JPS6330399B2 - - Google Patents
Info
- Publication number
- JPS6330399B2 JPS6330399B2 JP60272688A JP27268885A JPS6330399B2 JP S6330399 B2 JPS6330399 B2 JP S6330399B2 JP 60272688 A JP60272688 A JP 60272688A JP 27268885 A JP27268885 A JP 27268885A JP S6330399 B2 JPS6330399 B2 JP S6330399B2
- Authority
- JP
- Japan
- Prior art keywords
- electrolytic
- electrolytic fluorination
- reaction
- weight
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000003682 fluorination reaction Methods 0.000 claims description 20
- -1 aliphatic tertiary amine Chemical class 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 150000003464 sulfur compounds Chemical class 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 18
- 239000000047 product Substances 0.000 description 15
- 239000011541 reaction mixture Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- RVZRBWKZFJCCIB-UHFFFAOYSA-N perfluorotributylamine Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RVZRBWKZFJCCIB-UHFFFAOYSA-N 0.000 description 5
- 239000012261 resinous substance Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 125000005360 alkyl sulfoxide group Chemical group 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 3
- MMCXKYPKYQMCRM-UHFFFAOYSA-N 2-methyl-3,4,4a,5,6,7,8,8a-octahydro-1h-isoquinoline Chemical compound C1CCCC2CN(C)CCC21 MMCXKYPKYQMCRM-UHFFFAOYSA-N 0.000 description 2
- CMJLMPKFQPJDKP-UHFFFAOYSA-N 3-methylthiolane 1,1-dioxide Chemical compound CC1CCS(=O)(=O)C1 CMJLMPKFQPJDKP-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- NJBCRXCAPCODGX-UHFFFAOYSA-N 2-methyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CNCC(C)C NJBCRXCAPCODGX-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 238000005796 dehydrofluorination reaction Methods 0.000 description 1
- 238000004334 fluoridation Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- MRQNKLRMROXHTI-UHFFFAOYSA-N perfluoro-N-methyldecahydroisoquinoline Chemical compound FC1(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C(F)(F)N(C(F)(F)F)C(F)(F)C(F)(F)C21F MRQNKLRMROXHTI-UHFFFAOYSA-N 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60272688A JPS62133094A (ja) | 1985-12-04 | 1985-12-04 | 電解フツ素化方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60272688A JPS62133094A (ja) | 1985-12-04 | 1985-12-04 | 電解フツ素化方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62133094A JPS62133094A (ja) | 1987-06-16 |
| JPS6330399B2 true JPS6330399B2 (de) | 1988-06-17 |
Family
ID=17517407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60272688A Granted JPS62133094A (ja) | 1985-12-04 | 1985-12-04 | 電解フツ素化方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62133094A (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01136198U (de) * | 1988-02-29 | 1989-09-18 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62224690A (ja) * | 1986-03-26 | 1987-10-02 | Dainippon Ink & Chem Inc | 有機化合物の電気化学的フツ素化法 |
| JP2584825B2 (ja) * | 1988-05-10 | 1997-02-26 | 株式会社トクヤマ | 電解フッ素化方法 |
-
1985
- 1985-12-04 JP JP60272688A patent/JPS62133094A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01136198U (de) * | 1988-02-29 | 1989-09-18 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62133094A (ja) | 1987-06-16 |
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