JPWO2006129607A1 - Flame retardant bedding products - Google Patents

Flame retardant bedding products Download PDF

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Publication number
JPWO2006129607A1
JPWO2006129607A1 JP2007518972A JP2007518972A JPWO2006129607A1 JP WO2006129607 A1 JPWO2006129607 A1 JP WO2006129607A1 JP 2007518972 A JP2007518972 A JP 2007518972A JP 2007518972 A JP2007518972 A JP 2007518972A JP WO2006129607 A1 JPWO2006129607 A1 JP WO2006129607A1
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Prior art keywords
fiber
flame
polyester
compounds
flame retardant
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Inventor
田中 健
健 田中
渡 見尾
渡 見尾
丸山 茂
茂 丸山
真彦 三歩一
真彦 三歩一
進 岩出
進 岩出
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Kaneka Corp
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Kaneka Corp
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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47CCHAIRS; SOFAS; BEDS
    • A47C31/00Details or accessories for chairs, beds, or the like, not provided for in other groups of this subclass, e.g. upholstery fasteners, mattress protectors, stretching devices for mattress nets
    • A47C31/001Fireproof means
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47CCHAIRS; SOFAS; BEDS
    • A47C27/00Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas
    • A47C27/12Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas with fibrous inlays, e.g. made of wool, of cotton
    • A47C27/121Spring, stuffed or fluid mattresses or cushions specially adapted for chairs, beds or sofas with fibrous inlays, e.g. made of wool, of cotton with different inlays
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/02Bed linen; Blankets; Counterpanes
    • A47G9/0207Blankets; Duvets
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/10Pillows
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/07Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • D04H1/4258Regenerated cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43835Mixed fibres, e.g. at least two chemically different fibres or fibre blends

Abstract

本発明の課題は中綿に弾力性に優れるポリエステルを使用した寝具であって、多量のハロゲン含有繊維を使用しなくても長時間の炎にも耐え得る高度の難燃性を備えた寝具を提供することである。中綿とそれを覆う側地からなる難燃性寝具製品であって、中綿においてセルロース系繊維(A)、ポリエステル系繊維(B)およびハロゲン含有繊維(C)を必須成分とすることにより、上記課題を解決した寝具製品が得られる。本発明の寝具製品は優れた難燃性のほか比較的少量のハロゲン含有繊維を使用しているので、多量のポリエステル繊維を使用できるため優れたクッション性を有する寝具を提供することができる。さらに、本発明によればポリエステル系繊維やセルロース系繊維等、易燃性繊維を側地として用いた難燃性寝具製品であっても、難燃性が充分に発揮される為、難燃性と同時に優れた風合いや触感に優れた寝具を提供することができる。An object of the present invention is to provide a bedding using polyester having excellent elasticity for batting, and having a high degree of flame resistance that can withstand a long flame without using a large amount of halogen-containing fiber. It is to be. It is a flame retardant bedding product comprising a batting and a side covering covering it, and the above-mentioned problem is obtained by making the cellulose fiber (A), the polyester fiber (B) and the halogen-containing fiber (C) as essential components in the batting. A bedding product that solves this problem is obtained. Since the bedding product of the present invention uses a relatively small amount of halogen-containing fibers in addition to excellent flame retardancy, a large amount of polyester fibers can be used, so that a bedding having excellent cushioning properties can be provided. Furthermore, according to the present invention, even if it is a flame retardant bedding product using a flammable fiber as a side fabric, such as a polyester fiber and a cellulose fiber, the flame retardant property is sufficiently exerted. At the same time, it is possible to provide bedding with excellent texture and touch.

Description

本発明は、高度に難燃化された寝具製品に関する。   The present invention relates to a highly flame retardant bedding product.

火災の防止には、家屋内の寝具製品、インテリア製品や家具等に使用される素材への難燃性付与が好ましい。また、難燃性が付与された素材は寝具製品やインテリア製品の触感や吸湿性などの快適さを損なわないものでなければならない。
寝具製品やインテリア製品の中で、マットレスパッドやコンフォーター、あるいは枕等、クッション性を要求される製品がある。多くの場合、これらの製品において、中綿にはクッション性を発現するため優れた弾力性を有するポリエステル繊維が使用される。また、側地には吸湿性に優れる綿や耐久性に優れるポリエステルなどの繊維が使用される。これらの製品に対して、様々な難燃化の検討がされてきたが、その殆どが側地の難燃化に関するものであった。
繊維を難燃化するにはアンチモン化合物や燐化合物のような難燃化剤を含む繊維やガラス繊維のような難燃性の繊維を使用する必要がある。このような繊維は触感あるいは吸湿性などの快適さが劣る。従って、中綿を有する寝具では側地ではなく中綿を難燃化することが望ましい。
In order to prevent fire, it is preferable to impart flame retardancy to materials used in bedding products, interior products, furniture, and the like in a house. In addition, the material to which flame retardancy is imparted must not impair the comfort and hygroscopicity of bedding products and interior products.
Among bedding products and interior products, there are products that require cushioning, such as mattress pads, comforters, or pillows. In many cases, in these products, polyester fibers having excellent elasticity are used for the batting to exhibit cushioning properties. In addition, fibers such as cotton having excellent hygroscopicity and polyester having excellent durability are used for the side ground. Although various flame retardant examinations have been made for these products, most of them have been related to the flame retardant of the side land.
In order to make the fiber flame retardant, it is necessary to use a fiber containing a flame retardant such as an antimony compound or a phosphorus compound or a flame retardant fiber such as a glass fiber. Such fibers are inferior in comfort such as touch or moisture absorption. Therefore, it is desirable that the bedding having the batting is made flame retardant instead of the side cloth.

近年、寝具やインテリア繊維製品には高度の難燃性が要求されるようになっている。このような難燃性は、例えば米国カリフォルニア州の枕等の燃焼試験方法Technical Bulletin 604の2003年10月発行のドラフト(以下TB604)に記載されている。ここでは、長時間、例えば20秒間、火炎と接しても燃焼しないなど、高度の難燃性が要求される。   In recent years, bedding and interior textile products have been required to have a high degree of flame retardancy. Such flame retardancy is described, for example, in a draft (hereinafter referred to as TB604) issued in October 2003 of a combustion test method Technical Bulletin 604 such as a pillow in California, USA. Here, a high degree of flame retardancy is required, for example, it does not burn even when in contact with a flame for a long time, for example, 20 seconds.

特許文献1には難燃剤を大量に添加した高度に難燃化したハロゲン含有繊維と、難燃化していないポリエステルなどの他の繊維とを組み合わせた難燃繊維複合体による寝具用繊維製品が提案されている。特許文献1にはその難燃繊維複合体を中綿に使用することについては開示されていない。しかし、特許文献1に記載された含ハロゲン繊維とポリエステル繊維の複合体を中綿に使用しても、高度の難燃性、例えばTB604に記載された難燃性を達成するには多量の難燃性ハロゲン含有繊維を使用することが必要であることが判明した。多量のハロゲン含有繊維を使用するとポリエステル繊維の使用量が減少し、中綿の弾力性が低下する。
特開平05−093330号公報
Patent Document 1 proposes a textile product for bedding using a flame retardant fiber composite that combines a highly flame retardant halogen-containing fiber to which a large amount of a flame retardant is added and other fibers such as polyester that is not flame retardant. Has been. Patent Document 1 does not disclose the use of the flame retardant fiber composite for filling. However, even when the composite of halogen-containing fiber and polyester fiber described in Patent Document 1 is used for batting, a large amount of flame retardant is required to achieve high flame retardancy, for example, flame retardancy described in TB604. It has been found necessary to use a functional halogen-containing fiber. When a large amount of halogen-containing fiber is used, the amount of polyester fiber used is reduced and the elasticity of the batting is lowered.
JP 05-093330 A

本発明の目的は中綿に弾力性に優れ安価なポリエステルおよび難燃性に優れるハロゲン含有繊維を使用した寝具であって、多量のハロゲン含有繊維を使用しなくても優れた難燃性を有する寝具を提供することである。
本発明の他の目的はポリエステル系繊維やセルロース系繊維等、触感や吸湿性などの快適さを有するが易燃性である繊維を側地として使用しても高度の難燃性を有する寝具を提供することである。
An object of the present invention is a bedding using a polyester having excellent elasticity and inexpensive polyester and a halogen-containing fiber excellent in flame retardancy, and has excellent flame retardancy without using a large amount of halogen-containing fiber. Is to provide.
Another object of the present invention is to provide a bedding having a high degree of flame retardancy even when using a fiber that is comfortable, such as polyester fiber and cellulosic fiber, but has a tactile sensation and hygroscopicity but is flammable. Is to provide.

本発明者らは、前記問題を解決するため鋭意検討を重ねた結果、中綿とそれを覆う側地からなる難燃性寝具製品であって、前記中綿にセルロース系繊維(A)およびポリエステル系繊維(B)およびハロゲン含有繊維(C)を用いることで、多量のハロゲン含有繊維を使用しなくても長時間の炎にも耐え得る、優れた難燃性を備えた難燃性寝具製品が得られることを見出した。   As a result of intensive studies to solve the above problems, the present inventors have obtained a flame retardant bedding product comprising a batting and a side covering covering the batting, the cellulosic fiber (A) and the polyester fiber on the batting. By using (B) and the halogen-containing fiber (C), a flame-retardant bedding product having excellent flame resistance that can withstand a long-term flame without using a large amount of halogen-containing fiber is obtained. I found out that

すなわち、本発明は次のとおりである。
(1)中綿とそれを覆う側地からなる難燃性寝具製品であって、前記中綿がセルロース系繊維(A)10〜40重量%、ポリエステル系繊維(B)50〜80重量%、ハロゲン含有繊維(C)10〜40重量%を含む繊維で構成された難燃性寝具製品。
(2)セルロース系繊維(A)が木綿、麻、レーヨン、ポリノジック、キュプラ、アセテート及びトリアセテートよりなる群から選ばれた少なくとも1つの繊維である(1)記載の難燃性寝具製品。
(3)セルロース系繊維(A)が珪酸、または珪酸アルミニウムから選ばれる難燃剤を20〜50重量%含有するレーヨン繊維である(1)または(2)に記載の難燃性寝具製品。
(4)セルロース系繊維(A)がリン酸エステル系化合物、含ハロゲンリン酸エステル系化合物、縮合リン酸エステル系化合物、ポリリン酸塩系化合物、赤リン、アミン化合物、ホウ酸、臭化物等のハロゲン化合物、尿素−ホルムアルデヒド化合物、硫酸アンモニウムよりなる群から選ばれる少なくとも一つの難燃剤を、セルロース系繊維に対して6〜25重量%添加した繊維である(1)または(2)に記載の難燃性寝具製品。
(5)ポリエステル系繊維(B)が、融点が200℃を超えるポリエステル繊維、低融点バインダー繊維、難燃性ポリエステル繊維よりなる群から選ばれる少なくとも一つの繊維である(1)〜(4)のいずれかに記載の難燃性寝具製品。
(6)低融点バインダー繊維が低融点ポリエステル単一成分よりなる繊維、融点が200℃を超えるポリエステルと低融点ポリエステルの複合よりなる繊維、融点が200℃を超えるポリエステルと低融点ポリオレフィンの複合よりなる繊維よりなる群から選ばれる少なくとも一つの繊維である(5)記載の難燃性寝具製品。
(7)難燃性ポリエステル繊維がリン系化合物、リン酸エステル系化合物、含ハロゲンリン酸エステル系化合物、縮合リン酸エステル系化合物、ポリリン酸塩系化合物、ホスファゼン化合物、赤リン、ヒンダードアミン化合物等のアミン化合物、ホウ酸、臭化物等のハロゲン化合物、尿素−ホルムアルデヒド化合物、硫酸アンモニウム、水和金属化合物、金属酸化物、有機金属化合物、シリコーン系化合物よりなる群から選ばれる少なくとも一つの難燃剤を添加した繊維である(5)記載の難燃性寝具製品。
(8)ハロゲン含有繊維(C)がモダアクリル繊維である(1)〜(7)のいずれかに記載の難燃性寝具製品。
(9)側地が、セルロース系繊維および/またはポリエステル系繊維を含む(1)〜(8)記載の難燃性寝具製品。
(10)側地が、セルロース系繊維20〜80重量%、ポリエステル系繊維80〜20重量%からなる(9)記載の難燃性寝具製品。
That is, the present invention is as follows.
(1) A flame-retardant bedding product comprising a batting and a side land covering the batting, the batting comprising 10 to 40% by weight of a cellulose fiber (A), 50 to 80% by weight of a polyester fiber (B), containing a halogen A flame retardant bedding product composed of fibers containing 10 to 40% by weight of fibers (C).
(2) The flame-retardant bedding product according to (1), wherein the cellulosic fiber (A) is at least one fiber selected from the group consisting of cotton, hemp, rayon, polynosic, cupra, acetate, and triacetate.
(3) The flame-retardant bedding product according to (1) or (2), wherein the cellulosic fiber (A) is a rayon fiber containing 20 to 50% by weight of a flame retardant selected from silicic acid or aluminum silicate.
(4) Cellulosic fiber (A) is a phosphoric acid ester compound, halogenated phosphoric acid ester compound, condensed phosphoric acid ester compound, polyphosphate compound, red phosphorus, amine compound, boric acid, bromide, or other halogen The flame retardancy according to (1) or (2), which is a fiber in which at least one flame retardant selected from the group consisting of a compound, a urea-formaldehyde compound and ammonium sulfate is added in an amount of 6 to 25% by weight based on the cellulosic fiber. Bedding products.
(5) The polyester fiber (B) is at least one fiber selected from the group consisting of a polyester fiber having a melting point exceeding 200 ° C., a low-melting point binder fiber, and a flame-retardant polyester fiber (1) to (4) A flame retardant bedding product according to any one of the above.
(6) Low melting point binder fiber is a fiber consisting of a single component of low melting point polyester, a fiber consisting of a composite of a polyester having a melting point exceeding 200 ° C and a low melting point polyester, a composite of a polyester having a melting point exceeding 200 ° C and a low melting point polyolefin The flame-retardant bedding product according to (5), which is at least one fiber selected from the group consisting of fibers.
(7) The flame retardant polyester fiber is a phosphorus compound, a phosphate ester compound, a halogen-containing phosphate ester compound, a condensed phosphate ester compound, a polyphosphate compound, a phosphazene compound, red phosphorus, a hindered amine compound, or the like. Fiber added with at least one flame retardant selected from the group consisting of amine compounds, halogen compounds such as boric acid, bromide, urea-formaldehyde compounds, ammonium sulfate, hydrated metal compounds, metal oxides, organometallic compounds, and silicone compounds The flame retardant bedding product according to (5).
(8) The flame-retardant bedding product according to any one of (1) to (7), wherein the halogen-containing fiber (C) is a modacrylic fiber.
(9) The flame-retardant bedding product according to any one of (1) to (8), wherein the side ground includes cellulosic fibers and / or polyester fibers.
(10) The flame-retardant bedding product according to (9), wherein the side fabric is composed of 20 to 80% by weight of cellulosic fibers and 80 to 20% by weight of polyester fibers.

本発明によれば、中綿とそれを覆う側地からなる難燃性寝具製品であって、前記中綿に、セルロース系繊維(A)およびポリエステル系繊維(B)およびハロゲン含有繊維(C)を用いることで、多量のハロゲン含有繊維を使用しなくても長時間の炎にも耐え得る難燃性を備えた難燃性寝具製品を提供することができる。
また、本発明によれば中綿として比較的少量のハロゲン含有繊維を使用しているので、多量のポリエステル繊維を使用できるため優れたクッション性などの風合いを有する寝具を提供することができる。また、多量のポリエステル繊維を使用しているため、本発明の寝具は加工性を損なわず、低コストである。
さらに、本発明によればポリエステル系繊維やセルロース系繊維等、易燃性繊維を側地として用いた難燃性寝具製品であっても、難燃性が充分に発揮される為、難燃性と同時に優れた風合いや触感に優れた寝具を提供することができる。
According to this invention, it is a flame-retardant bedding product which consists of a batting and the side ground which covers it, Comprising: Cellulosic fiber (A), a polyester-type fiber (B), and a halogen-containing fiber (C) are used for the said batting. Thus, it is possible to provide a flame retardant bedding product having flame retardancy that can withstand a long-term flame without using a large amount of a halogen-containing fiber.
In addition, according to the present invention, since a relatively small amount of halogen-containing fiber is used as the batting, a large amount of polyester fiber can be used, so that it is possible to provide a bedding having a texture such as excellent cushioning properties. In addition, since a large amount of polyester fiber is used, the bedding of the present invention does not impair processability and is low in cost.
Furthermore, according to the present invention, even if it is a flame retardant bedding product using a flammable fiber as a side fabric, such as a polyester fiber and a cellulose fiber, the flame retardant property is sufficiently exerted. At the same time, it is possible to provide bedding with excellent texture and touch.

本発明に使用する中綿は、セルロース系繊維(A)、ポリエステル系繊維(B)およびハロゲン含有繊維(C)の少なくとも3種類の繊維で構成される。
セルロース系繊維(A)は、優れた風合や吸湿性などの快適性を与えると共に、燃焼時に炭化膜を形成するのに効果的な成分である。本発明に用いるセルロース系繊維(A)の例としては、木綿、麻、レーヨン、ポリノジック、キュプラ、アセテートおよびトリアセテートあるいは難燃セルロース繊維があげられ、これらは単独使用しても良く、2種類以上組み合わせて使用しても良い。
The batting used in the present invention is composed of at least three kinds of fibers: a cellulosic fiber (A), a polyester fiber (B), and a halogen-containing fiber (C).
The cellulosic fiber (A) is an effective component for forming a carbonized film at the time of combustion while giving comfort such as excellent texture and hygroscopicity. Examples of cellulosic fibers (A) used in the present invention include cotton, hemp, rayon, polynosic, cupra, acetate and triacetate or flame retardant cellulose fibers, which may be used alone or in combination of two or more. May be used.

セルロース系繊維(A)としては通常の難燃化されていないセルロース系繊維や難燃化されたセルロース系繊維を使用することができる。難燃化されたセルロース系繊維としてはセルロース系繊維に難燃剤として珪酸および/または珪酸アルミニウムを含有した珪酸含有セルロース系繊維、その他難燃剤を製造時に含有させた難燃性セルロース系繊維および難燃剤を用いて後加工等により難燃化した難燃性セルロース系繊維があげられる。難燃性セルロース系繊維(A)の基質であるセルロース系繊維の具体例としては、前記のセルロース系繊維の具体例があげられる。   As the cellulosic fiber (A), a normal non-flammable cellulosic fiber or a flame-retardant cellulosic fiber can be used. As the flame retardant cellulose fiber, the cellulose fiber containing silicic acid and / or aluminum silicate as the flame retardant, and the flame retardant cellulose fiber and flame retardant containing the other flame retardant at the time of production. Incombustible cellulosic fibers made flame retardant by post-processing using Specific examples of the cellulosic fiber that is a substrate of the flame retardant cellulosic fiber (A) include the specific examples of the cellulosic fiber.

前記珪酸含有セルロース系繊維としては、難燃剤として珪酸および/または珪酸アルミニウムを繊維中に20〜50重量%含有するセルロース繊維が好ましい。この繊維は1.7〜8dtex程度の繊度、38〜128mm程度のカット長を有していることが好ましい。その具体例としては、例えば珪酸を繊維中に約30重量%含有したサテリ(Sateri)社のヴィジル(Visil)や珪酸アルミニウムを繊維中に約33重量%含有したサテリ(Sateri)社のヴィジルAP(Visil AP)があげられる。その他難燃性セルロース系繊維としてレンチング社(Lenzing A.G)のレンチングFR(Lenzing FR)あげられる。難燃性セルロース系繊維はこれらに限定されるものではない。   The silicic acid-containing cellulose fiber is preferably a cellulose fiber containing 20 to 50% by weight of silicic acid and / or aluminum silicate as a flame retardant. This fiber preferably has a fineness of about 1.7 to 8 dtex and a cut length of about 38 to 128 mm. Specific examples thereof include, for example, Visili from Sateri, which contains about 30% by weight of silicic acid in the fiber, and Visil AP, from Sateri, which contains about 33% by weight of aluminum silicate in the fiber. Visil AP). Other flame retardant cellulosic fibers include Lenzing FR manufactured by Lenzing AG. The flame retardant cellulosic fiber is not limited to these.

セルロース系繊維を後加工等により難燃化した繊維を使用することができる。用いられる難燃剤としてはトリフェニルホスフェート、トリクレジルホスフェート、トリキシレニルホスフェート、トリメチルホスフェート、トリエチルホスフェート、クレジルフェニルホスフェート、キシレニルジフェニルホスフェート、レゾルシノールビス(ジフェニルホスフェート)、2−エチルヘキシルジフェニルホスフェート、ジメチルホスフェート、トリアリルホスフェート(レオフォス)、芳香族リン酸エステル、ホスホノカルボン酸アミド誘導体、テトラキス・ヒドロキシメチルホスホニウム誘導体、N−メチロールジメチルホスホノプロピオンアミドなどのリン酸エステル系化合物、トリス(クロロエチル)ホスフェート、トリスジクロロプロピルホスフェート、トリス−β−クロロプロピルホスフェート、クロロアルキルホスフェート、トリス(トリブロモネオペンチル)ホスフェート、ジエチル−N,N−ビス(2−ヒドロキシエチル)アミノメチルホスフェート、トリス(2,6−ジメチルフェニル)ホスフェートなどの含ハロゲンリン酸エステル系化合物、芳香族縮合リン酸エステル、含ハロゲン縮合リン酸エステルなどの縮合リン酸エステル系化合物、ポリリン酸アンモニウム・アミド、ポリクロロホスフォネートなどのポリリン酸塩系化合物、ポリリン酸カルバメートなどのポリリン酸エステル系化合物、赤リン、アミン化合物、ホウ酸、臭化物等のハロゲン化合物、尿素―ホルムアルデヒド化合物、硫酸アンモニウム、グアニジン系縮合物等があげられる。これらは単独で使用しても良く、2種以上組み合わせても良い。これら難燃剤の添付量としては、中綿の難燃性を維持するために、中綿全体に対して0.5重量%以上になるように添付するのが好ましい。   It is possible to use a fiber obtained by making a cellulosic fiber flame-retardant by post-processing or the like. The flame retardant used is triphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, trimethyl phosphate, triethyl phosphate, cresyl phenyl phosphate, xylenyl diphenyl phosphate, resorcinol bis (diphenyl phosphate), 2-ethylhexyl diphenyl phosphate, Phosphate ester compounds such as dimethyl phosphate, triallyl phosphate (leophos), aromatic phosphate ester, phosphonocarboxylic acid amide derivative, tetrakis hydroxymethylphosphonium derivative, N-methyloldimethylphosphonopropionamide, tris (chloroethyl) Phosphate, trisdichloropropyl phosphate, tris-β-chloropropyl phosphate, chloroalkyl Halogen-containing phosphate ester compounds such as phosphate, tris (tribromoneopentyl) phosphate, diethyl-N, N-bis (2-hydroxyethyl) aminomethyl phosphate, tris (2,6-dimethylphenyl) phosphate, aromatic Condensed phosphate esters, condensed phosphate ester compounds such as halogen-containing condensed phosphate esters, polyphosphate compounds such as ammonium polyphosphate / amide and polychlorophosphonate, polyphosphate ester compounds such as polyphosphate carbamate, Examples thereof include halogen compounds such as red phosphorus, amine compounds, boric acid and bromide, urea-formaldehyde compounds, ammonium sulfate, and guanidine-based condensates. These may be used alone or in combination of two or more. The amount of the flame retardant attached is preferably 0.5% by weight or more with respect to the entire batting in order to maintain the flame retardancy of the batting.

本発明に用いるポリエステル系繊維(B)は、本発明の中綿に優れた嵩高性、耐久性を与えるための成分である。また、この成分は燃焼時に溶融することで、その溶融物が炭化膜を覆うことにより出来上がった炭化膜の強度を向上させる効果がある。ポリエステル系繊維(B)の具体例としては、汎用的な融点が200℃を超えるポリエステル繊維、低融点バインダー繊維、難燃性ポリエステル繊維があげられる。これらは単独使用しても良く、2種類以上組み合わせて使用しても良い。   The polyester fiber (B) used in the present invention is a component for imparting excellent bulkiness and durability to the batting of the present invention. Further, this component has an effect of improving the strength of the carbonized film formed by melting the component during combustion and covering the carbonized film with the melt. Specific examples of the polyester fiber (B) include polyester fibers having a general melting point exceeding 200 ° C., low melting point binder fibers, and flame retardant polyester fibers. These may be used alone or in combination of two or more.

低融点バインダー繊維としては低融点ポリエステル単一成分よりなる繊維、通常のポリエステルと低融点ポリエステルの複合よりなる繊維、通常のポリエステルと低融点ポリオレフィンの複合よりなる繊維よりなる群から選ばれた少なくとも1つの繊維であるのが好ましい。一般的に低融点ポリエステルの融点は概ね110〜200℃、低融点ポリプロピレンの融点は概ね140〜160℃、低融点ポリエチレンの融点は概ね95〜130℃であり、概ね110〜200℃程度で融解接着能力を有するものであれば特に限定はない。低融点バインダー繊維としては、例えば東レ(株)製のサフメットR(4.4dtex×51mm、溶融温度110℃)、があげられる。   The low melting point binder fiber is at least one selected from the group consisting of a fiber consisting of a single component of a low melting point polyester, a fiber consisting of a composite of a normal polyester and a low melting point polyester, and a fiber consisting of a composite of a normal polyester and a low melting point polyolefin. One fiber is preferred. Generally, the melting point of low-melting polyester is approximately 110 to 200 ° C, the melting point of low-melting polypropylene is approximately 140 to 160 ° C, and the melting point of low-melting polyethylene is approximately 95 to 130 ° C. There is no particular limitation as long as it has the ability. Examples of the low-melting-point binder fiber include Safmet R (4.4 dtex × 51 mm, melting temperature 110 ° C.) manufactured by Toray Industries, Inc.

難燃ポリエステル系繊維としては、後処理により繊維に難燃化剤を添付した繊維、繊維紡糸時に難燃化剤が練り込まれた繊維、難燃化剤を共重合法により導入された繊維をあげることができる。難燃ポリエステル系繊維はこれらに限定されない。代表的な難燃化剤としては、ハロゲン化合物、あるいはリン化合物等があげられるが、特にこれに限られたものではない。   The flame retardant polyester fiber includes a fiber in which a flame retardant is attached to the fiber by post-processing, a fiber in which a flame retardant is kneaded during fiber spinning, and a fiber in which a flame retardant is introduced by a copolymerization method. I can give you. The flame retardant polyester fiber is not limited to these. Typical flame retardants include halogen compounds or phosphorus compounds, but are not particularly limited thereto.

リン化合物の具体例としては、フェニルホスホン酸ジメチル、フェニルホスホン酸ジフェニル、〔2−(βヒドロキシエトキシカルボニル)エチル〕メチルホスフィン酸、〔2−(βヒドロキシエトキシカルボニル)エチル〕フェニルホスフィン酸、(2−カルボキシルエチル)メチルホスフィン酸、(2−カルボキシルエチル)フェニルホスフィン酸、(2−メトキシカルボキシルエチル)フェニルホスフィン酸メチル、(4−メトキシカルボニルフェニル)フェニルホスフィン酸メチル、(1,2−ジカルボキシエチル)ジメチルホスフィンオキシド、(2,3−ジカルボキシプロピル)ジメチルホスフィンオキシド、(2,3−ジメトキシカルボニルエチル)ジメチルホスフィンオキシド、〔1,2−ジ(β−ヒドロキシエトキシカルボニル)〕ジメチルホスフィンオキシドなどが挙げられるが、これらに限定されるものではない。   Specific examples of the phosphorus compound include dimethyl phenylphosphonate, diphenyl phenylphosphonate, [2- (βhydroxyethoxycarbonyl) ethyl] methylphosphinic acid, [2- (βhydroxyethoxycarbonyl) ethyl] phenylphosphinic acid, (2 -Carboxylethyl) methylphosphinic acid, (2-carboxylethyl) phenylphosphinic acid, (2-methoxycarboxylethyl) phenylphosphinic acid methyl, (4-methoxycarbonylphenyl) phenylphosphinic acid methyl, (1,2-dicarboxyethyl) ) Dimethylphosphine oxide, (2,3-dicarboxypropyl) dimethylphosphine oxide, (2,3-dimethoxycarbonylethyl) dimethylphosphine oxide, [1,2-di (β-hydroxyethoxycarbo) Le)], such as dimethyl phosphine oxide, and the like, but not limited thereto.

本発明に用いるハロゲン含有繊維(C)は、中綿の難燃性向上のために使用される成分であり、燃焼時に酸素欠乏ガスを発生することにより自己消火を助ける効果がある成分である。本発明に用いられるハロゲン含有繊維(C)としては、例えば塩化ビニル、塩化ビニリデンなどのハロゲン含有モノマーの単独重合体や共重合体、これらのハロゲン含有モノマーと共重合可能なモノマー、例えばアクリロニトリル、スチレン、酢酸ビニル、アクリル酸エステルなどとの共重合体、またはハロゲン含有モノマーがPVA系ポリマーにグラフトしたグラフト重合体などからなる繊維があげられるが、これらに限定されるものではない。ハロゲン含有繊維(C)としては、ハロゲン含有モノマーとアクリロニトリルの共重合体からなる繊維であるモダアクリル繊維が好ましい。特に、アクリロニトリルを30〜70重量%、塩化ビニルに代表されるハロゲン含有ビニル系単量体70〜30重量%及びこれらと共重合可能なビニル系単量体0〜10重量%よりなる共重合体からなるモダアクリル繊維が好ましい。   The halogen-containing fiber (C) used in the present invention is a component used for improving the flame retardancy of the batting, and is a component that has an effect of assisting self-extinguishing by generating an oxygen-deficient gas during combustion. Examples of the halogen-containing fiber (C) used in the present invention include homopolymers and copolymers of halogen-containing monomers such as vinyl chloride and vinylidene chloride, and monomers copolymerizable with these halogen-containing monomers, such as acrylonitrile and styrene. , Vinyl acetate, a copolymer with acrylic acid ester, or the like, or a fiber made of a graft polymer in which a halogen-containing monomer is grafted on a PVA polymer, but is not limited thereto. The halogen-containing fiber (C) is preferably a modacrylic fiber that is a fiber made of a copolymer of a halogen-containing monomer and acrylonitrile. In particular, a copolymer comprising 30 to 70% by weight of acrylonitrile, 70 to 30% by weight of a halogen-containing vinyl monomer represented by vinyl chloride, and 0 to 10% by weight of a vinyl monomer copolymerizable therewith. Modacrylic fibers made of are preferred.

前記モダアクリル繊維には、中綿の難燃性を強化するために難燃剤が添加されていることが好ましい。難燃剤の具体例としては、三酸化アンチモン、五酸化アンチモン、アンチモン酸、オキシ塩化アンチモンなどのアンチモン化合物、酸化第二スズ、メタスズ酸、オキシハロゲン化第一スズ、オキシハロゲン化第二スズ、水酸化第一スズ、四塩化スズなどのSn系化合物、酸化亜鉛などのZn化合物、酸化マグネシウム、水酸化マグネシウムなどのMg系化合物、酸化モリブデンなどのMo系化合物、酸化チタン、チタン酸バリウムなどのTi系化合物、硫酸メラミン、スルファミン酸グアニジンなどのN系化合物、ポリ燐酸アンモニウム、ジブチルアミノフォスフェートなどのP系化合物、水酸化アルミニウム、硫酸アルミニウム、珪酸アルミニウムなどのAl系化合物、酸化ジルコニウムなどのZr系化合物、シリケート、ガラス等のSi系化合物、カオリン、ゼオライト、モンモリロナイト、タルク、パーライト、ベントナイト、バーミキュライト、珪藻土、黒鉛等の天然もしくは合成鉱産物系化合物、塩化パラフィン、ヘキサブロモベンセン、ヘキサブロモシクロドデカンなどのハロゲン化合物が挙げられる。また、錫酸マグネシウム、錫酸亜鉛、錫酸ジルコニウムなどの複合化合物を使用しても良い。これらについては、単独で使用しても良く、2種以上組み合わせても良い。   It is preferable that a flame retardant is added to the modacrylic fiber in order to enhance the flame retardancy of the batting. Specific examples of flame retardants include antimony compounds such as antimony trioxide, antimony pentoxide, antimonic acid, antimony oxychloride, stannic oxide, metastannic acid, stannous oxyhalide, stannic oxyhalide, water Sn compounds such as stannous oxide and tin tetrachloride; Zn compounds such as zinc oxide; Mg compounds such as magnesium oxide and magnesium hydroxide; Mo compounds such as molybdenum oxide; Ti such as titanium oxide and barium titanate Compounds, N compounds such as melamine sulfate and guanidine sulfamate, P compounds such as ammonium polyphosphate and dibutylaminophosphate, Al compounds such as aluminum hydroxide, aluminum sulfate and aluminum silicate, and Zr compounds such as zirconium oxide Si such as compound, silicate, glass Compounds, kaolin, zeolite, montmorillonite, talc, pearlite, bentonite, vermiculite, diatomaceous earth, natural or synthetic mineral based compound such as graphite, paraffin chloride, hexabromo benzene, halogenated compounds such as hexabromocyclododecane and the like. Moreover, you may use complex compounds, such as magnesium stannate, zinc stannate, and a zirconium stannate. These may be used alone or in combination of two or more.

これらの中ではアンチモン化合物が、燃焼時にモダアクリル繊維中より脱離したハロゲン原子と反応し、ハロゲン化アンチモンを生成することで極めて高い難燃性を発揮することから好ましい。アンチモン化合物はモダアクリル繊維に対して6〜50重量%添加することが好ましい。アンチモン化合物が添加されたモダアクリル繊維の具体例としては株式会社カネカ製のカネカロンPBXやソルーシア(Solutia)社のエスイーエフ(SEF)があげられるがこれらに限定されるものではない。   Among these, the antimony compound is preferable because it reacts with a halogen atom desorbed from the modacrylic fiber at the time of combustion and produces antimony halide, thereby exhibiting extremely high flame retardancy. The antimony compound is preferably added in an amount of 6 to 50% by weight based on the modacrylic fiber. Specific examples of the modacrylic fiber to which the antimony compound is added include Kanekaron PBX manufactured by Kaneka Corporation and SEF (SEF) manufactured by Solutia, but are not limited thereto.

セルロース系繊維(A)、ポリエステル系繊維(B)、ハロゲン含有繊維(C)の割合はセルロース系繊維(A)10〜40重量%、ポリエステル系繊維(B)50〜80重量%、ハロゲン含有繊維(C)10〜40重量%である。風合いや吸湿性、弾力性などの快適性、耐洗濯性や耐久性、炭化膜の形成の度合い、形状維持性能、自己消火性の速度によりさらに特定の割合が決定される。   Cellulosic fibers (A), polyester fibers (B), and halogen-containing fibers (C) are 10 to 40 wt% cellulose fibers (A), 50 to 80 wt% polyester fibers (B), and halogen-containing fibers. (C) 10 to 40% by weight. The specific ratio is further determined by comfort such as texture, hygroscopicity, elasticity, washing resistance and durability, degree of carbonized film formation, shape maintenance performance, and self-extinguishing speed.

セルロース系繊維(A)は寝具製品にセルロース系繊維(A)の持つ風合い、吸湿性を与え、且つ燃焼時の中綿の炭化膜形成あるいは形状維持に寄与する主要成分である。セルロース系繊維(A)が10重量%未満の場合にはセルロース系繊維(A)の持つ風合い、吸湿性が充分には得られず、また中綿の炭化膜生成能力が不十分となる。また、中綿におけるセルロース系繊維(A)の割合が40重量を超えると中綿の持つ弾力性が悪くなるあるいは消火性能が悪くなる為、40重量%以下であることが必要である。   Cellulosic fiber (A) is a main component that gives the bedding product the texture and hygroscopicity of cellulosic fiber (A) and contributes to the formation of a carbonized carbon film or the maintenance of the shape of the cotton pad during combustion. When the cellulosic fiber (A) is less than 10% by weight, the cellulosic fiber (A) has insufficient texture and hygroscopicity, and the carbonization ability of the filling is insufficient. Further, if the ratio of the cellulose fiber (A) in the batting exceeds 40 weights, the elasticity of the batting is deteriorated or the fire extinguishing performance is deteriorated. Therefore, it is necessary to be 40% by weight or less.

ポリエステル系繊維(B)は、寝具製品の耐洗濯性や耐久性あるいは弾力性を向上させる主要成分である。ポリエステル系繊維(B)は燃焼により容易に溶融するためにその割合が80重量%を超えると中綿中の溶融成分の割合が多くなり、難燃性能が不充分となる。また、ポリエステル系繊維(B)の割合が50重量%未満でも難燃性に何ら問題はない。しかし、コンフォーターやマットレスパッド、詰め綿枕、クッションなど弾力性を必要とする寝具製品の中綿に対して、弾力性を与えるためにポリエステル系繊維(B)の割合が50重量%以上であることが必要である。   The polyester fiber (B) is a main component that improves the washing resistance, durability or elasticity of the bedding product. Since the polyester fiber (B) is easily melted by combustion, if its proportion exceeds 80% by weight, the proportion of the melted component in the batting increases, and the flame retardancy is insufficient. Moreover, there is no problem in flame retardancy even if the proportion of the polyester fiber (B) is less than 50% by weight. However, the proportion of polyester fiber (B) must be 50% by weight or more to give elasticity to the batting of bedding products that require elasticity such as comforters, mattress pads, padded cotton pillows, and cushions. is required.

ハロゲン含有繊維(C)は中綿に自己消火性を付与する主要成分であるが、ハロゲン含有繊維(C)の割合が40重量%を超えると、セルロース系繊維(A)の持つ風合い、ポリエステル系繊維(B)の持つ弾力性が充分に得られなくなる他、寝具製品の燃焼時、ハロゲン含有繊維(C)が人体に影響を及ぼすガスを多量に発生する。   Halogen-containing fiber (C) is a main component that imparts self-extinguishing properties to batting, but when the proportion of halogen-containing fiber (C) exceeds 40% by weight, the texture of cellulose fiber (A), polyester fiber The elasticity of (B) cannot be sufficiently obtained, and the halogen-containing fiber (C) generates a large amount of gas that affects the human body when the bedding product is burned.

本発明の中綿においては、セルロース系繊維(A)、ポリエステル系繊維(B)、ハロゲン含有繊維(C)及び必要に応じて使用する他の繊維が充分に混綿されていることが好ましい。混綿された本発明の中綿は所定の形状の側地に詰め込んで使用してよい。あるいは不織布を作成するように、上記の混合された繊維を混綿後、ウェブとし、このウェブを多層化した中綿を使用することができる。本発明の高度に難燃化された中綿はコンフォーター、マットレスパッド、詰め綿枕、寝具用クッションなどの中綿を必要とする寝具製品に使用される。   In the batting of the present invention, it is preferable that the cellulosic fiber (A), the polyester fiber (B), the halogen-containing fiber (C) and other fibers used as necessary are sufficiently mixed. The blended cotton of the present invention may be used by being packed in a side of a predetermined shape. Alternatively, the mixed fibers can be used as a web after blending the above-mentioned fibers so as to form a nonwoven fabric. The highly flame retardant batting of the present invention is used in bedding products that require batting such as comforters, mattress pads, stuffed cotton pillows, and bedding cushions.

本発明の高度に難燃化された中綿を覆う側地としては、寝具製品やインテリア家具で汎用的に使用されているセルロース系繊維および/あるいはポリエステル系繊維で構成された側地が好ましいが、特に限定されるものではない。風合いや吸湿性、耐久性といった、寝具製品やインテリア家具に望まれる性能を満足するには、側地の構成がセルロース系繊維20〜80重量%、ポリエステル系繊維80〜20重量%であるのが好ましい。   As the side covering the highly flame-retardant batting of the present invention, a side consisting of cellulose fibers and / or polyester fibers generally used in bedding products and interior furniture is preferable, It is not particularly limited. In order to satisfy performances desired for bedding products and interior furniture such as texture, hygroscopicity and durability, the composition of the side fabric is 20 to 80% by weight of cellulosic fibers and 80 to 20% by weight of polyester fibers. preferable.

本発明の高度に難燃化された中綿にはセルロース系繊維(A)およびポリエステル系繊維(B)およびハロゲン含有繊維(C)が必須成分である。セルロース系繊維(A)は炭化促進効果を有しており、速やかに炭化し炎に晒された際の収縮が小さく安定した炭化膜を形成する。また、ポリエステル系繊維(B)は本発明である難燃性寝具製品に優れた弾力性能を付与することができる。ハロゲン含有繊維(C)は中綿の消火性能を向上させることができる。   Cellulosic fibers (A), polyester fibers (B), and halogen-containing fibers (C) are essential components in the highly flame-retardant filling of the present invention. The cellulosic fiber (A) has a carbonization promoting effect, and forms a stable carbonized film that is quickly carbonized and has a small shrinkage when exposed to flame. Moreover, the polyester fiber (B) can impart excellent elasticity performance to the flame-retardant bedding product of the present invention. The halogen-containing fiber (C) can improve the fire extinguishing performance of the batting.

上記のように、本発明によれば高度に難燃化された寝具製品を得ることが可能である。また、本発明によればクッション、枕、マットレスパット、コンフォーター、布団などの寝具製品の素材独特の風合いや心地よさを充分に引き出しながら、人体に影響を与えるガスの発生を最小限に抑えた寝具製品を得ることが可能である。
以下、実施をあげて本発明をさらに詳しく説明するが、本発明はかかる実施例のみに限定されるものではない。
As described above, according to the present invention, it is possible to obtain a highly flame-retardant bedding product. In addition, according to the present invention, the generation of gas affecting the human body is minimized while fully drawing out the unique texture and comfort of the materials of bedding products such as cushions, pillows, mattress pads, comforters and futons. It is possible to obtain a bedding product.
Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to the examples.

(中綿の製造)
セルロース系繊維(A)として、汎用的なセルロース繊維であるダイワボウレーヨン社のコロナR(繊度1.7dtex、カット長38mm)あるいは難燃セルロース系繊維であるサテリ(Sateri)社製のヴィジル(Visil)(繊度3.5dtex、カット長50mm)を使用した。ポリエステル系繊維(B)として、汎用的なポリエステル繊維である東レ(TORAY)社製のテトロンR(繊度6dtex、カット長51mm)あるいは難燃ポリエステル繊維であるトレビラ(TREVIRA)社製のトレビラCSを使用した。ハロゲン含有繊維(C)として難燃剤としてアンチモン化合物を含有するカネカ(KANEKA)社製のカネカロンPBX(繊度2dtex、カット長51mm)を使用した。これらの繊維を表1に示す混率でカードにより開繊してウェブ状にし、多層化して中綿を作成した。
(Manufacture of batting)
As cellulosic fiber (A), Corona R (fineness 1.7 dtex, cut length 38 mm) of Daiwabo Rayon, which is a general-purpose cellulose fiber, or Visil (Satel), a flame-retardant cellulosic fiber, is used. (Fineness 3.5 dtex, cut length 50 mm) was used. As the polyester fiber (B), Tetron R (fineness 6dtex, cut length 51mm) manufactured by Toray, which is a general-purpose polyester fiber, or Trevira CS manufactured by Trevira, which is a flame-retardant polyester fiber, is used. did. Kanekaron PBX (fineness: 2 dtex, cut length: 51 mm) manufactured by Kaneka Corporation containing an antimony compound as a flame retardant was used as the halogen-containing fiber (C). These fibers were opened with a card at a blending ratio shown in Table 1 to form a web, and the layers were formed into a batting.

Figure 2006129607
Figure 2006129607

(側地の作成)
木綿繊維50重量%とポリエステル繊維50重量%を混紡によりメートル番手34番手の紡績糸を得た。この紡績糸を周知の方法により、目付け120g/m2の平織り生地を作成した。
(Create side land)
A spun yarn with a metric count of 34 was obtained by blending 50% by weight of cotton fiber and 50% by weight of polyester fiber. A plain weave fabric having a basis weight of 120 g / m 2 was prepared from this spun yarn by a known method.

(難燃性評価用クッションの作成方法)
作成した中綿を、縦約30.5cm×横約30.5cmにカットする。その中綿を縦約38.1cm×横約38.1cmにカットした生地(側地)に挟み込み、重さ325gのプレートを載せてクッションの高さが89mm(3.5inch)以上102mm(4.0inch)以内となるように調整し、4辺をカタン糸を用いて閉じ、難燃性評価用クッションを作成した。
(How to make a cushion for flame retardant evaluation)
The produced filling is cut into a length of about 30.5 cm and a width of about 30.5 cm. The batting is sandwiched between fabrics (side ground) cut to about 38.1cm in length and 38.1cm in width, and a plate with a weight of 325g is placed on it, and the height of the cushion is 89mm (3.5inch) or more and 102mm (4.0inch) ) Was adjusted so as to be within the range, and four sides were closed with a cut yarn to create a flame retardant evaluation cushion.

(難燃性評価方法)
難燃性は米国カリフォルニア州の燃焼試験方法Technical Bulletin 604の2004年10月発行のドラフト(TB604)Section2に基づいて実施した。米国カリフォルニア州のTB604燃焼試験方法を簡単に説明すると、枕類やクッション類を対象とした試験の場合、水平にした前記難燃性評価用クッションの一つの角より下側3/4インチの所から35mmの炎を20秒間着炎する。6分後の重量減少率が25重量%以下であれば合格である。表2において重量減少率が25重量%以内のものを○、25重量%を越えるものを×とした。
使用するバーナーチューブは内径6.5mm、外形8mm、長さ200mmである。燃料ガスは純度99%以上のブタンガスで、ブタンガス流量45ml/minで炎の高さは約35mmである。
(Flame retardance evaluation method)
The flame retardancy was carried out based on a draft (TB604) Section 2 issued in October 2004 by the combustion test method Technical Bulletin 604 in California, USA. The TB604 combustion test method in California, USA will be briefly described. In the test for pillows and cushions, the test piece is 3/4 inch below one corner of the flame retardant evaluation cushion that is leveled. A 35 mm flame is applied for 20 seconds. If the weight loss rate after 6 minutes is 25% by weight or less, it is acceptable. In Table 2, when the weight reduction rate was within 25% by weight, “◯” was given, and when it was over 25% by weight, “X” was given.
The burner tube used has an inner diameter of 6.5 mm, an outer diameter of 8 mm, and a length of 200 mm. The fuel gas is butane gas with a purity of 99% or more, the butane gas flow rate is 45 ml / min, and the height of the flame is about 35 mm.

(弾力性評価方法)
弾力性評価は、前記難燃性評価用クッションを用いておこなった。中綿の量は1000g/m2であった。弾力性の評価はクッションの目視によりなされた。難燃性評価用クッションが寝具製品として十分なボリューム感を有するものを○(例えばポリエステル繊維を中綿に使用したクッションと同じボリューム感がある場合)、寝具として使用可能なレベルのボリューム感を有するものを△、それより劣るものを×(例えばレーヨン繊維を中綿に使用したクッションと同じボリューム感がある場合)として評価した。
(Elasticity evaluation method)
The elasticity evaluation was performed using the above-mentioned flame retardant evaluation cushion. The amount of batting was 1000 g / m 2 . The elasticity was evaluated by visual inspection of the cushion. A flame retardant evaluation cushion that has sufficient volume as a bedding product (for example, when the same volume as a cushion using polyester fiber is used for batting) and a volume that can be used as bedding △, and inferior ones were evaluated as × (for example, when there is the same volume feeling as a cushion using rayon fibers in batting).

(実施例1〜9、比較例1〜9)
作成した難燃性評価用クッションについて難燃性および弾力性を評価した。結果を表2に示す。
(Examples 1-9, Comparative Examples 1-9)
The prepared flame retardant evaluation cushion was evaluated for flame retardancy and elasticity. The results are shown in Table 2.

Figure 2006129607
Figure 2006129607

実施例1〜9では、何れの場合においても燃焼試験における難燃性、炭化膜の状態は良好であった。さらに、ポリエステル系繊維(B)が中綿全体に対し50〜70重量%含まれているため、コンフォーターやマットレスパッド、詰め綿枕、寝具用クッションなどの寝具製品に必要な弾力性を充分に得ることができた。
比較例1では、ポリエステル系繊維(B)の中でも難燃性ポリエステル系繊維は自己消火性に優れる。しかし、セルロース系繊維(A)を含まない為に、炭化膜の状態が不充分であった。このため、溶融した難燃性ポリエステル系繊維の熱が中綿の内部にまで伝わり、その熱でさらに難燃性ポリエステル系繊維の溶融が進んだ。その結果接炎終了6分後の重量減少率が25重量%を超え、充分な難燃性を得ることができなかった。
比較例2,3では、比較例1に比べてハロゲン含有繊維(C)を含むが、セルロース系繊維(A)を含まない為に、炭化膜の状態が不充分となり、中綿の消火能力が劣るものであった。
比較例4〜6では、難燃性、炭化膜の状態は良好であったが、ポリエステル系繊維(B)の混合割合が少なく、充分な弾力性が得られなかった。また、比較例6のようにハロゲン含有繊維(C)の混率が高いと、充分な風合いや吸湿性および弾力性が得られない他、燃焼時、人体に悪影響を及ぼす多量のガスを発生する為、実用化が困難となる。
In Examples 1 to 9, in any case, the flame retardancy and the state of the carbonized film in the combustion test were good. Furthermore, since the polyester fiber (B) is contained in an amount of 50 to 70% by weight based on the entire batting, the elasticity necessary for bedding products such as a comforter, mattress pad, padded cotton pillow, bedding cushion, etc. is sufficiently obtained. I was able to.
In Comparative Example 1, the flame retardant polyester fiber is excellent in self-extinguishing property among the polyester fibers (B). However, since the cellulosic fiber (A) is not included, the state of the carbonized film was insufficient. For this reason, the heat | fever of the fuse | melted flame-retardant polyester-type fiber was transmitted to the inside of batting, and the fusion | melting of the flame-retardant polyester-type fiber further advanced with the heat. As a result, the weight reduction rate 6 minutes after the completion of flame contact exceeded 25% by weight, and sufficient flame retardancy could not be obtained.
In Comparative Examples 2 and 3, the halogen-containing fiber (C) is included as compared with Comparative Example 1, but since the cellulose-based fiber (A) is not included, the state of the carbonized film becomes insufficient, and the fire fighting ability of the filling is inferior. It was a thing.
In Comparative Examples 4 to 6, the flame retardancy and the state of the carbonized film were good, but the mixing ratio of the polyester fiber (B) was small, and sufficient elasticity was not obtained. Further, when the mixing ratio of the halogen-containing fiber (C) is high as in Comparative Example 6, a sufficient texture, hygroscopicity and elasticity cannot be obtained, and a large amount of gas that adversely affects the human body is generated during combustion. It becomes difficult to put it into practical use.

本発明は中綿としてセルロース系繊維(A)、ポリエステル系繊維(B)およびハロゲン含有繊維(C)を使用する難燃性寝具製品に関するものである。本発明の寝具製品は多量のハロゲン含有繊維(C)を使用しないにもかかわらず長時間火炎に接触させる燃焼テストにおいても燃焼を防止できる高度の難燃性を有する。また、ポリエステル系繊維(B)が有する弾力性を損なわない。このようにクッション、枕、マットレスパット、コンフォーター、布団などの寝具分野において、産業上の利用が可能である。   The present invention relates to a flame retardant bedding product using cellulosic fibers (A), polyester fibers (B) and halogen-containing fibers (C) as batting. The bedding product of the present invention has a high degree of flame retardancy capable of preventing combustion even in a combustion test in which a large amount of the halogen-containing fiber (C) is not used, but in contact with a flame for a long time. Moreover, the elasticity which a polyester-type fiber (B) has is not impaired. Thus, it can be used industrially in the field of bedding such as cushions, pillows, mattress pads, comforters, and futons.

Claims (10)

中綿とそれを覆う側地からなる難燃性寝具製品であって、前記中綿がセルロース系繊維(A)10〜40重量%、ポリエステル系繊維(B)50〜80重量%、ハロゲン含有繊維(C)10〜40重量%を含む繊維で構成された難燃性寝具製品。   A flame-retardant bedding product comprising a batting and a side covering covering the batting, the batting comprising 10 to 40% by weight of a cellulose fiber (A), 50 to 80% by weight of a polyester fiber (B), a halogen-containing fiber (C ) Flame retardant bedding products composed of fibers containing 10-40% by weight. セルロース系繊維(A)が木綿、麻、レーヨン、ポリノジック、キュプラ、アセテート及びトリアセテートよりなる群から選ばれた少なくとも一つの繊維である請求項1記載の難燃性寝具製品。   The flame-retardant bedding product according to claim 1, wherein the cellulosic fiber (A) is at least one fiber selected from the group consisting of cotton, hemp, rayon, polynosic, cupra, acetate and triacetate. セルロース系繊維(A)が珪酸、または珪酸アルミニウムから選ばれる難燃剤を20〜50重量%含有するレーヨン繊維である請求項1または請求項2に記載の難燃性寝具製品。   The flame-retardant bedding product according to claim 1 or 2, wherein the cellulosic fiber (A) is a rayon fiber containing 20 to 50% by weight of a flame retardant selected from silicic acid or aluminum silicate. セルロース系繊維(A)がリン酸エステル系化合物、含ハロゲンリン酸エステル系化合物、縮合リン酸エステル系化合物、ポリリン酸塩系化合物、赤リン、アミン化合物、ホウ酸、臭化物等のハロゲン化合物、尿素−ホルムアルデヒド化合物、硫酸アンモニウムよりなる群から選ばれる少なくとも一つの難燃剤を、セルロース系繊維に対して6〜25重量%添加した繊維である請求項1または請求項2に記載の難燃性寝具製品。   Cellulose fibers (A) are phosphoric acid ester compounds, halogenated phosphoric acid ester compounds, condensed phosphoric acid ester compounds, polyphosphate compounds, red phosphorus, amine compounds, boric acid, bromide and other halogen compounds, urea The flame retardant bedding product according to claim 1 or 2, which is a fiber obtained by adding 6 to 25% by weight of at least one flame retardant selected from the group consisting of a formaldehyde compound and ammonium sulfate to a cellulosic fiber. ポリエステル系繊維(B)が、融点が200℃を超えるポリエステル繊維、低融点バインダー繊維、難燃性ポリエステル繊維よりなる群から選ばれる少なくとも一つの繊維である請求項1〜4のいずれかに記載の難燃性寝具製品。   The polyester fiber (B) is at least one fiber selected from the group consisting of a polyester fiber having a melting point exceeding 200 ° C, a low melting point binder fiber, and a flame retardant polyester fiber. Flame retardant bedding products. 低融点バインダー繊維が低融点ポリエステル単一成分よりなる繊維、融点が200℃を超えるポリエステルと低融点ポリエステルの複合よりなる繊維、融点が200℃を超えるポリエステルと低融点ポリオレフィンの複合よりなる繊維よりなる群から選ばれる少なくとも一つの繊維である請求項5記載の難燃性寝具製品。   The low melting point binder fiber is a fiber composed of a single component of a low melting point polyester, a fiber composed of a composite of a polyester having a melting point exceeding 200 ° C and a low melting point polyester, and a fiber composed of a composite of a polyester having a melting point exceeding 200 ° C and a low melting point polyolefin. The flame-retardant bedding product according to claim 5, wherein the bedding product is at least one fiber selected from the group. 難燃性ポリエステル繊維がリン系化合物、リン酸エステル系化合物、含ハロゲンリン酸エステル系化合物、縮合リン酸エステル系化合物、ポリリン酸塩系化合物、ホスファゼン化合物、赤リン、ヒンダードアミン化合物等のアミン化合物、ホウ酸、臭化物等のハロゲン化合物、尿素−ホルムアルデヒド化合物、硫酸アンモニウム、水和金属化合物、金属酸化物、有機金属化合物、シリコーン系化合物よりなる群から選ばれる少なくとも一つの難燃剤を添加した繊維である請求項5記載の難燃性寝具製品。   Flame retardant polyester fiber is a phosphorus compound, phosphate ester compound, halogen-containing phosphate ester compound, condensed phosphate ester compound, polyphosphate compound, phosphazene compound, red phosphorus, hindered amine compound and other amine compounds, A fiber to which at least one flame retardant selected from the group consisting of halogen compounds such as boric acid and bromide, urea-formaldehyde compounds, ammonium sulfate, hydrated metal compounds, metal oxides, organometallic compounds, and silicone compounds is added. Item 6. A flame-retardant bedding product according to item 5. ハロゲン含有繊維(C)がモダアクリル繊維である請求項1〜7のいずれかに記載の難燃性寝具製品。   The flame-retardant bedding product according to any one of claims 1 to 7, wherein the halogen-containing fiber (C) is a modacrylic fiber. 側地が、セルロース系繊維および/またはポリエステル系繊維を含む請求項1〜8のいずれかに記載の難燃性寝具製品。   The flame-retardant bedding product according to any one of claims 1 to 8, wherein the side ground includes cellulosic fibers and / or polyester fibers. 側地が、セルロース系繊維20〜80重量%、ポリエステル系繊維80〜20重量%からなる請求項9記載の難燃性寝具製品。   The flame-retardant bedding product according to claim 9, wherein the side fabric is composed of 20 to 80% by weight of cellulosic fibers and 80 to 20% by weight of polyester fibers.
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