JPS63215574A - Monolithic refractory block - Google Patents

Monolithic refractory block

Info

Publication number
JPS63215574A
JPS63215574A JP62047655A JP4765587A JPS63215574A JP S63215574 A JPS63215574 A JP S63215574A JP 62047655 A JP62047655 A JP 62047655A JP 4765587 A JP4765587 A JP 4765587A JP S63215574 A JPS63215574 A JP S63215574A
Authority
JP
Japan
Prior art keywords
fiber
monolithic
monolithic refractory
block
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62047655A
Other languages
Japanese (ja)
Other versions
JPH0555476B2 (en
Inventor
行雄 尾崎
岩城 克弘
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shinagawa Refractories Co Ltd
Original Assignee
Shinagawa Refractories Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinagawa Refractories Co Ltd filed Critical Shinagawa Refractories Co Ltd
Priority to JP62047655A priority Critical patent/JPS63215574A/en
Publication of JPS63215574A publication Critical patent/JPS63215574A/en
Publication of JPH0555476B2 publication Critical patent/JPH0555476B2/ja
Granted legal-status Critical Current

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  • Looms (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明はブロック内に不定形耐火物の品質に類似する耐
火性繊維を縦、横及び垂直方向に植込み、ブロックが万
−割れても、剥離・脱落を防止することができる不定形
耐火ブロックに関する。
Detailed Description of the Invention [Industrial Application Field] The present invention has refractory fibers similar to the quality of monolithic refractories embedded in the block in the vertical, horizontal and vertical directions, so that even if the block breaks, This invention relates to a monolithic fireproof block that can prevent peeling and falling off.

[従来の技術] 従来より鋼材(丸棒)、鋼板、金網あるいはメタルラス
を施工現場において事前に窯炉の缶壁に取付けた後、不
定形耐火物を吹付け、あるいは流込み施工し、不定形耐
火ブロックを強化する施工法が主として採用されている
[Conventional technology] Traditionally, steel materials (round bars), steel plates, wire mesh, or metal lath are attached to the can wall of a kiln in advance at the construction site, and then monolithic refractories are sprayed or poured to create an monolithic shape. Construction methods that strengthen fireproof blocks are mainly used.

また、不定形耐火物製造工場で、前記鋼材等を植込んだ
不定形耐火ブロックを製造することもあるが、量的には
極めて少ない。
In addition, monolithic refractory blocks in which the above-mentioned steel materials and the like are embedded are sometimes manufactured at monolithic refractory manufacturing plants, but the quantity thereof is extremely small.

[発明が解決しようとする問題点コ 不定形耐火ブロックの欠陥は温度変化に弱く、簡単に割
れることである。このため、耐スポール性を向上させる
ため、不定形耐火物自身の品質改善を計るとともに、万
−割れても、剥離・脱落しすi’  1%  I−A 
 )−古3:素 1   +−hn  /     l
 W  n)a 制d a−蚤+++植込みが行なわれ
ている。鋼製補強材を植込んだ不定形耐火ブロックは温
度変化あるいは熱膨張差により亀裂を生じ易く、亀裂が
生ずると、その部分に炉内の高温ガスが侵入して鋼製補
強材が酸化損傷あるいは溶融して最後には切断されてし
まい、剥離脱落し、耐用が短命であった。上述のような
、不定形耐火物と前記補強材の熱膨張率の相異等に起因
する欠点を改善するために、補強材の膨張を吸収するた
めの諸対策が講じられている。例えば、パラフィンある
いはタールを補強材表面に塗布するか、あるいはビニー
ルテープで補強材表面を被覆する方法が用いられている
が、完全ではなく、植込みピッチを細かくすればする程
、不完全となり、逆に不定形耐火ブロックに割れの発生
を助長する結果となっている。
[Problems to be Solved by the Invention] A defect of the monolithic refractory block is that it is susceptible to temperature changes and easily cracks. Therefore, in order to improve the spall resistance, we are trying to improve the quality of the monolithic refractory itself, and also to ensure that even if it cracks, it will not peel or fall off.
)-old 3: prime 1 +-hn/l
W n) a control d a- flea +++ implantation is being carried out. Monolithic refractory blocks with steel reinforcement embedded in them are prone to cracking due to temperature changes or differences in thermal expansion. When cracks occur, high-temperature gases from the furnace enter the cracked areas, causing oxidation damage or damage to the steel reinforcement. It melted and was eventually cut, peeling off and falling off, resulting in a short lifespan. In order to improve the above-mentioned drawbacks caused by the difference in coefficient of thermal expansion between the monolithic refractory and the reinforcing material, various measures have been taken to absorb the expansion of the reinforcing material. For example, methods have been used to apply paraffin or tar to the surface of the reinforcing material, or to cover the surface of the reinforcing material with vinyl tape. This has resulted in the occurrence of cracks in monolithic fireproof blocks.

[問題点を解決するための手段] 鋼材(丸棒)、鋼板、金網あるいはメタルラスの代わり
に、不定形耐火物の品質(膨張率)と類似する耐火性繊
維を3次元織物として使用することにより上述の問題点
を解決することができることを見出し、本発明を完成す
るに至った。
[Means for solving the problem] Instead of steel materials (round bars), steel plates, wire mesh, or metal lath, by using refractory fibers similar in quality (expansion coefficient) to monolithic refractories as a three-dimensional fabric. The inventors have discovered that the above-mentioned problems can be solved, and have completed the present invention.

従って、本発明は耐火性繊維よりなる3次元織物0.1
〜25重量%及び不定形耐火物99.9〜75重量%か
らなる不定形耐火ブロックにある。
Therefore, the present invention provides a three-dimensional fabric made of fire-resistant fibers with a thickness of 0.1
~25% by weight and a monolithic refractory block comprising 99.9~75% by weight of the monolithic refractory.

[作 用] 本発明の不定形耐火ブロックは不定形耐火物の品質に類
似した天然石綿ファイバー、ガラスファイバー、アルミ
ナファイバー、珪酸アルミナファイバー、ジルコニアフ
ァイバー、カーボンファイバー、チタン酸カリファイバ
ー及びシリコン・チタンファイバーからなる群より選択
された1種または2種以上よりなる耐火性繊維を補強材
として使用し、更に、これらの補強材を3次元織物とし
て不定形耐火ブロックの縦、横及び垂直方向に植込み、
耐用を大幅に延長したものである。
[Function] The monolithic refractory block of the present invention is made of natural asbestos fibers, glass fibers, alumina fibers, alumina silicate fibers, zirconia fibers, carbon fibers, potassium titanate fibers, and silicon titanium fibers similar in quality to monolithic refractories. Refractory fibers made of one or more types selected from the group consisting of are used as a reinforcing material, and further, these reinforcing materials are implanted as a three-dimensional fabric in the vertical, horizontal and vertical directions of the monolithic refractory block,
It has significantly extended durability.

以下、本発明の不定形耐火ブロックに使用することがで
きる3次元織物の構造の1例を添付の第1図及び第2図
を使用して説明するが、本発明の不定形耐火ブロックは
これらに限定されるものではないことを理解されたい。
Hereinafter, one example of the structure of a three-dimensional fabric that can be used for the monolithic fireproof block of the present invention will be explained using the attached FIGS. 1 and 2. It should be understood that this is not limited to.

第1図は直交タイプの3次元織物を示す図であり、図中
、(1)は縦方向の耐火繊維であり、(2)は横方向の
耐火繊維であり、(3)は垂直方向の耐火繊維を示す。
Figure 1 is a diagram showing an orthogonal type three-dimensional fabric. In the figure, (1) is the fireproof fiber in the vertical direction, (2) is the fireproof fiber in the horizontal direction, and (3) is the fireproof fiber in the vertical direction. Indicates fireproof fiber.

第2図は絡みタイプの3次元織物を示す図である。FIG. 2 is a diagram showing a tangled type three-dimensional fabric.

上述のような3次元織物を所定の寸法の金枠内に設置し
く例えば、針金を用いて吊す)、この金枠内に不定形耐
火物を投入し、振動を加えて成形し、次に、所定の期間
にわたり養生し、その後に脱枠し、乾燥することにより
本発明の不定形耐火ブロックを製造することができる。
A three-dimensional fabric as described above is placed in a metal frame of predetermined dimensions (for example, suspended using wire), an unshaped refractory is placed in this metal frame, and is shaped by applying vibration, and then, The monolithic refractory block of the present invention can be manufactured by curing for a predetermined period of time, then removing the frame, and drying.

本発明の不定形耐火ブロックを製造する際に使用するこ
とができる不定形耐火物は骨材がアルミナ、シリカ、ジ
ルコン、ジルコニア、カーボン、炭化珪素及び窒化硼素
からなる群の1種以上を含有するものであればよい。こ
れらの不定形耐火物に慣用の水分量の水を添加し、慣用
の方法により混練したものを上述の金枠に投入すること
ができる。
In the monolithic refractory that can be used in manufacturing the monolithic refractory block of the present invention, the aggregate contains one or more of the group consisting of alumina, silica, zircon, zirconia, carbon, silicon carbide, and boron nitride. It is fine as long as it is something. A customary amount of water can be added to these monolithic refractories, kneaded by a customary method, and the resulting mixture can be put into the above-mentioned metal frame.

に当たり、耐火性繊維と不定形耐火物の材質は上述のも
のを適宜選択することができるが、上述の問題点を解決
するためにも熱膨張率のほぼ等しい材質の耐火性繊維と
不定形耐火物を選択することが好ましい。
In this case, the materials for the refractory fiber and the monolithic refractory can be selected as appropriate from those mentioned above, but in order to solve the above problems, the refractory fiber and the monolithic refractory are made of materials with approximately the same coefficient of thermal expansion. It is preferable to select items.

本発明の不定形耐火ブロックはブロック内に植込んだ耐
火性繊維よりなる3次元織物が熱膨張吸収材として作用
し、更に、不定形耐火ブロックに亀裂を生じても、耐火
性繊維がスタッドの働きをして剥離脱落を生じ難い。
In the monolithic refractory block of the present invention, the three-dimensional fabric made of refractory fibers embedded in the block acts as a thermal expansion absorber, and furthermore, even if a crack occurs in the monolithic refractory block, the refractory fibers remain in the studs. It works well and does not easily peel off or fall off.

[実 施 例] 以下に実施例を挙げ、本発明を更に説明する。[Example] The present invention will be further explained with reference to Examples below.

実施例 耐火性繊維として珪酸アルミナファイバー(3μφ)を
使用し、これを1000本束ねて3mmφの糸を造り、
この糸より製造された250×250X250mm3次
元織物(直交タイプ)を使用した[放鳥カンバス(株)
社製の市販品コ。
Example Alumina silicate fibers (3μφ) were used as fire-resistant fibers, and 1000 fibers were bundled to make a 3mmφ thread.
A 250 x 250 x 250 mm three-dimensional fabric (orthogonal type) manufactured from this yarn was used [Houtori Canvas Co., Ltd.]
A commercially available product made by the company.

この3次元織物を鋼製の型枠(300X300y  Q
  n  n  、、、−’+rbr−ILLAk−m
  ls プ 9 −J−−L  +−1−rh  M
This three-dimensional fabric is placed in a steel formwork (300x300y Q
n n , , -'+rbr-ILLAk-m
ls pu 9 -J--L +-1-rh M
.

置した。この際に、型枠と3次元織物の間隙を等しく保
つように注意した。
I placed it. At this time, care was taken to maintain the same gap between the formwork and the three-dimensional fabric.

次に、アルミナキャスタブル(ローセメントハイアルミ
ナキャスタブル: ALot53.3重量%;5iOt
42.8重要%)水を6.7重量%添加して3分間混練
して不定形耐火物を造り、この不定形耐火物を前記型枠
内に投入し、次に、型枠を5分間振動テーブルに乗せて
加振することにより不定形耐火物を充填した。加振後、
型枠に入れたままの状態で12時間養生し、次に、脱枠
し、次に、24時間で600℃まで昇温することにより
乾燥して本発明の不定形耐火ブロックを得た。
Next, alumina castable (low cement high alumina castable: ALot 53.3% by weight; 5iOt
42.8% by weight) 6.7% by weight of water was added and kneaded for 3 minutes to make a monolithic refractory, this monolithic refractory was put into the mold, and then the mold was kneaded for 5 minutes. The monolithic refractory was filled by placing it on a vibrating table and vibrating it. After excitation,
The block was cured in the form for 12 hours, then removed from the frame, and then dried by increasing the temperature to 600°C for 24 hours to obtain the monolithic refractory block of the present invention.

比較例 上述の実施例の不定形耐火ブロックと同材質のアルミナ
キャスタブルを用いて、3次元織物を使用せずに同様の
寸法の不定形耐火ブロックを造った。
Comparative Example Using alumina castable made of the same material as the monolithic refractory block of the above-described example, a monolithic refractory block of similar dimensions was made without using a three-dimensional fabric.

参考例 上述の実施例及び参考例で製造した不定形耐火ブロック
についてパネルスポーリングテストを行なった(5回実
施)。試験炉としては、灯油を用いて1400℃まで昇
温可能であり、パネル式で、クレーンで吊って取外し・
移動が可能である鏡壁(反バーナ壁)を備える炉[試験
炉寸法: 1500(L)x 1000(W)x 12
00(H)mm]を使用した。前記鏡壁に実施例及び比
較例で得られた不定形耐火ブロックをセットし、試験炉
に取り付けた。その後、バーナに点火し、8時間かけて
1200℃まで昇温しで10分間保持後、パネル(鏡壁
)をクレーンで吊って、試験炉より取外し、10分間強
制空冷(1ONm’/分の空気吹付け)後、試験炉に取
付けて1200℃で10分間加熱後、パネルを取外し、
上述と同様に強制空冷を行なう操作をlO回反復した。
Reference Example A panel spalling test was conducted on the monolithic fireproof blocks manufactured in the above-mentioned Examples and Reference Examples (conducted 5 times). The test furnace can be heated up to 1400℃ using kerosene, and is a panel type furnace that can be removed and lifted by a crane.
Furnace equipped with a movable mirror wall (anti-burner wall) [Test furnace dimensions: 1500 (L) x 1000 (W) x 12
00 (H) mm] was used. The monolithic refractory blocks obtained in Examples and Comparative Examples were set on the mirror wall and attached to a test furnace. After that, the burner was ignited and the temperature was raised to 1200℃ over 8 hours, held for 10 minutes, and then the panel (mirror wall) was lifted with a crane, removed from the test furnace, and forced air cooled for 10 minutes (1ONm'/min air After spraying), install it in a test furnace and heat it at 1200℃ for 10 minutes, then remove the panel.
The same forced air cooling operation as described above was repeated 10 times.

その結果、いずれの場合も、比較例で得られた不定形耐
火ブロックは2〜3回の操作で大きな放射状の亀裂を生
じ、その後、面に平行な亀裂を生じ、5〜6回目の操作
で大きく且つ厚く(70〜80non)剥離脱落した。
As a result, in all cases, the monolithic refractory blocks obtained in the comparative examples developed large radial cracks after 2 to 3 operations, then cracks parallel to the surface, and after the 5th or 6th operation. It peeled off in a large and thick manner (70 to 80 nanometers).

これに対し本発明の不定形耐火ブロックは3〜5回目の
操作で微亀裂を生ずるが、その数は極めて少なく、剥離
脱落は全く見られなかった。
On the other hand, although the monolithic refractory block of the present invention developed microcracks after the third to fifth operations, the number of microcracks was extremely small, and no peeling or falling off was observed.

[発明の効果コ このようにして得られた本発明の不定形耐火ブロックは
内部に縦、横及び垂直方向に植込んだ補強材(3次元織
物)を有するために、ブロックに亀裂が生じても、厚く
剥離脱落したり、大きく剥離脱落することがなくなり、
耐用を大幅に延長することができる。
[Effects of the Invention] Since the monolithic fireproof block of the present invention thus obtained has reinforcing materials (three-dimensional fabric) embedded in the interior in the vertical, horizontal and vertical directions, cracks may occur in the block. Also, it will not peel off thickly or fall off in a big way,
The service life can be significantly extended.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は直交タイプの3次元織物を示す図であり、第2
図は絡みタイプの3次元織物を示す図である。図中、(
1)・・・縦方向の耐火繊維;(2)・・・横方向の耐
火繊維;(3)・・・垂直方向の耐火繊維。
Figure 1 is a diagram showing an orthogonal type three-dimensional fabric;
The figure shows a tangled type three-dimensional fabric. In the figure, (
1) ... fireproof fibers in the longitudinal direction; (2) ... fireproof fibers in the horizontal direction; (3) ... fireproof fibers in the vertical direction.

Claims (1)

【特許請求の範囲】 1、耐火性繊維よりなる3次元織物0.1〜25重量%
及び不定形耐火物99.9〜75重量%からなる不定形
耐火ブロック。 2、耐火性繊維が天然石綿ファイバー、ガラスファイバ
ー、アルミナファイバー、珪酸アルミナファイバー、ジ
ルコニアファイバー、カーボンファイバー、チタン酸カ
リファイバー及びシリコン・チタンファイバーからなる
群より選択された1種または2種以上よりなる特許請求
の範囲第1項記載の不定形耐火ブロック。 3、不定形耐火物の骨材がアルミナ、シリカ、ジルコン
、ジルコニア、カーボン、炭化珪素及び窒化硼素からな
る群より選択された1種または2種以上からなる特許請
求の範囲第1項記載の不定形耐火ブロック。
[Claims] 1. Three-dimensional fabric made of fire-resistant fibers 0.1 to 25% by weight
and a monolithic refractory block consisting of 99.9 to 75% by weight of monolithic refractories. 2. The fire-resistant fiber is one or more selected from the group consisting of natural asbestos fiber, glass fiber, alumina fiber, alumina silicate fiber, zirconia fiber, carbon fiber, potash titanate fiber, and silicon/titanium fiber. A monolithic refractory block according to claim 1. 3. The aggregate of the monolithic refractory is composed of one or more selected from the group consisting of alumina, silica, zircon, zirconia, carbon, silicon carbide, and boron nitride. Shaped fireproof block.
JP62047655A 1987-03-04 1987-03-04 Monolithic refractory block Granted JPS63215574A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62047655A JPS63215574A (en) 1987-03-04 1987-03-04 Monolithic refractory block

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62047655A JPS63215574A (en) 1987-03-04 1987-03-04 Monolithic refractory block

Publications (2)

Publication Number Publication Date
JPS63215574A true JPS63215574A (en) 1988-09-08
JPH0555476B2 JPH0555476B2 (en) 1993-08-17

Family

ID=12781270

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62047655A Granted JPS63215574A (en) 1987-03-04 1987-03-04 Monolithic refractory block

Country Status (1)

Country Link
JP (1) JPS63215574A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020537737A (en) * 2017-10-23 2020-12-24 ポスコPosco Refractory

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5114624A (en) * 1974-06-24 1976-02-05 Caterpillar Tractor Co
JPS5879875A (en) * 1981-10-20 1983-05-13 オフイス・ナシヨナル・デトウデ・エ・ド・リシエルシユ・エアロスパシヤル Highly mechanical and thermally resistant ceramic composite material and manufacture
JPS58217473A (en) * 1982-06-11 1983-12-17 川崎製鉄株式会社 Carbon-containing refractories
JPS59156970A (en) * 1983-02-23 1984-09-06 黒崎窯業株式会社 Refractory brick
JPS611538A (en) * 1984-06-12 1986-01-07 Aisin Warner Ltd Control device of automatic transmission for four-wheel drive

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5114624A (en) * 1974-06-24 1976-02-05 Caterpillar Tractor Co
JPS5879875A (en) * 1981-10-20 1983-05-13 オフイス・ナシヨナル・デトウデ・エ・ド・リシエルシユ・エアロスパシヤル Highly mechanical and thermally resistant ceramic composite material and manufacture
JPS58217473A (en) * 1982-06-11 1983-12-17 川崎製鉄株式会社 Carbon-containing refractories
JPS59156970A (en) * 1983-02-23 1984-09-06 黒崎窯業株式会社 Refractory brick
JPS611538A (en) * 1984-06-12 1986-01-07 Aisin Warner Ltd Control device of automatic transmission for four-wheel drive

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020537737A (en) * 2017-10-23 2020-12-24 ポスコPosco Refractory

Also Published As

Publication number Publication date
JPH0555476B2 (en) 1993-08-17

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