JPS63270764A - 殺菌性ポリマー成形体の製造法 - Google Patents
殺菌性ポリマー成形体の製造法Info
- Publication number
- JPS63270764A JPS63270764A JP63063512A JP6351288A JPS63270764A JP S63270764 A JPS63270764 A JP S63270764A JP 63063512 A JP63063512 A JP 63063512A JP 6351288 A JP6351288 A JP 6351288A JP S63270764 A JPS63270764 A JP S63270764A
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- metal
- bactericidal
- polymer
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 47
- 229920000642 polymer Polymers 0.000 title claims abstract description 36
- 238000000465 moulding Methods 0.000 title claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 70
- 238000005342 ion exchange Methods 0.000 claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- 229920000620 organic polymer Polymers 0.000 claims abstract description 10
- 150000003839 salts Chemical class 0.000 claims abstract description 8
- 239000010457 zeolite Substances 0.000 claims description 83
- 229910021536 Zeolite Inorganic materials 0.000 claims description 75
- 229910021645 metal ion Inorganic materials 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 19
- 229910052709 silver Inorganic materials 0.000 claims description 16
- 239000004332 silver Substances 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 13
- 230000001954 sterilising effect Effects 0.000 claims description 13
- 239000011701 zinc Substances 0.000 claims description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 6
- 150000002736 metal compounds Chemical class 0.000 claims description 4
- 229910052680 mordenite Inorganic materials 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 16
- 239000000203 mixture Substances 0.000 abstract description 9
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract description 9
- 239000000377 silicon dioxide Substances 0.000 abstract description 7
- 229910052681 coesite Inorganic materials 0.000 abstract description 4
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 4
- 229910052682 stishovite Inorganic materials 0.000 abstract description 4
- 229910052905 tridymite Inorganic materials 0.000 abstract description 4
- 229920002292 Nylon 6 Polymers 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract description 2
- 229910000366 copper(II) sulfate Inorganic materials 0.000 abstract description 2
- 150000001455 metallic ions Chemical class 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 230000002459 sustained effect Effects 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- -1 silver ions Chemical class 0.000 description 11
- 239000000243 solution Substances 0.000 description 8
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- 125000000524 functional group Chemical group 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 229920001059 synthetic polymer Polymers 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000233866 Fungi Species 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910001603 clinoptilolite Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000005033 polyvinylidene chloride Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 229910001923 silver oxide Inorganic materials 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000222120 Candida <Saccharomycetales> Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- OUHYWZDPYGIBRF-UHFFFAOYSA-N [K].[Tm] Chemical compound [K].[Tm] OUHYWZDPYGIBRF-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
- 229910052676 chabazite Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229910052675 erionite Inorganic materials 0.000 description 1
- 229940023064 escherichia coli Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical class [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000002504 physiological saline solution Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Multicomponent Fibers (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63063512A JPS63270764A (ja) | 1988-03-18 | 1988-03-18 | 殺菌性ポリマー成形体の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63063512A JPS63270764A (ja) | 1988-03-18 | 1988-03-18 | 殺菌性ポリマー成形体の製造法 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58007361A Division JPS59133235A (ja) | 1983-01-21 | 1983-01-21 | 殺菌性ポリマー組成物及びその製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63270764A true JPS63270764A (ja) | 1988-11-08 |
| JPH0372102B2 JPH0372102B2 (enrdf_load_stackoverflow) | 1991-11-15 |
Family
ID=13231346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63063512A Granted JPS63270764A (ja) | 1988-03-18 | 1988-03-18 | 殺菌性ポリマー成形体の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63270764A (enrdf_load_stackoverflow) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02238923A (ja) * | 1989-03-13 | 1990-09-21 | Kyoraku Co Ltd | 抗菌性成形品の製造方法 |
| JPH02251292A (ja) * | 1989-03-24 | 1990-10-09 | Shinagawa Nenryo Kk | 冷却塔用殺菌材 |
| US6071542A (en) * | 1995-03-16 | 2000-06-06 | Kanebo Ltd. | Antibacterial zeolite causing little discoloration and method of the production thereof |
| EP2457596A1 (de) * | 2010-11-29 | 2012-05-30 | Kami Klaus Kahrom | Antimikrobielle Oberflächenschicht mit eingelagerten Aktivkohlekugeln |
-
1988
- 1988-03-18 JP JP63063512A patent/JPS63270764A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02238923A (ja) * | 1989-03-13 | 1990-09-21 | Kyoraku Co Ltd | 抗菌性成形品の製造方法 |
| JPH02251292A (ja) * | 1989-03-24 | 1990-10-09 | Shinagawa Nenryo Kk | 冷却塔用殺菌材 |
| US6071542A (en) * | 1995-03-16 | 2000-06-06 | Kanebo Ltd. | Antibacterial zeolite causing little discoloration and method of the production thereof |
| EP2457596A1 (de) * | 2010-11-29 | 2012-05-30 | Kami Klaus Kahrom | Antimikrobielle Oberflächenschicht mit eingelagerten Aktivkohlekugeln |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0372102B2 (enrdf_load_stackoverflow) | 1991-11-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4775585A (en) | Polymer article having an antibacterial property containing zeolite particles therein and the processes for producing same | |
| US5064599A (en) | Process for producing an antibacterial fiber article | |
| US4959268A (en) | Polymer containing amorphous aluminosilicate particles and process for producing the same | |
| CA2037314C (en) | Antimicrobial composition | |
| KR100587465B1 (ko) | 은 담지 무기계 항균제 및 이를 함유한 열가소성 수지 마스터배치 | |
| JPS62195038A (ja) | 抗菌性ポリエステル系成形体 | |
| JPH0384066A (ja) | 抗菌作用を有する樹脂組成物およびその製造方法 | |
| JPS63270764A (ja) | 殺菌性ポリマー成形体の製造法 | |
| JPH0694534B2 (ja) | 抗菌性を有するポリエステル系成形体 | |
| JPH0411670B2 (enrdf_load_stackoverflow) | ||
| JP2784240B2 (ja) | アルミナを母体とする抗菌性組成物 | |
| JPH0360866B2 (enrdf_load_stackoverflow) | ||
| JPH0696484B2 (ja) | 抗菌ならびに防カビおよびｃｏｄ低下機能を有するゼオライト‐活性炭複合体およびその製造方法 | |
| JPH057329B2 (enrdf_load_stackoverflow) | ||
| JPH0816295B2 (ja) | 抗菌性繊維構造物素材 | |
| JPH0132254B2 (enrdf_load_stackoverflow) | ||
| JP3185697B2 (ja) | 耐久性に優れた抗菌剤 | |
| JP2648282B2 (ja) | Ｍｒｓａ用殺菌剤 | |
| JPH0339335A (ja) | 抗菌性樹脂組成物 | |
| JPH11189919A (ja) | 抗菌性ポリプロピレンテレフタレート繊維 | |
| JPH0343456A (ja) | 抗菌性を有する樹脂組成物 | |
| JPH03145411A (ja) | 耐候性及び耐熱性を有する殺菌性ポリマー組成物 | |
| JPH02160914A (ja) | 抗菌性アクリル系繊維及びその製造方法 | |
| JPH0465511A (ja) | 抗菌性繊維 |