JPS6368712A - Accelerating method for afterburning of particulate in exhaust gas - Google Patents

Accelerating method for afterburning of particulate in exhaust gas

Info

Publication number
JPS6368712A
JPS6368712A JP61213292A JP21329286A JPS6368712A JP S6368712 A JPS6368712 A JP S6368712A JP 61213292 A JP61213292 A JP 61213292A JP 21329286 A JP21329286 A JP 21329286A JP S6368712 A JPS6368712 A JP S6368712A
Authority
JP
Japan
Prior art keywords
particulates
particulate
fuel
exhaust gas
afterburning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP61213292A
Other languages
Japanese (ja)
Other versions
JPH0515890B2 (en
Inventor
Tamotsu Kobuchi
存 小渕
Hideo Ouchi
日出夫 大内
Akihiko Oi
明彦 大井
Heigoro Aoyama
青山 兵五郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology
Priority to JP61213292A priority Critical patent/JPS6368712A/en
Publication of JPS6368712A publication Critical patent/JPS6368712A/en
Publication of JPH0515890B2 publication Critical patent/JPH0515890B2/ja
Granted legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/023Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Processes For Solid Components From Exhaust (AREA)

Abstract

PURPOSE:To control the formation of particulates for reducing a load on a trap by dispersively adding at least one chosen among an alkali metal compound and an alkaline earth metal compound in the state of an aqueous solution into fuel. CONSTITUTION:At least one aqueous compound chosen among an alkali metal compound and an alkaline earth metal compound such as the carbonate, hydrogen carbonate, carboxylate and hydroxide of sodium, potassium and calcium is dispersively added as a particulate afterburning accelerator harmless to fuel used for a diesel engine. The fuel having an added afterburning accelerator is supplied to the engine to be burned, and then the particulates in exhaust gas are collected in a trap to be afterburned. In this case, the aqueous effect of said aqueous compound controls the discharge of the particulates, and improves removing efficiency for the particulates owing to their afterburning in the particulate trap for sharp reduction in the discharge of the particulates.

Description

【発明の詳細な説明】 [技術分野] 本発明は、ディーゼルエンジン燃焼排ガス中のパーティ
キュレートの再燃焼促進方法に間するものである。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to a method for promoting reburning of particulates in diesel engine combustion exhaust gas.

ディーゼルエンジンから排出されるパーティキュレート
を捕集するフィルタートラップをエンジ□ンと排気管出
口との間に装着することは、この分−野で公知の技術で
ある。
It is a known technique in the art to install a filter trap between the engine and the exhaust pipe outlet to collect particulates emitted from a diesel engine.

フィルタートラップは、パーティキュレートを捕集する
部材であれば種類を問わないが、エンジンの作動期間に
おいてフィルタートラップにパーティキュレートが捕集
されるにつれて、フィルターの目詰まりが生じ、背圧が
上昇するため、エンジン性能が低下し、さらにはエンジ
ン作動が困難になる。
The filter trap can be of any type as long as it collects particulates, but as particulates are collected in the filter trap during engine operation, the filter becomes clogged and back pressure increases. , engine performance deteriorates, and even engine operation becomes difficult.

本発明は、フィルタートラップに捕集されたパーティキ
ュレートの再燃焼の着火温度を低下させ、あるいは燃焼
の速度を高める効果のある水溶性でかつ無公害な燃焼促
進剤で、パーティキュレートの排出を低減するためのフ
ィルタートラップの性能を継続的に維持するためのもの
である。
The present invention is a water-soluble and non-polluting combustion accelerator that reduces the ignition temperature for re-combustion of particulates collected in filter traps or increases the combustion rate, thereby reducing particulate emissions. This is to continuously maintain the performance of the filter trap.

[従来技術] 上記のフィルタートラップの性能低下を防止し、またエ
ンジントラブルを解決するため、特許出願公開昭59−
93916、昭59−77025、昭60−42332
などのフィルター再生装置が考案され、再燃焼に要する
エネルギーの節約及び再生性能の向上が図られているが
、さらにエネルギーの節約と捕集装置性能の維持向上と
簡易化が必要とされる。
[Prior Art] In order to prevent the above-mentioned filter trap from deteriorating in performance and to solve engine troubles, a patent application was published in 1982-
93916, 1984-77025, 1984-42332
Filter regeneration devices such as the above have been devised to save energy required for re-combustion and improve regeneration performance, but there is a need to further save energy, maintain and improve the performance of the collection device, and simplify it.

パーティキュレートの再燃焼を促進する方法として、特
許出願公開昭59−155527に提案される銅なとの
金属を含むパーティキュレート再燃焼促進剤を燃料に添
加し、不完全燃焼生成物であるパーティキュレートのフ
ィルター上での再燃焼を容易にすることが行われている
が、この方法では直接軽油に溶かして使用するため、油
溶性化合物にしなければならず、使用できる金属化合物
が限られ、しかも高価になる。本発明の水溶性の着火促
進剤を使用して、水の効果でパーティキュレートの生成
抑制を図り、フィルタートラップの負荷の軽減を図ると
共に、捕集されたパーティキュレートの再燃焼を促進さ
せるという試みはなされていない。
As a method for promoting the reburning of particulates, a particulate reburning accelerator containing a metal such as copper is added to the fuel, which is proposed in Patent Application Publication No. 59-155527. However, since this method is used by directly dissolving it in light oil, it must be made into an oil-soluble compound, which limits the number of metal compounds that can be used, and it is also expensive. become. An attempt to use the water-soluble ignition accelerator of the present invention to suppress the generation of particulates through the effect of water, reduce the load on the filter trap, and promote reburning of the collected particulates. Not talked about.

[発明が解決しようとする問題点] ディーゼルエンジンにおける窒素酸化物の生成とパーテ
ィキュレートの生成には相反する燃焼条件があり、一般
に窒素酸化物の生成を抑制するような燃焼条件では、パ
ーティキュレートの生成、排出が増大することは公知の
事実である。ディーゼルエンジンからの窒素酸化物の排
出を抑制する技術の1つとして、燃焼最高温度を低下さ
せる水の利用には、上記lに記述した如く、燃料と水を
混合して供給する方法、水を吸気系で霧化して供給する
フユミゲーション法、水を燃焼室内に直接噴射する方法
が考案されている。
[Problems to be solved by the invention] There are conflicting combustion conditions for the generation of nitrogen oxides and particulates in a diesel engine, and in general, under combustion conditions that suppress the generation of nitrogen oxides, the generation of particulates is It is a known fact that production and emissions increase. One of the technologies to suppress nitrogen oxide emissions from diesel engines is to use water to lower the maximum combustion temperature, as described in section 1 above. A fumigation method in which water is atomized and supplied through the intake system, and a method in which water is directly injected into the combustion chamber have been devised.

今後の大気汚染防止には窒素酸化物とパーティキュレー
トの一層の同時低減が必要であり、パーティキュレート
の除去のためのフィルタートラップの効率の向上ならび
に使用方法の改善が課題となっている。
In order to prevent air pollution in the future, further simultaneous reduction of nitrogen oxides and particulates will be necessary, and issues include improving the efficiency of filter traps for removing particulates and improving their usage.

本発明は、窒素酸化物を低減する作用を有する水に水溶
性でかつ二次汚染のおそれのない安全なパーティキュレ
ート再燃焼促進剤を添加し、水の効果でパーティキュレ
ートの排出を抑制すると共にパーティキュレートトラッ
プの再燃焼による除去効率を高め、パーティキュレート
排出の大幅な低減を図るものである。
The present invention adds a safe particulate reburning promoter that is water-soluble and has no risk of secondary pollution to water, which has the effect of reducing nitrogen oxides, and suppresses particulate emissions through the effect of water. The aim is to improve removal efficiency through re-combustion of particulate traps and significantly reduce particulate emissions.

[問題点を解決するための手段] 上記のような従来の欠点を除去するために、本発明では
、安全なパーティキュレート再燃焼促進剤としてナトリ
ウム、カリウム、カルシウムの炭酸塩、炭酸水素塩、カ
ルボン酸塩、水酸化物等のアルカリ金属化合物やアルカ
リ土類金属化合物のうち水溶性化合物を、燃料に対して
0.1mmoI/ tから5mmol/ 1 、望まし
くは2mmoI/ 1となるように水に溶解した形で燃
料と共に燃焼系に供給する。再燃焼促進剤を含む水溶液
の燃焼系への供給方法としては、第1に、乳化剤等の分
散剤を使用して水溶液を軽油中にエマルジョンとして分
散させ、通常のディーゼル燃料と全く同じ方法で燃焼さ
せる―+1 、゛方法がある。この場合は、エンジンのi構的改良゛
・は不必要であり、現用のエンジンをそのまま使用′・
することができる。この方法において、水溶液中道剤を
含む水溶液の第2の添加方法は、噴射ノズルを、通して
水溶液そのものをエンジンの吸気バイブ中あるいはシリ
ンダー内へ直接噴射する方式である。この場合は、現用
のディーゼルエンジンに水噴射機構を付加したものを使
用する。この方法においても、水溶液と軽油の供給量の
比を考慮して、上述した最適添加量となるように水溶液
中の再燃焼促進剤の濃度を決める。
[Means for Solving the Problems] In order to eliminate the above-mentioned conventional drawbacks, the present invention uses sodium, potassium, and calcium carbonates, hydrogen carbonates, and carbonates as safe particulate reburning promoters. Water-soluble compounds of alkali metal compounds and alkaline earth metal compounds such as acid salts and hydroxides are dissolved in water at a concentration of 0.1 mmol/t to 5 mmol/1, preferably 2 mmol/1 relative to the fuel. It is supplied to the combustion system together with fuel in the form of The first method for supplying an aqueous solution containing a reburning accelerator to the combustion system is to disperse the aqueous solution in light oil as an emulsion using a dispersant such as an emulsifier, and then combust it in exactly the same way as normal diesel fuel. -+1 There is a way to do it. In this case, structural improvements to the engine are unnecessary, and the current engine can be used as is.
can do. In this method, the second method of adding the aqueous solution containing the aqueous solution neutralizing agent is to directly inject the aqueous solution itself into the intake vibe of the engine or into the cylinder through an injection nozzle. In this case, a current diesel engine with a water injection mechanism added will be used. In this method as well, the concentration of the reburning accelerator in the aqueous solution is determined in consideration of the ratio of the supply amounts of the aqueous solution and light oil so as to achieve the above-mentioned optimum addition amount.

いずれの供給方法においても、排気ガスパイプ途中には
パーティキュレート捕集、再燃焼用フィルタートラップ
を設置してパーティキュレートの除去を行う。再燃焼促
進剤を添加しない場合に比べて、本発明の促進剤を添加
した場合、パーティ−ターの電力あるいは燃料の一部を
燃焼させフィルタートラップを加熱するのに要するエネ
ルギーなどを節約することができる。
In either supply method, particulates are removed by installing a filter trap for particulate collection and reburning in the middle of the exhaust gas pipe. Compared to the case where no reburning accelerator is added, when the accelerator of the present invention is added, the electric power of the particulater or the energy required to burn a part of the fuel and heat the filter trap can be saved. can.

以下、本発明の実施例を図面と共に説明する。Embodiments of the present invention will be described below with reference to the drawings.

実施例、 ディーゼルエンジンからのパーティキュレー
トに対する再燃焼促進剤の効果について第1図は、パー
ティキュレート再燃焼促進剤を使用せず、市販軽油のみ
を用いた場合のパーティキュレートの示差熱分析チャー
トであり、1はパーティキュレートの重量変化、2は燃
焼雰囲気温度、3は発熱量、4は燃焼終端温度を示して
いる。
Example: Effect of reburning accelerator on particulates from a diesel engine Figure 1 is a differential thermal analysis chart of particulates when only commercially available light oil is used without using a particulate reburning accelerator. , 1 indicates the weight change of the particulates, 2 indicates the combustion atmosphere temperature, 3 indicates the calorific value, and 4 indicates the combustion end temperature.

第2図は、本発明による炭酸水素ナトリウムを水に0.
17讐tX添加し、これを軽油に 10讐tX混合し、
水エマルジヨン燃料とし、燃焼させた場合のパーティキ
ュレートの示差熱分析結果を示した、もので、再燃焼が
促進され、燃焼終端温度も著しi く低下している。
FIG. 2 shows the amount of sodium bicarbonate according to the present invention added to water at 0.0%.
Add 17Tx and mix this with 10TX to light oil.
The results of differential thermal analysis of particulates when burned as a water emulsion fuel show that re-combustion is promoted and the combustion end temperature is significantly lowered.

・−第3図は、水エマルジヨン燃料に本発明の炭酸して
おり、第3図中5は通常の市販軽油を用いた場合のパー
ティキュレート再燃焼終端温度であり、6は、10χ水
エマルジヨン燃料を用いた場合のパーティキュレート再
燃焼終端温度であり、7.8.9は、それぞれIOX水
エマルジョン燃料にカリウムまたはナトリウムを0.2
.0.6.2.Ommol/ f添加混合した場合のパ
ーティキュレートの再燃焼温度で、再燃焼促進剤を添加
しない場合(6)に比較して再燃焼温度は低下している
。カリウムとナトリウムの効果は、はぼ同等であり、9
で判るように、再燃焼温度は軽油の場合の温度に比べて
約1506Cも低下している。
・-Figure 3 shows the water emulsion fuel carbonated according to the present invention. In Figure 3, 5 is the particulate re-combustion terminal temperature when ordinary commercially available light oil is used, and 6 is the 10χ water emulsion fuel. 7.8.9 is the particulate reburning terminal temperature when using IOX water emulsion fuel with 0.2% potassium or sodium, respectively.
.. 0.6.2. The reburning temperature of particulates when Ommol/f is added and mixed is lower than the case (6) in which no reburning accelerator is added. The effects of potassium and sodium are almost the same, 9
As can be seen, the reburning temperature is approximately 1506C lower than the temperature for diesel oil.

て適当であり、その社会的もしくは工業的価値は大きい
It has great social and industrial value.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図 市販軽油より生成したパーティキュレートの示
差熱分析チャート 第2図 炭酸水素ナトリウムを添加した水エマルジヨン
燃料より生成したパーテ ィキュレートの示差熱分析チャート 第3図 炭酸水素ナトリウムおよび炭酸水素カリウムに
よるパーティキュレート の再燃焼促進効果
Fig. 1 Differential thermal analysis chart of particulates produced from commercially available light oil Fig. 2 Differential thermal analysis chart of particulates produced from water emulsion fuel to which sodium bicarbonate has been added Fig. 3 Particulates produced from sodium bicarbonate and potassium bicarbonate Reburning promotion effect

Claims (2)

【特許請求の範囲】[Claims] (1)ディーゼルエンジンにおいて、燃料に対し、アル
カリ金属化合物及びアルカリ土類金属化合物の中から選
ばれる少なくとも1種を水溶液の形で添加分散させてこ
れを燃焼させると共に、この際に生成した燃焼排ガス中
のパーティキュレートをトラップに捕集し、これを再燃
焼させることを特徴とするディーゼルエンジン燃焼排ガ
ス中のパーティキュレートの再燃焼方法。
(1) In a diesel engine, at least one selected from alkali metal compounds and alkaline earth metal compounds is added and dispersed in the form of an aqueous solution to fuel, and this is combusted, and the combustion exhaust gas generated at this time A method for re-burning particulates in diesel engine combustion exhaust gas, which comprises collecting the particulates in a trap and re-burning them.
(2)ディーゼルエンジンにおいて、シリンダー内への
燃料噴射の他にシリンダー内あるいは吸気系内にアルカ
リ金属化合物及びアルカリ土類金属化合物の中から選ば
れる少なくとも1種の水溶液を噴射して燃料の燃焼を行
うと共に、この際に生成した燃焼排ガス中のパーティキ
ュレートをトラップに捕集し、これを再燃焼させること
を特徴とするディーゼルエンジン燃焼排ガス中のパーテ
ィキュレートの再燃焼方法。
(2) In a diesel engine, in addition to fuel injection into the cylinder, at least one aqueous solution selected from alkali metal compounds and alkaline earth metal compounds is injected into the cylinder or into the intake system to promote combustion of the fuel. A method for re-burning particulates in diesel engine combustion exhaust gas, which comprises performing the above steps, collecting the particulates in the combustion exhaust gas generated at this time in a trap, and re-burning them.
JP61213292A 1986-09-10 1986-09-10 Accelerating method for afterburning of particulate in exhaust gas Granted JPS6368712A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61213292A JPS6368712A (en) 1986-09-10 1986-09-10 Accelerating method for afterburning of particulate in exhaust gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61213292A JPS6368712A (en) 1986-09-10 1986-09-10 Accelerating method for afterburning of particulate in exhaust gas

Publications (2)

Publication Number Publication Date
JPS6368712A true JPS6368712A (en) 1988-03-28
JPH0515890B2 JPH0515890B2 (en) 1993-03-02

Family

ID=16636702

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61213292A Granted JPS6368712A (en) 1986-09-10 1986-09-10 Accelerating method for afterburning of particulate in exhaust gas

Country Status (1)

Country Link
JP (1) JPS6368712A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GR890100306A (en) * 1989-05-08 1991-10-10 Konstantinos Potiris Method and apparatus producing and using a catalytic fuel for better burning of hydrocarbons
US5293742A (en) * 1991-06-27 1994-03-15 Donaldson Company, Inc. Trap apparatus with tubular filter element
FR2719081A1 (en) * 1994-04-20 1995-10-27 Rhone Poulenc Chimie Reduction of carbonaceous particulate emissions in vehicle exhausts

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4815405B2 (en) * 2007-08-20 2011-11-16 本田技研工業株式会社 Exhaust gas purification device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5730523A (en) * 1980-07-29 1982-02-18 Tsuchiya Mfg Co Ltd Treatment of fine particles in exhaust gas
JPS59155527A (en) * 1982-09-23 1984-09-04 ゼネラル・モ−タ−ズ・コ−ポレ−シヨン Purifier for exhaust gas
JPS60108516A (en) * 1983-11-15 1985-06-14 Mitsubishi Motors Corp Device for regenerating particulate trapping filter in diesel-engine
JPS60108519A (en) * 1983-11-15 1985-06-14 Mitsubishi Motors Corp Device for regenerating particulate trapping filter in diesel-engine

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5730523A (en) * 1980-07-29 1982-02-18 Tsuchiya Mfg Co Ltd Treatment of fine particles in exhaust gas
JPS59155527A (en) * 1982-09-23 1984-09-04 ゼネラル・モ−タ−ズ・コ−ポレ−シヨン Purifier for exhaust gas
JPS60108516A (en) * 1983-11-15 1985-06-14 Mitsubishi Motors Corp Device for regenerating particulate trapping filter in diesel-engine
JPS60108519A (en) * 1983-11-15 1985-06-14 Mitsubishi Motors Corp Device for regenerating particulate trapping filter in diesel-engine

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GR890100306A (en) * 1989-05-08 1991-10-10 Konstantinos Potiris Method and apparatus producing and using a catalytic fuel for better burning of hydrocarbons
US5293742A (en) * 1991-06-27 1994-03-15 Donaldson Company, Inc. Trap apparatus with tubular filter element
FR2719081A1 (en) * 1994-04-20 1995-10-27 Rhone Poulenc Chimie Reduction of carbonaceous particulate emissions in vehicle exhausts

Also Published As

Publication number Publication date
JPH0515890B2 (en) 1993-03-02

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