JPS6395128A - Production of optical glass element - Google Patents

Production of optical glass element

Info

Publication number
JPS6395128A
JPS6395128A JP24243086A JP24243086A JPS6395128A JP S6395128 A JPS6395128 A JP S6395128A JP 24243086 A JP24243086 A JP 24243086A JP 24243086 A JP24243086 A JP 24243086A JP S6395128 A JPS6395128 A JP S6395128A
Authority
JP
Japan
Prior art keywords
mold
optical glass
alloy film
film containing
glass element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP24243086A
Other languages
Japanese (ja)
Inventor
Kiyoshi Kuribayashi
清 栗林
Hideto Monju
秀人 文字
Makoto Umetani
誠 梅谷
Masaki Aoki
正樹 青木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP24243086A priority Critical patent/JPS6395128A/en
Publication of JPS6395128A publication Critical patent/JPS6395128A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B11/00Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
    • C03B11/06Construction of plunger or mould
    • C03B11/08Construction of plunger or mould for making solid articles, e.g. lenses
    • C03B11/084Construction of plunger or mould for making solid articles, e.g. lenses material composition or material properties of press dies therefor
    • C03B11/086Construction of plunger or mould for making solid articles, e.g. lenses material composition or material properties of press dies therefor of coated dies
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2215/00Press-moulding glass
    • C03B2215/02Press-mould materials
    • C03B2215/08Coated press-mould dies
    • C03B2215/10Die base materials
    • C03B2215/12Ceramics or cermets, e.g. cemented WC, Al2O3 or TiC
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2215/00Press-moulding glass
    • C03B2215/02Press-mould materials
    • C03B2215/08Coated press-mould dies
    • C03B2215/14Die top coat materials, e.g. materials for the glass-contacting layers
    • C03B2215/16Metals or alloys, e.g. Ni-P, Ni-B, amorphous metals
    • C03B2215/17Metals or alloys, e.g. Ni-P, Ni-B, amorphous metals comprising one or more of the noble meals, i.e. Ag, Au, platinum group metals

Abstract

PURPOSE:To obtain high-precision optical glass element having excellent image- forming quality inexpensively, by making a mold with a material having improved heat resistance and processing accuracy as a parent material, a specific alloy layer on the pressing face of the mold and molding glass element with the mold. CONSTITUTION:A material (e.g. tungsten carbide or zirconia) having heat resistance and processing accuracy is used as a parent material and processed into a desired shape to make a mold. Further an alloy film containing 95-100wt% Ir and the rest of Pt, an alloy film containing 95-100wt% Rf and the rest of Pt, an alloy film containing 95-98wt% Os and the rest of Pt or an alloy film containing 95-98wt% Rh and the rest or Pt is formed on the pressing face of the mold. Then the mold is used and optical glass elements are press molded to give optical glass elements requiring no abrasion process after molding.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は光学ガラス素子の製造方法に関し、得にプレス
成形後研磨工程を必要としない高精度光学ガラス素子を
プレス成形する際に用いる光学ガラス素子のプレス成形
用型に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for manufacturing an optical glass element, and in particular to a method for manufacturing an optical glass element used in press molding a high precision optical glass element that does not require a polishing step after press molding. The present invention relates to a press molding die.

従来の技術 高精度な光学ガラス素子を直接プレスにより成形するた
めには、像形成品質が良好な事が要求される。このため
型材料としては高温度のもとてガラスに対して化学的に
不活性であること、型のガラスプレス面が十分硬くすり
傷等の損傷を受けにくいこと、また高温度でのプレスで
型が塑性変形などをしないこと、耐熱性、耐熱衝撃性に
優れていること、さらに型の加工性が良く精密加工に可
能なことなどが必要であり、これらの性質を比較的満足
する型材料として例えば特開昭52−45613号公報
に示されているようにシリコンカーバイド(sic)ま
たはシリコンナイトライド(Si3N4)が用いられ、
さらに特開昭59−121126号公報に示されている
チタンカーバイド(Tic)および金属の混合材料など
もあり、様々な検討がなされている。
2. Description of the Related Art In order to directly mold a high-precision optical glass element by pressing, it is required that the quality of image formation be good. For this reason, the mold material must be chemically inert to glass even at high temperatures, the glass pressing surface of the mold must be sufficiently hard and resistant to damage such as scratches, and it must also be suitable for pressing at high temperatures. It is necessary that the mold does not undergo plastic deformation, has excellent heat resistance and thermal shock resistance, and that the mold has good workability and is capable of precision machining.Mold materials that relatively satisfy these properties are required. For example, silicon carbide (SIC) or silicon nitride (Si3N4) is used as shown in Japanese Patent Application Laid-Open No. 52-45613,
Furthermore, there are also mixed materials of titanium carbide (Tic) and metals, which are disclosed in Japanese Patent Laid-Open No. 59-121126, and various studies have been made.

発明が解決しようとする問題点 このように従来の型材料、例えばシリコンカーバイドお
よびシリコンナイトライドの場合では、その硬度が極め
て高いためガラスプレス面を球面形状あるいは非球面形
状に高精度に加工することが非常に困難であった。しか
もこれらの材料はいずれも焼結タイプのものであるため
、その焼結性を向上させる目的で焼結助剤として第三成
分を含有するため、鉛やアルカリ元素を含有するガラス
素子と比較的反応しやすく、プレス成形をくり返すと型
とガラス素子との反応が進み、ガラスが型に付着するよ
うになり像形成品質の良い高精度な光学ガラス素子を成
形することができなかった。
Problems to be Solved by the Invention As described above, in the case of conventional mold materials such as silicon carbide and silicon nitride, their hardness is extremely high, so it is difficult to process the glass press surface into a spherical or aspherical shape with high precision. was extremely difficult. Moreover, since these materials are all sintered types, they contain a third component as a sintering aid to improve their sintering properties, so they are relatively weak compared to glass elements containing lead or alkali elements. It easily reacts, and when press molding is repeated, the reaction between the mold and the glass element progresses, causing the glass to adhere to the mold, making it impossible to mold a highly precise optical glass element with good image formation quality.

また、チタンカーバイドおよび金属の混合材料の場合も
プレス成形をくり返すと型とガラス素子とがくっつき高
精度な光学ガラス素子をプレス成形“することができな
いという欠点を有していた。
Further, in the case of a mixed material of titanium carbide and metal, the mold and the glass element stick together when press molding is repeated, making it impossible to press-form a highly precise optical glass element.

本発明はかかる点に鑑みてなされたもので、光学ガラス
素子の直接プレス成形法により像形成品質の良い高精度
な光学ガラス素子の成形を可能にするためのプレス成形
用型と光学縁ラス素子の製造方法とを提供することを目
的としている。
The present invention has been made in view of the above points, and provides a press molding mold and an optical edge lath element to enable the molding of highly accurate optical glass elements with good image forming quality by a direct press molding method of optical glass elements. The purpose is to provide a manufacturing method for

問題点を解決するための手段 本発明は上記問題点を解決するため、型の母材として精
密加工が容易で、耐熱性、耐熱衝撃性に優れた材料、例
えばタングステンカーバイド、サーメット、又はジルコ
ニアを選び、これらの母材上に光学ガラス素子との反応
性に乏しく、硬度も高いIrを95〜100wt%含有
し残部がPtからなる合金膜、あるいはRuを95〜1
00wt%含有し残部がPtからなる合金膜、あるいは
Osを95〜98wt%含有し残部がPtからなる合金
膜、あるいはRhを95〜98wt%含有し残部がP、
tからなる合金膜を形成して構成したプレス成形型を用
いることにより像形成品質の良好な高精度の光学ガラス
素子をプレス成形により製造することを可能にしようと
したものである。
Means for Solving the Problems In order to solve the above problems, the present invention uses a material that is easy to precisely process and has excellent heat resistance and thermal shock resistance, such as tungsten carbide, cermet, or zirconia, as the base material for the mold. On these base materials, an alloy film containing 95 to 100 wt% of Ir, which has poor reactivity with optical glass elements and high hardness, and the balance is Pt, or an alloy film containing 95 to 1 wt% of Ru, is formed.
An alloy film containing 00 wt% and the balance being Pt, or an alloy film containing 95 to 98 wt% Os and the balance being Pt, or an alloy film containing 95 to 98 wt% Rh and the balance being P,
The present invention is intended to make it possible to manufacture a high-precision optical glass element with good image forming quality by press molding by using a press mold formed by forming an alloy film made of T.

作用 本発明はIrを95〜100wt%含有し残部がPtか
ら成る合金、Ruを95〜100wt%含有し残部がP
tから成る合金、O3を95〜98wt%含有し残部が
Ptから成る合金およびRhを95〜98w t%含有
し残部がPtから    成る合金が高温度において鉛
又はアルカリ元素を含有する光学ガラスと反応しないこ
と、および規定した合金組成で十分硬く型表面にすり傷
等が発生したり、合金膜がプレスにより塑性変形をおこ
したりしないことを見いだし、前記の合金膜を精密加工
が容易で耐熱性もある材料、例えばタングステンカーバ
イド、サーメット、又はジルコニア母材上に形成して光
学ガラス素子のプレス成形用型として用いることにより
像形成品質が良好で高精度な光学ガラス素子の直接プレ
ス成形を可能としたものである。
Function The present invention is an alloy containing 95 to 100 wt% of Ir and the balance being Pt, and an alloy containing 95 to 100 wt% of Ru and the balance being P.
An alloy consisting of t, an alloy containing 95 to 98 wt% O3 and the balance being Pt, and an alloy consisting of 95 to 98 wt% Rh and the balance being Pt react with optical glass containing lead or alkali elements at high temperatures. We found that the specified alloy composition is sufficiently hard and does not cause scratches on the mold surface, nor does the alloy film undergo plastic deformation when pressed. By forming it on a certain material such as tungsten carbide, cermet, or zirconia base material and using it as a press molding mold for optical glass elements, it has become possible to directly press mold optical glass elements with good image formation quality and high precision. It is something.

実施例 以下、本発明の一実施例について図面を用いて説明する
EXAMPLE Hereinafter, an example of the present invention will be described with reference to the drawings.

直径20m、厚さ61mのタングステンカーバイド、サ
ーメットおよびジルコニアを曲率半径46mの凹面形状
の上型、および曲率半径200mの凹面形状の下型から
成る一対の光学ガラス素子のプレス成形様型にそれぞれ
加工した。これらの型のプレス面を超微細なダイヤモン
ド砥粒を用いて鏡面研磨した。次にこの研磨面上にスパ
ッタ法によりIrを95〜100wt%含有し残部がP
tから成る合金膜、あるいはRuを95〜100wt%
含有し残部がPtから成る合金膜、あるいはO3を95
〜98wt%含有し残部がPtから成る合金膜、あるい
はRhを95〜98wt%含有し残部がPtから成る合
金膜を形成してプレス成形用型とした。図にこのように
して作製した上下型をプレスマシンにセットしたものを
示す。11は上型ブロック、12は成形用上型、13は
下型ブロック、14は成形用下型、15は被成形ガラス
、16はプランジャー、17はストッパー、18は位置
決めセンサー、19および22はヒータ、20および2
1は熱電対、23はおおいである。
Tungsten carbide, cermet, and zirconia with a diameter of 20 m and a thickness of 61 m were processed into a pair of press-molding molds for optical glass elements, each consisting of a concave upper mold with a curvature radius of 46 m and a concave lower mold with a curvature radius of 200 m. . The press surfaces of these molds were mirror polished using ultrafine diamond abrasive grains. Next, on this polished surface, 95 to 100 wt% of Ir was added by sputtering, and the balance was P.
An alloy film consisting of T or 95 to 100 wt% Ru
An alloy film containing O3 with the remainder being Pt or 95% of O3
An alloy film containing ~98 wt% of Rh with the balance being Pt, or an alloy film containing 95~98 wt% of Rh with the balance being Pt was formed to form a press molding die. The figure shows the upper and lower molds produced in this way set in a press machine. 11 is an upper mold block, 12 is an upper mold for molding, 13 is a lower mold block, 14 is a lower mold for molding, 15 is glass to be molded, 16 is a plunger, 17 is a stopper, 18 is a positioning sensor, 19 and 22 are Heater, 20 and 2
1 is a thermocouple, and 23 is a cover.

酸化鉛(PbO)約57wt%、シリカ(Sin2)約
37wt%、および残りが微量成分からなる酸化鉛系光
学をだ円形状に加工し、300℃に保持された上下の成
形型12および14の下型14上に設置し、520℃ま
で昇温した後プレス圧約50 kg / a艷によりプ
レス1分間保持した後、そのまま上下の成形型を300
℃まで冷却して両面が凸形にプレス成形された光学ガラ
ス素子を作製し取り出し口より取り出して光学ガラス素
子のプレス成形工程が完了する。以上のような工程を1
000回くり返した後使用した上下の成形型12および
14をプレスマシンより取りはずし成形型の表面状態、
およびプレスされた光学ガラス素子のプレス面を走査型
電子顕微鏡を用い観察評価した。
A lead oxide optical system consisting of approximately 57 wt% lead oxide (PbO), approximately 37 wt% silica (Sin2), and the remainder being trace components was processed into an elliptical shape and placed in upper and lower molds 12 and 14 held at 300°C. Place it on the lower mold 14, raise the temperature to 520°C, hold the press for 1 minute at a press pressure of about 50 kg/a, and then press the upper and lower molds at 300°C.
The optical glass element is cooled to .degree. C. and press-molded to have convex surfaces on both sides, and taken out from the outlet to complete the press-molding process of the optical glass element. The above process 1
After repeating 000 times, remove the upper and lower molds 12 and 14 from the press machine and check the surface condition of the molds.
The pressed surface of the pressed optical glass element was observed and evaluated using a scanning electron microscope.

以上のようにして異なった母材を使用し、これら母材上
に組成の異なる合金膜を形成した成形型を用いプレス実
験をくり返した。第1表にはWCを母材とし、前記母材
上に各種組成の合金膜を形成して構成した成形型の実験
結果を示した。
As described above, pressing experiments were repeated using different base materials and molds with alloy films of different compositions formed on these base materials. Table 1 shows the experimental results of molds constructed by using WC as a base material and forming alloy films of various compositions on the base material.

☆:比較例 また母材にTicを主成分とするサーメット、あるいは
AlzOzを主成分とするサーメット、あるいはZr0
zを用い表1に示した合金膜を前記母材上に形成して構
成した成形型においてもWCを母材とした場合と同一の
プレス実験結果となった。このように耐熱性、耐熱衝撃
性のある母材を用いた場合、母材上にコーディングする
合金膜により合金膜により成形型の良し悪しが決まった
☆: Comparative example The base material was a cermet whose main component was Tic, a cermet whose main component was AlzOz, or a cermet whose main component was Zr0.
A mold formed by forming the alloy film shown in Table 1 on the base material using WC gave the same press experiment results as when WC was used as the base material. In this way, when a base material with heat resistance and thermal shock resistance is used, the quality of the mold is determined by the alloy film coated on the base material.

以上述べたように、光学ガラス素子のプレス成形用型の
母材としては、タングステンカーバイド、サーメットお
よびジルコニアだけに限定されるも−のではなく加工精
度に優れ、耐熱性が有り、貴金属系合金膜との接着性の
良い全ての材料に適合するものである。
As mentioned above, the base material for press molding molds for optical glass elements is not limited to tungsten carbide, cermet, and zirconia, but also has excellent processing accuracy, heat resistance, and noble metal alloy films. It is suitable for all materials that have good adhesive properties.

なお本発明を説明するために凹面形状のプレス成形用型
を使用したが、型表面の形状は本実施例のような形状に
限定されるものではなく、プリズム等の光学ガラス素子
形状にも適合するものであることは言うまでもない。
Although a concave press molding mold was used to explain the present invention, the shape of the mold surface is not limited to the shape of this example, and is also suitable for the shape of optical glass elements such as prisms. Needless to say, it is something that can be done.

発明の効果 以上述べてきたように、本発明は加工精度に優れ、耐熱
性があり、貴金属合金膜との接着性も良い材料、例えば
タングステンカーバイド、サーメット、あるいはジルコ
ニアをプレス成形用型の母材として選び、これらの母材
上に硬度が高く、光学ガラスとの反応性の無いIrを9
5〜100wt%含有し残部がPtから成る合金膜、あ
るいはRuを95〜10〇wt%含有し残部がPtから
成る合金膜、あるいはOsを95〜98wt%含有し残
部がPtから成る合金膜、あるいはRhを95〜98w
t%含有し残部がPtから成る合金膜を形成することに
より像形成品質の良好な高精度な光学ガラス素子の直接
プレス成形用型を提供したものであり、高精度な光学ガ
ラス素子を安価に量生するためのきわめて有用な発明で
ある。
Effects of the Invention As described above, the present invention uses materials that have excellent processing accuracy, heat resistance, and good adhesion to noble metal alloy films, such as tungsten carbide, cermet, or zirconia, as a base material for press molding molds. Ir, which has high hardness and has no reactivity with optical glass, is applied on these base materials.
An alloy film containing 5 to 100 wt% of Ru with the balance being Pt, or an alloy film containing 95 to 100 wt% of Ru with the balance being Pt, or an alloy film containing 95 to 98 wt% of Os and the balance being Pt, Or Rh 95-98w
The present invention provides a mold for direct press molding of high-precision optical glass elements with good image formation quality by forming an alloy film containing Pt with the remainder being Pt, making it possible to produce high-precision optical glass elements at low cost. This is an extremely useful invention for mass production.

【図面の簡単な説明】[Brief explanation of the drawing]

図は本発明の光学ガラス素子のプレス成形用型を組み込
んだプレスマシンの概略図である。 11・・・・・・上型ブロック、12・・・・・・成形
用上型、13・・・・・・下型ブロック、14・・・・
・・成形用下型、15・・・・・・被成形ガラス、16
・・・・・・プランジャー、17・・・・・・ストッパ
ー、18・・・・・・位置決めセンサー、19・・・・
・・ヒータ、20・・・・・・熱電対、22・・・・・
・ヒータ、23・・・・・・おおい。
The figure is a schematic diagram of a press machine incorporating a mold for press molding an optical glass element of the present invention. 11... Upper mold block, 12... Upper mold for molding, 13... Lower mold block, 14...
... Lower mold for molding, 15 ... Glass to be formed, 16
... Plunger, 17 ... Stopper, 18 ... Positioning sensor, 19 ...
... Heater, 20 ... Thermocouple, 22 ...
・Heater, 23...Oi.

Claims (1)

【特許請求の範囲】[Claims] 耐熱性が有り、加工精度に優れた材料を母材とし、前記
母材を所望の形状に加工した後、そのプレス面にIrを
95〜100wt%含有し、残部がPtから成る合金膜
、あるいはRuを95〜100wt%含有し、残部がP
tから成る合金膜、あるいはOsを95〜98wt%含
有し、残部がPtから成る合金膜、あるいはRhを95
〜98wt%含有し、残部がPtから成る合金膜を形成
して構成した成形型を用いて光学ガラス素子をプレス成
形することを特徴とする光学ガラス素子の製造方法。
After using a material that is heat resistant and has excellent processing accuracy as a base material and processing the base material into a desired shape, an alloy film containing 95 to 100 wt% Ir and the remainder Pt on the pressed surface, or Contains 95 to 100 wt% Ru, with the balance being P.
An alloy film containing t, or an alloy film containing 95 to 98 wt% of Os and the remainder being Pt, or an alloy film containing 95 wt% of Rh.
A method for producing an optical glass element, characterized in that the optical glass element is press-molded using a mold formed by forming an alloy film containing Pt in an amount of 98 wt% and the remainder being Pt.
JP24243086A 1986-10-13 1986-10-13 Production of optical glass element Pending JPS6395128A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24243086A JPS6395128A (en) 1986-10-13 1986-10-13 Production of optical glass element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24243086A JPS6395128A (en) 1986-10-13 1986-10-13 Production of optical glass element

Publications (1)

Publication Number Publication Date
JPS6395128A true JPS6395128A (en) 1988-04-26

Family

ID=17088982

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24243086A Pending JPS6395128A (en) 1986-10-13 1986-10-13 Production of optical glass element

Country Status (1)

Country Link
JP (1) JPS6395128A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60246230A (en) * 1984-05-17 1985-12-05 Matsushita Electric Ind Co Ltd Mold for press molding of optical glass element

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60246230A (en) * 1984-05-17 1985-12-05 Matsushita Electric Ind Co Ltd Mold for press molding of optical glass element

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