JPWO2006064538A1 - Method for producing metal-rubber composite product - Google Patents

Method for producing metal-rubber composite product Download PDF

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JPWO2006064538A1
JPWO2006064538A1 JP2005512624A JP2005512624A JPWO2006064538A1 JP WO2006064538 A1 JPWO2006064538 A1 JP WO2006064538A1 JP 2005512624 A JP2005512624 A JP 2005512624A JP 2005512624 A JP2005512624 A JP 2005512624A JP WO2006064538 A1 JPWO2006064538 A1 JP WO2006064538A1
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rubber
cavity
metal
mold
metal part
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JP4138805B2 (en
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松本 義春
義春 松本
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Toyo Tire Corp
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Toyo Tire and Rubber Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14467Joining articles or parts of a single article
    • B29C45/14491Injecting material between coaxial articles, e.g. between a core and an outside sleeve for making a roll
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14336Coating a portion of the article, e.g. the edge of the article
    • B29C45/14418Sealing means between mould and article
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/2669Moulds with means for removing excess material, e.g. with overflow cavities

Abstract

防振ブッシュのような金属−ゴム複合品の成形時におけるゴムバリを防止する。そのため、キャビティ16の縁部に沿ってゴム溜まり凹部54,56が設けられた成形型10を用いて、最初の成形時に、キャビティ内にゴム材料Rを注入することにより内外筒2,3とゴム弾性体4を一体成形するとともに、ゴム溜まり凹部54,56にゴム材料を充填させてシール用ゴム62,64を成形する。そして、脱型時にシール用ゴム62,64をゴム溜まり凹部54,56内に残置させ、その状態で成形型10内に内筒2と外筒3をセットして、2回目以降の成形を行い、シール用ゴム62,64によりキャビティ16からのゴム材料Rの流出を防止する。Prevents rubber burrs when molding metal-rubber composites such as vibration-proof bushings. Therefore, by using the molding die 10 provided with the rubber reservoir recesses 54 and 56 along the edge of the cavity 16, the rubber material R is injected into the cavity at the time of the first molding, so that the inner and outer cylinders 2 and 3 and the rubber The elastic body 4 is integrally molded, and the rubber reservoir recesses 54 and 56 are filled with a rubber material to form the sealing rubbers 62 and 64. Then, the sealing rubbers 62 and 64 are left in the rubber reservoir recesses 54 and 56 at the time of demolding, and the inner cylinder 2 and the outer cylinder 3 are set in the molding die 10 in that state, and the second and subsequent moldings are performed. The rubber rubber R for sealing prevents the rubber material R from flowing out of the cavity 16.

Description

本発明は、金属部品とゴム弾性体とが一体に成形された金属−ゴム複合品の製造方法と、それに用いる成形型に関し、特に、防振装置の製造に好適な製造方法および成形型に関するものである。  The present invention relates to a method for manufacturing a metal-rubber composite product in which a metal part and a rubber elastic body are integrally molded, and a mold used therefor, and more particularly to a manufacturing method and a mold suitable for manufacturing a vibration isolator. It is.

内筒と、これを同心的に取り囲む外筒と、両筒の間に介設されたゴム弾性体とからなるブッシュ型の防振装置を製造する場合、次のような方法が一般的である。すなわち、内筒と外筒を成形型内にセットし、この内外筒間と成形型内面との間で形成されるキャビティ内にゴム材料を注入して、当該キャビティ内にゴム材料を充填させることにより、内外筒間にゴム弾性体を一体に加硫成形する方法である。  When manufacturing a bush type vibration isolator comprising an inner cylinder, an outer cylinder that concentrically surrounds the inner cylinder, and a rubber elastic body interposed between the two cylinders, the following method is generally used. . That is, an inner cylinder and an outer cylinder are set in a mold, and a rubber material is injected into a cavity formed between the inner and outer cylinders and an inner surface of the mold, and the rubber material is filled into the cavity. Thus, a rubber elastic body is integrally vulcanized and molded between the inner and outer cylinders.

このような防振装置の製造においては、内筒の端面や外筒の外周面にゴムバリを生じさせないことが、防振装置としての性能を確保し、また見栄えの点からも求められる。そのため、従来よりゴムバリを防止するための方策が採られている。  In the manufacture of such a vibration isolator, it is required from the viewpoint of ensuring the performance as a vibration isolator and preventing the appearance of rubber burrs on the end surface of the inner cylinder and the outer peripheral surface of the outer cylinder. For this reason, measures for preventing rubber burrs have been taken.

従来の一般的な方策としては、例えば、内筒端面へのゴムバリ防止であれば、内筒端部の外径とこれを保持する成形型の凹部の内径との寸法を調整して、両者を隙間なく嵌合させるという方法がある(例えば、日本国特開平7−276382号公報)。しかしながら、このように成形型と内筒との金属同士の嵌合によりシール性を確保しようとする場合、嵌合度合をきつくする必要があり、その場合、成形型が摩耗しやすくなり、成形型の耐久性を損なう。また、脱型時に外れにくいという問題がある。  As a conventional general measure, for example, to prevent rubber burrs on the inner cylinder end face, adjust the dimensions of the outer diameter of the inner cylinder end and the inner diameter of the recess of the mold that holds the inner cylinder. There is a method of fitting with no gap (for example, Japanese Patent Laid-Open No. 7-276382). However, when the sealing property is to be secured by fitting the metal between the mold and the inner cylinder in this way, it is necessary to tighten the degree of fitting. Impairs the durability. There is also a problem that it is difficult to come off during demolding.

また、上記公報に記載されているように、内筒端面に当接する成形型部分に、ゴム弾性体とは異種材料からなる弾性材料や軟質材料を配設して、型閉め時に内筒をこれらの弾性材料や軟質材料に押し当てることにより、シール性を確保するという方策がある。しかしながら、このような弾性材料や軟質材料などのシール材を別途配設する方法では、配設コストがかかり、また製品ごとにシール材の形状、寸法などが異なるため、多種類のシール材を用意する必要があり、この点からもコスト高になる。  Further, as described in the above publication, an elastic material or a soft material made of a material different from the rubber elastic body is disposed on the mold portion that contacts the end surface of the inner cylinder, and these inner cylinders are disposed when the mold is closed. There is a measure to ensure sealing performance by pressing against an elastic material or soft material. However, such a method of separately disposing a sealing material such as an elastic material or a soft material requires a disposition cost, and since the shape and dimensions of the sealing material are different for each product, various types of sealing materials are prepared. From this point of view, the cost is high.

また、日本国特開2000−43062号公報には、内筒の端部に大径部と小径部を設けて、両者の間の段差部分に成形型のエッジを圧接させることにより、内筒端部のゴムバリを防止する方法が記載されている。しかしながら、この場合、内筒の端部に上記の段差部分を設けるための加工が別途必要となり、コスト高につながる。また、成形型のエッジを圧接させることから、この部分の摩耗の問題も懸念される。
:日本国特開平7−276382号公報 :日本国特開2000−43062号公報
Japanese Patent Application Laid-Open No. 2000-43062 discloses an inner cylinder end by providing a large-diameter portion and a small-diameter portion at an end portion of the inner cylinder, and press-contacting the edge of the mold to the step portion between the two A method for preventing rubber burr in the part is described. However, in this case, processing for providing the above-described stepped portion at the end of the inner cylinder is separately required, leading to high costs. In addition, since the edges of the mold are brought into pressure contact, there is a concern about the problem of wear in this portion.
: Japanese Unexamined Patent Publication No. 7-276382 : Japanese Unexamined Patent Publication No. 2000-43062

本発明は、上記に鑑みてなされたものであり、製品の脱型不良や成形型の摩耗の問題を回避しつつ、しかも低コストに、ゴムバリを防止することができる金属−ゴム複合品の製造方法および成形型を提供することを目的とする。  The present invention has been made in view of the above, and manufacture of a metal-rubber composite product capable of preventing rubber burrs at low cost while avoiding the problem of product demolding failure and mold wear. It is an object to provide a method and a mold.

本発明に係る製造方法は、成形型内に金属部品をセットし、前記金属部品と前記成形型との間に形成されるキャビティ内にゴム材料を注入して前記金属部品の表面にゴム弾性体を一体に成形する金属−ゴム複合品の製造方法であって、前記キャビティに面する前記金属部品表面の縁部に沿ってゴム溜まり凹部が設けられた成形型を用いて、前記成形型内に金属部品をセットして前記キャビティ内にゴム材料を注入することにより、当該キャビティ内に前記ゴム材料を充填させて前記金属部品とゴム弾性体を一体成形するとともに、前記ゴム溜まり凹部に前記ゴム材料を充填させてシール用ゴムを成形し、前記で成形した金属部品とゴム弾性体の一体成形品を成形型から脱型するとともに、前記ゴム溜まり凹部にて成形された前記シール用ゴムを当該ゴム溜まり凹部内に残置させ、前記シール用ゴムを残置させた状態で前記成形型内に金属部品をセットし、前記キャビティ内にゴム材料を注入して、前記金属部品と前記ゴム弾性体を一体成形するものである。  In the manufacturing method according to the present invention, a metal part is set in a mold, a rubber material is injected into a cavity formed between the metal part and the mold, and a rubber elastic body is formed on the surface of the metal part. A metal-rubber composite product manufacturing method in which a rubber reservoir recess is provided along an edge of the surface of the metal part facing the cavity. By setting a metal part and injecting a rubber material into the cavity, the rubber material is filled into the cavity to integrally form the metal part and a rubber elastic body, and the rubber material is formed in the rubber reservoir recess. The sealing rubber is molded by molding the sealing rubber, removing the integrally molded metal part and rubber elastic body from the molding die, and molding the rubber reservoir recess. The metal part is set in the mold while the rubber for sealing is left, the rubber for sealing is left, the rubber material is injected into the cavity, and the metal part and the rubber elastic body are It is an integral molding.

また、本発明に係る成形型は、金属部品の表面にゴム弾性体を一体に成形してなる金属−ゴム複合品を成形するための成形型であって、前記ゴム弾性体を成形するためのキャビティを備え、前記キャビティに面する前記金属部品表面の縁部に沿ってゴム溜まり凹部が設けられ、前記ゴム溜まり凹部は、前記金属部品表面に面する成形型部分に設けられるとともに、微小隙間を介して前記キャビティに連通しており、該微小隙間を通ってゴム材料が充填されることにより前記キャビティからの前記ゴム材料の流出の防止するシール用ゴムを成形するものである。  A molding die according to the present invention is a molding die for molding a metal-rubber composite product formed by integrally molding a rubber elastic body on the surface of a metal part, and for molding the rubber elastic body. A rubber reservoir recess is provided along an edge of the surface of the metal part facing the cavity, and the rubber pool recess is provided in a mold part facing the metal part surface and has a minute gap. A rubber for sealing that prevents the rubber material from flowing out of the cavity is molded by being filled with the rubber material through the minute gap.

かかる本発明によれば、成形型にはキャビティのシール部に相当する箇所にゴム溜まり凹部が設けられており、最初の成形時に、製品のゴム弾性体を成形するとともに、そのゴム材料をゴム溜まり凹部にも充填させることでシール用ゴムを設ける。次いで、その脱型時にシール用ゴムを成形型に残置させることにより、以後の成形において、キャビティからのゴム材料の流出を防止するためのシール材として機能させることができる。  According to the present invention, the molding die is provided with the rubber reservoir recess at a location corresponding to the seal portion of the cavity, and at the time of the first molding, the rubber elastic body of the product is molded and the rubber material is stored in the rubber reservoir. Sealing rubber is provided by filling the recess. Next, by leaving the sealing rubber in the mold during the mold removal, it can function as a seal material for preventing the rubber material from flowing out of the cavity in the subsequent molding.

上記本発明においては、前記シール用ゴムが前記金属部品表面における前記キャビティに面する部分の縁部に沿って当該金属部品の表面に当接し、これにより前記キャビティからの前記ゴム材料の流出が防止されることが好ましい。  In the present invention, the sealing rubber contacts the surface of the metal part along the edge of the metal part surface facing the cavity, thereby preventing the rubber material from flowing out of the cavity. It is preferred that

本発明においては、前記ゴム溜まり凹部が微小隙間を介して前記キャビティに連通していることが好ましい。この場合、最初の成形時に、キャビティにゴム材料を注入すると、該ゴム材料が微小隙間を通ってゴム溜まり凹部に充填される。  In the present invention, it is preferable that the rubber reservoir recess communicates with the cavity through a minute gap. In this case, when a rubber material is injected into the cavity at the time of the first molding, the rubber material passes through the minute gap and is filled into the rubber reservoir recess.

また、本発明において、前記ゴム溜まり凹部は開口側が狭まった断面形状に形成されていることが好ましい。このような断面形状であれば、ゴム溜まり凹部内に成形されたシール用ゴムが製品脱型時に外れず、シール材としての繰り返し使用が可能となる。  In the present invention, the rubber reservoir recess is preferably formed in a cross-sectional shape with a narrow opening side. With such a cross-sectional shape, the sealing rubber molded in the rubber reservoir recess does not come off during product demolding and can be used repeatedly as a sealing material.

本発明において、前記成形型には、前記キャビティに対して開口する大気開放ベントが設けられてもよい。このような大気開放ベントを設けることにより、キャビティ内の気体を外気に抜くことができ、成形性を向上することができる。また、一度に複数の製品を成形可能な多数個取りの成形型において、大気開放ベントから余剰のゴム材料を排出させることによりキャビティバランスをとることができる。  In the present invention, the mold may be provided with an open air vent that opens to the cavity. By providing such an air release vent, the gas in the cavity can be extracted to the outside air, and the moldability can be improved. Further, in a multi-cavity mold that can mold a plurality of products at a time, cavity balance can be achieved by discharging excess rubber material from the open vent.

本発明は、特に、金属部品である内筒及びこれを軸平行に取り囲む外筒と、前記内筒と前記外筒の間に介設されたゴム弾性体とからなる防振装置の製造に用いることが効果的である。この場合、前記内筒の端部外周面に面する成形型部分に前記ゴム溜まり凹部が設けられ、前記内筒端部の外周面とこれに面する前記成形型部分との間に前記キャビティと前記ゴム溜まり凹部とを連通させる微小隙間が形成されていることが好ましく、これにより、内筒端面へのゴムバリの発生を効果的に抑制することができる。  The present invention is particularly used for manufacturing a vibration isolator comprising an inner cylinder that is a metal part, an outer cylinder that surrounds the inner cylinder, and a rubber elastic body interposed between the inner cylinder and the outer cylinder. It is effective. In this case, the rubber reservoir recess is provided in the mold portion facing the outer peripheral surface of the end portion of the inner cylinder, and the cavity and the cavity between the outer peripheral surface of the inner cylinder end portion and the mold portion facing the same. It is preferable that a minute gap that communicates with the rubber reservoir recess is formed, and thereby, generation of rubber burrs on the inner cylinder end surface can be effectively suppressed.

また、この場合、前記外筒の軸方向端面に面する成形型部分に前記ゴム溜まり凹部が設けられ、該ゴム溜まり凹部の開口面の一部が前記外筒端面により覆われて前記キャビティと前記ゴム溜まり凹部とを連通させる微小隙間が形成されていることが好ましく、これにより、外筒端部において外周面へのゴムバリの発生を効果的に抑制することができる。  Also, in this case, the rubber reservoir recess is provided in the mold portion facing the axial end surface of the outer cylinder, and a part of the opening surface of the rubber reservoir recess is covered by the outer cylinder end surface, and the cavity and the It is preferable that a minute gap that communicates with the rubber reservoir recess is formed, whereby the generation of rubber burrs on the outer peripheral surface at the outer cylinder end can be effectively suppressed.

本発明によれば、製品のゴム弾性体を成形するためのゴム材料をそのままシール材としても利用するので、低コストにゴムバリを防止することができる。また、異なる品種の製品に対しても、成形型にゴム溜まり凹部を設けておけば、最初の成形時に、その成形型に応じたシール材が形成されるので、異種材料からなるシール材を別途配設する場合に比べて明らかに有利である。  According to the present invention, since the rubber material for molding the rubber elastic body of the product is used as it is as the sealing material, rubber burrs can be prevented at low cost. Also, even if different types of products are provided, if a rubber reservoir recess is provided in the mold, a seal material corresponding to the mold will be formed at the time of the first molding. There is a clear advantage over the arrangement.

また、ゴム材料からなるシール材でゴムバリを防止するものであるため、成形型と金属部品との金属同士のきつい嵌合によりシール性を確保する必要がなく、製品の脱型不良や成形型の摩耗の問題を回避することができる。  In addition, since a rubber material is used to prevent rubber burrs, there is no need to ensure sealing performance by tightly fitting the metal between the mold and metal parts. Wear problems can be avoided.

以下に本発明を実施するための最良の形態を図面に基づいて説明するが、本発明はこれら実施形態に限定されるものではない。  The best mode for carrying out the present invention will be described below with reference to the drawings. However, the present invention is not limited to these embodiments.

図1は、本発明の一実施形態に係る成形型10の断面図であり、図2は、その要部拡大断面図、図3,4は、更にその一部拡大図である。この成形型10は、図8に示す防振ブッシュ(防振装置)1を加硫成形するための射出成形用金型である。  FIG. 1 is a cross-sectional view of a molding die 10 according to an embodiment of the present invention, FIG. 2 is an enlarged cross-sectional view of a main part thereof, and FIGS. The mold 10 is an injection mold for vulcanizing the vibration isolating bush (vibration isolator) 1 shown in FIG.

この防振ブッシュ1は、金属製の内筒2と、これを同心的に取り囲む金属製の外筒3と、これら内筒2と外筒3の間に介在して両者を結合するゴム弾性体4とを備えてなる。ゴム弾性体4には、軸方向の貫通孔であるすぐり部5が設けられており、すぐり部5は内筒2を挟んで径方向に相対する2箇所に設けられている。また、ゴム弾性体4の一方の端面には、内筒2を挟んで径方向に相対する2箇所に凸部6が設けられており、凸部6はすぐり部5とは重ならない周方向位置に設けられている。凸部6は、後記する注入経路のゲート24と大気開放ベント28を接続するために形成されている。  The anti-vibration bush 1 includes a metal inner cylinder 2, a metal outer cylinder 3 concentrically surrounding the metal inner cylinder 2, and a rubber elastic body that is interposed between the inner cylinder 2 and the outer cylinder 3 to couple them together. 4 and. The rubber elastic body 4 is provided with a straight portion 5 which is a through hole in the axial direction, and the straight portion 5 is provided at two locations opposed to each other in the radial direction across the inner cylinder 2. Further, on one end surface of the rubber elastic body 4, convex portions 6 are provided at two locations facing each other in the radial direction across the inner cylinder 2, and the convex portions 6 do not overlap with the straight portions 5. Is provided. The convex portion 6 is formed to connect the gate 24 of the injection path to be described later and the air release vent 28.

図1に示すように、成形型10は、上型12と、上型12に対して上下動することで型閉め及び型開き可能な下型14とを備えてなり、上型12と下型14とを型閉めすることにより上記ゴム弾性体4を成形するためのキャビティ16が形成されるようになっている。なお、成形型10は複数の防振ブッシュを一度に成形することができるように、上記キャビティ16を複数個、例えば8個備える。  As shown in FIG. 1, the molding die 10 includes an upper die 12 and a lower die 14 that can be closed and opened by moving up and down relative to the upper die 12. A cavity 16 for molding the rubber elastic body 4 is formed by closing the mold 14. The molding die 10 includes a plurality of, for example, eight cavities 16 so that a plurality of vibration-proof bushings can be molded at a time.

上型12の上面にはランナブロック18が設けられており、このランナブロック18を上下に貫通するスプルー20と、ランナブロック18と上型12との接合面に形成される水平ランナ22と、キャビティ16へのゲート24と、上型12を上下に貫通して水平ランナ22とゲート24とを連結するランナ孔26とにより、キャビティ16内に成形材料であるゴム材料Rを注入するための注入経路が形成されている。  A runner block 18 is provided on the upper surface of the upper mold 12, a sprue 20 penetrating the runner block 18 in the vertical direction, a horizontal runner 22 formed on a joint surface between the runner block 18 and the upper mold 12, a cavity An injection path for injecting a rubber material R, which is a molding material, into the cavity 16 by a gate 24 to 16 and a runner hole 26 that penetrates the upper mold 12 vertically and connects the horizontal runner 22 and the gate 24. Is formed.

成形型10には、キャビティ16の上端面に対して開口する大気開放ベント28が設けられている。大気開放ベント28は、上記ゲート24とは径方向の反対側に設けられており、キャビティ16から上方に延び、ランナブロック18と上型12との接合面に沿って成形型外に引き出されている。  The molding die 10 is provided with an air release vent 28 that opens to the upper end surface of the cavity 16. The air release vent 28 is provided on the opposite side of the gate 24 in the radial direction, extends upward from the cavity 16, and is drawn out of the mold along the joint surface between the runner block 18 and the upper mold 12. Yes.

成形型10内には上記内筒2と外筒3がセットされる。詳細には、上型12と下型14には、内筒2をその軸方向を上下方向に向けた姿勢で保持する中子ピン30,32が設けられており、中子ピン30,32は内筒2の内側に挿入されることにより内筒2を上下方向から挟み込むように保持する。上型12の中子ピン30は、脱型性向上のため、バネ34により下方に付勢されている。下型14の中子ピン32は、エジェクタ36により上下動可能に設けられており、脱型時に内筒2を上方に押し上げることで製品が取り出されるようになっている。一方、外筒3は、内筒2を取り囲むように上下型12,14に保持され、このようにして保持された内外筒2,3間および上下型12,14間に、中空円柱状の上記キャビティ16が形成される。  The inner cylinder 2 and the outer cylinder 3 are set in the mold 10. Specifically, the upper mold 12 and the lower mold 14 are provided with core pins 30 and 32 for holding the inner cylinder 2 in a posture in which the axial direction thereof is directed in the vertical direction. By being inserted inside the inner cylinder 2, the inner cylinder 2 is held so as to be sandwiched from above and below. The core pin 30 of the upper mold 12 is urged downward by a spring 34 in order to improve the demoldability. The core pin 32 of the lower die 14 is provided so as to be movable up and down by an ejector 36, and a product is taken out by pushing up the inner cylinder 2 upward when removing the die. On the other hand, the outer cylinder 3 is held by the upper and lower molds 12 and 14 so as to surround the inner cylinder 2, and the hollow cylinder-shaped above-mentioned is formed between the inner and outer cylinders 2 and 3 and the upper and lower molds 12 and 14 thus held. A cavity 16 is formed.

上型12は、複数の型部に分解可能に構成されており、詳細には、図2に示すように、ゴム弾性体4の上面を成形する上面成形部38と、その内周面に嵌合されて内筒2の端面2aを当接支持する筒状の内筒支持部40と、上面成形部38の外周面に外嵌されて外筒3の端面3aを当接支持するリング状の外筒支持部42とを備えてなる。なお、上面成形部38には、上記すぐり部5を成形するためのコア部44が設けられている。  The upper mold 12 is configured to be disassembled into a plurality of mold parts. Specifically, as shown in FIG. 2, the upper mold 12 is fitted to the upper surface molding part 38 for molding the upper surface of the rubber elastic body 4 and the inner peripheral surface thereof. A ring-shaped inner tube support portion 40 that is joined to and supports the end surface 2a of the inner tube 2 and a ring-shaped member that is externally fitted to the outer peripheral surface of the upper surface molding portion 38 and contacts and supports the end surface 3a of the outer tube 3. And an outer cylinder support portion 42. The upper surface forming portion 38 is provided with a core portion 44 for forming the straight portion 5.

下型14も、同様に複数の型部に分解可能に構成されており、詳細には、ゴム弾性体4の下面を成形する下面成形部46と、その内周面に嵌合されて内筒2の端面2aを当接支持する筒状の内筒支持部48と、下面成形部46の外周面に外嵌されて外筒3の端面3aを当接支持するリング状の外筒支持部50とを備えてなる。なお、下面成形部46には、上記すぐり部5を成形するためのコア部52が設けられている。  Similarly, the lower mold 14 is configured to be disassembled into a plurality of mold parts. Specifically, the lower mold 14 is fitted into the lower surface molding part 46 that molds the lower surface of the rubber elastic body 4 and the inner peripheral surface thereof, and the inner cylinder. A cylindrical inner cylinder support portion 48 that abuts and supports the two end surfaces 2a, and a ring-shaped outer cylinder support portion 50 that is fitted on the outer peripheral surface of the lower surface molding portion 46 and abuts and supports the end surface 3a of the outer cylinder 3. And comprising. The lower surface molding portion 46 is provided with a core portion 52 for molding the straight portion 5.

図2に示されるように、成形型10には、内筒2及び外筒3の表面におけるキャビティ16に面する部分の縁部に沿って、ゴム溜まり凹部54,56が設けられている。すなわち、内筒2及び外筒3においてゴム弾性体4で覆われる部分と覆われない部分との境界に沿うように、成形型10にはゴム溜まり凹部54,56が設けられている。  As shown in FIG. 2, the molding die 10 is provided with rubber reservoir recesses 54 and 56 along the edge portions of the surfaces of the inner cylinder 2 and the outer cylinder 3 facing the cavity 16. In other words, the rubber mold recesses 54 and 56 are provided in the mold 10 along the boundary between the portion covered with the rubber elastic body 4 and the portion not covered in the inner cylinder 2 and the outer cylinder 3.

図2,3に示されるように、内筒2側のゴム溜まり凹部54は、内筒2の端部外周面に面する成形型部分において、内筒2の外周面に向けて内向きに開口するように設けられており、上記した上面成形部38又は下面成形部46と、その内側に配された内筒支持部40,48との間で形成されている。ゴム溜まり凹部54は、内筒2の外周面の全周にわたって設けられている。また、ゴム溜まり凹部54は、その開口側が奥側よりも断面積が小さくなるように開口側に狭まった断面形状に形成されており、図3に示すようにこの実施形態ではアリ溝状に形成されている。そして、内筒2端部の外周面とこれに面する上面成形部38又は下面成形部46の内周面に、キャビティ16とゴム溜まり凹部54とを連通させる微小隙間(スリット)58が形成されている。微小隙間58は、後述する最初の成形時に、キャビティ16内からゴム溜まり凹部54にゴム材料Rを流出させて当該凹部54をゴム材料Rで充填させることができる寸法であれば、特に限定されないが、0.5mm以下であることが好ましく、より好ましくは0.05〜0.4mmであり、この実施形態では約0.1mmに設定されている。  As shown in FIGS. 2 and 3, the rubber reservoir recess 54 on the side of the inner cylinder 2 opens inward toward the outer peripheral surface of the inner cylinder 2 in the mold portion facing the outer peripheral surface of the end of the inner cylinder 2. And is formed between the upper surface molding portion 38 or the lower surface molding portion 46 described above and the inner cylinder support portions 40 and 48 disposed on the inner side thereof. The rubber reservoir recess 54 is provided over the entire circumference of the outer peripheral surface of the inner cylinder 2. Further, the rubber reservoir recess 54 is formed in a cross-sectional shape narrowed on the opening side so that the cross-sectional area of the opening side is smaller than the back side, and in this embodiment, it is formed in a dovetail shape as shown in FIG. Has been. A minute gap (slit) 58 that allows the cavity 16 and the rubber reservoir recess 54 to communicate with each other is formed on the outer peripheral surface of the end portion of the inner cylinder 2 and the inner peripheral surface of the upper surface molding portion 38 or the lower surface molding portion 46 facing this. ing. The minute gap 58 is not particularly limited as long as it is a size that allows the rubber material R to flow out of the cavity 16 into the rubber reservoir recess 54 and fill the recess 54 with the rubber material R during the first molding described later. 0.5 mm or less, more preferably 0.05 to 0.4 mm, and in this embodiment, it is set to about 0.1 mm.

図2,4に示されるように、外筒3側のゴム溜まり凹部56は、外筒3の軸方向端面3aに面する成形型部分において、外筒3の端面3aに向けて開口するように設けられており、上記した上面成形部38又は下面成形部46と、その外側に配された外筒支持部42,50との間で形成されている。ゴム溜まり凹部56は、外筒3の端面3aの全周にわたって設けられている。また、ゴム溜まり凹部56は、その開口側が奥側よりも断面積が小さくなるように開口側に狭まった断面形状に形成されている。そして、ゴム溜まり凹部56の開口面は、外周側が外筒3の端面3aにより覆われており、該端面3aにより覆われていない内周側部分がキャビテイ16とゴム溜まり凹部56とを連通させる微小隙間(スリット)60として確保されている。微小隙間60は、後述する最初の成形時に、キャビティ16内からゴム溜まり凹部56にゴム材料Rを流出させて当該凹部56をゴム材料Rで充填させることができる寸法であれば、特に限定されないが、0.5mm以下であることが好ましく、より好ましくは0.05〜0.4mmであり、この実施形態では約0.3mmに設定されている。  As shown in FIGS. 2 and 4, the rubber reservoir recess 56 on the outer cylinder 3 side is opened toward the end surface 3 a of the outer cylinder 3 in the molding die portion facing the axial end surface 3 a of the outer cylinder 3. It is provided, and is formed between the above-described upper surface molding portion 38 or the lower surface molding portion 46 and the outer cylinder support portions 42 and 50 disposed on the outside thereof. The rubber reservoir recess 56 is provided over the entire circumference of the end surface 3 a of the outer cylinder 3. Further, the rubber reservoir recess 56 is formed in a cross-sectional shape narrowed to the opening side so that the opening side has a smaller cross-sectional area than the back side. The opening surface of the rubber reservoir recess 56 is covered with the end surface 3 a of the outer cylinder 3 on the outer peripheral side, and the inner peripheral side portion not covered with the end surface 3 a is a minute that allows the cavity 16 and the rubber reservoir recess 56 to communicate with each other. It is secured as a gap (slit) 60. The minute gap 60 is not particularly limited as long as it is a size that allows the rubber material R to flow out of the cavity 16 into the rubber reservoir recess 56 and fill the recess 56 with the rubber material R during the first molding described later. 0.5 mm or less, more preferably 0.05 to 0.4 mm, and in this embodiment, it is set to about 0.3 mm.

以上よりなる成形型10を用い、本実施形態では次のようにして防振ブッシュ1を製造する。  In the present embodiment, the anti-vibration bush 1 is manufactured as follows using the molding die 10 as described above.

(1)まず、図2に示すようにゴム溜まり凹部54,56にゴムが充填されていない状態で、一回目の防振ブッシュ1の成形を行う。詳細には、下型14を下降させて型開きした状態で、内筒2と外筒3をセットし、下型14を上昇させて型閉めしてから、スプルー20よりゴム材料Rをキャビティ16内に注入する。これにより、図5に示すように、キャビティ16内にゴム材料Rが充填されてゴム弾性体4が内外筒2,3に一体に加硫成形される。同時に、キャビティ16内に注入されたゴム材料Rが、微小隙間58,60を通ってゴム溜まり凹部54,56に充填されて、シール用ゴム62,64が加硫成形される。また、この時、余剰のゴム材料Rは大気開放ベント28からキャビティ16外に排出される。(1) First, as shown in FIG. 2, the first vibration isolating bush 1 is molded in a state where the rubber reservoir recesses 54 and 56 are not filled with rubber. Specifically, the inner cylinder 2 and the outer cylinder 3 are set in a state where the lower mold 14 is lowered and the mold is opened, the lower mold 14 is raised and the mold is closed, and then the rubber material R is removed from the sprue 20 into the cavity 16. Inject into. As a result, as shown in FIG. 5, the rubber material R is filled into the cavity 16, and the rubber elastic body 4 is integrally vulcanized and molded into the inner and outer cylinders 2 and 3. At the same time, the rubber material R injected into the cavity 16 is filled into the rubber reservoir recesses 54 and 56 through the minute gaps 58 and 60, and the sealing rubbers 62 and 64 are vulcanized. At this time, the surplus rubber material R is discharged out of the cavity 16 from the atmosphere opening vent 28.

(2)次に、上記(1)で成形した防振ブッシュ1を成形型10から脱型する。脱型は、図6に示すように下型14を下降させて型開きし、下型14の中子ピン32をエジェクタ36により上方に押し出すことで行われる。この脱型の際に、ゴム溜まり凹部54,56にて成形されたシール用ゴム62,64は、ゴム溜まり凹部54,56が開口側で狭まった断面形状を持つため、ゴム弾性体4とともに脱型されず切断されて、ゴム溜まり凹部54,56内に残置される。なお、脱型時には、上型12をランナブロック18から接離することでスプルー20及びランナ22,26で固まったゴムを取り出すことができる。(2) Next, the vibration isolating bush 1 molded in the above (1) is removed from the mold 10. Demolding is performed by lowering the lower mold 14 and opening the mold as shown in FIG. 6 and pushing the core pin 32 of the lower mold 14 upward by the ejector 36. During this demolding, the sealing rubbers 62 and 64 formed in the rubber reservoir recesses 54 and 56 have a cross-sectional shape in which the rubber reservoir recesses 54 and 56 are narrowed on the opening side. It is cut without being molded and left in the rubber reservoir recesses 54 and 56. At the time of mold removal, the rubber solidified by the sprue 20 and the runners 22 and 26 can be taken out by contacting and separating the upper mold 12 from the runner block 18.

(3)上記のようにしてシール用ゴム62,64を残置させた状態で、図7に示すように、成形型10内に内筒2と外筒3をセットし、キャビティ16内にゴム材料Rを注入して、2回目以降の防振ブッシュ1の成形を行う。(3) With the sealing rubbers 62 and 64 left as described above, the inner cylinder 2 and the outer cylinder 3 are set in the mold 10 as shown in FIG. R is injected to form the vibration isolating bush 1 for the second and subsequent times.

2回目以降の成形においては、シール用ゴム62,64が、キャビティ16の縁部に沿って内筒2の端部外周面および外筒3の端面3aに当接し、これによりキャビティ16からのゴム材料Rの流出が防止され、ゴムバリが皆無となる。なお、シール用ゴム62,64は、厳密には内筒2の外周面や外筒3の端面3aに当接していないてもよく、数μm程度の隙間が確保されることで、ゴム材料Rの流出を防止しつつ、この部分からのガス抜きも可能となる。また、2回目以降の成形において、キャビティ16内の大部分の気体は、大気開放ベント28から排出され、成形性を確保することができる。  In the second and subsequent moldings, the sealing rubbers 62 and 64 abut against the outer peripheral surface of the end of the inner cylinder 2 and the end surface 3 a of the outer cylinder 3 along the edge of the cavity 16. The outflow of the material R is prevented, and there is no rubber burr. Strictly speaking, the sealing rubbers 62 and 64 may not be in contact with the outer peripheral surface of the inner cylinder 2 or the end surface 3a of the outer cylinder 3, and a rubber material R is secured by ensuring a gap of about several μm. It is also possible to vent the gas from this part while preventing the outflow. Further, in the second and subsequent moldings, most of the gas in the cavity 16 is exhausted from the atmosphere opening vent 28, and moldability can be ensured.

なお、このようにして成形されたシール用ゴム62,64は、多数回の繰り返し使用により劣化してくるが、その場合には、成形型10を分解してシール用ゴム62,64を清掃除去すればよく、その後、再度上記のようにしてシール用ゴム62,64を成形すればよい。  The sealing rubbers 62 and 64 molded in this way deteriorate due to repeated use. In this case, the molding die 10 is disassembled and the sealing rubbers 62 and 64 are removed by cleaning. Then, the sealing rubbers 62 and 64 may be molded again as described above.

以上よりなる本実施形態であると、防振ブッシュ1のゴム弾性体4を成形するためのゴム材料Rをそのままシール用ゴム62,64としても利用するので、低コストにゴムバリを防止することができる。  In the present embodiment configured as described above, the rubber material R for forming the rubber elastic body 4 of the vibration isolating bush 1 is also used as the sealing rubbers 62 and 64 as it is, so that rubber burrs can be prevented at low cost. it can.

また、様々な品種の防振装置に対しても、成形型10に上記のようなゴム溜まり凹部54,56を設けておけば、最初の成形時に、その成形型10に応じたシール用ゴム62,64が形成されるので、様々な形状のシール材を別途用意する必要がなく、多品種少量生産にも適している。  In addition, for various types of vibration isolators, if the above-described rubber reservoir recesses 54 and 56 are provided in the mold 10, the sealing rubber 62 corresponding to the mold 10 is formed at the time of the first molding. 64 are formed, it is not necessary to prepare seal materials of various shapes separately, and it is suitable for high-mix low-volume production.

また、ゴム材料Rからなるシール用ゴム62,64でゴムバリを防止するものであるため、成形型と内筒や外筒との金属同士のきつい嵌合によりシール性を確保する必要がなく、そのため、防振ブッシュの脱型不良や成形型の摩耗の問題を回避することができる。  Further, since the sealing rubbers 62 and 64 made of the rubber material R prevent rubber burrs, it is not necessary to ensure sealing performance by tightly fitting the metal between the mold and the inner and outer cylinders. In addition, it is possible to avoid the problem of demolding of the vibration isolating bush and the wear of the mold.

なお、上記した実施形態では、防振ブッシュの成形型及び製造方法について説明したが、本発明はこれに限定されるものではなく、他の防振装置にも同様に適用することができ、また、金属部品とその表面に一体に成形されるゴム弾性体とからなる各種の金属−ゴム複合品にも同様に適用することができる。  In the above-described embodiment, the mold and the manufacturing method of the vibration isolating bush have been described. However, the present invention is not limited to this, and can be similarly applied to other vibration isolating apparatuses. The present invention can be similarly applied to various metal-rubber composite products composed of a metal part and a rubber elastic body formed integrally on the surface of the metal part.

[図1]本発明の一実施形態に係る成形型の縦断面図である。
[図2]同成形型の一部の拡大断面図である。
[図3]同成形型における内筒端部を拡大して示す断面図である。
[図4]同成形型における外筒端部を拡大して示す断面図である。
[図5]同成形型のゴム材料注入後の状態を示す断面図である。
[図6]同成形型の脱型時の状態を示す断面図である。
[図7]同成形型のシール用ゴム成形後の断面図である。
[図8]防振ブッシュの断面図である。
FIG. 1 is a longitudinal sectional view of a mold according to an embodiment of the present invention.
FIG. 2 is an enlarged sectional view of a part of the mold.
FIG. 3 is an enlarged cross-sectional view showing an inner cylinder end portion in the same mold.
FIG. 4 is an enlarged cross-sectional view showing an outer cylinder end portion in the same mold.
FIG. 5 is a cross-sectional view showing a state after injection of a rubber material of the same mold.
FIG. 6 is a cross-sectional view showing a state when the mold is removed.
FIG. 7 is a cross-sectional view of the molding die after molding a rubber for sealing.
FIG. 8 is a cross-sectional view of a vibration isolating bush.

符号の説明Explanation of symbols

1…防振ブッシュ、2…内筒、3…外筒、3a…外筒の端面、4…ゴム弾性体、10…成形型、16…キャビティ、28…大気開放ベント、54,56…ゴム溜まり凹部、58,60…微小隙間、62,64…シール用ゴムDESCRIPTION OF SYMBOLS 1 ... Anti-vibration bush, 2 ... Inner cylinder, 3 ... Outer cylinder, 3a ... End surface of an outer cylinder, 4 ... Rubber elastic body, 10 ... Mold, 16 ... Cavity, 28 ... Air release vent, 54, 56 ... Rubber reservoir Recess, 58, 60 ... minute gap, 62, 64 ... rubber for sealing

本発明は、金属部品とゴム弾性体とが一体に成形された金属−ゴム複合品の製造方法関し、特に、防振装置の製造に好適な製造方法関するものである。 The present invention, metal parts and metal rubber elastic body and is formed integrally - relates to the method of manufacturing a rubber composite article, and in particular relates to a preferred production method for the manufacture of anti-vibration device.

本発明は、上記に鑑みてなされたものであり、製品の脱型不良や成形型の摩耗の問題を回避しつつ、しかも低コストに、ゴムバリを防止することができる金属−ゴム複合品の製造方法提供することを目的とする。 The present invention has been made in view of the above, and manufacture of a metal-rubber composite product capable of preventing rubber burrs at low cost while avoiding the problem of product demolding failure and mold wear. It aims to provide a method.

上記本発明において、成形型としては、金属部品の表面にゴム弾性体を一体に成形してなる金属−ゴム複合品を成形するための成形型であって、前記ゴム弾性体を成形するためのキャビティを備え、前記キャビティに面する前記金属部品表面の縁部に沿ってゴム溜まり凹部が設けられ、前記ゴム溜まり凹部は、前記金属部品表面に面する成形型部分に設けられるとともに、微小隙間を介して前記キャビティに連通しており、該微小隙間を通ってゴム材料が充填されることにより前記キャビティからの前記ゴム材料の流出の防止するシール用ゴムを成形するものを用いることができる。 Oite to the present invention, as the mold, the metal formed by molding integrally the rubber elastic body on the surface of metal parts - a mold for molding a rubber composite articles, molding the rubber elastic body And a rubber reservoir recess is provided along an edge of the surface of the metal part facing the cavity. The rubber reservoir recess is provided in a mold part facing the surface of the metal part and is minute. A rubber that communicates with the cavity through a gap and is filled with a rubber material through the minute gap to form a rubber for sealing that prevents the rubber material from flowing out of the cavity can be used. The

Claims (9)

成形型内に金属部品をセットし、前記金属部品と前記成形型との間に形成されるキャビティ内にゴム材料を注入して前記金属部品の表面にゴム弾性体を一体に成形する金属−ゴム複合品の製造方法であって、
前記キャビティに面する前記金属部品表面の縁部に沿ってゴム溜まり凹部が設けられた成形型を用いて、
前記成形型内に金属部品をセットして前記キャビティ内にゴム材料を注入することにより、当該キャビティ内に前記ゴム材料を充填させて前記金属部品とゴム弾性体を一体成形するとともに、前記ゴム溜まり凹部に前記ゴム材料を充填させてシール用ゴムを成形し、
前記で成形した金属部品とゴム弾性体の一体成形品を成形型から脱型するとともに、前記ゴム溜まり凹部にて成形された前記シール用ゴムを当該ゴム溜まり凹部内に残置させ、
前記シール用ゴムを残置させた状態で前記成形型内に金属部品をセットし、前記キャビティ内にゴム材料を注入して、前記金属部品と前記ゴム弾性体を一体成形する
ことを特徴とする金属−ゴム複合品の製造方法。
Metal-rubber in which a metal part is set in a mold, a rubber material is injected into a cavity formed between the metal part and the mold, and a rubber elastic body is integrally formed on the surface of the metal part A method of manufacturing a composite product,
Using a molding die provided with a rubber reservoir recess along the edge of the metal part surface facing the cavity,
By setting a metal part in the mold and injecting a rubber material into the cavity, the rubber material is filled into the cavity to integrally form the metal part and a rubber elastic body, and the rubber reservoir Filling the recess with the rubber material to form a sealing rubber,
The molded part of the metal part and the rubber elastic body molded as described above is removed from the molding die, and the sealing rubber molded in the rubber reservoir recess is left in the rubber reservoir recess,
A metal part is set in the mold with the sealing rubber remaining, and a rubber material is injected into the cavity to integrally form the metal part and the rubber elastic body. -Manufacturing method of rubber composite products.
前記シール用ゴムが前記金属部品表面における前記キャビティに面する部分の縁部に沿って当該金属部品の表面に当接し、これにより前記キャビティからの前記ゴム材料の流出が防止されることを特徴とする請求項1記載の金属−ゴム複合品の製造方法。The sealing rubber abuts against the surface of the metal part along the edge of the metal part surface facing the cavity, thereby preventing the rubber material from flowing out of the cavity. The method for producing a metal-rubber composite product according to claim 1. 前記ゴム溜まり凹部が微小隙間を介して前記キャビティに連通している請求項1記載の金属−ゴム複合品の製造方法。The method for producing a metal-rubber composite product according to claim 1, wherein the rubber reservoir recess communicates with the cavity through a minute gap. 前記ゴム溜まり凹部は開口側が狭まった断面形状に形成されている請求項1記載の金属−ゴム複合品の製造方法。2. The method for producing a metal-rubber composite product according to claim 1, wherein the rubber reservoir recess is formed in a cross-sectional shape with a narrow opening side. 前記成形型には、前記キャビティに対して開口する大気開放ベントが設けられたことを特徴とする請求項1記載の金属−ゴム複合品の製造方法。2. The method for producing a metal-rubber composite product according to claim 1, wherein the molding die is provided with an open air vent that opens to the cavity. 前記金属−ゴム複合品が、金属部品である内筒及びこれを軸平行に取り囲む外筒と、前記内筒と前記外筒の間に介設されたゴム弾性体とからなる防振装置であることを特徴とする請求項1記載の金属−ゴム複合品の製造方法。The metal-rubber composite product is a vibration isolator comprising an inner cylinder that is a metal part, an outer cylinder that surrounds the inner cylinder, and a rubber elastic body interposed between the inner cylinder and the outer cylinder. The method for producing a metal-rubber composite product according to claim 1. 前記内筒の端部外周面に面する成形型部分に前記ゴム溜まり凹部が設けられ、前記内筒端部の外周面とこれに面する前記成形型部分との間に前記キャビティと前記ゴム溜まり凹部とを連通させる微小隙間が形成されたことを特徴とする請求項6記載の金属−ゴム複合品の製造方法。The rubber reservoir recess is provided in a mold part facing the outer peripheral surface of the end portion of the inner cylinder, and the cavity and the rubber reservoir are provided between the outer peripheral surface of the inner cylinder end part and the mold part facing the outer peripheral surface. 7. The method for producing a metal-rubber composite product according to claim 6, wherein a minute gap is formed to communicate with the recess. 前記外筒の軸方向端面に面する成形型部分に前記ゴム溜まり凹部が設けられ、該ゴム溜まり凹部の開口面の一部が前記外筒端面により覆われて前記キャビティと前記ゴム溜まり凹部とを連通させる微小隙間が形成されたことを特徴とする請求項6記載の金属−ゴム複合品の製造方法。The rubber reservoir recess is provided in a mold portion facing the axial end surface of the outer cylinder, and a part of the opening surface of the rubber reservoir recess is covered with the outer cylinder end surface to form the cavity and the rubber reservoir recess. 7. The method for producing a metal-rubber composite product according to claim 6, wherein a minute gap to be communicated is formed. 金属部品の表面にゴム弾性体を一体に成形してなる金属−ゴム複合品を成形するための成形型であって、
前記ゴム弾性体を成形するためのキャビティを備え、
前記キャビティに面する前記金属部品表面の縁部に沿ってゴム溜まり凹部が設けられ、
前記ゴム溜まり凹部は、前記金属部品表面に面する成形型部分に設けられるとともに、微小隙間を介して前記キャビティに連通しており、該微小隙間を通ってゴム材料が充填されることにより前記キャビティからの前記ゴム材料の流出の防止するシール用ゴムを成形するものである金属−ゴム複合品のための成形型。
A molding die for molding a metal-rubber composite product formed by integrally molding a rubber elastic body on the surface of a metal part,
A cavity for molding the rubber elastic body;
A rubber reservoir recess is provided along the edge of the metal part surface facing the cavity,
The rubber reservoir recess is provided in a mold part facing the surface of the metal part and communicates with the cavity through a minute gap, and the cavity is filled with a rubber material through the minute gap. A molding die for a metal-rubber composite product for molding a sealing rubber for preventing the rubber material from flowing out of the rubber.
JP2005512624A 2004-12-13 2004-12-13 Method for producing metal-rubber composite product Expired - Fee Related JP4138805B2 (en)

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