltrimethoxysilane used was 13.3 g (60 mmol). The silane compound copolymer (A3) 15.3g was obtained.

The weight average molecular weight (Mw) of the silane compound copolymer (A3) was 2,600, and the molecular weight distribution (Mw / Mn) was 1.60.
In addition, IR spectrum data of the silane compound copolymer (A3) is shown below.
^{Si-Ph: 700cm -1, 742cm} -1, Si-O: 1132cm -1, -CO: 1738cm -1

(Production Example 4)
In Production Example 1, instead of using 16.7 g (84 mmol) of phenyltrimethoxysilane and 8.0 g (36 mmol) of 3-acetoxypropyltrimethoxysilane, 11.9 g (60 mmol) of phenyltrimethoxysilane (manufactured by Tokyo Chemical Industry Co., Ltd.) ) And 3-glycidoxypropyltrimethoxysilane (Tokyo Kasei Kogyo Co., Ltd.) 14.2 g (60 mmol) are used in the same manner as in Production Example 1 to obtain 16.3 g of the silane compound copolymer (A4). It was.

The weight average molecular weight (Mw) of the silane compound copolymer (A4) was 2,800, and the molecular weight distribution (Mw / Mn) was 1.56.
In addition, IR spectrum data of the silane compound copolymer (A4) is shown below.
^{Si-Ph: 700cm -1, 742cm} -1, Si-O: 1132cm -1, epoxy group: 1254cm ^-1

(Production Example 5)
In a 300 ml eggplant-shaped flask, 11.9 g (60 mmol) of phenyltrimethoxysilane (manufactured by Tokyo Chemical Industry Co., Ltd.) as the silane compound (2) and 3-chloropropyltrimethoxysilane (manufactured by Tokyo Chemical Industry Co., Ltd.) as the silane compound (1) ) 11.9 g (60 mmol), 60 ml of toluene as a solvent and 30 ml of distilled water were added, and then 0.15 g (1.5 mmol) of phosphoric acid (manufactured by Kanto Chemical Co., Inc.) was added as a catalyst while stirring. Stirring was continued for an hour.

  After completion of the reaction, the reaction solution was neutralized with a saturated aqueous sodium hydrogen carbonate solution. To this was added 100 ml of ethyl acetate, and the mixture was stirred for a while and allowed to stand. Then, water was removed, the organic layer was washed twice with distilled water, and dried over anhydrous magnesium sulfate. After magnesium sulfate was filtered off, the filtrate was dropped into a large amount of n-hexane to cause reprecipitation, and hexane was removed to take out the precipitate. The obtained precipitate was dissolved and recovered in methyl ethyl ketone (MEK), and the solvent was distilled off under reduced pressure with an evaporator, followed by vacuum drying to obtain 12.9 g of a silane compound copolymer (A5).

The weight average molecular weight (Mw) of the silane compound copolymer (A5) was 3,600, and the molecular weight distribution (Mw / Mn) was 1.63.
In addition, IR spectrum data of the silane compound copolymer (A5) is shown below.
^{Si-Ph: 700cm -1, 741cm} -1, Si-O: 1133cm -1, -Cl: 648cm -1

(Production Example 6)
In Production Example 5, the same procedure as in Production Example 5 was conducted except that the amount of phenyltrimethoxysilane used was 16.7 g (84 mmol) and the amount of 3-chloropropyltrimethoxysilane used was 7.15 g (36 mmol). 13.4 g of compound copolymer (A6) was obtained.

The weight average molecular weight (Mw) of the silane compound copolymer (A6) was 3,300, and the molecular weight distribution (Mw / Mn) was 1.59.
In addition, IR spectrum data of the silane compound copolymer (A6) is shown below.
^{Si-Ph: 700cm -1, 742cm} -1, Si-O: 1133cm -1, -Cl: 648cm -1

(Production Example 7)
In Production Example 5, the same procedure as in Production Example 5 was conducted except that the amount of phenyltrimethoxysilane used was 14.3 g (72 mmol) and the amount of 3-chloropropyltrimethoxysilane used was 9.54 g (48 mmol). 13.1 g of compound copolymer (A7) was obtained.

The weight average molecular weight (Mw) of the silane compound copolymer (A7) was 3,400, and the molecular weight distribution (Mw / Mn) was 1.61.
In addition, IR spectrum data of the silane compound copolymer (A7) is shown below.
Si—Ph: 699 cm ⁻¹ , 741 cm ⁻¹ , Si—O: 1132 cm ⁻¹ , —Cl: 648 cm ⁻¹

(Production Example 8)
In Production Example 5, in place of 11.9 g of 3-chloropropyltrimethoxysilane, 10.5 g (60 mmol) of 2-cyanoethyltrimethoxysilane (manufactured by Amax Co.) was used in the same manner as in Production Example 5, except that silane 12.3 g of compound copolymer (A8) was obtained.

The weight average molecular weight (Mw) of the silane compound copolymer (A8) was 3,500, and the molecular weight distribution (Mw / Mn) was 1.61.
In addition, IR spectrum data of the silane compound copolymer (A8) is shown below.
^{Si-Ph: 700cm -1, 742cm} -1, Si-O: 1133cm -1, -CN: 2252cm -1

(Production Example 9)
In Production Example 8, the amount of phenyltrimethoxysilane used was 16.7 g (84 mmol), and the amount of 2-cyanoethyltrimethoxysilane used was 6.31 g (36 mmol). 13.3 g of copolymer (A9) was obtained.

The weight average molecular weight (Mw) of the silane compound copolymer (A9) was 3,200, and the molecular weight distribution (Mw / Mn) was 1.64.
In addition, IR spectrum data of the silane compound copolymer (A9) is shown below.
Si—Ph: 699 cm ⁻¹ , 742 cm ⁻¹ , Si—O: 1131 cm ⁻¹ , —CN: 2253 cm ⁻¹

(Production Example 10)
The same procedure as in Production Example 8 was conducted except that the amount of phenyltrimethoxysilane used was 14.3 g (72 mmol) and the amount of 2-cyanoethyltrimethoxysilane used was 7.01 g (48 mmol). 12.9 g of copolymer (A10) was obtained.

The weight average molecular weight (Mw) of the silane compound copolymer (A10) was 3,300, and the molecular weight distribution (Mw / Mn) was 1.62.
In addition, IR spectrum data of the silane compound copolymer (A10) is shown below.
Si—Ph: 699 cm ⁻¹ , 742 cm ⁻¹ , Si—O: 1131 cm ⁻¹ , —CN: 2253 cm ⁻¹

Example 1
10 g of the silane compound copolymer (A1) obtained in Production Example 1 and 1.5 g of 3,4-epoxycyclohexanecarboxylic acid 3,4-epoxycyclohexylmethyl (manufactured by Sigma-Aldrich) as the component (B), (C) As components, cycloaliphatic-1,2,4-tricarboxylic acid-1,2-anhydride (manufactured by Mitsubishi Gas Chemical Company) 0.15 g as an alicyclic acid anhydride having a carboxyl group, and other alicyclic acid anhydrides As a product, 1.35 g of 4-methylcyclohexane-1,2-dicarboxylic acid anhydride (manufactured by Tokyo Chemical Industry Co., Ltd.) was added, and the entire volume was sufficiently mixed and defoamed to obtain a curable composition (1).

(Examples 2 to 8)
In Example 1, the silane compound copolymer, the component (B), and the component (C) are used in the same manner as in Example 1 except that they are used in the types and amounts described in Table 1 below. Compositions (2) to (8) were obtained.

(Examples 9 and 10)
In Examples 4 and 5, a curable composition (9) was obtained in the same manner as in Examples 4 and 5 except that 0.5 parts by mass of IRGAFOS168 (manufactured by Ciba Japan), which is a phosphorus-based antioxidant, was further added. , (10) were obtained.

(Comparative Examples 1 and 2)
In Example 1, a curable composition was obtained in the same manner as in Example 1, except that the silane compound copolymer, the component (B), and the component (C) were used in the amounts shown in Table 1 below. (11) and (12) were obtained, respectively.

(Comparative Example 3)
In Example 1, a curable composition (in the same manner as in Example 1 except that 1.5 g of an alicyclic amine-based curing agent (trade name: EH3895, manufactured by ADEKA) was used instead of the component (C). 13) was obtained.

(Comparative Example 4)
In Example 1, instead of the component (C), 1.45 g of 4-methylcyclohexane-1,2-dicarboxylic acid anhydride (manufactured by Tokyo Chemical Industry Co., Ltd.) and 0.05 g of a curing catalyst triphenylphosphine (manufactured by Kanto Chemical Co., Ltd.) A curable composition (14) was obtained in the same manner as in Example 1, except that

(Comparative Example 5)
In Example 3, it replaces with a silane compound copolymer (A2), and it uses similarly to Example 3 except using 10g of silane compound copolymers (A4) obtained by manufacture example 4, curable composition (15 )

(Examples 11-16, Comparative Examples 6-13)
In Example 1, the silane compound copolymer, the component (B), the component (C), etc. were used in the same manner as in Example 1 except that they were used in the types and amounts shown in Table 1 below. Sex compositions (16) to (29) were obtained.

For the cured products of the curable compositions (1) to (29) obtained in Examples 1 to 16 and Comparative Examples 1 to 13, the adhesive strength, initial transmittance, and transmittance after heating were as follows. It was measured.
The measurement results are shown in Table 2 and Table 2 below.

(Adhesion test)
The curable composition was applied to a mirror surface of a 2 mm square silicon chip to a thickness of about 2 μm, and the coated surface was placed on an adherend (silver-plated copper plate) and pressure-bonded. Then, it heat-processed at 180 degreeC for 2 hours, it was made to harden | cure, and the adherend with a test piece was obtained. The test piece-attached adherend is left for 30 seconds on a measurement stage of a bond tester (series 4000, manufactured by Daisy) heated in advance to a predetermined temperature (23 ° C., 100 ° C.), and has a height of 50 μm from the adherend. From the position, stress was applied in a horizontal method (shear direction) to the bonded surface at a speed of 200 μm / s, and the adhesive force between the test piece and the adherend at 23 ° C. and 100 ° C. was measured.

(Measurement of initial transmittance)
The curable composition was poured into a mold so as to have a length of 25 mm, a width of 20 mm, and a thickness of 1 mm, and cured by heating at 140 ° C. for 6 hours to prepare test pieces. About the obtained test piece, the initial transmittance (%) of wavelength 450nm was measured with the spectrophotometer (MPC-3100, Shimadzu Corporation make).

(Measurement of transmittance after heating)
Each test piece whose initial transmittance was measured was put into an oven at 150 ° C. for 100 hours and 300 hours, and the transmittance (%) at a wavelength of 450 nm was measured again.

From Table 2 and Table 2, the cured products of Examples 1 to 16 have high adhesive strength at both 23 ° C. and 100 ° C., and are excellent in initial transmittance and transmittance after heating. It was a thing.
On the other hand, the cured products of Comparative Examples 1, 6 and 10 are inferior in adhesive strength, and the cured products of Comparative Examples 2, 7 and 11 have low transmittance after heating, and Comparative Examples 3, 4, 8, 9, 12 and The cured product of 13 was inferior in adhesive strength and low in transmittance after heating. The cured product of Comparative Example 5 was found to have reduced transmittance when heated for 300 hours.

Claims (12)

(A) In the molecule, the following formulas (i), (ii) and (iii)

[Wherein R ¹ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, X ⁰ represents a halogen atom, a cyano group or a group represented by the formula: OG (wherein G represents a protecting group for a hydroxyl group) D) represents a single bond or a linking group. R ² represents an alkyl group having 1 to 20 carbon atoms or a phenyl group which may have a substituent. ]
(I) and (ii), (i) and (iii), (ii) and (iii), or (i), (ii) and (iii) having repeating units A silane compound copolymer having a weight average molecular weight of 1,000 to 30,000,
(B) An epoxy compound, and (C) a curing agent containing an alicyclic acid anhydride having a carboxyl group and other alicyclic acid anhydrides, are prepared in (A) and [(B) + (C)]. A curable composition containing, in mass ratio, (A): [(B) + (C)] = 100: 20 to 100: 60. The silane compound copolymer of the above (A) is a group represented by the formula: R ¹ —CH (X ⁰ ) —D— ([R ¹ —CH (X ⁰ ) —D]) and R ² The silane compound copolymer of [R ¹ —CH (X ⁰ ) —D]: [R ² ] = 55: 45 to 25:75 in a molar ratio of the abundance ([R ² ]). The curable composition according to 1. (A ′) Formula (1): R ¹ —CH (X ⁰ ) —D—Si (OR ³ ) _p (X ¹ ) _3-p
[Wherein R ¹ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, X ⁰ represents a halogen atom, a cyano group or a group represented by the formula: OG (wherein G represents a protecting group for a hydroxyl group) D) represents a single bond or a linking group. R ³ represents an alkyl group having 1 to 6 carbon atoms, X ¹ represents a halogen atom, and p represents an integer of 0 to 3. ]
And at least one of the silane compounds (1) represented by formula (2): R ² Si (OR ⁴ ) _q (X ² ) _3-q
(In the formula, R ² represents an alkyl group having 1 to 20 carbon atoms or an optionally substituted phenyl group, R ⁴ represents an alkyl group having 1 to 6 carbon atoms, and X ² represents a halogen atom. Q represents an integer of 0 to 3.)
A silane compound copolymer having a weight average molecular weight of 1,000 to 30,000, obtained by condensing a mixture of silane compounds containing at least one of the silane compounds (2) represented by:
A curing agent containing (B) an epoxy compound, and (C) an alicyclic acid anhydride having a carboxyl group and another alicyclic acid anhydride, (A ′) and [(B) + (C)] (A '): [(B) + (C)] = 100: 20 to 100: 60.   In the silane compound copolymer (A ′), the silane compound (1) and the silane compound (2) are in a molar ratio of [silane compound (1)]: [silane compound (2)] = 55:45. The curable composition according to claim 3, which is a silane compound copolymer obtained by condensation at a ratio of ˜25: 75.   The mass ratio of the curing agent (C) is (alicyclic acid anhydride having a carboxyl group) :( other alicyclic acid anhydride) = 50: 50 to 10:90. The curable composition according to 1.   Furthermore, the curable composition of Claim 1 or 3 containing antioxidant.   The curable composition according to claim 6, wherein the antioxidant is a phosphorus-based antioxidant.   The curable composition according to claim 1, which is a composition for an optical element fixing material.   Hardened | cured material formed by hardening | curing the curable composition of Claim 1 or 3.   The cured product according to claim 9, which is an optical element fixing material.   The method which uses the curable composition of Claim 1 or 3 as an adhesive agent for optical element fixing materials.   The method which uses the curable composition of Claim 1 or 3 as a sealing agent for optical element fixing materials.