JPS6351995A - Water treating system - Google Patents

Water treating system

Info

Publication number
JPS6351995A
JPS6351995A JP61196807A JP19680786A JPS6351995A JP S6351995 A JPS6351995 A JP S6351995A JP 61196807 A JP61196807 A JP 61196807A JP 19680786 A JP19680786 A JP 19680786A JP S6351995 A JPS6351995 A JP S6351995A
Authority
JP
Japan
Prior art keywords
treatment
water
degassing
anaerobic
pipeline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61196807A
Other languages
Japanese (ja)
Inventor
Mikio Kitagawa
幹夫 北川
Miwako Watanabe
渡辺 美和子
Motoyuki Yoda
依田 元之
Mitsuhiro Kaneko
金子 充宏
Naoto Ichiyanagi
直人 一柳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kurita Water Industries Ltd
Original Assignee
Kurita Water Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kurita Water Industries Ltd filed Critical Kurita Water Industries Ltd
Priority to JP61196807A priority Critical patent/JPS6351995A/en
Publication of JPS6351995A publication Critical patent/JPS6351995A/en
Pending legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Treating Waste Gases (AREA)
  • Degasification And Air Bubble Elimination (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

PURPOSE:To efficiently remove reductive sulfide by providing both an anaerobic treating means and a degassing means having an evacuating means. CONSTITUTION:Water to be treated is introduced into an anaerobic treating tank 2 through a pipeline 1 and subjected to anaerobic treatment. Treated water is taken out through a pipeline 3 and introduced into a degassing tower 6 via a water sealing tank 4 and a pipeline 5. A sprinkler 6a is provided to the upper part of the inside of the degassing tower 6 and the anaerobically treated water introduced thereinto is uniformly sprinkled in the tower. An evacuating pump 11 is connected to the degassing tower 6 and the inside thereof is evacuated. The gas discharge side of the evacuating pump 11 is connected to a desulfurization device 13 via a pipeline 12. Digested gas fed from the anaerobic treating tank 2 is introduced into the desulfurization device 13 via a pipeline 14. Thereby the treated water wherein reductive sulfide is sufficiently removed is obtained.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は有機性物質を含有する廃水の処理を行う水処理
装置に関するものであり、詳しくはこの廃水中に含まれ
ている還元性硫化物を効率よく除去することができる水
処理装置に関するものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a water treatment device for treating wastewater containing organic substances, and more specifically, it relates to a water treatment device for treating wastewater containing organic substances. The present invention relates to a water treatment device that can efficiently remove water.

[従来の技術] 硫酸根を含む有機性廃水を鎌気性IA理すると、硫酸根
の一部又は全てがHS−1S2−などの還元性硫化物に
変化する。この還元性硫化物は消(ヒガス中に含まれて
液中から取り除かれるが、一部は水中に溶解し、処理水
水質の悪化や後処理装置の腐食等の問題を生じさせる。
[Prior Art] When organic wastewater containing sulfate radicals is subjected to sickle IA treatment, some or all of the sulfate radicals change into reducing sulfides such as HS-1S2-. Although these reducible sulfides are contained in sulfur gas and removed from the liquid, some of them are dissolved in the water, causing problems such as deterioration of the quality of treated water and corrosion of post-treatment equipment.

(廃水を嫌気性処理した場合、その処理水に溶存酸素か
含まれていないので、空気で曝気する等該処理水に溶存
酸素を含ませる後処理を行った後放流をすることが多い
のであるが、この後処理を行う装置において還元性硫化
物による腐食が生じ易い。) 従来、水中の還元性硫化物を除去する方法としては、F
e塩による凝集処理、過酸化物による酸化処理、好気性
下における散水濾床や活性汚泥処理等の生物処理或いは
空気を吹き込むストリッピング処理等が行われている。
(When wastewater is anaerobically treated, the treated water does not contain dissolved oxygen, so it is often discharged after post-treatment to add dissolved oxygen to the treated water, such as by aerating it with air.) (However, corrosion due to reducing sulfides is likely to occur in the equipment that performs this post-treatment.) Conventionally, as a method for removing reducing sulfides from water, F
Coagulation treatment using e-salt, oxidation treatment using peroxide, biological treatment such as trickling filter or activated sludge treatment under aerobic conditions, and stripping treatment by blowing air are performed.

[発明が解決しようとする問題点] 上記従来の処理方法では次のような問題があった。[Problem that the invention attempts to solve] The conventional processing method described above has the following problems.

凝集処理方法では、生成するスラッジ量が多大となる。In the agglomeration treatment method, a large amount of sludge is generated.

過酸化物による処理方法は、過酸化物薬品コストが嵩み
、処理コストが極めて高いものとなる。
In the treatment method using peroxide, the cost of peroxide chemicals increases and the treatment cost becomes extremely high.

好気性下における生物処理方法では、ベギュアトアに代
表される硫黄酸化菌の増殖が多く、余剰汚泥処理対策が
必要になると共に、濾床の閉塞を生じるおそれがある。
In biological treatment methods under aerobic conditions, sulfur-oxidizing bacteria such as Beguyatoa proliferate frequently, requiring measures to dispose of excess sludge and potentially clogging the filter bed.

空気を吹き込むストリッピング処理方法では、空気の吹
込量が多く、それに伴う排ガスの処理二が多くなる。
In the stripping treatment method in which air is blown, the amount of air blown is large, and the amount of exhaust gas that must be processed accordingly increases.

[問題点を解決するための手段] 本発明の水処理装置は、有機性物質を含有する被処理水
を導入して嫌気性処理する嫌気性処理手段と、減圧手段
を備えており、該嫌気性処理手段からの処理液を導入し
て減圧により脱ガス処理する脱ガス手段とを備えたこと
を特徴とするものである。
[Means for Solving the Problems] The water treatment apparatus of the present invention is equipped with an anaerobic treatment means for introducing and anaerobically treating water containing organic substances, and a depressurization means. The present invention is characterized by comprising a degassing means for introducing the treatment liquid from the treatment means and performing degassing treatment under reduced pressure.

[作用] 本発明の水処理装置では、まず有機性物質を含有する被
処理水を嫌気性処理する。そして、この処理液(還元性
硫化物やメタン等を溶解している)を脱ガス手段に導入
し、減圧下に晒すことにより、この処理水中に溶存して
いるV光性硫化物やメタン等をガス化させ、除去する。
[Function] In the water treatment apparatus of the present invention, first, water to be treated containing organic substances is anaerobically treated. Then, this treatment liquid (in which reducible sulfides, methane, etc. are dissolved) is introduced into a degassing means and exposed to reduced pressure, thereby eliminating the V-photoactive sulfide, methane, etc. dissolved in this treatment water. is gasified and removed.

[実施例] 以下図面を参照して実施例について説明する。[Example] Examples will be described below with reference to the drawings.

第1図は本発明の実施例に係る水処理装置の構成を示す
系統図である。第1図において有機性物質を含有する被
処理水は、配管1から嫌気性処理4ff 2に導入され
、嫌気性処理される。この嫌気性処理水は、配管3にて
取り出され、水封槽4及び配管5を経て脱ガス塔6に導
入される。脱ガス塔6内の上部には散水器6aが設置さ
れ、導入された嫌気性処理水を塔内に均一に散水してい
る。また、脱ガス塔6内にはハニカム4構造や積層波板
状等の適宜の構造を有している充填材が装填されており
、散水された嫌気性処理水はこの充填材の表面を薄膜状
に流下して該脱ガス塔6の下部に達し、配管7にて取り
出され、水封4ff a及び配管9を経て、後処理装置
10に導入され、後処理を受けた後放流される。
FIG. 1 is a system diagram showing the configuration of a water treatment apparatus according to an embodiment of the present invention. In FIG. 1, water to be treated containing organic substances is introduced from a pipe 1 to an anaerobic treatment 4ff2, where it is anaerobically treated. This anaerobically treated water is taken out through a pipe 3 and introduced into a degassing tower 6 via a water seal tank 4 and a pipe 5. A water sprinkler 6a is installed in the upper part of the degassing tower 6, and the introduced anaerobically treated water is uniformly sprinkled inside the tower. In addition, the degassing tower 6 is loaded with a filler having an appropriate structure such as a honeycomb 4 structure or a laminated corrugated plate shape, and the sprayed anaerobic treated water coats the surface of this filler with a thin film. It flows down to the lower part of the degassing tower 6, is taken out through a pipe 7, passes through a water seal 4ffa and a pipe 9, is introduced into a post-treatment device 10, and is discharged after being post-treated.

前記脱ガス塔6には減圧ポンプ11が接続されており、
脱ガス塔6内を減圧している。この減圧ポンプ11のガ
ス排出側は配管12を介して脱硫装置13に接続されて
いる。また、この脱硫装M13には配管14を経て嫌気
性IA埋(92の消化ガスが導入されるようにな)てい
る。
A vacuum pump 11 is connected to the degassing tower 6,
The pressure inside the degassing tower 6 is reduced. The gas discharge side of this pressure reducing pump 11 is connected to a desulfurization device 13 via a pipe 12. Further, this desulfurization unit M13 is connected to an anaerobic IA tank (so that 92 digestion gas is introduced) through a pipe 14.

脱ガス塔6内に装填される充填材としては、脱ガス塔6
内に導入された水が薄膜状となり広い表面積を形成でき
る構造をもったものが好適であり、上記の如くハニカム
構造や積層aE溝構造有しているものが好適である。な
お、この充填材を選定するに際しては、ガス吸収塔や脱
臭装置と同等の選定基準に従って選定するが好適である
As the packing material loaded into the degassing tower 6, the degassing tower 6
It is preferable to have a structure in which the water introduced therein becomes a thin film to form a large surface area, and as mentioned above, a structure having a honeycomb structure or a laminated aE groove structure is preferable. In addition, when selecting this filler, it is preferable to select it according to the same selection criteria as a gas absorption tower or a deodorization device.

減圧ポンプ11としては、脱ガス塔6がその導入側及び
排出側のいずれも水封槽4.8にて封じられた密閉形と
なっているので、該脱ガス塔6内を流れる処理水から発
生するガスのみを吸引する小容量のもので足りる。なお
、この減圧ポンプ11や配管12.14等を構成する材
料としては還元性硫化物等に対する耐食性の高い材質の
ものを用いるのが好適である。
As for the decompression pump 11, since the degassing tower 6 is of a closed type where both the inlet side and the discharge side are sealed with a water seal tank 4.8, the degassing tower 6 is of a closed type, so that the treated water flowing inside the degassing tower 6 is A small capacity device that sucks only the generated gas is sufficient. Note that it is preferable to use materials that are highly resistant to corrosion against reducing sulfides and the like as materials constituting the vacuum pump 11, the piping 12, 14, and the like.

脱硫装置13としては、導入されるガス二が少ない場合
や或いは硫黄分の濃度が低い場合には、乾式脱硫装置が
好適であり、脱硫した後メタンガスの燃焼や大気放出を
行う。また、生物脱臭により脱硫とメタンの生物分解を
行うようにした脱硫装置も採用できる。脱硫装置に導入
されるガス量が多い場合やその硫黄分濃度が高い場合に
は、湿式脱硫により還元性硫化物を硫化ソーダなどの硫
化物として回収したり、硫酸第2鉄溶液に吸収させ、車
体硫黄を生成、回収するように構成された装置などが好
適に採用できる。
As the desulfurization device 13, a dry desulfurization device is suitable when the amount of gas to be introduced is small or when the concentration of sulfur content is low, and after desulfurization, methane gas is combusted or released into the atmosphere. Furthermore, a desulfurization device that performs desulfurization and biodegradation of methane through biological deodorization can also be adopted. When the amount of gas introduced into the desulfurization equipment is large or the sulfur concentration is high, the reducing sulfide can be recovered as a sulfide such as sodium sulfide by wet desulfurization, or absorbed in a ferric sulfate solution. A device configured to generate and recover vehicle body sulfur can be suitably employed.

本実施例装置では、この脱硫装置13に脱ガス塔6から
のガスと共に嫌気性処理槽2からの消化ガスが導入され
ており、水処理製蓋全体のガス処理系統が集約されコン
パクトな構成となっている。
In the device of this embodiment, the digestion gas from the anaerobic treatment tank 2 is introduced into the desulfurization device 13 together with the gas from the degassing tower 6, and the gas treatment system for the entire water treatment lid is consolidated, resulting in a compact configuration. It has become.

後処理装置10は、脱ガス処理した水に溶存酸素を付加
すると共に残留有機物を酸化除去するためのものであり
、散気管10a等適宜の空気(酸素)添加手段を備えて
構成されている。
The post-treatment device 10 is for adding dissolved oxygen to the degassed water and oxidizing and removing residual organic matter, and is equipped with appropriate air (oxygen) addition means such as an aeration pipe 10a.

なお、脱ガス塔6の処理水を下水道放流する場合や、或
いは嫌気性処理槽2及び脱ガス塔6よりなる水処理装置
を中高濃度廃水の前処理ないし中間処理装置として使用
する場合など、脱ガス塔6からの処理水が更に活性汚泥
処理等の好気性処理に付されるときには、この後処理装
置10は不要である。
In addition, when the treated water from the degassing tower 6 is discharged into the sewer system, or when the water treatment device consisting of the anaerobic treatment tank 2 and the degassing tower 6 is used as a pre-treatment or intermediate treatment device for medium-high concentration wastewater, degassing is necessary. When the treated water from the gas tower 6 is further subjected to aerobic treatment such as activated sludge treatment, this post-treatment device 10 is not necessary.

本発明の水処理装置を運転するに際し、脱ガス塔6内の
圧力が低いほどガス化する効率は向上するが、0 、 
5 k g / c rr?(380t o r r 
)程度の減圧度でも充分である。なお、大気圧に近い圧
力で運転する場合には、脱ガス塔内における処理水の滞
留時間を長くすることにより脱ガスを充分に行うことが
できる。
When operating the water treatment apparatus of the present invention, the lower the pressure inside the degassing tower 6, the higher the gasification efficiency.
5kg/crr? (380t o r r
) is sufficient. Note that when operating at a pressure close to atmospheric pressure, sufficient degassing can be achieved by lengthening the residence time of the treated water in the degassing tower.

脱ガス塔6内に導入する嫌気性処理水は、通常、中性も
しくはその近傍のpHを有しているのであるが、特にp
Hを低下させてから脱ガス塔内に導入する必要はない。
The anaerobically treated water introduced into the degassing tower 6 usually has a pH of neutral or around it, but in particular it has a pH of neutral or around it.
There is no need to reduce H before introducing it into the degassing column.

ただし、この脱ガス塔に導入する嫌気性処理水のpHを
酸性域とすることにより該脱ガス塔内におけるガス化の
効率は向上する。
However, by setting the pH of the anaerobically treated water introduced into the degassing tower into an acidic range, the efficiency of gasification within the degassing tower is improved.

以下に、嫌気性処理水が本発明の如き脱ガス手段により
効率よく還元性硫化物を除去できることについて実験例
を挙げて説明する。
Hereinafter, the ability to efficiently remove reducible sulfides from anaerobically treated water by the degassing means of the present invention will be explained with reference to experimental examples.

直径65mm、高さ800mmのカラム内に、%B“ラ
シリング(市販品)を1.43u充填し、カラム内圧力
を減圧ポンプにより360torrに調整した。カラム
内に硫化ソーダを用いpHを7.0に調整したHS−濃
度として43〜122mg/uの合成嫌気性処理水を、
カラム内滞留時間(HRT)1.5〜2.OHrで、−
過式で散水し、カラム処理水のHS″″濃度、減圧ポン
プ排ガス中のH2S1度を測定した。結果を表−1に示
す。
A column with a diameter of 65 mm and a height of 800 mm was filled with 1.43 u of %B "Rashiring (commercial product), and the pressure inside the column was adjusted to 360 torr using a vacuum pump. Sodium sulfide was used in the column to adjust the pH to 7.0. Synthetic anaerobically treated water with an HS concentration of 43 to 122 mg/u adjusted to
Column residence time (HRT) 1.5-2. In OHr, -
Water was sprinkled using a filter method, and the HS″″ concentration in the column-treated water and the H2S concentration in the vacuum pump exhaust gas were measured. The results are shown in Table-1.

表−1減圧ストリッピング結果 表−1よりHRT2.OHrの条件では、HS−はほぼ
完全に水中から除去されることが認められる。
Table-1 Results of vacuum stripping From Table-1, HRT2. It is observed that under OHr conditions, HS- is almost completely removed from water.

比較例として、ベギュアトアを主とする硫黄酸化細菌を
生育させたカラム内をpH7,0に調整したHS−濃度
80〜110mg/uの合成嫌気性処理水をカラム内空
塔HRT1.8Hrで空気と共に流下させた。その結果
、カラムI;A埋水のHs −濃度は0.1mg/fL
以下であるが、カラム内に蓄積するS量(s Oとして
析出した量と、イオウ細菌の菌体中に含まれた3 m 
)が流入smの50%程度となり、カラムの閉寒を生じ
た。この方法では、頻繁にカラム内を洗浄しなければ、
連続運転ができなかった。
As a comparative example, synthetic anaerobic treated water with an HS concentration of 80 to 110 mg/u, which was adjusted to pH 7.0 in a column in which sulfur-oxidizing bacteria, mainly Beguatoa, were grown, was mixed with air at a column HRT of 1.8 Hr. I let it flow down. As a result, the Hs concentration in column I; A buried water was 0.1 mg/fL.
The amount of S accumulated in the column (the amount precipitated as sO) and the amount of sulfur contained in the cells of the sulfur bacteria are as follows.
) was about 50% of the inflow sm, causing the column to freeze. With this method, unless you wash the column frequently,
Continuous operation was not possible.

[発明の効果] 以上の通り、本発明の水処理装2によれは、還元性硫化
物が十分に除去された処理水が得られる。この還元性硫
化物を除去するに際しては、特別な薬品(例えば過酸化
物等)が不要であり、また処理すべき排ガス量も少ない
ので、ランニングコストが低い。また、凝集剤等も不要
であり、1疑集スラツジが発生せず、かつ硫黄酸化菌の
増ン直による処理水流通系統の閉塞もないので、装置の
保守、管理が容易である。
[Effects of the Invention] As described above, with the water treatment device 2 of the present invention, treated water from which reducible sulfides have been sufficiently removed can be obtained. When removing this reducible sulfide, no special chemicals (for example, peroxide, etc.) are required, and the amount of exhaust gas to be treated is small, so running costs are low. In addition, there is no need for a flocculant, no sludge is generated, and there is no blockage of the treated water distribution system due to the proliferation of sulfur-oxidizing bacteria, making the equipment easy to maintain and manage.

本発明の水処理装置によれば、還元性硫化物のほかにア
ンモニア等も除去することができ、また排ガス中からメ
タンや硫黄等の有価物を回収することもできる。
According to the water treatment apparatus of the present invention, ammonia and the like can be removed in addition to reducible sulfides, and valuable substances such as methane and sulfur can also be recovered from exhaust gas.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例に係る水処理装置の構成を示す
系統図である。 2・・・嫌気性処理槽、   4.8・・・水封槽、6
・・・脱ガス塔、     10・・・後処理装置、1
1・・・減圧ポンプ、   13・・・脱硫製蓋。 代理人  弁理士  重 で  剛 沼纜亜〈
FIG. 1 is a system diagram showing the configuration of a water treatment apparatus according to an embodiment of the present invention. 2... Anaerobic treatment tank, 4.8... Water sealing tank, 6
... Degassing tower, 10 ... After-treatment device, 1
1...Reducing pump, 13...Desulfurization lid. Agent: Patent Attorney Shige, Gounuma Mina

Claims (5)

【特許請求の範囲】[Claims] (1)有機性物質を含有する被処理水を導入して嫌気性
処理する嫌気性処理手段と、 減圧手段とを備えており、該嫌気性処理手段からの処理
液を導入して脱ガス処理する脱ガス手段と、 を有する水処理装置。
(1) Equipped with an anaerobic treatment means that introduces water to be treated containing organic substances for anaerobic treatment, and a depressurization means, and introduces the treatment liquid from the anaerobic treatment means for degassing treatment. A water treatment device comprising: a degassing means for degassing;
(2)前記脱ガス手段からの排ガスが導入される脱硫装
置を有する特許請求の範囲第1項に記載の水処理装置。
(2) The water treatment device according to claim 1, further comprising a desulfurization device into which exhaust gas from the degassing means is introduced.
(3)前記嫌気性処理手段からの消化ガス及び脱ガス手
段からの排ガスが導入される脱硫装置を有する特許請求
の範囲第1項に記載の水処理装置。
(3) The water treatment apparatus according to claim 1, further comprising a desulfurization device into which the digestion gas from the anaerobic treatment means and the exhaust gas from the degassing means are introduced.
(4)前記脱ガス手段からの処理液を導入して好気性処
理する好気性処理手段を有する特許請求の範囲第1項な
いし第3項のいずれか1項に記載の水処理装置。
(4) The water treatment apparatus according to any one of claims 1 to 3, further comprising an aerobic treatment means for introducing the treatment liquid from the degassing means and subjecting it to aerobic treatment.
(5)前記脱ガス手段に導入される嫌気性処理水に、p
H調整剤を添加する手段を設けた特許請求の範囲第1項
ないし第4項のいずれか1項に記載の水処理装置。
(5) In the anaerobically treated water introduced into the degassing means, p
The water treatment device according to any one of claims 1 to 4, further comprising means for adding an H regulator.
JP61196807A 1986-08-22 1986-08-22 Water treating system Pending JPS6351995A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61196807A JPS6351995A (en) 1986-08-22 1986-08-22 Water treating system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61196807A JPS6351995A (en) 1986-08-22 1986-08-22 Water treating system

Publications (1)

Publication Number Publication Date
JPS6351995A true JPS6351995A (en) 1988-03-05

Family

ID=16363974

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61196807A Pending JPS6351995A (en) 1986-08-22 1986-08-22 Water treating system

Country Status (1)

Country Link
JP (1) JPS6351995A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04176392A (en) * 1990-11-08 1992-06-24 Ishikawajima Harima Heavy Ind Co Ltd Treating equipment for anaerobic waste water
JP2008168264A (en) * 2007-01-15 2008-07-24 Kazuaki Tamatsubo Method of and apparatus for recovering dissolved methane

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04176392A (en) * 1990-11-08 1992-06-24 Ishikawajima Harima Heavy Ind Co Ltd Treating equipment for anaerobic waste water
JP2008168264A (en) * 2007-01-15 2008-07-24 Kazuaki Tamatsubo Method of and apparatus for recovering dissolved methane

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