JPS63300924A - Thermoelectric thermometer - Google Patents

Thermoelectric thermometer

Info

Publication number
JPS63300924A
JPS63300924A JP13630287A JP13630287A JPS63300924A JP S63300924 A JPS63300924 A JP S63300924A JP 13630287 A JP13630287 A JP 13630287A JP 13630287 A JP13630287 A JP 13630287A JP S63300924 A JPS63300924 A JP S63300924A
Authority
JP
Japan
Prior art keywords
pipe
thermocouple
inner tube
oxidizing atmosphere
outer tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13630287A
Other languages
Japanese (ja)
Inventor
Shuichi Matsuda
秀一 松田
Hiroyuki Ishizuka
石塚 洋幸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP13630287A priority Critical patent/JPS63300924A/en
Publication of JPS63300924A publication Critical patent/JPS63300924A/en
Pending legal-status Critical Current

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  • Measuring Temperature Or Quantity Of Heat (AREA)

Abstract

PURPOSE:To obtain a thermoelectric thermometer which is usable under temperature conditions of >=1,800 deg.C in a nonoxidizing and an oxidizing atmosphere by protecting a thermocouple with a high fusion point by an inside pipe made of metal with a high fusion point. CONSTITUTION:This thermometer is provided with an outside pipe 1 made of airtight ceramics which has superior heat resistance in a high-temperature oxidizing atmosphere, the inside pipe 2 made of high-fusion-point metal provided inside the pipe 1, and a thermocouple element 5. Those are made of materials which are not fused even at >=1,800 deg.C, the thermocouple 5 is protected by the inside pipe 2 through a heat-resistant insulator 7, and the inside pipe 2 reacts on neither the thermocouple 5 nor the insulator 7. Further, the inside pipe 2 is surrounded with the outside pipe 1 and shielded from an external oxidizing atmosphere, and the outside pipe 1 never loses its airtightness even in the oxidizing atmosphere of >=1,800 deg.C. Further, the ceramics which forms the outside pipe 1 inhibits outside air from penetrating the outside pipe 1 and enters the pipe. Consequently, the inside pipe 2 is protected by the outside pipe 1.

Description

【発明の詳細な説明】 〔発明の目的〕 (産業上の利用分野) 本発明は熱電温度計に関する。[Detailed description of the invention] [Purpose of the invention] (Industrial application field) The present invention relates to thermocouple thermometers.

(従来の技術) 熱電温度J1は、熱電対を利用して、その一端を一定温
度に保持し、他端を測定物に近づけておいて、その温度
差で生じた電力を71111定してnl定物の温度を求
めるものであり、工業分野での温度測定に広く使用され
ている。
(Prior art) Thermocouple temperature J1 is determined by using a thermocouple, keeping one end at a constant temperature, and keeping the other end close to the object to be measured, and then calculating the power generated by the temperature difference by constant 71111nl. It is used to determine the temperature of a constant object, and is widely used for temperature measurement in the industrial field.

例えば原子炉の状態を模擬的に試験する原子炉模擬試験
装置において、模擬燃料棒などの近傍の温度をalll
定するために熱電温度計が使用されている。
For example, in a nuclear reactor simulation test device that simulates the state of a nuclear reactor, the temperature near the simulated fuel rods, etc.
A thermocouple thermometer is used to determine the

しかして、前述の原子炉模擬試験装置において模擬燃料
棒の近傍の温度を測定する場合の様に、熱マヒ温度計が
温度測定を行なう場合に使用する雰囲気としては酸化雰
囲気が一般的である。
Therefore, an oxidizing atmosphere is generally used when a thermoparalysis thermometer measures temperature, such as when measuring the temperature near a simulated fuel rod in the above-mentioned nuclear reactor simulation test device.

従来、酸化雰囲気で温度測定するために使用する熱電温
度計には、白金と白金ロジウム合金からなる素子の組合
せからなる熱電対を使用し、この熱電対をそのまま裸で
、あるいは白金などの金属からなる保護管の内部に絶縁
物を介して収納したシース形の構造のものが使用されで
いる。
Conventionally, thermocouples used to measure temperature in oxidizing atmospheres use thermocouples consisting of a combination of elements made of platinum and platinum-rhodium alloys, and these thermocouples can be used as is or made from metals such as platinum. A sheath-shaped structure is used, which is housed inside a protective tube with an insulator interposed therebetween.

(発明が解決しようとする問題点) しかしながら、従来の酸化雰囲気中で使用する熱電温度
計において、熱電対として使用している白金と白金・ロ
ジウム合金系熱電対は融点が1800℃であり、それ以
上の温度では溶融して熱電対として使用できなくなる。
(Problems to be Solved by the Invention) However, in conventional thermocouples used in oxidizing atmospheres, platinum and platinum-rhodium alloy thermocouples used as thermocouples have a melting point of 1800°C; At higher temperatures, it will melt and become unusable as a thermocouple.

すなわち、熱雷温度計が1800℃以上の温度条件下で
は熱電温度計が破損してして使用できなくなる。
That is, under the temperature condition of 1800° C. or higher, the thermocouple thermometer is damaged and becomes unusable.

従って、従来の熱雷温度計では酸化雰囲気中で1800
℃以上の温度を−I11定することができなかった。
Therefore, the conventional thermal lightning thermometer has a temperature of 1800 in an oxidizing atmosphere.
It was not possible to determine the temperature higher than -I11.

本発明は前記事情に基づいてなされたもので、非酸化雰
囲気は勿論のこと酸化雰囲気中にて1800℃以上の温
度条件下での使用が可能な熱電温度計を提供することを
目的とするものである。
The present invention has been made based on the above circumstances, and an object of the present invention is to provide a thermocouple thermometer that can be used not only in a non-oxidizing atmosphere but also in an oxidizing atmosphere at a temperature of 1800°C or higher. It is.

〔発明の構成〕 (問題点を解決するための手段と作用)前記目的を達成
するために本発明の熱電温度計は、高温酸化雰囲気での
耐熱性に優れた気密質のセラミックスからなる外側管と
、この外側管の内部に設けられた高融点金属からなる内
側管と、この内側管の内部に絶縁粉末を介して設けられ
た高融点金属からなる熱雷対素子とを具備してなること
を特徴とするものである。
[Structure of the Invention] (Means and Effects for Solving the Problems) In order to achieve the above object, the thermocouple of the present invention has an outer tube made of airtight ceramics that has excellent heat resistance in a high-temperature oxidizing atmosphere. and an inner tube made of a high-melting point metal provided inside this outer tube, and a thermal lightning pair element made of a high-melting point metal provided inside this inner tube with an insulating powder interposed therebetween. It is characterized by:

すなわち、高融点の熱雷対を高融点金属からなる内側管
で保護し、さらに外側管により1800℃以上の高温下
での外部の酸化雰囲気から内側管を保訛することができ
る。従って、熱電対および内側管を高温下で酸化させる
ことなく使用して温度を測定することができる。
That is, the high melting point thermal lightning pair can be protected by the inner tube made of a high melting point metal, and the outer tube can further protect the inner tube from the external oxidizing atmosphere at a high temperature of 1800° C. or higher. Therefore, thermocouples and inner tubes can be used to measure temperature at high temperatures without oxidation.

(実施例) 以下本発明の実施例を図面について説明する。(Example) Embodiments of the present invention will be described below with reference to the drawings.

第1図ないし第4図は本発明の熱電温度51の一実施例
を示している。
1 to 4 show an embodiment of the thermoelectric temperature 51 of the present invention.

図中1は外側管で、先端が閉塞されている。In the figure, 1 is an outer tube whose tip is closed.

外側管1は高温下での耐熱性に優れた気密質のセラミッ
クスで形成されており、この条件を満たす性質を持った
セラミックスとしてはジルコニア(Zr 02 )が挙
げられる。ジルコニアは温度2100℃においてもタン
グステンなどの金属と反応することがなく、またち密な
組織を有している。この他のセラミックスとしてはべり
リアなどが挙げられる。
The outer tube 1 is made of an airtight ceramic that has excellent heat resistance under high temperatures, and an example of a ceramic that satisfies this condition is zirconia (Zr 02 ). Zirconia does not react with metals such as tungsten even at a temperature of 2100° C. and has a dense structure. Other ceramics include Berria.

なお、外側管1は気密性を高めるために肉厚を0.2r
m以上に設定する。2は内側管で、先端が閉塞されてい
る。内側管2は後述する熱電対および絶縁物と反応しな
い性質の高融点金属で形成されており、この条件を満た
す高融点金属としてはタンタル(Ta ) 、タングス
テン(W)、モリブデン(Mo)などが挙げられる。特
にタンタルは常温での機械加工性が良いので内側管2の
材料として適している。内側管2は前記高融点金属を材
料として粉末冶金法により製作する。この内側管2は外
側管1の内部に軸方向に沿って設けられている。内側管
2の閉塞された先端は外側管1の閉塞された先端の内部
に設けた例えばタングステンからなるストッパ3で支持
され、内側管2の基端は外側管1の開放された基端に嵌
着した例えばジルコシアからなるシール体4を貫通して
外部に延出している。5は熱雷対で、融点が高い金属か
らなる素子を組合わせて構成されている。例えばタング
ステン線からなる素子5aとレニウム入りタングステン
線からなる素子5bとで構成されている。熱電対5は内
側管2の内部に軸方向に沿って設けられており、熱電対
5の先端は内側管2の先端に位置し、熱7u対5の基端
は内側管2の開放した基端に嵌告したシール体6を貫通
して外部に延出している。内側管1の内部には耐熱性絶
縁物7としてベリリア(Be O)粉末などの耐熱絶縁
粉末が充填しである。これにより熱電対5は内側管2に
対して電気的に絶縁されている。
In addition, the outer tube 1 has a wall thickness of 0.2r to improve airtightness.
Set to m or more. 2 is an inner tube whose tip is closed. The inner tube 2 is made of a high melting point metal that does not react with thermocouples and insulators, which will be described later. Examples of high melting point metals that meet this condition include tantalum (Ta), tungsten (W), and molybdenum (Mo). Can be mentioned. In particular, tantalum is suitable as a material for the inner tube 2 because it has good machinability at room temperature. The inner tube 2 is manufactured by powder metallurgy using the above-mentioned high melting point metal. This inner tube 2 is provided inside the outer tube 1 along the axial direction. The closed end of the inner tube 2 is supported by a stopper 3 made of tungsten, for example, provided inside the closed end of the outer tube 1, and the proximal end of the inner tube 2 is fitted into the open proximal end of the outer tube 1. The seal body 4 is made of, for example, zirconia and extends to the outside. 5 is a thermal lightning pair, which is constructed by combining elements made of a metal with a high melting point. For example, it is composed of an element 5a made of a tungsten wire and an element 5b made of a tungsten wire containing rhenium. The thermocouple 5 is provided inside the inner tube 2 along the axial direction, the tip of the thermocouple 5 is located at the tip of the inner tube 2, and the base end of the thermocouple 5 is located at the open base of the inner tube 2. It extends outside through a seal body 6 fitted on the end. The inside of the inner tube 1 is filled with a heat-resistant insulating powder such as beryllia (Be 2 O) powder as a heat-resistant insulating material 7 . Thereby, the thermocouple 5 is electrically insulated from the inner tube 2.

さらに外側管1と内側管2との間には空隙部が形成され
、この空隙部はアルゴンガスなどの不活性ガスが封入さ
れて非酸化雰囲気とされており、さらにこの空隙部には
内側管2の外周面に巻装したタングステンなどの高融点
金属からなるコイル8が設けである。゛このコイル8は
内側管2を外側管1の内周面に接触しないように支持す
る役目をなすものである。
Furthermore, a gap is formed between the outer tube 1 and the inner tube 2, and this gap is filled with an inert gas such as argon gas to create a non-oxidizing atmosphere. A coil 8 made of a high melting point metal such as tungsten is wound around the outer peripheral surface of the coil 2 . ``This coil 8 serves to support the inner tube 2 so that it does not come into contact with the inner peripheral surface of the outer tube 1.

なお、内側管2から延出しだ熱電対5の基端は補償導線
9に接続しである。
Note that the base end of the thermocouple 5 extending from the inner tube 2 is connected to the compensation conductor 9.

この様に構成された熱雷温度計は外側管1の先端すなわ
ち熱電対5の先端がΔ−1定物の近傍に位置するように
して設置し、補償導線9を図示しない′計測器に接続す
る。そして、測定物の温度に応じて熱電対5の素子5a
、5bの間に生じる起電力を測定してtP1定物の温度
を求める。
The thermometer constructed in this way is installed so that the tip of the outer tube 1, that is, the tip of the thermocouple 5, is located near the Δ-1 constant, and the compensation lead 9 is connected to a measuring instrument (not shown). do. The element 5a of the thermocouple 5 is then
, 5b is measured to determine the temperature of the tP1 constant.

しかして、この熱雷温度計において、熱電対5はタング
ステン(融点3410℃)とレニウム入りタングステン
(融点2800℃)からなる素子5a、5bを用いたも
のであるから、1800℃以上の高い温度の下でも溶融
することなく温度を測定することができる。この熱電対
5は耐熱性絶縁物7を介して内側管2で保護されている
。内側管2は例えばタンタルで形成されているので18
00℃以上の高温においても溶融することがなく、しか
も内側管2は熱電対5と耐熱性絶縁物7と反応すること
がない。さらに、内側管2は外側管1で囲まれ外部の酸
化雰囲気から遮断されて直接さらされることがない。外
側管1は例えばジルコニアで形成されているので、外部
が1800℃以上の高い温度下の酸化雰囲気であっても
気密性が損われることがなく溶融することもない。しか
も、外側管1を形成するセラミックスは気密質であるか
ら外部の空気が外側管1を透過して管内部に浸入するこ
とがない。これにより内側管2は外側管1により保護さ
れる。なお、ジルコニアからなる外側管1とタンタルか
らなる内側管2とは1800℃以上の温度で相互に反応
するので、両者の間に空隙部を形成し、この空隙部に内
側管2と反応しないタングステンなどからなるコイル8
で内側管2を外側管1に接触しないように支持している
。また、内側管2と外側管1との間の空隙部を非酸化雰
囲気として内側管2の酸化を防止している。従って、こ
れらの構成の組合わせにより熱電対5および内側管2が
1800℃以上の高温下での酸化雰囲気から保護して酸
化を防止できる。
In this thermal lightning thermometer, the thermocouple 5 uses elements 5a and 5b made of tungsten (melting point 3410°C) and rhenium-containing tungsten (melting point 2800°C), so it can withstand high temperatures of 1800°C or higher. Temperature can be measured even at low temperatures without melting. This thermocouple 5 is protected by an inner tube 2 via a heat-resistant insulator 7. Since the inner tube 2 is made of tantalum, for example, 18
It does not melt even at high temperatures of 00° C. or higher, and the inner tube 2 does not react with the thermocouple 5 and the heat-resistant insulator 7. Furthermore, the inner tube 2 is surrounded by the outer tube 1 and is shielded from the external oxidizing atmosphere so that it is not directly exposed to it. Since the outer tube 1 is made of zirconia, for example, even if the outside is in an oxidizing atmosphere at a high temperature of 1800° C. or higher, the airtightness will not be impaired and it will not melt. Moreover, since the ceramic forming the outer tube 1 is airtight, external air does not pass through the outer tube 1 and enter the inside of the tube. The inner tube 2 is thereby protected by the outer tube 1. Note that since the outer tube 1 made of zirconia and the inner tube 2 made of tantalum react with each other at temperatures above 1800°C, a gap is formed between them, and tungsten, which does not react with the inner tube 2, is inserted into this gap. Coil 8 consisting of
The inner tube 2 is supported so as not to come into contact with the outer tube 1. Further, the gap between the inner tube 2 and the outer tube 1 is made into a non-oxidizing atmosphere to prevent the inner tube 2 from being oxidized. Therefore, by combining these structures, the thermocouple 5 and the inner tube 2 can be protected from an oxidizing atmosphere at a high temperature of 1800° C. or higher, thereby preventing oxidation.

このため、この熱電温度計は1800℃以上の高温下で
の酸化雰囲気中に設けて使用し測定物の温度をaに1定
することができる。具体的には酸化雰囲気の中で230
0℃までの温度を測定することができる。例えば原子炉
模擬試験装置において模擬燃料棒の近傍の温度は180
0℃以上であるが、この場所の温度もδ−1定すること
が可能である。また、酸化雰囲気に限らず非酸化雰囲気
での温度測定にも使用することができる。
Therefore, this thermocouple thermometer can be used by being installed in an oxidizing atmosphere at a high temperature of 1800° C. or higher, and the temperature of the object to be measured can be fixed at a. Specifically, 230 in an oxidizing atmosphere.
Temperatures down to 0°C can be measured. For example, in a nuclear reactor simulation test device, the temperature near the simulated fuel rods is 180℃.
Although it is 0°C or higher, the temperature at this location can also be fixed by δ-1. Furthermore, it can be used for temperature measurement not only in an oxidizing atmosphere but also in a non-oxidizing atmosphere.

なお、外側管1の内部で内側管2を支持する支持部材は
実施例のものに限定されず、他のものでもよい。例えば
耐熱性絶縁粉末を使用してもよい。
Note that the support member that supports the inner tube 2 inside the outer tube 1 is not limited to that of the embodiment, and may be of other types. For example, heat-resistant insulating powder may be used.

また、内側管2を形成する高融点金属が外側管1を形成
するセラミックスと反応しないものであれば、外側管1
と内側管2とを直接接触して設けてもよい。
In addition, if the high melting point metal forming the inner tube 2 does not react with the ceramic forming the outer tube 1, the outer tube 1
and the inner tube 2 may be provided in direct contact with each other.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明の熱電温度計によれば、高温
下での酸化雰囲気における酸化の問題を解決して温度の
測定が可能であり、従来困難であった温度Δ−1定範囲
と温度測定分野を拡大することができる。
As explained above, according to the thermocouple thermometer of the present invention, it is possible to measure temperature by solving the problem of oxidation in an oxidizing atmosphere at high temperatures. The field of measurement can be expanded.

【図面の簡単な説明】[Brief explanation of drawings]

第1図ないし第4図は本発明の熱雷温度計の一実施例を
示し、第1図は軸方向に沿う断面図、第2図は第1図A
部の拡大断面図、第3図は第1図B部の拡大断面図、第
4図は第1図C部の拡大断面図である。 1・・・外側管、2・・・内側管、5・・・熱電対、7
・・・耐熱性絶縁物、8・・・コイルばね。
1 to 4 show an embodiment of the thermal lightning thermometer of the present invention, FIG. 1 is a cross-sectional view along the axial direction, and FIG. 2 is a cross-sectional view along the axial direction.
FIG. 3 is an enlarged sectional view of section B in FIG. 1, and FIG. 4 is an enlarged sectional view of section C in FIG. 1...Outer tube, 2...Inner tube, 5...Thermocouple, 7
...Heat-resistant insulator, 8...Coil spring.

Claims (3)

【特許請求の範囲】[Claims] (1)高温酸化雰囲気での耐熱性に優れた気密質のセラ
ミックスからなる外側管と、この外側管の内部に設けら
れた高融点金属からなる内側管と、この内側管の内部に
絶縁粉末を介して設けられた高融点金属からなる熱電対
素子とを具備してなることを特徴とする熱電温度計。
(1) An outer tube made of airtight ceramics with excellent heat resistance in high-temperature oxidizing atmospheres, an inner tube made of high-melting point metal installed inside this outer tube, and an insulating powder inside the inner tube. 1. A thermocouple thermometer comprising: a thermocouple element made of a high melting point metal;
(2)外側管を形成するセラミックスはジルコニアであ
る特許請求の範囲第1項記載の熱電温度計。
(2) The thermocouple according to claim 1, wherein the ceramic forming the outer tube is zirconia.
(3)外側管と前記内側管との間に空隙部が形成され、
この空隙部は非酸化雰囲気とされ、この空隙部には前記
内側管を前記外側管と接触しない状態で支持する支持体
を設けてなる特許請求の範囲第1項または第2項記載の
熱電温度計。
(3) a gap is formed between the outer tube and the inner tube;
The thermoelectric temperature according to claim 1 or 2, wherein the void is in a non-oxidizing atmosphere, and the void is provided with a support that supports the inner tube without contacting the outer tube. Total.
JP13630287A 1987-05-30 1987-05-30 Thermoelectric thermometer Pending JPS63300924A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13630287A JPS63300924A (en) 1987-05-30 1987-05-30 Thermoelectric thermometer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13630287A JPS63300924A (en) 1987-05-30 1987-05-30 Thermoelectric thermometer

Publications (1)

Publication Number Publication Date
JPS63300924A true JPS63300924A (en) 1988-12-08

Family

ID=15172011

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13630287A Pending JPS63300924A (en) 1987-05-30 1987-05-30 Thermoelectric thermometer

Country Status (1)

Country Link
JP (1) JPS63300924A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02146334U (en) * 1989-05-16 1990-12-12
JP2000088668A (en) * 1998-09-16 2000-03-31 Isuzu Ceramics Res Inst Co Ltd Thermocouple
JP2006170692A (en) * 2004-12-14 2006-06-29 Toho Titanium Co Ltd Thermometer for measuring temperature in chlorination furnace
US7080941B1 (en) * 2001-11-13 2006-07-25 Lam Research Corporation Temperature sensing system for temperature measurement in a high radio frequency environment
WO2015020172A1 (en) * 2013-08-08 2015-02-12 株式会社フルヤ金属 Thermometer

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JPS52102080A (en) * 1976-02-20 1977-08-26 Yamari Trading Method of producing special thermocouple
JPS52131776A (en) * 1976-04-28 1977-11-04 Nisshin Steel Co Ltd Terminal for measuring temperature
JPS53107378A (en) * 1977-03-01 1978-09-19 Toshiba Ceramics Co Protection tubing for measuring temperature of melting metal continuously and method for manufacturing said tubing
JPS5345072B2 (en) * 1973-07-06 1978-12-04
JPS57101730A (en) * 1980-12-17 1982-06-24 Sumitomo Alum Smelt Co Ltd Protecting tube for measuring temperature of fused salt bath
JPS5914036B2 (en) * 1977-05-30 1984-04-02 カネボウ株式会社 New method for producing rifamycin SV derivatives
JPS60198423A (en) * 1984-03-21 1985-10-07 Kawasaki Steel Corp Instrument for measuring temperature of molten metal

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JPS5345072B2 (en) * 1973-07-06 1978-12-04
JPS52102080A (en) * 1976-02-20 1977-08-26 Yamari Trading Method of producing special thermocouple
JPS52131776A (en) * 1976-04-28 1977-11-04 Nisshin Steel Co Ltd Terminal for measuring temperature
JPS53107378A (en) * 1977-03-01 1978-09-19 Toshiba Ceramics Co Protection tubing for measuring temperature of melting metal continuously and method for manufacturing said tubing
JPS5914036B2 (en) * 1977-05-30 1984-04-02 カネボウ株式会社 New method for producing rifamycin SV derivatives
JPS57101730A (en) * 1980-12-17 1982-06-24 Sumitomo Alum Smelt Co Ltd Protecting tube for measuring temperature of fused salt bath
JPS60198423A (en) * 1984-03-21 1985-10-07 Kawasaki Steel Corp Instrument for measuring temperature of molten metal

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02146334U (en) * 1989-05-16 1990-12-12
JP2000088668A (en) * 1998-09-16 2000-03-31 Isuzu Ceramics Res Inst Co Ltd Thermocouple
US7080941B1 (en) * 2001-11-13 2006-07-25 Lam Research Corporation Temperature sensing system for temperature measurement in a high radio frequency environment
JP2006170692A (en) * 2004-12-14 2006-06-29 Toho Titanium Co Ltd Thermometer for measuring temperature in chlorination furnace
WO2015020172A1 (en) * 2013-08-08 2015-02-12 株式会社フルヤ金属 Thermometer
JPWO2015020172A1 (en) * 2013-08-08 2017-03-02 株式会社フルヤ金属 thermometer
EP3032231B1 (en) * 2013-08-08 2018-12-19 Furuya Metal Co., Ltd. Thermometer
US10215646B2 (en) 2013-08-08 2019-02-26 Furuya Metal Co., Ltd. Thermometer
US10215645B2 (en) 2013-08-08 2019-02-26 Furuya Metal Co., Ltd. Thermometer

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