JPS6471852A - Production of alkylthiobenzaldehydes - Google Patents

Production of alkylthiobenzaldehydes

Info

Publication number
JPS6471852A
JPS6471852A JP62229296A JP22929687A JPS6471852A JP S6471852 A JPS6471852 A JP S6471852A JP 62229296 A JP62229296 A JP 62229296A JP 22929687 A JP22929687 A JP 22929687A JP S6471852 A JPS6471852 A JP S6471852A
Authority
JP
Japan
Prior art keywords
formula
mercaptides
hydrocarbon solvent
halogenated hydrocarbon
phase transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62229296A
Other languages
Japanese (ja)
Other versions
JP2513490B2 (en
Inventor
Akira Ikeda
Masanao Murata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ihara Chemical Industry Co Ltd
Original Assignee
Ihara Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ihara Chemical Industry Co Ltd filed Critical Ihara Chemical Industry Co Ltd
Priority to JP62229296A priority Critical patent/JP2513490B2/en
Publication of JPS6471852A publication Critical patent/JPS6471852A/en
Application granted granted Critical
Publication of JP2513490B2 publication Critical patent/JP2513490B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE:To obtain the titled compound useful as a synthetic intermediate for pharmaceuticals and agricultural chemicals in high yield and purity, suppressing side-reactions, by reacting benzaldehydes with mercaptides in a halogenated hydrocarbon solvent in the presence of a phase transfer catalyst. CONSTITUTION:The objective compound of formula II can be produced by reacting benzaldehydes of formula I (X is halogen) with mercaptides of formula MS-R (R is alkyl; M is alkali metal or alkaline-earth metal). The reaction is carried out in a halogenated hydrocarbon solvent (e.g. chlorobenzene) in the presence of a phase transfer catalyst (e.g. tetrabutylammonium bromide) at 20-100 deg.C for 1-5hr. The amounts of the catalyst and the mercaptides are 1-50mol.% and 1.0-1.2 times equivalent based on the compound of formula I, respectively.
JP62229296A 1987-09-12 1987-09-12 Method for producing alkylthiobenzaldehydes Expired - Lifetime JP2513490B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62229296A JP2513490B2 (en) 1987-09-12 1987-09-12 Method for producing alkylthiobenzaldehydes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62229296A JP2513490B2 (en) 1987-09-12 1987-09-12 Method for producing alkylthiobenzaldehydes

Publications (2)

Publication Number Publication Date
JPS6471852A true JPS6471852A (en) 1989-03-16
JP2513490B2 JP2513490B2 (en) 1996-07-03

Family

ID=16889911

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62229296A Expired - Lifetime JP2513490B2 (en) 1987-09-12 1987-09-12 Method for producing alkylthiobenzaldehydes

Country Status (1)

Country Link
JP (1) JP2513490B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0572712A2 (en) * 1992-06-03 1993-12-08 Sumitomo Seika Chemicals Co., Ltd. Processes for producing 2-substituted benzo(beta)thiophene
US6025526A (en) * 1999-02-10 2000-02-15 Occidental Chemical Corporation Synthesis of substituted mercapto-benzaldehydes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0572712A2 (en) * 1992-06-03 1993-12-08 Sumitomo Seika Chemicals Co., Ltd. Processes for producing 2-substituted benzo(beta)thiophene
US6025526A (en) * 1999-02-10 2000-02-15 Occidental Chemical Corporation Synthesis of substituted mercapto-benzaldehydes
WO2000047555A1 (en) * 1999-02-10 2000-08-17 Occidental Chemical Corporation Synthesis of mercapto-benzaldehydes
JP2002536433A (en) * 1999-02-10 2002-10-29 オクシデンタル ケミカル コーポレイション Synthesis of mercapto-benzaldehyde

Also Published As

Publication number Publication date
JP2513490B2 (en) 1996-07-03

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