JPWO2003002777A1 - Non-oriented electrical steel sheet and manufacturing method thereof - Google Patents

Abstract

C: 0 to 0.010% by mass percentage, Si and / or Al: 0.03% to 0.5%, or more than 0.5% to 2.5% Mn: 0.5% or less, P: By containing 0.10% or more, 0.26% or less, S: 0.015% or less, and N: 0.010% or less, it has excellent punching dimensional accuracy, and further has excellent high dimensional accuracy in low Si steel. Provided is a non-oriented electrical steel sheet having a magnetic flux density-low iron loss magnetic balance and an excellent high magnetic flux density-high strength balance for medium to high Si steels.

Description

（ただし、各元素含有量の単位はｍａｓｓ％。（２）式においても同様）
とＰ含有量の間の関係が、
Ｐ≦Ｐ_Ａ
を満足するか、あるいは、
以下の式で表される指数Ｐ_Ｆ：

が、
Ｐ_Ｆ≦０．２６
を満足するかのいずれかであり、
残部はＦｅおよび不可避不純物からなることを特徴とする磁気特性、打ち抜き精度に優れる電磁鋼板。
６．上記５において、鋼板がさらに、質量百分率で
Ｓｂおよび／またはＳｎ：合計で０．４０％以下
を含有することを特徴とする、強度、磁気特性および打ち抜き精度に優れた無方向性電磁鋼板。
なお、以上の鋼種において、副次的含有元素として、Ｃａ：０．０１％以下、Ｂ：０．００５％以下、Ｃｒ：０．１％以下、Ｃｕ：０．１％以下、Ｍｏ：０．１％以下の少なくともいずれかを含有しても良い。
７．上記１〜３のいずれかに記載の成分組成になる鋼スラブに対し、熱間圧延を、加熱温度がオーステナイト単相域で、かつコイル巻き取り温度が６５０℃以下の条件で行い、ついで脱スケール処理後、１回または中間焼鈍を含む２回以上の冷間圧延を行ったのち、７００℃以上のフェライト単相域で仕上げ焼鈍を行うことを特徴とする、磁気特性および打ち抜き精度に優れた無方向性電磁鋼板の製造方法。
８．上記１〜３のいずれかに記載の成分組成になる鋼スラブに対し、熱間圧延を、加熱温度がオーステナイト単相域で、かつコイル巻き取り温度が６５０℃以下の条件で行ったのち、熱延板焼鈍を、Ｎｉ含有量が０％（無添加）〜１．０ｍａｓｓ％の場合には、９００℃以上のフェライト単相域またはＡｃ３点以上のオーステナイト単相域で、一方Ｎｉ含有量が１．０ｍａｓｓ％超え、２．３ｍａｓｓ％以下の場合には、Ａｃ３点以上のオーステナイト単相域で行い、ついで脱スケール処理後、１回または中間焼鈍を含む２回以上の冷間圧延を行ったのち、７００℃以上のフェライト単相域で仕上げ焼鈍を行うことを特徴とする、磁気特性および打ち抜き精度に優れた無方向性電磁鋼板の製造方法。
９．上記５または６のスラブに対し、熱延加熱温度を１０００℃〜１２００℃、熱延巻き取り温度を６５０℃以下で熱間圧延を行い、ついで脱スケール後、１回または中間焼鈍を含む２回以上の冷間圧延を行ったのち、仕上げ焼鈍を行うことを特徴とする、強度、磁気特性および打ち抜き精度に優れた無方向性電磁鋼板の製造方法。
なお、上記９の電磁鋼板の製造方法において、熱延後に熱延板焼鈍を施しても良い。
また、上記７、８または９の何れかの電磁鋼板の製造方法において、仕上げ焼鈍の後、絶縁被膜を付与する処理を施しても良い。
発明を実施するための最良の形態
以下、本発明を由来するに至った実験結果について鋭明する。なお、以下に示す成分組成の％表示はいずれも「ｍａｓｓ％」である。
〔実験１〕
まず、無方向性電磁鋼板の鋼成分と打ち抜き寸法精度との関係を明らかにするため、Ｃ：０．００１６〜０．００２８％、Ｍｎ：０．２０〜０．２２％、Ａｌ：０．０００７〜０．００１４％、Ｎ：０．００１２〜０．００２２％およびＳｂ：０．０３％とほぼ一定にした成分を基本組成とし、Ｐ量を０．０２％と一定にしてＳｉ量を０．０３〜１．４９％の範囲で変化させた鋼、およびＳｉ量を０．１０〜０．１１％と一定にしてＰ含有量を０．０２〜０．２９％の範囲で変化させた鋼を、それぞれ実験室的に溶製した。ついで、これらの鋼材を、１１００℃で６０ｍｉｎ加熱後、板厚：２ｍｍまで熱延し、６００℃で２ｈのコイル巻き取り相当の均熱保持を行ったのち、放冷した。ついで、９００℃で６０ｓの熱延板焼鈍後、酸洗してから、板厚：０．５ｍｍまで冷延した後、７００〜９００℃の種々の温度で仕上げ焼鈍を施し、再結晶粒の粒径を種々に変化させた。その後、この仕上げ焼鈍板に、平均膜厚：０．６μｍの半有機絶縁被膜を塗布し焼き付けしたサンプルを作製して、打ち抜き試験に供した。
なお、平均結晶粒径は圧延方向に平行な、板厚方向断面を観察し、Ｊｅｆｆｒｉｅｓ法により求めた円相当径とした。
打ち抜き試験は、直径：２１ｍｍφの円形金型を用いて行い、クリアランスは板厚の８％とした。圧延方向となす角度が０°，４５°，９０°，１３５°の４方向の、打ち抜き円形の直径（内径）を測定し、その４点の平均径を求めると共に、４点中の最大径と最小径の差を測定し、打ち抜き異方性の指標とした。
得られた結果を、圧延方向に切り出した引張試験片（ＪＩＳ ５号）より求めた降伏強度（ＹＰ）との関係で整理して図１，図２に示す。
図１，２から明らかなように、全般的に、ＹＰが低い軟質な材料は、金型径に対して打ち抜き径の差が大きく、ＹＰの上昇に伴い打ち抜き径は金型寸法に近づいて、寸法精度は改善する傾向にある。これは従来から知られていたように、強度上昇により打ち抜き時のだれ変形が抑制された効果であると考えられる。
しかしながら、ここで注目すべきは、Ｐの添加により強度調整を行った試料は、Ｓｉ量の変化により強度が変化した従来型の電磁鋼板と比較して、同程度の強度レベルでも優れた寸法精度を示し、しかも比較的低ＹＰ域でも金型との寸法差が抑制されていることである（図１）。
また、Ｓｉ量を変化させた鋼は、強度の上昇に伴い打ち抜き径は金型寸法に近づくものの、図２に示されるとおり、最大径と最小径の差で表される異方性が大きいままである。これに対し、Ｐ量増加により強度上昇を図った鋼は、打ち抜き形状の異方性も改善されている。
これらの関係を仕上げ焼鈍板の平均結晶粒径との関係で整理したものが、図３、図４である。
図３，４から明らかなように、Ｓｉ量を変化させた鋼は、粒径が大きくなると打ち抜き寸法精度および打ち抜き異方性とも劣化するのに対し、Ｐを０．１３％以上添加した鋼は、結晶粒径が大きいものでも打ち抜き寸法精度および打ち抜き異方性とも良好なレベルにある。
Ｐを一定量以上含有させることによって打ち抜き寸法精度や打ち抜き異方性が効果的に改善される理由について、その詳細は明らかではないが、
（１）Ｐの添加により強度が上昇し、打ち抜き時のだれ変形が緩和される効果に加えて、
（２）鋼に対して脆化元素として知られているＰを適正量添加することにより、打ち抜き時の破断限界が早まる効果、および
（３）Ｐの添加により仕上げ焼鈍板の集合組織中の｛１００｝＜ｕｖｗ＞方位が増加する傾向にあり、これが異方性を緩和する効果などが複合的に作用した結果によるものと考えている。
次に、磁気特性の面から検討した結果について説明する。
発明者らは、鉄損を改善するものの飽和磁束密度を低下させるＳｉやＡｌの含有量を極力制限することにより、本質的に磁束密度を高くした鋼を素材として、製造条件と磁気特性の関係について詳細に検討した。
図５に、各鋼材の板厚：０．５ｍｍのサンプルについて、仕上げ焼鈍板の結晶粒径と商用周波域での鉄損（Ｗ_{１５／５０}：周波数５０Ｈｚ、最大磁束密度１．５Ｔにおける値）との関係について調査した結果を示す。
同図から明らかなように、低Ｓｉにすると電気抵抗が減少するため鉄損には不利となるが、鉄損は結晶粒径により大きく変化するため、粒径を約３０μｍ以上とすれば安定的に低鉄損となることが分かる。また、低Ａｌとして電気抵抗を減少させた場合にも、同様に、粒径を約３０μｍ以上とすることが低鉄損化に有効であることが確認された。
しかしながら、これまでは、本発明のような低Ｓｉ，Ａｌ組成の低級グレードに属する無方向性電磁鋼板の場合、仕上げ焼鈍板の平均結晶粒径は１５〜２５μｍ程度に制限されているのが通例であった。この理由は、図３，４の０．１１％Ｓｉ−０．０７％Ｐ鋼（図中の●印）の例に示すように、粒成長させると強度低下により打ち抜き性の劣化が著しくなるからである。
これに対し、Ｐ添加量を高めた鋼は、平均結晶粒径を約３０μｍ以上としても、良好な打ち抜き寸法精度が維持されている。
次に、図６に、各鋼種の平均結晶粒径と磁束密度との関係、また図７には、鉄損と磁束密度との関係について調べた結果を示す。ここで、Ｂ_５０は磁化力５０００Ａ／ｍにおける磁束密度である。
Ｓｉを添加した試料は、鉄損は改善されるものの磁束密度の低下が大きい。これに対し、Ｐを添加した試料は、結晶粒が成長して鉄損が改善された後も高い磁束密度を維持している。
ところで、Ｐは脆化元素であり、本発明のようにＰ添加量が多い場合、主に冷延工程において耳割れや層状割れなどの欠陥が発生することがある。本発明者らはこの現象を鋭意調査し、熱間圧延に際してスラブ加熱時に温度がフェライト／オーステナイト共存領域となると、フェライト粒とオーステナイト粒間でＰの分配が起こり、フェライト粒中で著しいＰの偏析が生じ、鋼の脆化が促進されることを究明した。このような脆化現象を防止するためには、本発明の鋼板の製造に当たり、熱間圧延のためのスラブ加熱の温度を、オーステナイト単相領域（あるいは可能であればフェライト単相）とすることが重要である。
なお、Ｐはフェライト形成元素であるため、スラブ加熱温度付近でのオーステナイト単相域を縮小する作用を有するが、低Ｓｉ鋼の成分範囲では、スラブ加熱温度が１０００〜１２００℃であればオーステナイト単相とすることができる。
以上のように、低Ｓｉ鋼に約０．１％以上のＰの添加が非常に有効であることが明らかになった。
そこで、０．５％以上のＳｉを含有する鋼板にもＰの積極的な添加を検討した。
〔実験２〕
Ｃ：０．００１３〜０．００２６、Ｍｎ：０．１８〜０．２３％、Ａｌ：０．０００１〜０．００１１％、Ｎ：０．００２０〜０．００２９％とほぼ一定とした成分として、Ｓｉ量を０．６０〜２．４２、およびＰ量を０．０４〜０．２９％まで変化させた種々の鋼を溶製し、１１００度で６０分加熱後、板厚２ｍｍまで熱延し、酸洗後板厚０．５０ｍｍまで冷延した。
その結果、鋼組成によっては圧延後の鋼板内部で板面と平行に層状の割れが発生する、不具合が発生した。
その結果を図８に示す。
層状割れ発生部分をＥＰＭＡによりマッピング分析したところ、割れ発生部分にはＰが偏析または濃化していることが観察された。そこでこのＰの偏析条件を詳細に検討したところ、熱延に際して、鋼片（スラブ）加熱時にフェライトとオーステナイト相の２相領域に均熱保持される条件となっており、フェライト相中にＰが分配されて濃化したことがわかった。
すなわち、中〜高Ｓｉ鋼領域においてはフェライト形成元素であるＳｉ、Ａｌ量が多いためにオーステナイト単相域がより縮小し、その結果、従来の加熱温度ではフェライト／オーステナイト２相域となりやすいという問題が明らかとなった。
また、Ｐが０．２６％を超えると、どのような組成条件であっても層状割れが発生していた。
そこで、種々のＳｉ，Ｍｎ，Ａｌ、Ｐ量を持つ鋼を研究設備にて作製し、約１０００〜１２００℃の温度域で、Ｐの偏析が圧延不良を発生しない程度に抑制できる条件を調査した。なお、上記のスラブ加熱温度は、鋼中に存在する炭化物・窒化物・硫化物などの析出安定化の観点から好適な温度である。
まず、スラブ加熱温度がオーステナイト単相域あるいはフェライト単相域となる条件下では、相分配による偏析は生じないので、Ｐ添加量そのものが所定量より少なければ層状割れは回避できると考えられる。前記実験より、Ｐの添加量は約０．２６％以下とすることが必要である。
そこでまず、中〜高Ｓｉ鋼がオーステナイト単相となる条件を調査した。
その結果、Ｓｉ＋Ａｌを０．５％より多く含有する鋼においては、Ｐ添加量が、
Ｐ≦Ｐ_Ａ’、ただし

（Ｓｉ，Ｍｎ，Ａｌ，Ｐの各含有量はｍａｓｓ％で表す）
の範囲であればオーステナイト単相域にあることが分かった。したがって、上の条件を満たし、かつＰ≦約０．２６％に限定すれば、Ｐによる脆化を抑制することができる。
次に、中〜高Ｓｉ鋼がフェライト単相となる条件を調査し、同様に、Ｐ添加量が、
Ｐ≧Ｐ_Ｆ’、ただし

（Ｓｉ，Ｍｎ，Ａｌ，Ｐの各含有量はｍａｓｓ％で表す）
の範囲であればフェライト単相域にあることが分かった。したがって、この条件を満たし、かつＰ≦約０．２６％に限定しても、Ｐによる脆化を抑制することができる。
次に、オーステナイト単相域あるいはフェライト単相域でのスラブ加熱が困難な場合に、Ｐの偏析を抑制する条件を調査した。フェライト／オーステナイト２相域においてＰ濃度の分配が生じた場合の、フェライト相中のＰ濃度も上記Ｐ_Ｆ’となるが、調査の結果、このＰ_Ｆ’を約０．２６以下とすれば、Ｐによる脆化が回避できることがわかった。
上記の２相領域における脆化回避条件と、フェライト単相域における脆化回避条件を整理すると、Ｐ≦約０．２６％かつＰ_Ｆ’≦約０．２６とまとめることができる。
以上の関係をまとめると、Ｐによる脆化の回避条件は、Ｐ≦約０．２６％で、かつ、Ｐ≦Ｐ_Ａ’またはＰ_Ｆ’≦約０．２６となる。
以上の結果より、Ｐ添加量が約０．２６％以内であり、かつ熱延加熱時にオーステナイト単相あるいはフェライト単相域に加熱される条件であれば、冷延後の層状割れなどのトラブルなく製造可能であること、さらに、フェライト／オーステナイト２相加熱となる条件であってもフェライト相へのＰ分配量が低くなる、Ｓｉ，Ａｌ量が比較的高い成分系では製造可能となることがわかった。
さらに、約０．１％以上のＰを添加しても熱延時のスラブ加熱温度域（１０００〜１２００℃付近）でオーステナイトあるいはフェライト単相組織となるような鋼組成を種々検討した。
その結果、磁気特性の改善および強度確保に好適な元素であるＮｉの添加が、Ｐ添加鋼において熱延温度付近でのオーステナイト領域を拡大する目的にも有効であることがわかった。
〔実験３〕
Ｃ：０．００１３〜０．００２６％、Ｍｎ：０．１８〜０．２３％、Ａｌ：０．０００７〜０．００１３％、Ｎ：０．００１４〜０．００２５％およびＰ：０．１６〜０．１８％とほぼ一定にした成分を基本組成とし、Ｓｉ量を０．９５〜２．４４％、Ｎｉ量を０〜２．２０％までそれぞれ変化させた試料を、実験２と同様に０．５０ｍｍまで圧延し、得られた冷延鋼板の層状割れの発生状況を調査した。その結果を図９に示す。
Ｎｉ無添加では割れていた１．１〜１．５％Ｓｉ鋼が、Ｎｉの添加により割れ発生なく圧延可能となっている。一方、Ｎｉ無添加では圧延できていた１．９５％Ｓｉ鋼や２．４％Ｓｉ鋼ではＮｉの増加により割れを発生する場合も生じており、Ｎｉの効果には適正領域が存在することがわかる。
Ｎｉの影響を加味して前記式を拡張すると、Ｓｉ＋Ａｌを０．５％より多く含有する鋼においては、Ｐ添加量が約０．２６％以下で、かつ、
Ｐ≦Ｐ_Ａ、ただし

の範囲であれば１０００〜１２００℃のスラブ加熱温度がオーステナイト単相域にあり、
Ｐ_Ｆ≦約０．２６、ただし

の範囲であれば、２相領域あるいはフェライト単相域であってもＰの濃化程度が少なく、いずれの場合もＰによる脆化が回避できることがわかった。
なお、上記の２つの式において、Ｓｉ，Ｍｎ，Ａｌ，Ｐ，Ｎｉの各含有量はｍａｓｓ％で表すものとする。また、Ｐ_ＦおよびＰ_Ａの技術的意味は、前記Ｐ_Ｆ’およびＰ_Ａ’と同じである。
〔実験４〕
実験２および３で０．５０ｍｍまで圧延された冷延鋼板について、仕上げ焼鈍を施したのち、平均膜厚０．６μｍの半有機絶縁被膜を塗布し、焼き付けを行った。
これらのサンプルに対して、実験１に記載の方法による打ち抜き試験を行い、打ち抜き径とその異方性を調査して、その結果を図１０および図１１に示した。
これらの図より、Ｓｉ＋Ａｌを０．５％より多く含有する鋼においても、Ｐ≧０．１０％を含有した鋼は、いずれも優れた打ち抜き寸法精度を示した。
ここで、Ｎｉ添加鋼においては、添加量は０．３８〜２．２０％の間で変化させた。
さらにこれらの試料の磁束密度Ｂ_５０と引張強度ＴＳの関係を図１２に示す。ここで、ＴＳは実験１と同様の引張試験により求め、磁束密度も実験１の方法で測定した。
約０．１％以上のＰを含有する鋼は従来の中〜高Ｓｉ組成（すなわちＳｉ＋Ａｌ＞０．５％）の電磁鋼板と比較して優れたＢ_５０−ＴＳバランスを示している。
特にＰの添加量の増大に伴い、ＴＳは増大するが磁束密度には低下が見られず、むしろ向上する傾向にあった。
これは、従来の電磁鋼板に関して通常行われていたＳｉ，Ａｌといった強磁性体以外の合金元素の添加による鋼板の強化が、磁束密度の低下を伴うことと比較して特徴的である。
これらの特性はモータの高トルク化、小型化、高速回転化といった要求のあるＤＣブラシレスモータやリラクタンスモータなど各種回転機（モータ、発電機）のロータ素材として好適なものである。
以上の知見により、優れた磁束密度と打ち抜き寸法精度を両立するための条件として、鋼中のＳｉ，Ａｌ，Ｐ、Ｎｉ量、さらには低Ｓｉ鋼の場合は仕上げ焼鈍板の平均結晶粒径を次の範囲に規定した。
低Ｓｉ鋼の場合、Ｓｉ，Ａｌの１種または２種の合計：約０．０３〜０．５％
ＳｉおよびＡｌは、鋼に添加すると脱酸効果を有するので脱酸剤として単独あるいは併用して使用される。その効果を発揮させるためには、Ｓｉ，Ａｌそれぞれ単独あるいは両者の合計で約０．０３％以上が必要である。また、Ｓｉ，Ａｌは比抵抗を増加させ鉄損を改善する作用もあるが、一方で飽和磁束密度の低下をもたらすので、その上限を０．５％に定めた。
中〜高Ｓｉ鋼の場合、Ｓｉ，Ａｌの１種または２種の合計：０．５％超〜約２．５％
優れた寸法精度とともに、機械的強度や低鉄損性が重視される場合には、Ｓｉ＋Ａｌの合計量が０．５％を超えて含有することができる。
既に述べたように、中〜高Ｓｉ鋼の場合でも、Ｐ添加の効果により、従来の低Ｐの中〜高Ｓｉ鋼と比較して、高い打ち抜き精度および強度−磁束密度バランスの材料が得られる。
しかしながら、Ｓｉ＋Ａｌの合計量が２．５％を超えると本発明の方法によっても通常の冷間圧延が困難になるので、その範囲を０．５％超〜約２．５％に規定した。
Ｐ：約０．１０％以上、約０．２６％以下
Ｐは、本発明において特に重要な元素である。Ｐは、従来から知られていたように、その高い固溶強化能により材料硬度を調整する機能を有している。特に低Ｓｉ，低Ａｌ鋼板は本来、比較的軟質であるが、本発明では低鉄損化のために平均結晶粒径を約３０μｍ以上とする必要があるので、鋼板がさらに軟質化するおそれがある。Ｐは、このような本発明鋼板の打ち抜き性の改善、すなわち鋼板の強度不足によるだれやかえりの増加を抑制するために必須の元素である。このような材料強度増加能に加えて、打ち抜き時の破断限界を早めることによって打ち抜き時の総変形量を抑制する効果や、仕上げ焼鈍板の集合組織中の｛１００｝＜ｕｖｗ＞方位を増加させて異方性を改善する効果、などの複合的な作用によって打ち抜き寸法精度を改善する。
また、鋼板の強度を増加させるにもかかわらず磁束密度を低下させない特性があり、この効果は中〜高Ｓｉ鋼においても発揮される。
これらの効果を発揮させるためには、Ｐは約０．１０％以上含有させる必要がある。一方、Ｐは元来、鋼に対して脆化元素であり、過剰に添加すると耳割れや層状割れを起こし易くなり、製造性が低下する。この点、本発明では、製造方法に工夫を加えたり、Ｎｉを添加することによって、従来困難とされた高Ｐ添加鋼の製造を可能とすることができる。しかしながら、含有量が約０．２６％を超えると、本発明の製造方法を採用してもＰ添加鋼の製造が難しくなるので、Ｐ量は約０．１０〜約０．２６％の範囲に限定した。
Ｎｉ：約２．３％以下（オプションとして添加可）
Ｎｉは、鋼の集合組織を改善して磁束密度を高める効果があるだけでなく、鋼の電気抵抗を増加して鉄損を低下させる効果や、固溶強化により鋼の強度を高めて打ち抜き加工時のだれを抑制する効果などを併せ持つので、積極的に添加することができる。
また、Ｎｉはオーステナイト形成元素であることから、好適なスラブ加熱温度である１０００〜１２００℃付近でのオーステナイト域（状態図中のγループ）を拡大する効果がある。とくに、Ｓｉ＋Ａｌ量が０．５％より多い組成の鋼に対しては、操業安定性を増大するのに有効となる。この効果を活用すると、本発明の様に脆化元素であるＰを積極的に添加する場合に生じ得る圧延不安定性を大幅に改善することができる。すなわち、高Ｐ鋼の安定製造のポイントは熱延時の過剰なＰ偏析の抑制であり、その有力な手段としてスラブ加熱温度がフェライト／オーステナイト２相域となることを回避することである。Ｓｉ含有量とＡｌ含有量の合計が０．５％を超えるとスラブ加熱温度で２相に分離し易くなるが、Ｎｉのγ域拡大効果により、このようなＳｉ、Ａｌ組成でも、スラブ加熱時にオーステナイト単相とすることが可能となる。
しかしながら、Ｎｉ含有量が約２．３％を超えると、フェライト（α）→オーステナイト（γ）変態開始温度が低下し、仕上げ焼鈍中にオーステナイト変態を起こして磁束密度の低下を招くおそれが生じる。また、変態温度以下の低温の仕上げ焼鈍温度では低Ｓｉ鋼において約３０μｍ以上の平均粒径を確保することが難しくなり、鉄損も劣化するようになる。従って、Ｎｉは約２．３％以下で含有させるものとした。なお、Ｎｉを添加する場合は、約０．５０％以上の添加が好ましい。
低Ｓｉ鋼において、仕上げ焼鈍板の平均結晶粒径：約３０μｍ以上、約８０μｍ以下
本発明の低Ｓｉ、低Ａｌ無方向性電磁鋼板において良好な鉄損特性を得るためには、図５にも示したとおり、仕上げ焼鈍板の平均結晶粒径を約３０μｍ以上にする必要がある。しかしながら、約８０μｍを超える粒経としてもそれ以上の鉄損改善効果は望めず、また本発明に属する鋼はいずれも変態鋼で再結晶焼鈍に適したフェライト単相域はおおむね７００〜９００℃の範囲であり、高Ｓｉ組成のフェライト単相鋼と比較すると低温であるため、過度に粒成長させるのは連続短時間焼鈍設備における生産性の点で不利となるので、約８０μｍを上限とした。
なお、中〜高Ｓｉ鋼においては、合金による電気抵抗の向上効果等を有することから、比較的低鉄損が得られ易いため、粒径はとくに限定せず、通常の範囲で良い。一般的には２０〜２００μｍ程度である。
次に、発明者らは、モータの高速回転化および極数増加などに伴い、近年重視されつつある、高周波域での磁気特性を改善する手法について検討した。その結果、板厚低減が有効であり、とくに低Ｓｉ鋼においてその効果が顕著であることがわかった。以下にその結果を導いた実験を示す。
〔実験５〕
図１３に、０．１１％Ｓｉ−０．１８％Ｐ鋼と０．９５％Ｓｉ−０．０２％Ｐ鋼および２．０％Ｓｉ−０．５％Ａｌ鋼の４００Ｈｚにおける鉄損の板厚依存性について調べた結果を示す。
同図に示したとおり、いずれの試料も板厚の減少により渦電流損が低下するため、高周波鉄損は改善される傾向にあること、そして板厚減少による高周波鉄損の改善効果は低Ｓｉ鋼の方が大きいことが分かる。
ところが、これまで無方向性電磁鋼板の板厚は０．５０ｍｍが主流で、それ以上の板厚低減は比抵抗元素であるＳｉやＡｌの含有量が高い高級グレードの一部に適用されるだけで、ＳｉやＡｌの含有量の少ない無方向性電磁鋼板に適用した製品例は見られなかった。
また、図１４に、これらの素材の磁束密度の板厚依存性について調べた結果を示す。
同図に示されているとおり、板厚を低減すると磁束密度がやや低下する傾向があるものの、その低下はごく僅かであり、またいずれの板厚においても低Ｓｉ鋼の方が格段に高い磁束密度を有している。特に電気自動車（ＥＶ）やハイブリッド電気自動車（ＨＥＶ）の駆動用モータなどの用途に対しては、高速回転型のリラクタンスモータが検討されていて、かような用途では、高磁束密度でかつ高周波における低鉄損性が重視されるが、これに対しては、本発明に示すような低Ｓｉ、低Ａｌの本質的に磁束密度が高い鋼板を薄くすることで対処することができる。
図１３に示したとおり、板厚低減の効果は約０．３５ｍｍ以下とすることで著しくなり、約０．３０ｍｍ以下とすることで一層顕著となる。なお、板厚は、薄いほど渦電流損の低減に有効であるため、特に板厚の下限は設けないが、一方でコアの積み工数が増大してコスト高となり、また積層コアのかしめが困難になるなどの弊害もあるので、一般的な生産に供する場合には下限は０．１０ｍｍ程度とするのが望ましい。
以下、本発明鋼におけるＳｉ，Ａｌ，ＰおよびＮｉ以外の成分の限定理由について説明する。
Ｃ：０〜約０．０１０％
Ｃは、時効効果作用により、鋼板製造後、時間の経過に伴って磁気特性（鉄損）を劣化させる元素であり、その程度はＣ含有量が約０．０１０％を超えると著しくなるので、Ｃ含有量は０．０１０％以下に制限した。なお、この時効劣化特性に関しては、Ｃ量が少なければ少ないほど好ましいので、本発明ではＣ量については実質的にゼロ（分析限界値未満）の場合を含むものとする。
Ｍｎ：約０．５％以下
Ｍｎは、ＭｎＳとしてＳを固定し、ＦｅＳに起因する熱間圧延中の脆化を抑制する効果がある。また、Ｍｎ含有量が増加するに伴い、比抵抗が増加し鉄損を改善する。しかしながらその一方で、Ｍｎ含有量の増加は磁束密度の低下を招くので、Ｍｎ含有量の上限を約０．５％に定めた。
Ｓ：約０．０１５％以下
Ｓは、不可避的不純物であり、上述のようにＦｅＳとして析出した場合、熱間脆性の原因となるだけでなく、微細に析出した場合には粒成長性を劣化させるので、鉄損低減の観点からはできる限り低減することが有利である。ここに、Ｓ量が約０．０１５％を超えると鉄損の劣化代が著しく大きくなるため、その上限を約０．０１５％に定めた。しかしその一方で、Ｓは打ち抜き時の剪断面形状を改善する効果も有しているため、どの程度まで低減するかは用途に応じて決定される。
Ｎ：約０．０１０％以下
Ｎは、不可避的混入不純物であり、ＡｌＮとして微細に析出した場合、粒成長を阻害し鉄損を劣化させるので、約０．０１０％以下に規制した。
以上、必須成分および抑制成分について説明したが、本発明では、その他にも磁気特性改善成分として、以下に述べる元素を適宜含有させることができる。
Ｓｂおよび／またはＳｎ：合計で約０．４０％以下
Ｓｂ，Ｓｎは、粒界に偏在し、鋼の再結晶に際して結晶粒界からの｛１１１｝方位の再結晶核の生成を抑制することにより、磁束密度および鉄損を改善する効果がある。この効果を得るためには、単独使用または併用いずれの場合にも合計で約０．０１％以上含有することが望ましい。とはいえ、過剰に含有させてもその効果は飽和に達し、むしろ含有量が０．４０％を超えると脆化して冷間圧延の際に割れを生じるようになるので、単独使用または併用いずれの場合でも合計で約０．４０％以下で含有させることが望ましい。
その他の副次的含有元素について説明する。
本発明では、脱酸剤として、また不純物として存在するＳをＭｎと共に効果的に捕捉する元素として約０．０１％以下の範囲でＣａを含有させることもできる。また、歪み取り焼鈍時の酸化、窒化を緩和するために約０．００５％以下のＢ、約０．１％以下のＣｒを添加することもできる。
また、この他にも、磁気特性を損なわない元素として公知のＣｕ、Ｍｏなどの元素を添加しても本発明の効果は損なわれないが、添加コストの面からは、各々の元素の含有量は約０．１％以下とすることが好ましい。
その他の成分について、例えばＴｉ、Ｎｂ、Ｖなどの炭窒化物形成元素は少量の存在が許容されるが、極力少ない方が鉄損を低く維持するため好ましい。
なお、中〜高Ｓｉにおいては、既に述べたように、スラブ加熱温度でオーステナイト相かフェライト相のいずれか単相にあるよう成分設計するか、あるいはオーステナイト／フェライトの２相状態にある場合には、よりＰが濃化しやすいフェライト相へのＰの分配濃化量が抑制されるよう成分設計を行い、Ｐの過剰な局所偏析を抑制し、安定的に高Ｐ添加鋼を製造できるようにする。
具体的には、鋼中に存在する炭化物、窒化物、硫化物などの析出安定化のため好適であるスラブ加熱温度（約１０００〜１２００℃）における、Ｐの過剰な局所偏析を抑制するために、
以下の式で表される指数Ｐ_Ａ：

とＰ含有量の間の関係が、
Ｐ≦Ｐ_Ａ
を満足するか、あるいは、
以下の式で表される指数Ｐ_Ｆ：

が、
Ｐ_Ｆ≦約０．２６
（Ｓｉ、Ｍｎ、Ａｌ、Ｎｉ、Ｐの単位はｍａｓｓ％）
であればよい。ここでＰ_Ａは種々のＳｉ，Ｍｎ，Ａｌ，Ｎｉ組成において約１０００〜１２００℃の温度域でオーステナイト単相である上限のＰ含有量を実験的に求めたものであり、Ｐ_Ｆはフェライト単相となる下限のＰ含有量を実験的に求めたものである。
次に、本発明の製造条件について鋭明する。
上記の好適成分組成に調整した溶鋼を、転炉精錬法あるいは電気炉溶解法などで溶製したのち、連続鋳造法や造塊一分塊圧延法によってスラブとする。
ついで、このスラブは、加熱後、熱間圧延に供される。ここで、鋼中に存在する炭化物、窒化物、硫化物などの析出安定化のためには、スラブ加熱温度は約１０００〜１２００℃が好適である。また、前述のように、スラブ加熱時の相状態がＰの過剰な局所偏析の抑制に極めて重要である。
Ｐはフェライト形成元素であるため、スラブ加熱温度付近でのオーステナイト単相域を縮小する作用を有するが、低Ｓｉ鋼の場合、本発明の成分範囲では、スラブ加熱温度が約１０００〜１２００℃であればオーステナイト単相とすることができる。また中〜高Ｓｉ鋼の場合も、前記Ｐ≦Ｐ_Ａを満足する成分系であれば、スラブ加熱温度が約１０００〜１２００℃の範囲においてオーステナイト単相とすることができる。さらに、中〜高Ｓｉ鋼の場合、Ｐ_Ｆ≦約０．２６を満足する成分系の場合は、フェライト／オーステナイト共存域となっても、フェライト相へのＰの偏析の程度は、脆化を回避できるレベルにとどまる。また、フェライト単相域で加熱される場合にも、Ｐ含有量が約０．２６％以内であれば層状割れ等なく製造することができる。
熱延後のコイル巻き取り温度も、本発明では、高Ｐ鋼の製造性を確保する上で重要なポイントである。すなわち、コイル巻き取り温度が高いと、コイル冷却中に鉄燐化物（Ｆｅ３Ｐ）が生成し、熱延板の曲げ性や圧延性を低下させるので、巻き取り温度は約６５０℃以下、好ましくは約６００℃以下、さらに好ましくは約５５０℃以下とできるだけ低温で巻き取りを行うことが望ましい。また、巻き取り後のコイルを水槽に浸漬、あるいはコイルに放水するなどの手段により、コイルを加速冷却する方法も有効である。
ついで、熱延コイルは、酸洗などの手法により脱スケール後、冷間圧延に供されるが、磁気特性をさらに向上させるために熱延板焼鈍を施すこともできる。
ここで、Ｓｉ含有量とＡｌ含有量の合計が０．５％以下である、低Ｓｉ鋼においては、熱延板焼鈍温度もフェライト／オーステナイト共存域（２相領域）を避けることが好ましい。これは、２相領域の焼鈍では結晶粒成長が進行しにくく、磁束密度等の磁気特性の向上が望めないためである。
以下、低Ｓｉ鋼における好適な熱延板焼鈍温度を、Ｎｉ量別に説明する。
Ｎｉ無添加鋼またはＮｉ量が１．０％以下と比較的少ないＮｉ含有量の場合には、無方向性電磁鋼板に対して通常、熱延板焼鈍を施す場合と同様、約９００℃以上のフェライト単相域で焼鈍することができる。また、焼鈍温度をより高温とし、Ａｃ３点以上のオーステナイト単相域（望ましくは１０５０〜１１００℃程度）とすることもできる。要は、両者の中間領域である２相領域での焼鈍（とくに９５０℃付近）を避けることが重要である。
一方、Ｎｉ量が１．０超〜２．３％と比較的多いＮｉ含有量の場合には、焼鈍中のオーステナイト生成温度が低下するため９００℃程度の焼鈍温度でも２相領域となり、磁束密度が低下する。とはいえ、９００℃以下のフェライト単相域での焼鈍では粒成長性不足のため、十分な磁束密度が得られない。従って、この成分系での熱延板焼鈍条件は、Ａｃ３点以上のオーステナイト単相域（望ましくは１０５０〜１１００℃程度）に限定した。
なお、中〜高Ｓｉ鋼の場合は前述のように細粒でも低鉄損が得られ易いので、焼鈍における粒成長は低Ｓｉ鋼ほど重要ではない。したがって、熱延板焼鈍温度はとくに限定しないが、通常は７００〜１１００℃の範囲内とすることが好ましい。
ついで、得られたコイルは、脱スケール後、冷間あるいは温間で１回の圧延、あるいは中間焼鈍を挟む２回以上の冷間（あるいは温間）圧延を行い、所定の板厚に仕上げる。
その後、仕上げ焼鈍を行うが、低Ｓｉ鋼の場合は、この仕上げ焼鈍を７００℃以上のフェライト単相域で行う。というのは、仕上げ焼鈍温度が７００℃未満では、安定して平均結晶粒径を約３０μｍ以上に成長させることが難しく、一方フェライト単相域を超えてオーステナイト粒が生成すると集合組織が劣化し、磁束密度および鉄損の劣化を招くからである。
なお、中〜高Ｓｉ鋼の場合は前述のように焼鈍における粒成長は低Ｓｉ鋼ほど重要ではないので、仕上げ焼鈍温度もとくに限定しないが、通常は７００〜１１００℃の範囲内とすることが好ましい。
なお、熱延板および冷延板のフェライト単相温度域、あるいはオーステナイト単相温度域は、予め同組成の鋼板を種々の温度域で加熱−水冷して得られた組織を光学顕微鏡などで観察して決定することができる。あるいは、他の方法として、Ｔｈｅｒｍｏ−Ｃａｌｃ^ＴＭ等の熱力学計算ソフトウェアにより求めた計算状態図により、予め推定することもできる。
仕上げ焼鈍の後は、一般的な無方向性電磁鋼板と同様に、絶縁被膜の付与を行うことができる。付与方法はとくに限定しないが、処理液の塗布後、焼付け処理を施す方法が好適である。
なお、得られたコイルは、必要な幅、寸法にスリット加工されたのち、ユーザーにてモータ固定子や、回転子の形状に打ち抜き加工後、積層され、製品化される。あるいは、場合によっては、打ち抜き後、歪み取り焼鈍（通常７５０℃×１〜２ｈ）を施した後に製品化される。
（実施例）
〔実施例１〕
表１に示す成分組成になる溶鋼を、実験室的に溶製し鋳込んだ後、熱延により板厚：３０ｍｍのシートバーとした。ついで、１１００℃で６０ｍｉｎの加熱後、板厚：２ｍｍまで熱延し、６００℃で２ｈのコイル巻き取り相当の均熱保持を行ったのち、放冷した。その後、９５０℃で６０ｓの熱延板焼鈍後、酸洗したのち、０．５０ｍｍ厚までの冷延（１回冷延）を行い、７００〜９００℃の種々の温度で仕上げ焼鈍を施して、再結晶粒径を種々に変化させた。なお、冷間圧延の際、Ｐ含有量が本発明の範囲を超える鋼Ｊは冷延中に板面と平行に層状の割れが多数発生したため、以降の処理を中止し、評価を行っていない。
なお、Ｎｏ．５６〜５９は熱延後、熱延板焼鈍を施さずに、８００℃での中間焼鈍を挟む２回冷延法で冷延したものである。
ついで、得られた仕上げ焼鈍板に平均膜厚：０．６μｍの半有機絶縁被膜を塗布したサンプルを作製し、各種試験に供した。
打ち抜き試験は、直径：２１ｍｍφの円形金型を用いて行い、クリアランスは板厚の８％とした。圧延方向となす角度が０°，４５°，９０°，１３５°の４方向の打ち抜き円形の直径（内径）を測定して、その４点の平均径を求めた。また、４点中最大径および最小径の差を取り、打ち抜き異方性の指標とした。
磁気特性は、圧延方向となす角度が０°および９０°となるように１８０ｍｍ×３０ｍｍに切り出した短冊状試験片を用いて、エプスタイン法で測定した。
降伏応力（ＹＰ）は、圧延方向と平行に切り出したＪＩＳ ５号試験片を用いて速度１０ｍｍ／ｍｉｎの条件で引張試験を行い、上降伏点を採用した。
得られた結果を表２および表３に示す。

Ｐ含有量が本発明の適正範囲に満たず、またＳｉ量および結晶粒径の変化により強度が変化している鋼Ａ〜Ｆ（Ｎｏ．１〜３３，５６，５７）では、ＹＰの増加につれて打ち抜き径は金型径に近づく傾向にあるが、最大径と最小径の差で表される打ち抜き寸法の異方性は１０〜２０μｍ程度と比較的大きい。また、Ｓｉ量が増加すると磁束密度が低下するという問題もある。
これに対して、本発明に従い、低Ｓｉ，Ａｌ組成としてＰを０．１０％以上含有させた鋼Ｇ〜Ｈは、ＹＰが３５０ＭＰａ以下と比較的低くても良好な打ち抜き径となり、しかも打ち抜き寸法の異方性も小さい。また、磁気特性の面からも、これらの鋼種で平均結晶粒径を３０μｍ以上に制御したもの（Ｎｏ．３７，３８，３９，４４，４５，４６，４７，５１，５２，５３，５４，５９）はいずれも、安定して低鉄損でかつ高磁束密度が得られている。
〔実施例２〕
表４に示す成分組成になる溶鋼を、実験室的に溶製し、実施例１と同様にして板厚：２ｍｍの熱延板としたのち、１１００℃で３０ｓの熱延板焼鈍後、酸洗してから、０．５０ｍｍ厚まで冷延した。ついで、７００℃以上でかつフェライト単相域の種々の温度で仕上げ焼鈍を施し、再結晶粒径を種々に変化させた。
ついで、実施例１と同様の半有機絶縁被膜を塗布したサンプルを作製して、各種試験に供した。
得られた結果を表５に示す。
ここで、鋼Ｋ〜Ｍは、Ｓｉを低減しＡｌによる脱酸を行ったものであり、鋼Ｎ，Ｏの組および鋼Ｑ、Ｒの組はＮｉ添加の影響を評価できるように溶製したものである。

本発明の鋼組成を満足し、かつ平均結晶粒径を３０μｍ以上と適正化したものはいずれも、優れた打ち抜き寸法精度を有し、また打ち抜き異方性が小さいだけでなく、磁気特性にも優れていた。特に、鋼Ｎと鋼Ｏ、および鋼Ｑと鋼Ｒをそれぞれ比較すると、Ｎｉを添加した鋼Ｏおよび鋼Ｒでは磁束密度の顕著な向上が認められる。
〔実施例３〕
表１の鋼Ｆ、表４の鋼Ｎおよび鋼Ｏに示した組成になる溶鋼を、実験室的に溶製し、実施例１と同様にして板厚：２ｍｍの熱延板としたのち、１１００℃で３０ｓの熱延板焼鈍後、酸洗したのち、冷延圧延により０．５０〜０．２ｍｍの種々の厚みに仕上げた。ついで、７００℃以上でかつフェライト単相域の種々の温度で仕上げ焼鈍を施し、再結晶粒径を３５〜４５μｍの間に制御した。
ついで、実施例１と同様の半有機絶縁被膜を塗布したサンプルを作製して、各種試験に供した。また、これらのサンプルについては４００Ｈｚでの高周波鉄損についても調査した。
得られた結果を表６に併記する。

板厚を薄くするにつれて特に高周波での鉄損が改善される傾向が顕著である。また、打ち抜き寸法精度も板厚減に伴って改善する傾向にあるが、本発明の成分範囲を満足する鋼Ｎ，Ｏの方が比較鋼Ｆよりも優れている。さらに、本発明鋼はいずれの板厚でも、打ち抜き寸法の異方性にも優れている。
〔実施例４〕
表７に示す成分組成になる溶鋼を、実験室的に溶製して鋼塊に鋳込んだのち、１１５０℃×１時間の均熱を施し、その後熱延により板厚３０ｍｍのシートバーとした。
得られたシートバーを、表８に示す温度（ＳＲＴ）に加熱して１時間保持したのち、２．０ｍｍまで熱延し、５８０℃×１時間のコイル巻き取り相当処理を施し、放冷した。そののち、一部の鋼を除き、表８に示す条件で熱延板焼鈍を施した。その後、酸洗ののち、０．５０ｍｍまで冷延を行った。
冷間圧延に際し、冷延中の板の状況、および冷延後の断面組織観察の結果より、冷間圧延時の加工性を評価した。
高Ｐ（≧０．１０％）でかつ本発明の成分範囲を満たさない鋼（Ｗ、Ｚ、ａ、ｃ、ｄ、ｋ、およびｌ）、および、成分範囲は本発明を満たすものの、スラブ加熱温度（ＳＲＴ）あるいは熱延巻き取り温度（ＣＴ）が本発明の範囲を外れるもの（Ｎｏ．２５、２６）では、板面に平行に層状の割れが多数観察され、一部の試料（Ｎｏ．５、１９、２５）においては圧延途中に層状に分離し、以降の圧延が困難となった。
これらの結果では、工業的に安定製造を行うことが困難であるため、これらの試料については以降の処理および評価を行わなかった。
ついで、冷延板に７００℃以上の種々の温度で仕上げ焼鈍を施したのち、実施例１と同様の半有機絶縁被膜を施したのち、各種試験に供した。
ここで強度は圧延方向と平行にＪＩＳ５号試験片を切り出し、引張速度１０ｍｍ／ｓで引張り、得られた引張強度（ＴＳ）で評価した。
得られた結果を表８に併記した。

本発明の範囲の成分とし、とくにＰを０．１％以上添加した鋼（Ｎｏ．２〜４、７、１３、１４、１６〜１８、および２１〜２４）は、いずれも優れた抜き打ち寸法精度を示す。
すなわち、Ｐ添加量が０．１％に満たない鋼（Ｎｏ．１，６、１０および１５）では、打ち抜き径はＳｉ＋Ａｌ量の増加に伴い改善する傾向が見られるものの、打ち抜き径の異方性が大きい。一方、本発明鋼は打ち抜き径並びに打ち抜き径の異方性ともに優れているのが明らかである。
さらに、これらの発明鋼はＰ含有量が０．１％に満たない比較鋼と同等以上の磁束密度を有するにも関わらず高強度であり、優れた強度−磁束密度バランスを有する。
〔実施例５〕
表４の鋼Ｍ、鋼Ｎおよび鋼Ｏに示した組成になる溶鋼を、実験室的に溶製・鋳込みの後、熱延により板厚：３０ｍｍのシートバーとした。ついで、表９に示す各温度（ＳＲＴ）に６０分間加熱した後、板厚：２ｍｍまで熱延し、表９に示す各温度（ＣＴ）にてコイル巻き取り相当の均熱保持を１時間行ったのち、放冷した。その後、一部の鋼を除き、表９に示す各温度で６０秒の熱延板焼鈍を施した。
得られた熱延鋼板について、室温（２３℃）で曲げ試験を行った。曲げ試験は、熱延板より１００ｍｍ×３０ｍｍの試験片を圧延方向が長手となるように採取し、ＪＩＳ−Ｃ２５５０に準じて曲げ半径１５ｍｍの繰り返し曲げ試験を行った。熱延板表面に亀裂の入るまでの回数を表９に示す。
また、スラブ加熱時、熱延板焼鈍時の組織（相）を次の方法で調査した。シートバー、熱延板とも、それぞれ所定温度（表９に記載）に所定時間（スラブ加熱：１時間、焼鈍：６０秒）保持した後、水焼き入れして加熱時の組織を凍結し、光学顕微鏡による組織観察により、相を同定した。結果を表９に併記する。
上記熱延板は酸洗したのち、０．５０ｍｍ厚までの冷延（１回冷延）を行い、脆化による冷延不良（層状割れ）が発生していないかを評価した。層状割れの発生していない冷延板については、表９に示す種々の温度で仕上げ焼鈍を施し、ついで、実施例１と同様の半有機絶縁被膜を塗布したサンプルを作製して、各種試験に供した。得られた結果を表９に示す。

本発明の鋼組成（低Ｓｉ鋼）において、本発明の製造条件を満足した場合（Ｎｏ．２、３、６、８、１０および１１）、高Ｐ添加にもかかわらず、問題なく鋼板が製造され、特性も良好であった。
他方、本発明のスラブ加熱温度が２相領域となった（Ｎｏ．１および４）場合は、脆化による冷延不良が発生し易く製品化が困難であることがわかる。また、コイル巻き取り温度が６５０℃より高い（Ｎｏ．５）した場合は、熱延板の加工性が低下し、得られた電磁鋼板の鉄損も低下した。さらに、熱延板焼鈍温度が２相域となった場合（Ｎｏ．７および１２）、および、Ｎｉを１．０ｍａｓｓ％より多く添加した鋼においてα単相域で熱延板焼鈍を行った場合（Ｎｏ．１３）は、得られた電磁鋼板の磁束密度が低下した。さらにまた、仕上げ焼鈍温度が本発明の製造条件を外れ、再結晶粒径を３０μｍ以上とするのに不十分な場合（Ｎｏ．９）も、磁気特性が劣化した。
産業上の利用の可能性
かくして、本発明によれば、高磁束密度かつ低鉄損という優れた磁気特性を有し、しかも高い打ち抜き寸法精度を有する無方向性電磁鋼板、およびさらに高強度を有する無方向性電磁鋼板を安定して得ることができる。
そして、本発明の無方向性電磁鋼板は、各種モータの鉄心素材、中でも特に高い寸法精度と高磁束密度が併せて要求されるリラクタンスモータや、さらに素材強度を要する埋め込み磁石型のＤＣブラシレスモータなどの鉄心素材として最適である。
【図面の簡単な説明】
図１は、降伏強度と打ち抜き径との関係に及ぼすＳｉ含有量およびＰ含有量の影響を示すグラフである。
図２は、降伏強度と打ち抜き異方性との関係に及ぼすＳｉ含有量およびＰ含有量の影響を示すグラフである。
図３は、平均結晶粒径と打ち抜き径との関係に及ぼすＳｉ含有量およびＰ含有量の影響を示すグラフである。
図４は、平均結晶粒径と打ち抜き異方性との関係に及ぼすＳｉ含有量およびＰ含有量の影響を示すグラフである。
図５は、平均結晶粒径と鉄損との関係に及ぼすＳｉ含有量およびＰ含有量の影響を示すグラフである。
図６は、平均結晶粒径と磁束密度との関係に及ぼすＳｉ含有量およびＰ含有量の影響を示すグラフである。
図７は、鉄損と磁束密度との関係に及ぼすＳｉ含有量およびＰ含有量の影響を示すグラフである。
図８は、層状割れの発生に及ぼすＳｉ含有量およびＰ含有量の影響を示すグラフである。
図９は、層状割れの発生に及ぼすＳｉ含有量およびＮｉ含有量の影響を示すグラフである。
図１０は、Ｐ含有量と打ち抜き径との関係に及ぼすＳｉ含有量およびＮｉ添加の影響を示すグラフである。
図１１は、Ｐ含有量と打ち抜き異方性との関係に及ぼすＳｉ含有量およびＮｉ添加の影響を示すグラフである。
図１２は、引張強度と磁束密度との関係に及ぼすＰ含有量の影響を示すグラフである。
図１３は、板厚と高周波鉄損との関係を示すグラフである。
図１４は、板厚と磁束密度との関係を示すグラフである。Technical field
The present invention relates to a non-oriented electrical steel sheet used as a core material of electric equipment. Among them, non-oriented electrical steel sheets suitable for iron core materials such as reluctance motors or embedded magnet type DC brushless motors that require higher strength, which require high punching dimensional accuracy and high magnetic flux density, and the production thereof It is about the method.
Background art
A non-oriented electrical steel sheet is a soft magnetic material mainly used as a core material of electric equipment such as a motor and a transformer. In order to improve the efficiency and reduce the size of these electrical devices, it is required that the magnetic steel sheets have low iron loss and high magnetic flux density. In the field of electric motors, the magnetic properties of magnetic steel sheets, which are core materials, are being improved, that is, low iron loss and high magnetic flux density are being promoted. The motors themselves are also more efficient than conventional asynchronous AC induction motors. Replacement with a simple synchronous motor and improvement in characteristics are progressing rapidly.
Synchronous motors are generally classified into surface magnet type (SPM) and embedded magnet type (IPM) DC brushless motors, and reluctance motors that use reluctance torque generated by the magnetic saliency of the rotor and stator. . Above all, in the case of a reluctance motor, the amount of generated torque depends on the shape of the rotor and the stator, the gap between the rotor and the stator, and the magnetic flux density of the material. Therefore, as a core material for a reluctance motor, high magnetic flux density and high dimensional accuracy in punching are more important than other motors.
Further, with the progress of inverters, the number of poles tends to increase with the rotation at high speed in order to improve motor efficiency and torque. Since these are all elements for increasing the operating frequency, not only the conventional magnetic characteristics at the commercial frequency (50 to 60 Hz) but also the high frequency range of 400 Hz or more are applied to the non-oriented electrical steel sheet as the motor material. It is also necessary to improve the magnetic characteristics in the magnetic field.
Until now, various efforts have been made to improve the magnetic flux density and iron loss of the non-oriented electrical steel sheet as described above.
In order to reduce the iron loss of the non-oriented electrical steel sheet, it is common to increase the Si content. For example, about 3.5 mass% of Si is added to the highest grade non-oriented electrical steel sheet. There are cases. However, as the Si content increases, the iron loss decreases, but the magnetic flux density also decreases.
On the other hand, in a low-grade non-oriented electrical steel sheet, since the Si content is suppressed, a relatively high magnetic flux density can be obtained, but there is a problem that iron loss is high.
As a method for improving iron loss of such a low Si steel, Japanese Patent Application Laid-Open No. 62-267421 discloses a non-directional electromagnetic device in which the amount of Si is 0.6 mass% or less and the amount of Al is 0.15 to 0.60 mass%. In steel sheets, the amount of impurities such as C, S, N, and O is regulated to reduce inclusions, which are obstacles to crystal grain growth, to make them harmless, to promote grain growth, and to achieve low iron loss. Technology has been proposed. However, since the grain growth of such a low Si steel is accompanied by a decrease in strength, there is a problem that the punching surface becomes droopy and burred during the punching process, resulting in a marked decrease in punchability.
As a method of improving the punching property by adjusting the hardness of the low Si steel, there is a technique of adding about 0.08 to 0.1 mass% of P. For example, Japanese Patent Application Laid-Open No. Sho 56-130425 discloses a technique. There is disclosed a technique for improving the punching property by adding P of less than 0.2 mass%. As a technique for positively adding P to low Si steel, Japanese Patent Application Laid-Open No. 2-66138 discloses a technique in which the amount of Si is suppressed to 0.1 mass% or less, and the content of Al is 0.1 to 1.0 mass%. A method is disclosed in which 0.1 to 0.25 mass% of P is added to an Al-added steel contained in a range to improve the magnetic characteristics by a combined effect of Al and P.
However, in these techniques, the improvement of the punchability by the addition of P focuses only on the suppression of drooping of the steel sheet by adjusting the hardness thereof, and no consideration is given to the dimensional accuracy after the punching.
On the other hand, in an embedded magnet type DC brushless motor, punching accuracy and high magnetic flux density are required from the viewpoint of high torque and miniaturization. In order to prevent detachment, it is necessary to keep the strength of the magnetic steel sheet high. As described above, high-grade Si steel is advantageous from the viewpoint of strength, but low Si is desirable from the viewpoint of magnetic flux density, and it has been conventionally difficult to achieve both strength and magnetic flux density.
Disclosure of the invention
(Problems to be solved by the invention)
As described above, high magnetic flux density and low iron loss characteristics of non-oriented electrical steel sheets are common properties desired for all uses of non-oriented electrical steel sheets such as various motors and transformers. From the viewpoint of the operation principle, particularly high magnetic flux density and high dimensional accuracy are important for the conductive magnetic steel sheet material.
However, up to now, a non-oriented electrical steel sheet having excellent magnetic properties such as high magnetic flux density and low iron loss and excellent punching properties, particularly excellent dimensional accuracy in punching, has not been found. Further, in addition to these characteristics, no non-oriented electrical steel sheet has been found which further satisfies the demand for strength required for an embedded magnet type DC brushless motor and the like.
Further, in addition to these magnetic properties and punching properties, no non-oriented electrical steel sheet has been found that is considered to be able to cope with the recent high-speed rotation of motors and the high frequency accompanying multipolarization.
The present invention has been developed in view of the above situation, and iron core materials such as motors and transformers, in particular,
・ It has an unprecedented excellent magnetic balance of high magnetic flux density and low iron loss, which is ideal as an iron core material that requires particularly high magnetic flux density and high dimensional accuracy like a reluctance motor. Excellent non-oriented electrical steel sheet, and
・ Electromagnetic steel sheet that combines high magnetic flux density, high strength characteristics important from the viewpoint of high-speed rotation of the rotor and prevention of scattering of embedded magnets, along with punching dimensional accuracy
With its advantageous manufacturing method.
Hereafter, for convenience, low Si steels are those in which the sum of Si and Al is about 0.03 mass% or more and 0.5 mass% or less, and those in which the sum of Si and Al exceeds 0.5 mass% are medium to high. It shall be called Si steel.
(Means for solving the problem)
By the way, the present inventors have conducted intensive studies to achieve the above object, and as a result, after reducing the amount of Si or Al to a low Si steel level to obtain a steel having a substantially high saturation magnetic flux density, By adjusting the particle size to a predetermined range and adding an appropriate amount of P, not only excellent magnetic properties such as high magnetic flux density and low iron loss can be obtained, but also the punching dimensional accuracy is remarkably improved. Was obtained. Further, in addition to controlling the total amount of Si and Al in a range of more than 0.05 mass% to about 2.5 mass%, by adding an appropriate amount of P, the magnetic flux density is maintained in addition to the effect of improving the punching dimensional accuracy. It has also been found that the strength can be greatly improved while maintaining the same, and an unprecedented magnetic-strength balance can be achieved.
The present invention is based on the above findings.
That is, the gist configuration of the present invention is as follows.
1. In percent by mass
C: 0 to 0.010%,
Si and / or Al: 0.03% or more and 0.5% or less in total
Mn: 0.5% or less,
P: 0.10% or more, 0.26% or less,
S: 0.015% or less and
N: 0.010% or less
, The balance being Fe and inevitable impurities, and
Average crystal grain size: 30 μm or more and 80 μm or less
Non-oriented electrical steel sheet with excellent magnetic properties and punching accuracy.
2. In the above item 1, the steel sheet may further have a mass percentage
Sb and / or Sn: 0.40% or less in total
A non-oriented electrical steel sheet excellent in magnetic properties and punching accuracy, characterized by containing:
3. In the above 1 or 2, the steel sheet further comprises a mass percentage
Ni: 2.3% or less
A non-oriented electrical steel sheet excellent in magnetic properties and punching accuracy, characterized by containing:
4. In the above 1, 2 or 3, a non-oriented electrical steel sheet excellent in magnetic properties and punching accuracy, wherein the thickness of the steel sheet is 0.35 mm or less.
5. In percent by mass
C: 0 to 0.010%,
Si and / or Al: more than 0.5 to 2.5% in total;
Mn: 0.5% or less,
P: 0.10% or more, 0.26% or less,
S: 0.015% or less and
N: 0.010% or less, and
As required Ni: 2.3% or less
Containing, and
Index P represented by the following equation_A:

(However, the unit of the content of each element is mass%. The same applies to equation (2).)
And the P content is
P ≦ P_A
Is satisfied or
Index P represented by the following equation_F:

But,
P_F≤0.26
Is either satisfied,
The remainder is made of Fe and unavoidable impurities, and is an electromagnetic steel sheet having excellent magnetic properties and excellent punching accuracy.
6. In the above item 5, the steel sheet further comprises a mass percentage
Sb and / or Sn: 0.40% or less in total
A non-oriented electrical steel sheet having excellent strength, magnetic properties, and punching accuracy.
In the above steel types, as the secondary contained elements, Ca: 0.01% or less, B: 0.005% or less, Cr: 0.1% or less, Cu: 0.1% or less, Mo: 0. It may contain at least one of 1% or less.
7. Hot rolling is performed on the steel slab having the component composition described in any of the above 1 to 3 under the condition that the heating temperature is in the austenite single phase region and the coil winding temperature is 650 ° C or less. After the treatment, cold rolling is performed once or twice or more including intermediate annealing, and then finish annealing is performed in a ferrite single phase region at 700 ° C. or more. Manufacturing method of grain-oriented electrical steel sheet.
8. The steel slab having the component composition described in any one of the above 1 to 3 is subjected to hot rolling under the condition that the heating temperature is in the austenite single-phase region and the coil winding temperature is 650 ° C. or less. When the Ni content is 0% (no addition) to 1.0 mass% in the rolled sheet annealing, the Ni content is 1% in the ferrite single phase region at 900 ° C. or more or the austenite single phase region at Ac 3 points or more. In the case of more than 2.0 mass% and 2.3 mass% or less, it is performed in an austenitic single phase region having an Ac of 3 or more points, and after descaling, cold rolling is performed once or twice or more including intermediate annealing. A method for producing a non-oriented electrical steel sheet having excellent magnetic properties and punching accuracy, wherein finish annealing is performed in a ferrite single phase region at 700 ° C. or higher.
9. The above 5 or 6 slab is subjected to hot rolling at a hot rolling heating temperature of 1000 ° C. to 1200 ° C. and a hot rolling take-up temperature of 650 ° C. or less, and after descaling, once or twice including intermediate annealing. A method for producing a non-oriented electrical steel sheet having excellent strength, magnetic properties and punching accuracy, comprising performing the above-mentioned cold rolling and then performing finish annealing.
In the method for manufacturing an electromagnetic steel sheet of the above item 9, hot-rolled sheet annealing may be performed after hot-rolling.
Further, in the method for manufacturing an electromagnetic steel sheet according to any one of the above items 7, 8 and 9, after the finish annealing, a treatment for providing an insulating film may be performed.
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the experimental results that led to the present invention will be elucidated. The percentages of the component compositions shown below are all “mass%”.
[Experiment 1]
First, in order to clarify the relationship between the steel composition of the non-oriented electrical steel sheet and the punching dimensional accuracy, C: 0.0016 to 0.0028%, Mn: 0.20 to 0.22%, Al: 0.0007 To 0.0014%, N: 0.0012 to 0.0022% and Sb: 0.03% as a basic composition, the P content is kept constant at 0.02%, and the Si content is set to 0.1%. Steel in which the P content was changed in the range of 0.02 to 0.29% while the Si content was kept constant in the range of 0.10 to 0.11%. , Respectively. Next, these steel materials were heated at 1100 ° C. for 60 minutes, hot-rolled to a thickness of 2 mm, and kept at 600 ° C. for 2 hours, equivalent to coil winding, and then allowed to cool. Then, after annealing the hot-rolled sheet at 900 ° C. for 60 s, pickling and then cold-rolling the sheet to a thickness of 0.5 mm, performing finish annealing at various temperatures of 700 to 900 ° C. The diameter was varied. Thereafter, a sample obtained by applying and baking a semi-organic insulating film having an average film thickness of 0.6 μm to this finished annealed plate was prepared and subjected to a punching test.
The average crystal grain size was a circle equivalent diameter obtained by observing a cross section in the plate thickness direction parallel to the rolling direction and determining by a Jeffries method.
The punching test was performed using a circular mold having a diameter of 21 mmφ, and the clearance was set to 8% of the plate thickness. The diameters (inner diameters) of the punched circles in the four directions at angles of 0 °, 45 °, 90 °, and 135 ° with the rolling direction are measured, and the average diameter of the four points is determined. The minimum diameter difference was measured and used as an index of punching anisotropy.
The obtained results are shown in FIGS. 1 and 2 arranged in relation to the yield strength (YP) obtained from a tensile test piece (JIS No. 5) cut out in the rolling direction.
As is clear from FIGS. 1 and 2, in general, a soft material having a low YP has a large difference in the punching diameter with respect to the die diameter, and the punching diameter approaches the die dimension as the YP increases. Dimensional accuracy tends to improve. This is considered to be an effect of suppressing drooping at the time of punching due to an increase in strength, as conventionally known.
However, it should be noted here that the sample whose strength has been adjusted by the addition of P has excellent dimensional accuracy even at the same strength level as compared to conventional magnetic steel sheets whose strength has changed due to the change in the amount of Si. And the dimensional difference from the mold is suppressed even in the relatively low YP region (FIG. 1).
Further, in the steel in which the amount of Si is changed, the punching diameter approaches the die size with the increase in strength, but as shown in FIG. 2, the anisotropy represented by the difference between the maximum diameter and the minimum diameter remains large. It is. On the other hand, in steel whose strength has been increased by increasing the amount of P, the anisotropy of the punched shape is also improved.
FIG. 3 and FIG. 4 summarize these relationships in relation to the average crystal grain size of the finish-annealed sheet.
As is clear from FIGS. 3 and 4, the steel with the changed amount of Si deteriorates in both the punching dimensional accuracy and the punching anisotropy as the grain size increases. Even when the crystal grain size is large, the punching dimensional accuracy and the punching anisotropy are at a satisfactory level.
Although the details of the reason why the punching dimensional accuracy and the punching anisotropy are effectively improved by containing P in a certain amount or more are not clear,
(1) In addition to the effect of increasing the strength due to the addition of P and reducing the sagging during punching,
(2) The effect of adding an appropriate amount of P, which is known as an embrittlement element, to the steel to accelerate the breaking limit at the time of punching, and
(3) The addition of P tends to increase the {100} <uvw> orientation in the texture of the finish-annealed sheet, which is considered to be the result of the combined effect of the effect of relaxing anisotropy and the like. I have.
Next, the results examined from the viewpoint of magnetic characteristics will be described.
The present inventors have limited the content of Si and Al, which improve the iron loss but reduce the saturation magnetic flux density, as much as possible. Was examined in detail.
FIG. 5 shows the crystal grain size of the finish-annealed sheet and the iron loss (W_15/50: Value at a frequency of 50 Hz and a maximum magnetic flux density of 1.5 T).
As is clear from the figure, when the Si content is low, the electric resistance decreases, which is disadvantageous for iron loss. However, since the iron loss greatly changes depending on the crystal grain size, it is stable if the grain size is about 30 μm or more. It can be seen that the iron loss is low. Also, when the electric resistance was reduced with low Al, it was similarly confirmed that setting the particle size to about 30 μm or more is effective for reducing iron loss.
However, until now, in the case of non-oriented electrical steel sheets belonging to a low grade having a low Si and Al composition as in the present invention, the average crystal grain size of the finish-annealed sheet is generally limited to about 15 to 25 μm. Met. The reason for this is that, as shown in the example of 0.11% Si-0.07% P steel (marked by ● in the figures) in FIGS. It is.
On the other hand, in the steel with an increased P content, good punching dimensional accuracy is maintained even when the average crystal grain size is about 30 μm or more.
Next, FIG. 6 shows the relationship between the average crystal grain size of each steel type and the magnetic flux density, and FIG. 7 shows the relationship between the iron loss and the magnetic flux density. Where B₅₀Is the magnetic flux density at a magnetization force of 5000 A / m.
In the sample to which Si was added, the iron loss was improved, but the magnetic flux density was greatly reduced. On the other hand, the sample to which P is added maintains a high magnetic flux density even after the crystal grains grow and the iron loss is improved.
By the way, P is an embrittlement element, and when P is added in a large amount as in the present invention, defects such as edge cracks and layer cracks may occur mainly in the cold rolling process. The present inventors have studied this phenomenon diligently, and when the temperature in the slab heating during hot rolling is in the coexistence region of ferrite / austenite, distribution of P occurs between ferrite grains and austenite grains, and significant segregation of P in the ferrite grains. Was found, and the embrittlement of steel was promoted. In order to prevent such an embrittlement phenomenon, in manufacturing the steel sheet of the present invention, the slab heating temperature for hot rolling is set to an austenite single phase region (or a ferrite single phase if possible). is important.
Since P is a ferrite-forming element, it has an effect of reducing the austenite single phase region near the slab heating temperature. However, in the component range of the low Si steel, if the slab heating temperature is 1000 to 1200 ° C., the austenitic single phase is reduced. Phase.
As described above, it has been found that the addition of about 0.1% or more of P to the low Si steel is very effective.
Therefore, aggressive addition of P was examined for steel sheets containing 0.5% or more of Si.
[Experiment 2]
C: 0.0013 to 0.0026, Mn: 0.18 to 0.23%, Al: 0.0001 to 0.0011%, N: 0.0020 to 0.0029% Various steels with the Si content varied from 0.60 to 2.42 and the P content varied from 0.04 to 0.29% were melted, heated at 1100 ° C. for 60 minutes, and hot rolled to a plate thickness of 2 mm. After pickling, it was cold rolled to a sheet thickness of 0.50 mm.
As a result, depending on the steel composition, a problem occurred in which a layered crack occurred parallel to the plate surface inside the rolled steel plate.
FIG. 8 shows the result.
Mapping analysis of the layered cracking portion by EPMA showed that P was segregated or concentrated in the cracking portion. Therefore, when the segregation condition of P was examined in detail, it was found that, during hot rolling, the solute was maintained in a two-phase region of ferrite and austenite during heating of a steel slab (slab), and P was contained in the ferrite phase. It was found to be distributed and thickened.
That is, in the medium to high Si steel region, the austenite single phase region is further reduced due to the large amounts of Si and Al, which are ferrite forming elements, and as a result, at the conventional heating temperature, a ferrite / austenite two phase region is likely to be formed. Became clear.
When P exceeds 0.26%, laminar cracking has occurred under any composition conditions.
Therefore, steels having various amounts of Si, Mn, Al, and P were produced in a research facility, and conditions were investigated under which the segregation of P could be suppressed to a level at which rolling failure did not occur in a temperature range of about 1000 to 1200 ° C. . The slab heating temperature is a suitable temperature from the viewpoint of stabilizing precipitation of carbides, nitrides, sulfides, and the like existing in steel.
First, under the condition that the slab heating temperature is in the austenite single phase region or the ferrite single phase region, segregation due to phase distribution does not occur. Therefore, it is considered that layered cracking can be avoided if the amount of P added is less than a predetermined amount. From the above experiment, it is necessary that the amount of P added be about 0.26% or less.
Therefore, first, the conditions under which the middle to high Si steel becomes an austenitic single phase were investigated.
As a result, in steel containing more than 0.5% of Si + Al, the amount of P added is
P ≦ P_A’, But

(Each content of Si, Mn, Al, and P is represented by mass%.)
It was found that the range was within the austenite single phase region. Therefore, embrittlement due to P can be suppressed if the above conditions are satisfied and P ≦ about 0.26%.
Next, the conditions under which the medium to high Si steel became a ferrite single phase were investigated.
P ≧ P_F’, But

(Each content of Si, Mn, Al, and P is represented by mass%.)
It was found that the ferrite was in the single-phase region within the range of. Therefore, even if this condition is satisfied and P is limited to about 0.26%, embrittlement due to P can be suppressed.
Next, the conditions for suppressing the segregation of P when the slab heating in the austenite single phase region or the ferrite single phase region is difficult were investigated. When the distribution of the P concentration occurs in the ferrite / austenite two phase region, the P concentration in the ferrite phase is also the above P concentration._F’, But as a result of the investigation, this P_F′ Is about 0.26 or less, embrittlement by P can be avoided.
When the embrittlement avoiding conditions in the two-phase region and the embrittlement avoiding conditions in the ferrite single-phase region are summarized, P ≦ about 0.26% and P_F'≦ about 0.26.
To summarize the above relationship, the conditions for avoiding embrittlement by P are P ≦ about 0.26% and P ≦ P_A’Or P_F≦≦ approximately 0.26.
From the above results, if the amount of P added is within about 0.26% and the condition is such that heating is performed in the austenite single phase or ferrite single phase region during hot rolling, there is no trouble such as laminar cracking after cold rolling. It is found that it can be manufactured, and that even under the condition of two-phase heating of ferrite / austenite, it can be manufactured with a component system in which the amount of P distribution to the ferrite phase is low and the amounts of Si and Al are relatively high. Was.
Furthermore, various steel compositions were studied to provide an austenite or ferrite single phase structure in the slab heating temperature range (around 1000 to 1200 ° C.) during hot rolling even if about 0.1% or more of P is added.
As a result, it was found that the addition of Ni, which is an element suitable for improving magnetic properties and ensuring strength, is also effective for expanding the austenite region near the hot rolling temperature in P-added steel.
[Experiment 3]
C: 0.0013 to 0.0026%, Mn: 0.18 to 0.23%, Al: 0.0007 to 0.0013%, N: 0.0014 to 0.0025%, and P: 0.16 to A sample in which a component substantially constant at 0.18% was used as a basic composition and a Si amount was changed from 0.95 to 2.44% and a Ni amount was changed from 0 to 2.20%, as in Experiment 2, The cold-rolled steel sheet was rolled to .50 mm, and the state of occurrence of layered cracks was examined. The result is shown in FIG.
A 1.1-1.5% Si steel that had been cracked without adding Ni can be rolled without cracking by adding Ni. On the other hand, in the 1.95% Si steel and the 2.4% Si steel that could be rolled without Ni addition, cracks may occur due to an increase in Ni, and there is a possibility that an appropriate region exists in the effect of Ni. Understand.
Extending the above equation taking into account the effect of Ni, in steels containing more than 0.5% of Si + Al, the amount of P added is about 0.26% or less, and
P ≦ P_A, But

Slab heating temperature of 1000 to 1200 ° C. is in the austenite single phase region,
P_F≤about 0.26, except

In this case, the degree of P enrichment is small even in the two-phase region or the ferrite single-phase region, and it was found that embrittlement due to P can be avoided in any case.
In the above two equations, each content of Si, Mn, Al, P, and Ni is represented by mass%. Also, P_FAnd P_AThe technical meaning of_F’And P_A'.
[Experiment 4]
The cold rolled steel sheet rolled to 0.50 mm in Experiments 2 and 3 was subjected to finish annealing, and then a semi-organic insulating film having an average film thickness of 0.6 μm was applied and baked.
A punching test was performed on these samples by the method described in Experiment 1 to check the punching diameter and its anisotropy, and the results are shown in FIGS. 10 and 11.
From these figures, all steels containing P ≧ 0.10% showed excellent punching dimensional accuracy even in steels containing more than 0.5% of Si + Al.
Here, in the Ni-added steel, the addition amount was changed between 0.38 to 2.20%.
Further, the magnetic flux density B of these samples₅₀FIG. 12 shows the relationship between the tensile strength and the tensile strength TS. Here, TS was obtained by the same tensile test as in Experiment 1, and the magnetic flux density was also measured by the method in Experiment 1.
Steel containing about 0.1% or more of P is superior in B steel to conventional magnetic steel sheets having a medium to high Si composition (ie, Si + Al> 0.5%).₅₀-TS balance is shown.
In particular, as the amount of P added increased, TS increased but the magnetic flux density did not decrease, but tended to increase.
This is characteristic in that the strengthening of the steel sheet by the addition of alloying elements other than ferromagnetic materials such as Si and Al, which is usually performed for conventional magnetic steel sheets, is accompanied by a decrease in magnetic flux density.
These characteristics are suitable as a rotor material for various types of rotating machines (motors, generators) such as DC brushless motors and reluctance motors, which are required to have higher torque, smaller size, and higher speed rotation of the motor.
Based on the above findings, as conditions for achieving both excellent magnetic flux density and punching dimensional accuracy, the amounts of Si, Al, P, and Ni in steel, and in the case of low Si steel, the average crystal grain size of the finish annealed sheet, It is specified in the following range.
In the case of low Si steel, the total of one or two of Si and Al: about 0.03 to 0.5%
Since Si and Al have a deoxidizing effect when added to steel, they are used alone or in combination as deoxidizing agents. In order to exert the effect, it is necessary that Si and Al are each used alone or about 0.03% or more in total. Further, Si and Al have the effect of increasing the specific resistance and improving the iron loss, but on the other hand, they lower the saturation magnetic flux density. Therefore, the upper limit is set to 0.5%.
For medium to high Si steels, the sum of one or two of Si and Al: more than 0.5% to about 2.5%
When importance is attached to mechanical strength and low iron loss together with excellent dimensional accuracy, the total amount of Si + Al can be contained in excess of 0.5%.
As described above, even in the case of a medium to high Si steel, a material having higher punching accuracy and strength-magnetic flux density balance can be obtained due to the effect of the addition of P, as compared with the conventional low P medium to high Si steel. .
However, if the total amount of Si + Al exceeds 2.5%, normal cold rolling becomes difficult even by the method of the present invention, so the range is specified to be more than 0.5% to about 2.5%.
P: about 0.10% or more, about 0.26% or less
P is a particularly important element in the present invention. P has a function of adjusting the material hardness by its high solid solution strengthening ability as conventionally known. In particular, low Si and low Al steel sheets are relatively soft by nature, but in the present invention, the average crystal grain size needs to be about 30 μm or more in order to reduce iron loss, so that the steel sheet may be further softened. is there. P is an essential element for improving the punching property of the steel sheet of the present invention, that is, for suppressing an increase in drooling and burrs due to insufficient strength of the steel sheet. In addition to such a material strength increasing ability, the effect of suppressing the total amount of deformation at the time of punching by accelerating the breaking limit at the time of punching, and increasing the {100} <uvw> orientation in the texture of the finished annealed sheet. The punching dimensional accuracy is improved by the combined effect of improving the anisotropy.
In addition, there is a characteristic that the magnetic flux density is not reduced despite increasing the strength of the steel sheet, and this effect is also exerted on medium to high Si steel.
In order to exhibit these effects, P must be contained at about 0.10% or more. On the other hand, P is originally an embrittlement element for steel, and when added excessively, ear cracks and layer cracks are liable to occur, and the productivity is reduced. In this regard, in the present invention, it is possible to manufacture a high-P-added steel, which has been conventionally difficult, by devising the manufacturing method or adding Ni. However, if the content exceeds about 0.26%, the production of P-added steel becomes difficult even when the production method of the present invention is employed. Therefore, the P content is in the range of about 0.10 to about 0.26%. Limited.
Ni: about 2.3% or less (can be added as an option)
Ni not only has the effect of improving the texture of the steel and increasing the magnetic flux density, but also has the effect of increasing the electrical resistance of the steel to reduce iron loss, and the punching by increasing the strength of the steel by solid solution strengthening. Since it also has the effect of suppressing dripping at the time, it can be added positively.
Further, since Ni is an austenite-forming element, it has an effect of expanding the austenite region (γ loop in the phase diagram) around 1000 to 1200 ° C., which is a suitable slab heating temperature. In particular, for steel having a composition in which the amount of Si + Al is more than 0.5%, it is effective to increase the operation stability. By utilizing this effect, rolling instability that can occur when P, which is an embrittlement element, is positively added as in the present invention can be significantly improved. That is, the point of stable production of high-P steel is suppression of excessive P segregation during hot rolling, and as an effective means thereof, avoiding the slab heating temperature from being in the ferrite / austenite two-phase region. If the sum of the Si content and the Al content exceeds 0.5%, it is easy to separate into two phases at the slab heating temperature. A single phase of austenite can be obtained.
However, when the Ni content exceeds about 2.3%, the ferrite (α) → austenite (γ) transformation start temperature decreases, and austenite transformation occurs during finish annealing, which may cause a decrease in magnetic flux density. Further, at a low finish annealing temperature lower than the transformation temperature, it is difficult to secure an average grain size of about 30 μm or more in a low Si steel, and iron loss also deteriorates. Therefore, Ni should be contained at about 2.3% or less. In addition, when adding Ni, about 0.50% or more of addition is preferable.
In low Si steel, average grain size of finish-annealed sheet: about 30 μm or more and about 80 μm or less
In order to obtain good iron loss characteristics in the low-Si, low-Al non-oriented electrical steel sheet of the present invention, as shown in FIG. 5, the average grain size of the finish-annealed sheet needs to be about 30 μm or more. . However, even if the grain size exceeds about 80 μm, no further effect of improving iron loss cannot be expected, and all of the steels belonging to the present invention are transformed steels and the ferrite single phase region suitable for recrystallization annealing is generally 700 to 900 ° C. Since the temperature is lower than that of the ferritic single-phase steel having a high Si composition, excessive grain growth is disadvantageous in terms of productivity in continuous short-time annealing equipment. Therefore, the upper limit is set to about 80 μm.
In addition, in the medium to high Si steels, since the alloy has an effect of improving electric resistance and the like, a relatively low iron loss is easily obtained, and thus the grain size is not particularly limited and may be in a normal range. Generally, it is about 20 to 200 μm.
Next, the inventors studied a technique for improving magnetic characteristics in a high-frequency range, which has been increasingly emphasized in recent years as the motor rotates at a higher speed and the number of poles increases. As a result, it was found that the reduction of the plate thickness was effective, and the effect was particularly remarkable in low Si steel. The experiment which led to the result is shown below.
[Experiment 5]
FIG. 13 shows the thickness of the iron loss at 400 Hz of the 0.11% Si-0.18% P steel, the 0.95% Si-0.02% P steel, and the 2.0% Si-0.5% Al steel. The result of examining the dependency is shown.
As shown in the figure, since the eddy current loss is reduced due to the decrease in the thickness of each sample, the high-frequency iron loss tends to be improved. It can be seen that steel is larger.
However, the thickness of non-oriented electrical steel sheets has hitherto been mainly 0.50 mm, and further reductions in thickness are only applied to some high-grade grades with high contents of Si and Al, which are specific resistance elements. Thus, there was no product example applied to a non-oriented electrical steel sheet having a low content of Si or Al.
FIG. 14 shows the results of examining the dependence of the magnetic flux density of these materials on the plate thickness.
As shown in the figure, when the sheet thickness is reduced, the magnetic flux density tends to decrease slightly, but the decrease is negligible, and at all sheet thicknesses, the low Si steel has a much higher magnetic flux. It has a density. Particularly for applications such as driving motors for electric vehicles (EV) and hybrid electric vehicles (HEV), high-speed rotation type reluctance motors are being studied. In such applications, high magnetic flux density and high frequency Low iron loss property is emphasized, but this can be dealt with by reducing the thickness of a steel sheet having low Si and low Al and having essentially high magnetic flux density as shown in the present invention.
As shown in FIG. 13, the effect of reducing the thickness becomes significant when the thickness is set to about 0.35 mm or less, and becomes more significant when the thickness is set to about 0.30 mm or less. The lower the thickness, the more effective the reduction of the eddy current loss. Therefore, there is no particular lower limit of the thickness. Therefore, the lower limit is desirably about 0.10 mm for general production.
Hereinafter, the reasons for limiting components other than Si, Al, P and Ni in the steel of the present invention will be described.
C: 0 to about 0.010%
C is an element that deteriorates the magnetic properties (iron loss) with the lapse of time after the steel sheet is manufactured due to the aging effect, and the degree becomes significant when the C content exceeds about 0.010%. C content was limited to 0.010% or less. In addition, as for the aging deterioration characteristic, the smaller the C content, the better. Therefore, the present invention includes a case where the C content is substantially zero (less than the analysis limit value).
Mn: about 0.5% or less
Mn has an effect of fixing S as MnS and suppressing embrittlement during hot rolling caused by FeS. Further, as the Mn content increases, the specific resistance increases and the iron loss is improved. However, on the other hand, since an increase in the Mn content causes a decrease in the magnetic flux density, the upper limit of the Mn content is set to about 0.5%.
S: about 0.015% or less
S is an unavoidable impurity, and as described above, when precipitated as FeS, not only causes hot embrittlement, but when precipitated finely, it deteriorates the grain growth property. It is advantageous to reduce as much as possible. Here, if the amount of S exceeds about 0.015%, the amount of deterioration of iron loss becomes remarkably large, so the upper limit is set to about 0.015%. However, on the other hand, S also has the effect of improving the shear profile at the time of punching, so the extent to which it is reduced is determined according to the application.
N: about 0.010% or less
N is an unavoidable impurity, and when finely precipitated as AlN, it inhibits grain growth and deteriorates iron loss. Therefore, N is regulated to about 0.010% or less.
As described above, the essential components and the suppressing components have been described. However, in the present invention, the following elements can be appropriately contained as magnetic property improving components.
Sb and / or Sn: about 0.40% or less in total
Sb and Sn are unevenly distributed at grain boundaries, and have an effect of improving magnetic flux density and iron loss by suppressing generation of recrystallization nuclei of {111} orientation from crystal grain boundaries during recrystallization of steel. In order to obtain this effect, it is desirable that the total content be about 0.01% or more when used alone or in combination. Nevertheless, even if it is contained excessively, the effect reaches saturation, and if the content exceeds 0.40%, it becomes brittle and cracks occur during cold rolling. In this case, it is desirable that the total content be about 0.40% or less.
Other secondary elements will be described.
In the present invention, Ca may be contained in an amount of about 0.01% or less as an element for effectively trapping S present as an impurity together with Mn as a deoxidizing agent. In addition, B of about 0.005% or less and Cr of about 0.1% or less can be added to alleviate oxidation and nitridation during strain relief annealing.
In addition, the addition of known elements such as Cu and Mo as elements that do not impair magnetic properties does not impair the effects of the present invention, but from the viewpoint of the cost of addition, the content of each element is reduced. Is preferably about 0.1% or less.
As for other components, for example, a small amount of a carbonitride-forming element such as Ti, Nb, or V is allowed, but it is preferable to keep the iron loss as low as possible.
As described above, in the case of medium to high Si, if the component is designed to be in a single phase of an austenite phase or a ferrite phase at a slab heating temperature, or if it is in a two-phase state of austenite / ferrite, In order to suppress the excessive local segregation of P, it is possible to stably produce a high P-added steel by designing a component so that the amount of P enriched in the ferrite phase in which P is more easily enriched is suppressed. .
Specifically, in order to suppress excessive local segregation of P at a slab heating temperature (about 1000 to 1200 ° C.) suitable for stabilizing precipitation of carbides, nitrides, sulfides, and the like existing in steel. ,
Index P represented by the following equation_A:

And the P content is
P ≦ P_A
Is satisfied or
Index P represented by the following equation_F:

But,
P_F≤ about 0.26
(The unit of Si, Mn, Al, Ni, and P is mass%.)
Should be fine. Where P_AIs an experimentally determined upper limit P content of an austenitic single phase in a temperature range of about 1000 to 1200 ° C. for various Si, Mn, Al, and Ni compositions._FIs the experimentally determined lower limit of the P content of the ferrite single phase.
Next, the production conditions of the present invention will be elucidated.
After smelting the molten steel adjusted to the above-mentioned suitable component composition by a converter refining method or an electric furnace melting method, it is formed into a slab by a continuous casting method or an ingot lump rolling method.
Next, the slab is subjected to hot rolling after heating. Here, in order to stabilize precipitation of carbides, nitrides, sulfides, and the like existing in steel, the slab heating temperature is preferably about 1000 to 1200 ° C. Further, as described above, the phase state during slab heating is extremely important for suppressing excessive local segregation of P.
Since P is a ferrite-forming element, it has an effect of reducing the austenite single-phase region around the slab heating temperature, but in the case of low Si steel, in the component range of the present invention, the slab heating temperature is about 1000 to 1200 ° C. If present, it can be made into an austenitic single phase. In the case of medium to high Si steel, the above P ≦ P_AWhen the slab heating temperature is in the range of about 1000 to 1200 ° C., the austenitic single phase can be obtained. Furthermore, for medium to high Si steels, P_FIn the case of a component system that satisfies ≦ about 0.26, the degree of segregation of P in the ferrite phase remains at a level at which embrittlement can be avoided even in the ferrite / austenite coexistence region. In addition, even when the ferrite is heated in a single phase region of ferrite, if the P content is within about 0.26%, it can be produced without layer cracks or the like.
In the present invention, the coil winding temperature after hot rolling is also an important point in ensuring the productivity of high-P steel. That is, if the coil winding temperature is high, iron phosphide (Fe3P) is generated during cooling of the coil, and the bendability and rollability of the hot-rolled sheet are reduced, so that the winding temperature is about 650 ° C. or less, preferably about It is desirable to perform winding at as low a temperature as possible, such as 600 ° C. or less, and more preferably about 550 ° C. or less. It is also effective to accelerate the cooling of the coil by means such as immersing the wound coil in a water tank or discharging water onto the coil.
Next, the hot-rolled coil is subjected to cold rolling after descaling by a technique such as pickling, but may be subjected to hot-rolled sheet annealing in order to further improve magnetic properties.
Here, in a low Si steel in which the total of the Si content and the Al content is 0.5% or less, it is preferable that the hot-rolled sheet annealing temperature also avoid the ferrite / austenite coexistence region (two-phase region). This is because the growth of crystal grains does not easily progress in annealing in the two-phase region, and improvement in magnetic properties such as magnetic flux density cannot be expected.
Hereinafter, a preferable hot-rolled sheet annealing temperature in the low Si steel will be described according to the amount of Ni.
When the Ni-free steel or the Ni content is a relatively small Ni content of 1.0% or less, the non-oriented electrical steel sheet is usually heated to about 900 ° C. or higher, similarly to the case of performing hot-rolled sheet annealing. Annealing can be performed in the ferrite single phase region. Further, the annealing temperature may be set to a higher temperature, and the austenite single phase region (desirably, about 1,050 to 1,100 ° C.) having an Ac point of 3 or more may be used. In short, it is important to avoid annealing (especially around 950 ° C.) in a two-phase region that is an intermediate region between the two.
On the other hand, when the Ni content is a relatively large Ni content of more than 1.0 to 2.3%, the austenite generation temperature during annealing is lowered, so that the two-phase region is obtained even at an annealing temperature of about 900 ° C. Decreases. However, sufficient magnetic flux density cannot be obtained in annealing in a ferrite single phase region at 900 ° C. or lower due to insufficient grain growth. Therefore, the conditions for annealing the hot-rolled sheet in this component system were limited to the austenitic single-phase region of Ac 3 points or more (preferably about 1050 to 1100 ° C.).
In the case of a medium to high Si steel, as described above, low iron loss is easily obtained even with fine grains, so that the grain growth in annealing is not as important as that of the low Si steel. Therefore, the hot-rolled sheet annealing temperature is not particularly limited, but is usually preferably in the range of 700 to 1100 ° C.
Next, after descaling, the obtained coil is rolled once in a cold or warm state, or is subjected to two or more cold (or warm) rolling steps with intermediate annealing to finish to a predetermined thickness.
Thereafter, finish annealing is performed. In the case of a low Si steel, the finish annealing is performed in a ferrite single phase region at 700 ° C. or higher. That is, if the final annealing temperature is lower than 700 ° C., it is difficult to stably grow the average crystal grain size to about 30 μm or more, while if austenite grains are generated beyond the ferrite single phase region, the texture deteriorates, This is because the magnetic flux density and iron loss deteriorate.
In the case of a medium to high Si steel, as described above, the grain growth during annealing is not as important as that of the low Si steel, and thus the finish annealing temperature is not particularly limited, but it is usually within the range of 700 to 1100 ° C. preferable.
The ferrite single-phase temperature range or austenite single-phase temperature range of the hot-rolled sheet and cold-rolled sheet was previously observed by heating and cooling water-cooled steel sheets of the same composition in various temperature ranges with an optical microscope. Can be determined. Alternatively, as another method, Thermo-Calc^TMIt can also be estimated in advance by a calculation state diagram obtained by thermodynamic calculation software such as.
After the finish annealing, an insulating coating can be applied in the same manner as a general non-oriented electrical steel sheet. The application method is not particularly limited, but a method of performing a baking treatment after applying the treatment liquid is preferable.
The obtained coil is slit into a required width and dimensions, and then punched into the shape of a motor stator or a rotor by a user, and then laminated and commercialized. Alternatively, in some cases, after punching, the product is produced after performing strain relief annealing (normally 750 ° C. × 1 to 2 hours).
(Example)
[Example 1]
A molten steel having the composition shown in Table 1 was smelted and cast in a laboratory, and then hot-rolled to form a sheet bar having a thickness of 30 mm. Then, after heating at 1100 ° C. for 60 minutes, the sheet was hot-rolled to a thickness of 2 mm, and kept at 600 ° C. for 2 hours, equivalent to coil winding, and then allowed to cool. Thereafter, after hot-rolled sheet annealing at 950 ° C. for 60 s, after pickling, cold rolling to a thickness of 0.50 mm (one time cold rolling) is performed, and finish annealing is performed at various temperatures of 700 to 900 ° C. The recrystallized grain size was varied. During cold rolling, steel J having a P content exceeding the range of the present invention caused many layered cracks parallel to the sheet surface during cold rolling, and the subsequent processing was stopped and evaluation was not performed. .
In addition, No. Nos. 56 to 59 are obtained by cold rolling by hot rolling twice without intermediary annealing at 800 ° C. without performing hot rolling sheet annealing.
Then, a sample in which a semi-organic insulating film having an average film thickness of 0.6 μm was applied to the obtained finish-annealed plate was prepared and subjected to various tests.
The punching test was performed using a circular mold having a diameter of 21 mmφ, and the clearance was set to 8% of the plate thickness. The diameters (inner diameters) of the punched circles in four directions having angles of 0 °, 45 °, 90 °, and 135 ° with the rolling direction were measured, and the average diameter of the four points was determined. The difference between the maximum diameter and the minimum diameter among the four points was taken as an index of punching anisotropy.
The magnetic properties were measured by the Epstein method using strip-shaped test pieces cut out to 180 mm × 30 mm so that the angles formed with the rolling direction were 0 ° and 90 °.
For the yield stress (YP), a tensile test was performed at a speed of 10 mm / min using a JIS No. 5 test piece cut out in parallel with the rolling direction, and the upper yield point was adopted.
Tables 2 and 3 show the obtained results.

In steels A to F (Nos. 1 to 33, 56, and 57) in which the P content is less than the appropriate range of the present invention and the strength is changed due to the change in the Si content and the crystal grain size, the YP increases. The punching diameter tends to approach the die diameter, but the anisotropy of the punching dimension represented by the difference between the maximum diameter and the minimum diameter is relatively large at about 10 to 20 μm. Also, there is a problem that the magnetic flux density decreases when the amount of Si increases.
On the other hand, according to the present invention, steels G to H containing 0.10% or more of P as a low Si and Al composition have good punching diameters even when YP is relatively low at 350 MPa or less. Has a small anisotropy. Further, from the viewpoint of magnetic properties, the average grain size of these steels was controlled to 30 μm or more (Nos. 37, 38, 39, 44, 45, 46, 47, 51, 52, 53, 54, 59). In each case), stable low iron loss and high magnetic flux density are obtained.
[Example 2]
Molten steel having the composition shown in Table 4 was smelted in a laboratory and made into a hot-rolled sheet having a thickness of 2 mm in the same manner as in Example 1. After annealing the hot-rolled sheet at 1100 ° C. for 30 s, the acid was added. After washing, it was cold rolled to a thickness of 0.50 mm. Subsequently, finish annealing was performed at 700 ° C. or higher and at various temperatures in the ferrite single phase region to change the recrystallized grain size in various ways.
Subsequently, samples coated with the same semi-organic insulating film as in Example 1 were prepared and subjected to various tests.
Table 5 shows the obtained results.
Here, steels K to M were obtained by reducing the amount of Si and deoxidizing with Al, and the steel N and O pairs and the steel Q and R pairs were melted so that the effects of Ni addition could be evaluated. Things.

Any steel satisfying the steel composition of the present invention and having an average crystal grain size of 30 μm or more has excellent punching dimensional accuracy, and has not only low punching anisotropy but also magnetic properties. It was excellent. In particular, when steel N and steel O and steel Q and steel R are compared with each other, a remarkable improvement in magnetic flux density is observed in steels O and R to which Ni is added.
[Example 3]
Molten steel having the composition shown in Steel F of Table 1 and Steel N and Steel O of Table 4 was smelted in a laboratory and made into a hot-rolled sheet having a thickness of 2 mm in the same manner as in Example 1. After the hot-rolled sheet was annealed at 1100 ° C. for 30 s, it was pickled and then cold-rolled to various thicknesses of 0.50 to 0.2 mm. Then, finish annealing was performed at 700 ° C. or more and at various temperatures in the ferrite single phase region, and the recrystallized grain size was controlled to 35 to 45 μm.
Subsequently, samples coated with the same semi-organic insulating film as in Example 1 were prepared and subjected to various tests. These samples were also examined for high-frequency iron loss at 400 Hz.
The results obtained are also shown in Table 6.

As the plate thickness is reduced, the tendency that iron loss particularly at high frequencies is improved is remarkable. The punching dimensional accuracy also tends to improve with a decrease in sheet thickness, but steels N and O that satisfy the component range of the present invention are superior to comparative steel F. Furthermore, the steel of the present invention is excellent in the anisotropy of the punched size at any thickness.
[Example 4]
Molten steel having the composition shown in Table 7 was smelted in a laboratory and cast into a steel ingot, then subjected to soaking at 1150 ° C. × 1 hour, and then hot-rolled into a sheet bar having a thickness of 30 mm. .
The obtained sheet bar was heated to the temperature (SRT) shown in Table 8 and held for 1 hour, then hot rolled to 2.0 mm, subjected to a coil winding process of 580 ° C. × 1 hour, and allowed to cool. . Thereafter, except for some steels, hot-rolled sheet annealing was performed under the conditions shown in Table 8. Then, after pickling, it was cold rolled to 0.50 mm.
During cold rolling, the workability during cold rolling was evaluated from the state of the sheet during cold rolling and the result of observation of the cross-sectional structure after cold rolling.
Steel (W, Z, a, c, d, k, and l) having a high P (≧ 0.10%) and not satisfying the component range of the present invention, and slab heating while the component range satisfies the present invention When the temperature (SRT) or hot-rolling temperature (CT) is out of the range of the present invention (Nos. 25 and 26), many layered cracks are observed parallel to the plate surface, and some samples (No. In 5, 19, and 25), they were separated into layers during rolling, and subsequent rolling became difficult.
From these results, it was difficult to carry out industrially stable production. Therefore, these samples were not subjected to subsequent processing and evaluation.
Next, the cold-rolled sheet was subjected to finish annealing at various temperatures of 700 ° C. or more, and then subjected to the same semi-organic insulating coating as in Example 1, and then subjected to various tests.
Here, the strength was determined by cutting out a JIS No. 5 test piece in parallel with the rolling direction, pulling it at a pulling speed of 10 mm / s, and evaluating the obtained tensile strength (TS).
Table 8 also shows the obtained results.

Steels (Nos. 2 to 4, 7, 13, 14, 16 to 18 and 21 to 24) to which P is added in an amount of 0.1% or more as components within the scope of the present invention have excellent punching dimensional accuracy. Is shown.
That is, in steels (Nos. 1, 6, 10 and 15) in which the amount of P added is less than 0.1%, although the punched diameter tends to improve with an increase in the Si + Al amount, the anisotropy of the punched diameter is observed. Is big. On the other hand, it is clear that the steel of the present invention is excellent in both the punching diameter and the anisotropy of the punching diameter.
Furthermore, these inventive steels have high strength despite having a magnetic flux density equal to or higher than that of comparative steel having a P content of less than 0.1%, and have an excellent strength-magnetic flux density balance.
[Example 5]
Molten steel having the compositions shown in Steel M, Steel N and Steel O in Table 4 was experimentally produced and cast, and then hot-rolled to form a sheet bar having a thickness of 30 mm. Then, after heating to each temperature (SRT) shown in Table 9 for 60 minutes, hot-rolling to a plate thickness: 2 mm, and maintaining the soaking temperature equivalent to coil winding at each temperature (CT) shown in Table 9 for 1 hour. After that, it was left to cool. After that, except for some steel, hot-rolled sheet annealing was performed at each temperature shown in Table 9 for 60 seconds.
A bending test was performed on the obtained hot-rolled steel sheet at room temperature (23 ° C.). In the bending test, a test piece of 100 mm × 30 mm was sampled from the hot-rolled sheet so that the rolling direction was elongated, and a repeated bending test with a bending radius of 15 mm was performed according to JIS-C2550. Table 9 shows the number of times until the surface of the hot rolled sheet cracks.
The structure (phase) during slab heating and hot-rolled sheet annealing was investigated by the following method. After the sheet bar and the hot-rolled sheet are each maintained at a predetermined temperature (described in Table 9) for a predetermined time (slab heating: 1 hour, annealing: 60 seconds), the structure at the time of heating is frozen by water quenching, and optical The phase was identified by microscopic observation of the structure. The results are also shown in Table 9.
The hot-rolled sheet was pickled and then cold-rolled to a thickness of 0.50 mm (one-time cold-rolling) to evaluate whether or not a cold-rolling defect (lamellar cracking) due to embrittlement occurred. The cold-rolled sheet having no layered cracks was subjected to finish annealing at various temperatures shown in Table 9, and then a sample coated with the same semi-organic insulating coating as in Example 1 was prepared. Provided. Table 9 shows the obtained results.

When the steel composition of the present invention (low Si steel) satisfies the manufacturing conditions of the present invention (Nos. 2, 3, 6, 8, 10, and 11), a steel sheet can be manufactured without any problem despite the addition of high P. And the characteristics were also good.
On the other hand, when the slab heating temperature of the present invention is in the two-phase region (Nos. 1 and 4), it can be seen that cold rolling failure due to embrittlement is likely to occur and commercialization is difficult. When the coil winding temperature was higher than 650 ° C. (No. 5), the workability of the hot rolled sheet was reduced, and the iron loss of the obtained electromagnetic steel sheet was also reduced. Furthermore, when the hot-rolled sheet annealing temperature is in the two-phase region (Nos. 7 and 12), and when the hot-rolled sheet annealing is performed in the α single-phase region in steel containing more than 1.0 mass% of Ni. In (No. 13), the magnetic flux density of the obtained electromagnetic steel sheet was reduced. Furthermore, when the finish annealing temperature was outside the production conditions of the present invention and was insufficient to make the recrystallized grain size 30 μm or more (No. 9), the magnetic properties were also deteriorated.
Industrial potential
Thus, according to the present invention, a non-oriented electrical steel sheet having excellent magnetic properties such as a high magnetic flux density and a low iron loss, and having a high punching dimensional accuracy, and a non-oriented electrical steel sheet having a further high strength can be stably obtained. Can be obtained.
The non-oriented electrical steel sheet of the present invention is used for iron core materials of various motors, among others, a reluctance motor requiring particularly high dimensional accuracy and a high magnetic flux density, and an embedded magnet type DC brushless motor requiring further material strength. Ideal for iron core material.
[Brief description of the drawings]
FIG. 1 is a graph showing the influence of the Si content and the P content on the relationship between the yield strength and the punch diameter.
FIG. 2 is a graph showing the influence of Si content and P content on the relationship between yield strength and punching anisotropy.
FIG. 3 is a graph showing the influence of the Si content and the P content on the relationship between the average crystal grain size and the punched diameter.
FIG. 4 is a graph showing the influence of the Si content and the P content on the relationship between the average crystal grain size and the punching anisotropy.
FIG. 5 is a graph showing the influence of the Si content and the P content on the relationship between the average crystal grain size and iron loss.
FIG. 6 is a graph showing the influence of the Si content and the P content on the relationship between the average crystal grain size and the magnetic flux density.
FIG. 7 is a graph showing the influence of the Si content and the P content on the relationship between iron loss and magnetic flux density.
FIG. 8 is a graph showing the influence of the Si content and the P content on the occurrence of layered cracks.
FIG. 9 is a graph showing the influence of the Si content and the Ni content on the occurrence of layered cracks.
FIG. 10 is a graph showing the influence of the Si content and Ni addition on the relationship between the P content and the punch diameter.
FIG. 11 is a graph showing the influence of Si content and Ni addition on the relationship between P content and punching anisotropy.
FIG. 12 is a graph showing the effect of the P content on the relationship between the tensile strength and the magnetic flux density.
FIG. 13 is a graph showing the relationship between the plate thickness and the high-frequency iron loss.
FIG. 14 is a graph showing the relationship between the plate thickness and the magnetic flux density.

Claims (11)

C: 0 to 0.010% by mass percentage;
At least one of Si and Al: 0.03% or more and 0.5% or less in total; Mn: 0.5% or less;
P: 0.10% or more, 0.26% or less,
S: 0.015% or less and N: 0.010% or less, the balance being a composition of Fe and unavoidable impurities, and an average crystal grain size of 30 μm or more and 80 μm or less. Grain-oriented electrical steel sheet. 2. The non-oriented electrical steel sheet according to claim 1, wherein the steel sheet further contains at least one of Sb and Sn by mass percentage: 0.40% or less in total. The non-oriented electrical steel sheet according to claim 1 or 2, wherein the steel sheet further contains Ni: 2.3% or less by mass percentage. The steel sheet according to any one of claims 1 to 3, wherein the steel sheet further comprises, by mass percentage, Ca: 0.01% or less, B: 0.005% or less,
A non-oriented electrical steel sheet comprising at least one of Cr: 0.1% or less, Cu: 0.1% or less, and Mo: 0.1% or less. The non-oriented electrical steel sheet according to any one of claims 1 to 4, wherein a thickness of the steel sheet is 0.35 mm or less. C: 0 to 0.010% by mass percentage;
At least one of Si and Al: more than 0.5% and 2.5% or less in total
Mn: 0.5% or less,
P: 0.10% or more, 0.26% or less,
S: 0.015% or less,
N: 0.010% or less, and optionally Ni: 2.3% or less, the balance being Fe and unavoidable impurities, and
Satisfies at least one relationship of P ≦ _{P A} and _{P F} ≦ 0.26,
However,

Here, the unit of the content of each element is mass%.
Non-oriented electrical steel sheet characterized by the above-mentioned. The non-oriented electrical steel sheet according to claim 6, wherein the steel sheet further contains at least one of Sb and Sn by mass percentage: 0.40% or less in total. The steel sheet according to claim 6 or 7, wherein the steel sheet further comprises, by mass percentage, Ca: 0.01% or less, B: 0.005% or less,
A non-oriented electrical steel sheet comprising at least one of Cr: 0.1% or less, Cu: 0.1% or less, and Mo: 0.1% or less. For a steel slab having the component composition according to any one of claims 1 to 4,
The hot rolling is performed under the condition that the heating temperature is in the austenite single-phase region and the coil winding temperature is 650 ° C. or less,
Then, after the descaling treatment, after performing cold rolling once or twice including intermediate annealing, finish annealing is performed in a ferrite single phase region at 700 ° C. or more, characterized in that the non-oriented electrical steel sheet is Production method. For a steel slab having the component composition according to any one of claims 1 to 4,
After performing the hot rolling under the condition that the heating temperature is in the austenite single phase region and the coil winding temperature is 650 ° C. or less,
When Ni is not added or the Ni content is 1.0 mass% or less, hot-rolled sheet annealing is performed in either a ferrite single-phase region of 900 ° C. or more or an austenitic single-phase region of Ac3 or more.
When the Ni content exceeds 1.0 mass% and is 2.3 mass% or less, hot-rolled sheet annealing is performed in an austenitic single-phase region of three or more Ac points.
Then, after descaling, cold rolling is performed once or twice or more including intermediate annealing.
A method for producing a non-oriented electrical steel sheet, comprising performing finish annealing in a ferrite single phase region at 700 ° C or higher. For a steel slab having the component composition according to any one of claims 6 to 8,
After performing the hot rolling under the condition that the heating temperature is 1000 to 1200 ° C and the coil winding temperature is 650 ° C or less,
Perform hot rolled sheet annealing as necessary,
Then, after descaling, cold rolling is performed once or twice or more including intermediate annealing.
A method for producing a non-oriented electrical steel sheet, comprising performing finish annealing.

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