JPS6320416B2 - - Google Patents
Info
- Publication number
- JPS6320416B2 JPS6320416B2 JP10622881A JP10622881A JPS6320416B2 JP S6320416 B2 JPS6320416 B2 JP S6320416B2 JP 10622881 A JP10622881 A JP 10622881A JP 10622881 A JP10622881 A JP 10622881A JP S6320416 B2 JPS6320416 B2 JP S6320416B2
- Authority
- JP
- Japan
- Prior art keywords
- acrylic acid
- methyl acrylate
- water
- methyl alcohol
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 87
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 86
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 35
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 34
- 238000005886 esterification reaction Methods 0.000 claims description 18
- 238000004821 distillation Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 13
- 239000007795 chemical reaction product Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- -1 butanol and octanol Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- CNHDIAIOKMXOLK-UHFFFAOYSA-N monomethylhydroquinone Natural products CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10622881A JPS588042A (ja) | 1981-07-09 | 1981-07-09 | アクリル酸メチルの蒸留方法 |
| US06/393,484 US4464229A (en) | 1981-07-09 | 1982-06-29 | Process for producing acrylic or methacrylic esters |
| MX193511A MX163005B (es) | 1981-07-09 | 1982-07-08 | Procedimiento mejorado para producir un ester acrilico o metacrilico |
| BR8203983A BR8203983A (pt) | 1981-07-09 | 1982-07-08 | Processo para produzir ester acrilico ou metacrilico |
| FR8211987A FR2509294A1 (fr) | 1981-07-09 | 1982-07-08 | Procede de fabrication d'esters de l'acide acrylique ou methacrylique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10622881A JPS588042A (ja) | 1981-07-09 | 1981-07-09 | アクリル酸メチルの蒸留方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS588042A JPS588042A (ja) | 1983-01-18 |
| JPS6320416B2 true JPS6320416B2 (fr) | 1988-04-27 |
Family
ID=14428264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10622881A Granted JPS588042A (ja) | 1981-07-09 | 1981-07-09 | アクリル酸メチルの蒸留方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS588042A (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63144505A (ja) * | 1986-12-09 | 1988-06-16 | Mitsubishi Electric Corp | 漏洩磁界キヤンセル装置 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59181239A (ja) * | 1983-03-30 | 1984-10-15 | Mitsubishi Rayon Co Ltd | 含フツ素アクリル酸エステル又はメタクリル酸エステルの製造方法 |
-
1981
- 1981-07-09 JP JP10622881A patent/JPS588042A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63144505A (ja) * | 1986-12-09 | 1988-06-16 | Mitsubishi Electric Corp | 漏洩磁界キヤンセル装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS588042A (ja) | 1983-01-18 |
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