JPS63500187A - 溶融塩浴での電解により遷移金属の粉末を製造する方法 - Google Patents
溶融塩浴での電解により遷移金属の粉末を製造する方法Info
- Publication number
- JPS63500187A JPS63500187A JP62500612A JP50061287A JPS63500187A JP S63500187 A JPS63500187 A JP S63500187A JP 62500612 A JP62500612 A JP 62500612A JP 50061287 A JP50061287 A JP 50061287A JP S63500187 A JPS63500187 A JP S63500187A
- Authority
- JP
- Japan
- Prior art keywords
- metal
- voltage
- salt bath
- electrolysis
- transition metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title claims description 13
- 150000003839 salts Chemical class 0.000 title claims description 9
- 238000005868 electrolysis reaction Methods 0.000 title claims description 8
- 229910052723 transition metal Inorganic materials 0.000 title claims description 8
- 150000003624 transition metals Chemical class 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000000034 method Methods 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 230000008021 deposition Effects 0.000 claims description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000004820 halides Chemical class 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 229910001507 metal halide Inorganic materials 0.000 claims description 3
- 150000005309 metal halides Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 2
- 229910001508 alkali metal halide Inorganic materials 0.000 claims 1
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 claims 1
- 239000008139 complexing agent Substances 0.000 claims 1
- 150000002221 fluorine Chemical class 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 229910052719 titanium Inorganic materials 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 6
- 210000001787 dendrite Anatomy 0.000 description 4
- 229910052735 hafnium Inorganic materials 0.000 description 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000004663 powder metallurgy Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 1
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001595 flow curve Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C5/00—Electrolytic production, recovery or refining of metal powders or porous metal masses
- C25C5/04—Electrolytic production, recovery or refining of metal powders or porous metal masses from melts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Length Measuring Devices By Optical Means (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR86/00390 | 1986-01-06 | ||
| FR8600390A FR2592664B1 (fr) | 1986-01-06 | 1986-01-06 | Procede d'elaboration de poudres de metaux de transition par electrolyse en bains de sels fondus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63500187A true JPS63500187A (ja) | 1988-01-21 |
| JPH0312156B2 JPH0312156B2 (enExample) | 1991-02-19 |
Family
ID=9331054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62500612A Granted JPS63500187A (ja) | 1986-01-06 | 1987-01-05 | 溶融塩浴での電解により遷移金属の粉末を製造する方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4770750A (enExample) |
| EP (1) | EP0253841B1 (enExample) |
| JP (1) | JPS63500187A (enExample) |
| CA (1) | CA1287814C (enExample) |
| DE (1) | DE3762890D1 (enExample) |
| FR (1) | FR2592664B1 (enExample) |
| WO (1) | WO1987004193A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005111272A1 (ja) * | 2004-04-06 | 2005-11-24 | Iox Co., Ltd. | プラズマ誘起電解による微粒子の製造方法 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991001942A1 (en) * | 1989-08-01 | 1991-02-21 | Australian Copper Company Pty. Ltd. | Production of copper compounds |
| WO2001062995A1 (en) * | 2000-02-22 | 2001-08-30 | Qinetiq Limited | Method for the manufacture of metal foams by electrolytic reduction of porous oxidic preforms |
| PL377451A1 (pl) * | 2005-10-05 | 2007-04-16 | Instytut Wysokich Ciśnień PAN | Sposób prowadzenia reakcji i reaktor chemiczny |
| EP3561091A1 (en) | 2011-12-22 | 2019-10-30 | Universal Achemetal Titanium, LLC | A method for extraction and refining of titanium |
| CA3047102C (en) | 2016-09-14 | 2023-12-05 | Universal Achemetal Titanium, Llc | A method for producing titanium-aluminum-vanadium alloy |
| RU2763465C2 (ru) | 2017-01-13 | 2021-12-29 | ЮНИВЕРСАЛ АКЕМЕТАЛ ТИТАНИУМ, ЭлЭлСи | Титановая лигатура для сплавов на основе ti-al |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1265427A (fr) * | 1960-06-03 | 1961-06-30 | Ciba Geigy | Procédé d'élaboration électrolytique des métaux niobium et tantale |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2951021A (en) * | 1952-03-28 | 1960-08-30 | Nat Res Corp | Electrolytic production of titanium |
| GB736567A (en) * | 1952-07-03 | 1955-09-07 | Horizons Titanium Corp | Improvements in production of metallic titanium |
-
1986
- 1986-01-06 FR FR8600390A patent/FR2592664B1/fr not_active Expired - Fee Related
-
1987
- 1987-01-05 JP JP62500612A patent/JPS63500187A/ja active Granted
- 1987-01-05 US US07/099,317 patent/US4770750A/en not_active Expired - Fee Related
- 1987-01-05 WO PCT/FR1987/000001 patent/WO1987004193A1/fr not_active Ceased
- 1987-01-05 DE DE8787900658T patent/DE3762890D1/de not_active Expired - Fee Related
- 1987-01-05 EP EP87900658A patent/EP0253841B1/fr not_active Expired - Lifetime
- 1987-01-05 CA CA000526634A patent/CA1287814C/fr not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1265427A (fr) * | 1960-06-03 | 1961-06-30 | Ciba Geigy | Procédé d'élaboration électrolytique des métaux niobium et tantale |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005111272A1 (ja) * | 2004-04-06 | 2005-11-24 | Iox Co., Ltd. | プラズマ誘起電解による微粒子の製造方法 |
| JPWO2005111272A1 (ja) * | 2004-04-06 | 2008-03-27 | 株式会社イオックス | プラズマ誘起電解による微粒子の製造方法 |
| JP4688796B2 (ja) * | 2004-04-06 | 2011-05-25 | 株式会社イオックス | プラズマ誘起電解による微粒子の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1287814C (fr) | 1991-08-20 |
| FR2592664A1 (fr) | 1987-07-10 |
| FR2592664B1 (fr) | 1990-03-30 |
| US4770750A (en) | 1988-09-13 |
| WO1987004193A1 (fr) | 1987-07-16 |
| EP0253841A1 (fr) | 1988-01-27 |
| JPH0312156B2 (enExample) | 1991-02-19 |
| EP0253841B1 (fr) | 1990-05-23 |
| DE3762890D1 (de) | 1990-06-28 |
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