JPS6362453B2 - - Google Patents
Info
- Publication number
- JPS6362453B2 JPS6362453B2 JP15728280A JP15728280A JPS6362453B2 JP S6362453 B2 JPS6362453 B2 JP S6362453B2 JP 15728280 A JP15728280 A JP 15728280A JP 15728280 A JP15728280 A JP 15728280A JP S6362453 B2 JPS6362453 B2 JP S6362453B2
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- precipitate
- leaching
- molybdenum
- vanadium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000002386 leaching Methods 0.000 claims description 68
- 239000007788 liquid Substances 0.000 claims description 57
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 50
- 229910052751 metal Inorganic materials 0.000 claims description 44
- 239000002184 metal Substances 0.000 claims description 44
- 239000002244 precipitate Substances 0.000 claims description 43
- 229910052720 vanadium Inorganic materials 0.000 claims description 37
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 35
- 239000010941 cobalt Substances 0.000 claims description 30
- 229910017052 cobalt Inorganic materials 0.000 claims description 30
- 239000003054 catalyst Substances 0.000 claims description 29
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 28
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 27
- 239000011733 molybdenum Substances 0.000 claims description 27
- 229910052750 molybdenum Inorganic materials 0.000 claims description 27
- 229910052759 nickel Inorganic materials 0.000 claims description 25
- 150000002739 metals Chemical class 0.000 claims description 22
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 22
- 239000002699 waste material Substances 0.000 claims description 21
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 18
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 16
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 12
- 239000011707 mineral Substances 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 7
- 230000001590 oxidative effect Effects 0.000 claims description 6
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims 3
- 150000003681 vanadium Chemical class 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 62
- 239000000203 mixture Substances 0.000 description 20
- 239000000243 solution Substances 0.000 description 18
- 230000008569 process Effects 0.000 description 15
- 238000011084 recovery Methods 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 229910052602 gypsum Inorganic materials 0.000 description 7
- 239000010440 gypsum Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 5
- 239000000920 calcium hydroxide Substances 0.000 description 5
- 235000011116 calcium hydroxide Nutrition 0.000 description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 5
- 239000006228 supernatant Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010814 metallic waste Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910001456 vanadium ion Inorganic materials 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15728280A JPS5782122A (en) | 1980-11-08 | 1980-11-08 | Treatment of waste metal catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15728280A JPS5782122A (en) | 1980-11-08 | 1980-11-08 | Treatment of waste metal catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5782122A JPS5782122A (en) | 1982-05-22 |
| JPS6362453B2 true JPS6362453B2 (fi) | 1988-12-02 |
Family
ID=15646249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15728280A Granted JPS5782122A (en) | 1980-11-08 | 1980-11-08 | Treatment of waste metal catalyst |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5782122A (fi) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8719840D0 (en) * | 1987-08-21 | 1987-09-30 | British Petroleum Co Plc | Separation process |
| WO2017069223A1 (ja) * | 2015-10-20 | 2017-04-27 | Ｌｅシステム株式会社 | レドックスフロー電池用のバナジウム電解液の製造方法 |
-
1980
- 1980-11-08 JP JP15728280A patent/JPS5782122A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5782122A (en) | 1982-05-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5245768B2 (ja) | ニッケル及びコバルトを含む硫化物の製造方法 | |
| TWI432583B (zh) | 自含釩鎳廢觸媒回收稀土、釩及鎳之方法 | |
| US4405569A (en) | Hydrometallurgical process for extracting metal values from complex ores containing arsenic and sulfur | |
| US5482534A (en) | Extraction or recovery of non-ferrous metal values from arsenic-containing materials | |
| GB2073723A (en) | Recovering chromium vanadium molybdenum and tungsten | |
| US4163043A (en) | Process for removing H2 S and CO2 from gases and regenerating the adsorbing solution | |
| EP0771881A1 (en) | An integrated process for the recovery of metals and fused alumina from spent catalysts | |
| JPS6019350B2 (ja) | コ−クス炉ガスの脱硫法 | |
| JP2004323934A (ja) | 有価金属の分離回収方法 | |
| WO2016157629A1 (ja) | ニッケル及びコバルトの混合硫化物の製造方法、ニッケル酸化鉱石の湿式製錬方法 | |
| CN106435197A (zh) | 一种scr脱硝废催化剂有价金属碱性萃取回收装置及工艺 | |
| EP0119685A1 (en) | Hydrometallurgical arsenopyrite process | |
| CN110629034A (zh) | 从钨废料回收渣中回收钴镍的方法 | |
| US4594102A (en) | Recovery of cobalt and nickel from sulphidic material | |
| CN109593965B (zh) | 一种从铝基石油精炼废催化剂中回收有价元素的方法 | |
| CA1197383A (en) | Process for the recovery of valuable metals from spent crude-oil sulfur-extraction catalysts | |
| JPS6362453B2 (fi) | ||
| US3950492A (en) | Process for removal of ammonia, hydrogen sulfide and hydrogen cyanide from gases containing these substances | |
| US2693405A (en) | Method of separating copper values from and ammoniacal solution | |
| CN109487075B (zh) | 利用还原性气体实现铝基石油精炼催化剂中有价元素综合回收的方法 | |
| CN112593074A (zh) | 黄钠铁矾低温焙烧浸出循环除铁工艺 | |
| JPH0123532B2 (fi) | ||
| JP3780358B2 (ja) | 石油系燃焼灰の処理方法 | |
| US2778727A (en) | Method of concentrating metal values from sulfur solutions | |
| JPS5824383B2 (ja) | ダツリユウハイシヨクバイカラノバナジウムノ カイシユウホウホウ |