JPS6327409A - Multilayer type cosmetic - Google Patents
Multilayer type cosmeticInfo
- Publication number
- JPS6327409A JPS6327409A JP16955186A JP16955186A JPS6327409A JP S6327409 A JPS6327409 A JP S6327409A JP 16955186 A JP16955186 A JP 16955186A JP 16955186 A JP16955186 A JP 16955186A JP S6327409 A JPS6327409 A JP S6327409A
- Authority
- JP
- Japan
- Prior art keywords
- water
- alkyl phenyl
- layer
- phenyl ether
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 125000005037 alkyl phenyl group Chemical group 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 8
- 229920000223 polyglycerol Polymers 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 abstract description 10
- 235000002639 sodium chloride Nutrition 0.000 abstract description 9
- 239000003921 oil Substances 0.000 abstract description 6
- 235000019198 oils Nutrition 0.000 abstract description 6
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 abstract description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 4
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 abstract description 3
- 229940032094 squalane Drugs 0.000 abstract description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract description 2
- 235000019341 magnesium sulphate Nutrition 0.000 abstract description 2
- 239000004006 olive oil Substances 0.000 abstract description 2
- 235000008390 olive oil Nutrition 0.000 abstract description 2
- 239000011780 sodium chloride Substances 0.000 abstract description 2
- 229940074404 sodium succinate Drugs 0.000 abstract description 2
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- -1 polyoxyethylene Polymers 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000006210 lotion Substances 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 235000012730 carminic acid Nutrition 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 2
- 235000019799 monosodium phosphate Nutrition 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- 239000001540 sodium lactate Substances 0.000 description 2
- 235000011088 sodium lactate Nutrition 0.000 description 2
- 229940005581 sodium lactate Drugs 0.000 description 2
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 2
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 2
- 150000003712 vitamin E derivatives Chemical class 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 244000280244 Luffa acutangula Species 0.000 description 1
- 235000009814 Luffa aegyptiaca Nutrition 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- YAGMLECKUBJRNO-UHFFFAOYSA-N octyl 4-(dimethylamino)benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=C(N(C)C)C=C1 YAGMLECKUBJRNO-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 235000019265 sodium DL-malate Nutrition 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 239000001394 sodium malate Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/03—Liquid compositions with two or more distinct layers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/002—Aftershave preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、ポリグリセリンアルキルフェニルエーテル型
の界面活性剤を含有することにより形成される新規な多
層型化粧料に関し、更に詳しくは油層及び水層が透明、
且つ両層の界面に活性剤層が存在せずくっきりと二層に
分離するという外観、及び使用時に軽く振盪することに
より容易に混合して乳化状となって、まろやかな使用感
触が得られるという特徴を有する多層型化粧料に関する
。Detailed Description of the Invention [Industrial Field of Application] The present invention relates to a novel multilayer cosmetic composition formed by containing a polyglycerin alkyl phenyl ether type surfactant, and more specifically, to a multilayer cosmetic composition containing a polyglycerin alkyl phenyl ether type surfactant. The layer is transparent,
In addition, there is no active agent layer at the interface between the two layers, and the product appears to be clearly separated into two layers, and when used, it can be easily mixed into an emulsified state by shaking lightly, giving it a mellow feel when used. The present invention relates to a multilayer cosmetic having characteristics.
［従来の技術］
従来よりポリオキシエチレンソルビトール脂肪酸エステ
ル、ポリオキシエチレンソルビタン脂肪酸エステル、ポ
リエチレングリコール脂肪酸エステル、ポリオキシエチ
レンオレイルアルコールエーテル、ポリオキシエチレン
硬化ヒマシ油、ポリオキシエチレン脂肪酸アミド、ソル
ビタン脂肪酸エステル等を用いた二層型、三層型等の多
層型化粧料は広く知られているが、使用時や運搬時の振
盪、振動により混合すると分離に長時間を要し、又分離
後も油層、水層のいずれか或は両層が完全に透明になら
なかったり、油層・水層の界面に不明瞭な界面活性剤層
が現れたりして外観状好ましくないという欠点を有して
いた。[Prior art] Conventionally, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene oleyl alcohol ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene fatty acid amide, sorbitan fatty acid ester, etc. Multi-layer cosmetics such as two-layer and three-layer types using The problem is that one or both of the water layers may not become completely transparent, or an unclear surfactant layer may appear at the interface between the oil layer and the water layer, resulting in an unfavorable appearance.
［発明が解決しようとする問題点］
本発明者等は、このような状況に鑑み様々な界面活性剤
について鋭意検討した結果、ポリグリセリンアルキルフ
ェニルエーテル型の界面活性剤を用いれば従来の多層型
化粧料の欠点を解消し、振盪時の混合、乳化が良好で、
静置時の分離が速で、且つ油層、水層が透明で両層の界
面に不明瞭な界面活性剤層が現れないということを見出
し本発明を完成するに至った。[Problems to be Solved by the Invention] In view of the above circumstances, the present inventors have conducted extensive studies on various surfactants, and have found that if a polyglycerin alkyl phenyl ether type surfactant is used, the conventional multilayer type surfactant can be used. Eliminates the drawbacks of cosmetics, provides good mixing and emulsification during shaking,
The present invention was completed based on the discovery that separation is quick when left still, the oil and water layers are transparent, and no unclear surfactant layer appears at the interface between the two layers.
［問題点を解決するための手段］
即ち、本発明は
（イ）ポリグリセリンアルキルフェニルエーテル型化合
物から選ばれる一種又は二種以上（ロ）水溶性塩
（ハ）常温で液状の油性物質
及び
（ニ）水
を必須成分として含有することを特徴とする多層型化粧
料である。[Means for Solving the Problems] That is, the present invention provides (a) one or more types selected from polyglycerin alkyl phenyl ether type compounds, (b) a water-soluble salt, (c) an oily substance that is liquid at room temperature, and (c) an oily substance that is liquid at room temperature. d) It is a multilayer cosmetic characterized by containing water as an essential ingredient.
以下、本発明について詳述する。The present invention will be explained in detail below.
本発明で用いるポリグリセリンアルキルフェニルエーテ
ル型化合物は、グリセリンの平均重合度（ｎ）が２以上
のポリグリセリンのアルキルフェニルエールであり、下
記一般式（１）又は（２）或はそれらの混合物で表され
る。これらのうちから一種又は二種以上が任意に選択さ
れて用いられる。The polyglycerin alkyl phenyl ether type compound used in the present invention is an alkyl phenyl ether of polyglycerin having an average degree of polymerization (n) of 2 or more, and is represented by the following general formula (1) or (2) or a mixture thereof. expressed. One or more of these may be arbitrarily selected and used.
式（１）
％式％
式（２）
Ｈ
■
ＲＣ６Ｈ４０［ＣＨ２ＣＨＣＨ２０］ ｎ８式（１）及
び（２）中、Ｒは炭素数２〜２４の直鎖又は分岐鎖の飽
和又は不飽和のアルキル基であり、例えばエチル、プロ
ピル、ブチル、ヘプチル、ヘキシル、オクチル、ノニル
、デシル、ウンデシル、ドデシル、トリデシル、テトラ
デシル、ペンタデシル、ヘキサデシル、ヘプタデシル、
オクタデシル、ノナデシル、エイコシル、２−へキシル
デシル、２−へブチルウンデシル、オレイル、２−オク
チルドデシル等が挙げられる。好ましくは炭素数が４〜
１８のアルキル基である。Formula (1) % Formula % Formula (2) H ■ RC6H40[CH2CHCH20] n8 In formulas (1) and (2), R is a linear or branched saturated or unsaturated alkyl group having 2 to 24 carbon atoms. Examples include ethyl, propyl, butyl, heptyl, hexyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl,
Examples include octadecyl, nonadecyl, eicosyl, 2-hexyldecyl, 2-hebutylundecyl, oleyl, 2-octyldodecyl, and the like. Preferably the number of carbon atoms is 4 or more
18 alkyl groups.
又上記式（１）及び（２）中のｎは、平均付加モル数で
２〜６０、好ましくは３〜２０の数である。Further, n in the above formulas (1) and (2) is a number of 2 to 60, preferably 3 to 20, in terms of the average number of added moles.
本発明のポリグリセリンアルキルフェニルエーテル型化
合物は、一般的にはアルキルフェノールにグリシドール
を付加重合させて合成される。The polyglycerol alkyl phenyl ether type compound of the present invention is generally synthesized by addition polymerizing glycidol to alkylphenol.
ポリグリセリンアルキルフェニルエール型化合物の配合
量は、０．０１〜５重量％（以下％と略す）、好ましく
は０．０５〜３％である。The blending amount of the polyglycerol alkyl phenyl ale type compound is 0.01 to 5% by weight (hereinafter abbreviated as %), preferably 0.05 to 3%.
水溶性塩類としては無機塩、有機酸塩を用いることがで
き、塩化ナトリウム、塩化カリウム、硫酸ナトリウム、
硫酸マグネシウム、炭酸ナトリウム、炭酸カルシウム、
亜硫酸ナトリウム、クエン酸ナトリウム、リンゴ酸ナト
リウム、コハク酸ナトリウム、酒石酸ナトリウム、乳酸
ナトリウム、ピロリドンカルボン酸ナトリウム、リン酸
二水素ナトリウム等が好ましく、これらの一種又は二種
以上を用いることが出きる。Inorganic salts and organic acid salts can be used as water-soluble salts, including sodium chloride, potassium chloride, sodium sulfate,
Magnesium sulfate, sodium carbonate, calcium carbonate,
Sodium sulfite, sodium citrate, sodium malate, sodium succinate, sodium tartrate, sodium lactate, sodium pyrrolidone carboxylate, sodium dihydrogen phosphate, etc. are preferred, and one or more of these can be used.
水溶性塩類の配合量は０．０１〜４％で好ましくは０゜
０５〜２％である。The amount of water-soluble salts added is 0.01 to 4%, preferably 0.05 to 2%.
常温で液状の油性物質としては、炭化水素類、脂肪酸類
、エステル類、油脂類等があり、流動パラフィン、スク
ワラン、イソステアリン酸、グリセリルトリオクタノエ
ート、イソプロピルミリステート、ホホバ油、ヒマシ油
、オリーブ油、サフラワー油、ミンク油、シリコーン油
、ビタミンＥ誘導体等が好ましく、これらの一種又は二
種以上を用いることができる。Oily substances that are liquid at room temperature include hydrocarbons, fatty acids, esters, fats and oils, and include liquid paraffin, squalane, isostearic acid, glyceryl trioctanoate, isopropyl myristate, jojoba oil, castor oil, and olive oil. , safflower oil, mink oil, silicone oil, vitamin E derivatives, etc. are preferred, and one or more of these can be used.
常温で液状の油性物質の配合量は１〜５０χで、その配
合量は目的とする使用性等によって決定される。The amount of the oily substance that is liquid at room temperature ranges from 1 to 50x, and the amount is determined depending on the intended usability.
本発明の多層型化粧料には、必要に応じて本発明の効果
を損なわない範囲で通常化粧品に用いられる油溶性、水
溶性及びその他の物質を配合することができる。例えば
エタノール、イソプロピルアルコール等の低級アルコー
ル、保湿剤、増粘剤、防腐剤、金属イオン封鎖剤、酸化
防止剤、紫外線吸収剤、生薬、薬剤、顔料、分散剤、色
素、香料等が挙げられる。The multilayer cosmetic composition of the present invention may contain oil-soluble, water-soluble, and other substances commonly used in cosmetics, if necessary, within a range that does not impair the effects of the present invention. Examples include lower alcohols such as ethanol and isopropyl alcohol, humectants, thickeners, preservatives, sequestering agents, antioxidants, ultraviolet absorbers, herbal medicines, drugs, pigments, dispersants, pigments, and fragrances.
本発明の多層型化粧料は、スキンローション、アフター
シェーブローション、カーマインローション、ボデーロ
ーション等のスキンケア製品、ヘアリンス、ヘアリキッ
ド、スカルプロージョン等のヘア製品、フレグランス製
品等幅広い応用が可能である。The multilayer cosmetic of the present invention can be widely applied to skin care products such as skin lotion, aftershave lotion, carmine lotion, and body lotion, hair products such as hair rinse, hair liquid, and scalp lotion, and fragrance products.
［実施例コ
次に本発明の実施例及び比較例を示し、本発明の効果を
より具体的に説明する。これらは本発明を何ら限定する
ものではない。[Example] Next, Examples and Comparative Examples of the present invention will be shown to explain the effects of the present invention more specifically. These do not limit the present invention in any way.
実施例１ 第−表の記号はそれぞれ次の内容を表す。Example 1 The symbols in Table 1 represent the following contents.
上 層：○・・・透明 Ｘ・・・白濁界 面二〇・
・・存在せず ×・・・存在する（活性剤層）
下 層：○・・・透明 △・・・やや白濁混合後の分
離の速き：Ｏ・・・速い ×・・・遅い第 １ 表
実施例２ スキンローション
（１）ポリグリセリン（６）
ノニルフェニルエーテル ０．６％
（２）ポリグリセリン（１０）
ノニルフェニルエーテル ０．４
（３）スクワラン １５（４）香料
０．１（５）エタノール
１５（６）防腐剤 ０８１（
７）グリセリン ５
（８）乳酸ナトリウム １
（９）色素 適量
（１０）精製水 ６２．８実施例３
アフターシェーブローション（１）ポリグリセリン（８
）
ノニルフェニルエーテル ２％
（２〕ポリグリセリン（５）
ノニルフェニルエーテル ０．５
（３）流動パラフィン ５
（４）グリセリル
トリオクタノエート ２
（５）香料 ０．２（６）ｌ−メ
ントール ０．３（７）エタノール
２０
（８）ヘチマ抽出液 ０．５（９）プロピ
レングリコール ５
（１０）リン酸二水素ナトリウム ０．５（１１）精製
水 ６４．０１実施例４ カーマイン
ローション
（１）ポリグリセリン（１０）
ノニルフェニルエーテル １
（２）イソプロピルミリステート ２
（３）ｐ−ジメチルアミノ
安息香酸オクチル １
（４）香料 ０．１（５）エタノ
ール １０（６Ｎ、３−
ブチレングリコール １０
（７）炭酸ナトリウム １．５（８）酸化チ
タン ５
（９）酸化鉄 適量
（１０）エデト酢酸三ナトリウム ０．２（１１）精製
水 ６９．２実施例４ スカルブロー
ジョン
（１）ポリグリセリン（８）
トチ゛シルフェニルエーテル４
（２）シリコーン油 ３
（３）ビタミンＥ誘導体 ０．５（４）香料
０．１（５）ｌ−メントール
０．１（６）エタノール ３０
（７）ジプロピレングリコール ７（８）ピロリド
ンカルボン酸
ナトリウム １Upper layer: ○...Transparent X...White cloudy interface Surface 20.
...Not present ×...Present (activator layer) Lower layer: ○...Transparent △...Slightly cloudy Separation speed after mixing: O...Fast ×...Slow 1st Table Example 2 Skin lotion (1) Polyglycerin (6) Nonylphenyl ether 0.6% (2) Polyglycerin (10) Nonylphenyl ether 0.4 (3) Squalane 15 (4) Fragrance
0.1(5) Ethanol
15(6) Preservative 081(
7) Glycerin 5 (8) Sodium lactate 1 (9) Pigment appropriate amount (10) Purified water 62.8 Example 3
Aftershave lotion (1) Polyglycerin (8
) Nonylphenyl ether 2% (2] Polyglycerin (5) Nonylphenyl ether 0.5 (3) Liquid paraffin 5 (4) Glyceryl trioctanoate 2 (5) Fragrance 0.2 (6) L-menthol 0. 3(7) Ethanol
20 (8) Loofah extract 0.5 (9) Propylene glycol 5 (10) Sodium dihydrogen phosphate 0.5 (11) Purified water 64.01 Example 4 Carmine lotion (1) Polyglycerin (10) Nonylphenyl Ether 1 (2) Isopropyl myristate 2 (3) Octyl p-dimethylaminobenzoate 1 (4) Fragrance 0.1 (5) Ethanol 10 (6N, 3-butylene glycol 10) (7) Sodium carbonate 1.5 (8) ) Titanium oxide 5 (9) Iron oxide appropriate amount (10) Trisodium edetacetate 0.2 (11) Purified water 69.2 Example 4 Scarbrosion (1) Polyglycerin (8) Polystylphenyl ether 4 (2 ) Silicone oil 3 (3) Vitamin E derivative 0.5 (4) Fragrance
0.1(5) l-menthol
0.1(6) Ethanol 30
(7) Dipropylene glycol 7 (8) Sodium pyrrolidone carboxylate 1
Claims (1)
物から選ばれる一種又は二種以上 （ロ）水溶性塩類 （ハ）常温で液状の油性物質 及び （ニ）水 を必須成分として含有することを特徴とする多層型化粧
料。[Scope of Claims] (1) Contains one or more selected from polyglycerol alkyl phenyl ether type compounds (2) water-soluble salts (3) oily substances that are liquid at room temperature and (2) water as essential components. A multi-layer cosmetic that is characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16955186A JPS6327409A (en) | 1986-07-18 | 1986-07-18 | Multilayer type cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16955186A JPS6327409A (en) | 1986-07-18 | 1986-07-18 | Multilayer type cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6327409A true JPS6327409A (en) | 1988-02-05 |
Family
ID=15888569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16955186A Pending JPS6327409A (en) | 1986-07-18 | 1986-07-18 | Multilayer type cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6327409A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0370856A2 (en) * | 1988-11-09 | 1990-05-30 | L'oreal | Eye make-up remover with two distinct phases |
| JPH10182420A (en) * | 1996-12-27 | 1998-07-07 | Kose Corp | Two-layer bath preparation |
| EP1475077A2 (en) * | 2003-05-09 | 2004-11-10 | Henkel Kommanditgesellschaft auf Aktien | Double phase liquid antitranspirant compositions |
| JP2010024177A (en) * | 2008-07-18 | 2010-02-04 | Nippon Menaade Keshohin Kk | Makeup remover |
| JP2018027917A (en) * | 2016-08-18 | 2018-02-22 | 森永製菓株式会社 | METHOD OF STABILIZING GLUCOSE p-COUMARIC ACID GLYCOSIDE, AND METHOD OF PRODUCING GLUCOSE p-COUMARIC ACID GLYCOSIDE SOLUTION USING THE SAME |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55139312A (en) * | 1979-04-12 | 1980-10-31 | Kanebo Ltd | Two-layer cleansing lotion |
| JPS58177910A (en) * | 1982-04-12 | 1983-10-18 | Shiseido Co Ltd | Three-layered type liquid skin cosmetic |
| JPS606609A (en) * | 1983-05-31 | 1985-01-14 | ロレアル | Oral cavity product |
| JPS6018594A (en) * | 1983-04-15 | 1985-01-30 | ロレアル | Detergent and foaming composition |
| JPS61145138A (en) * | 1984-12-17 | 1986-07-02 | ロレアル | Polyglyceroled nonionic surfactant, manufacture and cosmeticcomposition |
-
1986
- 1986-07-18 JP JP16955186A patent/JPS6327409A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55139312A (en) * | 1979-04-12 | 1980-10-31 | Kanebo Ltd | Two-layer cleansing lotion |
| JPS58177910A (en) * | 1982-04-12 | 1983-10-18 | Shiseido Co Ltd | Three-layered type liquid skin cosmetic |
| JPS6018594A (en) * | 1983-04-15 | 1985-01-30 | ロレアル | Detergent and foaming composition |
| JPS606609A (en) * | 1983-05-31 | 1985-01-14 | ロレアル | Oral cavity product |
| JPS61145138A (en) * | 1984-12-17 | 1986-07-02 | ロレアル | Polyglyceroled nonionic surfactant, manufacture and cosmeticcomposition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0370856A2 (en) * | 1988-11-09 | 1990-05-30 | L'oreal | Eye make-up remover with two distinct phases |
| JPH10182420A (en) * | 1996-12-27 | 1998-07-07 | Kose Corp | Two-layer bath preparation |
| EP1475077A2 (en) * | 2003-05-09 | 2004-11-10 | Henkel Kommanditgesellschaft auf Aktien | Double phase liquid antitranspirant compositions |
| EP1475077A3 (en) * | 2003-05-09 | 2005-01-26 | Henkel Kommanditgesellschaft auf Aktien | Double phase liquid antitranspirant compositions |
| JP2010024177A (en) * | 2008-07-18 | 2010-02-04 | Nippon Menaade Keshohin Kk | Makeup remover |
| JP2018027917A (en) * | 2016-08-18 | 2018-02-22 | 森永製菓株式会社 | METHOD OF STABILIZING GLUCOSE p-COUMARIC ACID GLYCOSIDE, AND METHOD OF PRODUCING GLUCOSE p-COUMARIC ACID GLYCOSIDE SOLUTION USING THE SAME |
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