JPS6319772A - Lead-acid battery - Google Patents
Lead-acid batteryInfo
- Publication number
- JPS6319772A JPS6319772A JP61164909A JP16490986A JPS6319772A JP S6319772 A JPS6319772 A JP S6319772A JP 61164909 A JP61164909 A JP 61164909A JP 16490986 A JP16490986 A JP 16490986A JP S6319772 A JPS6319772 A JP S6319772A
- Authority
- JP
- Japan
- Prior art keywords
- fine powder
- powder
- lead
- separator
- electrode plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002253 acid Substances 0.000 title claims description 14
- 239000000843 powder Substances 0.000 claims abstract description 29
- 239000011149 active material Substances 0.000 claims abstract description 5
- 239000011521 glass Substances 0.000 claims abstract description 5
- 239000002245 particle Substances 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract 2
- 229910052799 carbon Inorganic materials 0.000 claims abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract 2
- 239000010457 zeolite Substances 0.000 claims abstract 2
- 239000003792 electrolyte Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052681 coesite Inorganic materials 0.000 abstract description 3
- 229910052593 corundum Inorganic materials 0.000 abstract description 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 3
- 229910052682 stishovite Inorganic materials 0.000 abstract description 3
- 229910052905 tridymite Inorganic materials 0.000 abstract description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 3
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000007423 decrease Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 229910000464 lead oxide Inorganic materials 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical group [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/431—Inorganic material
- H01M50/434—Ceramics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/431—Inorganic material
- H01M50/434—Ceramics
- H01M50/437—Glass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/44—Fibrous material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0005—Acid electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Cell Separators (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は鉛蓄電池の保存特性の向上に関するものである
。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to improving the storage characteristics of lead-acid batteries.
従来の技術
従来の鉛蓄電池用負極板は、鉛又は鉛合金を鋳造あるい
はエキスバンド加工などに上り集電体格子を作成し、こ
の集電体に主成分が酸化鉛よりなる活物質原料を塗着、
乾燥しついで化成して極板としていた。Conventional technology A conventional negative electrode plate for a lead-acid battery is produced by casting or expanding lead or a lead alloy to create a current collector grid, and then coating this current collector with an active material whose main component is lead oxide. Arrival,
After drying, it was chemically converted into electrode plates.
ここでの活物質原料は酸化鉛を主体とする鉛粉と硫酸と
水を混合し練合したもので、機械的強度を改善するため
に耐酸性の合成樹脂繊維を添加したものである。The active material raw material here is a mixture of lead powder, mainly lead oxide, sulfuric acid, and water, and acid-resistant synthetic resin fibers are added to improve mechanical strength.
またその他の添加剤として、硫酸バリウム、リプニンス
ルホン酸ナトリウムなどがあるのみである。Other additives include barium sulfate and sodium lipninsulfonate.
発明が解決しようとする問題点
しかし、これらの添加剤のみでは近年発展の著しい密閉
形の鉛蓄電池、すなわち電解液量が少なく制限された電
池に要求される負極板の親水性および吸液性は不充分で
あった。Problems to be Solved by the Invention However, these additives alone cannot meet the hydrophilicity and liquid absorption properties of the negative electrode plate required for sealed lead-acid batteries, which have been rapidly developed in recent years, that is, batteries with a small and limited amount of electrolyte. It was insufficient.
またセパレータに対しても特に負極板に電解液が供給さ
れやすい特性を付与したものはなかった。In addition, there has been no separator that has characteristics that allow the electrolyte to be easily supplied to the negative electrode plate.
問題点を解決するだめの手段
本発明は負極用活物質ペーストに所定の吸液性の微粉末
、親水性の微粉末のいずれか一方あるいはこれらの混合
物の一定量と、この添加剤によって低下する粒子間およ
び活物質と格子界面の導電性を補なうだめの導電性微粉
末の一定量を添加し、親水性、吸液性の向上を図った負
極板と、この負極板と接するセパレータ表面に親水性微
粉末、吸液性微粉末のいずれか一方あるいはこれらの混
合物を塗布、充填してセパレータとの接触率の向上を図
り、負極板の電解液充填率の低下による問題点を解決し
たことを特徴とした鉛蓄電池である。Means to Solve the Problems The present invention provides negative electrode active material paste with a certain amount of either a predetermined liquid-absorbing fine powder, a hydrophilic fine powder, or a mixture thereof, and this additive. A negative electrode plate with a certain amount of conductive fine powder added to compensate for the conductivity between particles and at the interface between the active material and the lattice to improve hydrophilicity and liquid absorption, and the separator surface in contact with this negative electrode plate. By coating and filling either hydrophilic fine powder, liquid-absorbing fine powder, or a mixture thereof into the electrode, the contact rate with the separator was improved, and the problem caused by the decrease in the electrolyte filling rate of the negative electrode plate was solved. This is a lead-acid battery with the following characteristics.
作用
本発明による鉛蓄電池は、負極板の吸液性、親水性が向
上するとともに、電解液を最も多く含むセパレータとの
接触面積が向上するため、長期保存中に電解液中の水分
が電槽壁を通して大気中に拡散し減少して電解液量が所
定量より減少した場合においてもセパレータから電解液
の供給を受けやすいため、長期保存後の問題点の１つで
ある負極板中の電解液の充填率の低下による容量の低下
を抑制することが出来る。In the lead-acid battery according to the present invention, the liquid absorbency and hydrophilicity of the negative electrode plate are improved, and the contact area with the separator containing the largest amount of electrolyte is improved, so that water in the electrolyte is absorbed into the battery during long-term storage. Even if the amount of electrolyte decreases below a predetermined amount due to diffusion through the wall into the atmosphere, it is easy to receive electrolyte from the separator, which is one of the problems after long-term storage. It is possible to suppress a decrease in capacity due to a decrease in filling rate.
実施例
以下、本発明の一実施例を説明する。従来の正極板、負
極板およびセパレータを用いて製作した電池をムとし、
親水性の微粉末として平均粒径が１５ｍμのＳｉＯ２、
Ａｌ２Ｏ３、ＴｉＯ２を添加した負極板および平均粒径
が１５ｍμのＳｉＯ２、Ａｌ２Ｏ３、ＴｉＯ２をガラス
マット表面に１０ｇ／／／塗布したセパレータと従来の
正極板を用いて製作した電池をＢとして、電圧１２ｖ、
容量２，０ムｈの電池を製作した。EXAMPLE An example of the present invention will be described below. The battery is manufactured using conventional positive electrode plates, negative electrode plates, and separators.
SiO2 with an average particle size of 15 mμ as a hydrophilic fine powder,
B is a battery manufactured using a negative electrode plate containing Al2O3 and TiO2, a separator in which 10 g of SiO2, Al2O3, and TiO2 with an average particle size of 15 mμ is coated on the glass mat surface, and a conventional positive electrode plate.
A battery with a capacity of 2.0 μh was manufactured.
この電池の製作条件については上記以外は同一条件で実
施した。This battery was manufactured under the same conditions except for the above.
製作した電池の初期容量および常温で２年間放置した後
に容量の残存率と充電後の回復率の評価を行った。その
結果を次表に示す。The initial capacity of the manufactured battery, the remaining capacity after being left at room temperature for two years, and the recovery rate after charging were evaluated. The results are shown in the table below.
なお、充電条件は次の通りである。Note that the charging conditions are as follows.
１）充電条件：充電電流”８００ｍＡ
設定電圧＝１４，７ｖ
充電時間２６時間
２）放電条件：放電電流＝１．ＯＡ
カット電圧＝１０．５Ｖ
発明の効果
表に示したように本発明を密閉形鉛蓄電池に適用するこ
とにより、長期保存後の自己放電を抑制し、残存率を高
めるとともに充電後の回復率を大幅に向上させることが
出来るものである。1) Charging conditions: Charging current 800mA Set voltage = 14.7V Charging time 26 hours 2) Discharging conditions: Discharging current = 1.OA Cut voltage = 10.5V As shown in the effect table of the invention, the present invention was applied to a sealed type. By applying it to lead-acid batteries, it is possible to suppress self-discharge after long-term storage, increase the survival rate, and significantly improve the recovery rate after charging.
Claims (5)
成される鉛蓄電池であって、前記負極板に吸液性微粉末
、親水性微粉末を単独あるいは混合物で添加するととも
にさらに導電性微粉末を単独あるいは混合物で添加した
負極板と、セパレータとして使用するガラスマットの表
面および内部に上記の吸液性微粉末と親水性微粉末を単
独あるいは混合物で塗布、充填したことを特徴とする鉛
蓄電池。(1) A lead-acid battery consisting of a positive electrode plate, a negative electrode plate, a separator, and an electrolyte, in which a liquid-absorbing fine powder and a hydrophilic fine powder are added alone or in a mixture to the negative electrode plate, and in addition, a conductive fine powder is added to the negative electrode plate. A lead-acid battery comprising: a negative electrode plate to which is added either singly or in a mixture; and a glass mat used as a separator, on the surface and inside of which the above-mentioned liquid-absorbing fine powder and hydrophilic fine powder are applied and filled either singly or as a mixture. .
末および導電性微粉末の添加量が重量比で活物質総量の
０．０１〜３．０％である特許請求の範囲第１項記載の
鉛蓄電池。(2) A claim in which the amount of liquid-absorbing fine powder, hydrophilic fine powder, and conductive fine powder, which are additives of the negative electrode plate, is 0.01 to 3.0% by weight of the total amount of active materials. The lead-acid battery described in paragraph 1.
粉末がＳｉＯ＿２、Ａｌ＿２Ｏ＿３、ＴｉＯ＿２および
希土類元素の酸化物からなる群のいずれかであり、導電
性の微粉末がカーボンであることを特徴とする特許請求
の範囲第１項記載の鉛蓄電池。(3) The liquid-absorbing fine powder is zeolite, the hydrophilic fine powder is one of the group consisting of SiO_2, Al_2O_3, TiO_2 and rare earth element oxides, and the conductive fine powder is carbon. A lead-acid battery according to claim 1, characterized in that:
量が３０ｇ／ｍ＾２以下である特許請求の範囲第１項記
載の鉛蓄電池。(4) The lead-acid battery according to claim 1, wherein the coating amount and filling amount of the separator to the glass mat is 30 g/m^2 or less.
の粒径が平均２００μｍ以下である特許請求の範囲第１
項記載の鉛蓄電池。(5) Claim 1, in which the liquid-absorbing fine powder, the hydrophilic fine powder, and the conductive fine powder have an average particle size of 200 μm or less.
Lead-acid batteries as described in section.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61164909A JPS6319772A (en) | 1986-07-14 | 1986-07-14 | Lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61164909A JPS6319772A (en) | 1986-07-14 | 1986-07-14 | Lead-acid battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6319772A true JPS6319772A (en) | 1988-01-27 |
Family
ID=15802165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61164909A Pending JPS6319772A (en) | 1986-07-14 | 1986-07-14 | Lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6319772A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04326504A (en) * | 1991-04-25 | 1992-11-16 | Elna Co Ltd | Electric double layer capacitor |
| JPH04338623A (en) * | 1991-05-15 | 1992-11-25 | Elna Co Ltd | Electric double layer capacitor |
| JPH07240348A (en) * | 1994-02-28 | 1995-09-12 | Nec Corp | Electrical double layer capacitor |
| GB2305772A (en) * | 1995-09-28 | 1997-04-16 | Kenichi Fujita | Addition of carbon suspension obtained by electrolytic oxidation of carbon to lead-acid battery electrolyte activates electrodes when charged |
| EP0821422A3 (en) * | 1996-07-23 | 2000-07-05 | Matsushita Electric Industrial Co., Ltd. | Sealed lead-acid battery |
| CN1078753C (en) * | 1995-09-29 | 2002-01-30 | 藤田贤一 | Electrolyte and lead accumulator using the same |
-
1986
- 1986-07-14 JP JP61164909A patent/JPS6319772A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04326504A (en) * | 1991-04-25 | 1992-11-16 | Elna Co Ltd | Electric double layer capacitor |
| JPH04338623A (en) * | 1991-05-15 | 1992-11-25 | Elna Co Ltd | Electric double layer capacitor |
| JPH07240348A (en) * | 1994-02-28 | 1995-09-12 | Nec Corp | Electrical double layer capacitor |
| GB2305772A (en) * | 1995-09-28 | 1997-04-16 | Kenichi Fujita | Addition of carbon suspension obtained by electrolytic oxidation of carbon to lead-acid battery electrolyte activates electrodes when charged |
| GB2305772B (en) * | 1995-09-28 | 1998-09-16 | Kenichi Fujita | Electrolyte solution and lead-acid batteries using the same |
| CN1078753C (en) * | 1995-09-29 | 2002-01-30 | 藤田贤一 | Electrolyte and lead accumulator using the same |
| EP0821422A3 (en) * | 1996-07-23 | 2000-07-05 | Matsushita Electric Industrial Co., Ltd. | Sealed lead-acid battery |
| US6492059B1 (en) | 1996-07-23 | 2002-12-10 | Matsushita Electric Industrial Co., Ltd. | Separator for sealed lead-acid battery |
| US7132195B2 (en) | 1996-07-23 | 2006-11-07 | Matsushita Electric Industrial Co., Ltd. | Separator for sealed lead-acid battery |
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