JPS6319764A - Lead-acid battery - Google Patents
Lead-acid batteryInfo
- Publication number
- JPS6319764A JPS6319764A JP61164910A JP16491086A JPS6319764A JP S6319764 A JPS6319764 A JP S6319764A JP 61164910 A JP61164910 A JP 61164910A JP 16491086 A JP16491086 A JP 16491086A JP S6319764 A JPS6319764 A JP S6319764A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- fine powder
- lead
- hydrophilic
- fine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002253 acid Substances 0.000 title claims description 9
- 239000000843 powder Substances 0.000 claims abstract description 24
- 239000011149 active material Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract 2
- 239000008151 electrolyte solution Substances 0.000 claims 1
- 230000007423 decrease Effects 0.000 abstract description 4
- 239000007773 negative electrode material Substances 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 description 7
- 238000007600 charging Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 4
- 238000007599 discharging Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910000464 lead oxide Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical group [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000010280 constant potential charging Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は鉛蓄電池、とくに負極板の特性向上のための添
加剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to lead-acid batteries, particularly additives for improving the characteristics of negative electrode plates.
従来の技術
従来の鉛蓄電池用負極板は鉛あるいは鉛合金を鋳造ある
いはエキスバンド加工などにより集電体格子を作製し
この集電体に、主成分が酸化鉛よりなる活物質原料を塗
着、乾燥し、ついで化成して極板としていた。Conventional technology In the conventional negative electrode plate for lead-acid batteries, a current collector grid is made by casting or expanding lead or lead alloy.
An active material material whose main component is lead oxide was applied to this current collector, dried, and then chemically formed to form an electrode plate.
発明が解決しようとする問題点
この活物質原料は酸化鉛を主体とする鉛′粉と硫酸と水
を混合し練合したもので１機械的強度を改善するために
耐酸性の合成樹脂繊維°を添加したものである。Problems to be Solved by the Invention This active material raw material is a mixture of lead powder mainly composed of lead oxide, sulfuric acid, and water. is added.
またこの他の添加剤として、硫酸バリウム、リグニンス
ルホン酸ナトリウムなどがあるのカである。Other additives include barium sulfate and sodium ligninsulfonate.
しかしこれらの添加剤のみでは近年発展の著しい密閉形
の鉛蓄電池、すなわち電解液量が少なく制限された電池
に要求される負極板の親水性および吸液性の向上には不
充分であった。本発明はこのような問題を解決し、負極
板の特性向上を目的としたものである。However, these additives alone have not been sufficient to improve the hydrophilicity and liquid absorption properties of the negative electrode plate required for sealed lead-acid batteries, which have been rapidly developed in recent years, that is, batteries in which the amount of electrolyte is small and limited. The present invention aims to solve these problems and improve the characteristics of a negative electrode plate.
問題点を解決するための手段
本発明は負極用活物質ペーストに所定の親水性の微粉末
の一定量と、この添加によって低下する粒子間および活
物質と格子間の導電性を補なうため導電性の微粉末の一
定量を添加し、負極板の親水性、吸液性の向上を図った
ことを特徴としたものである。Means for Solving the Problems The present invention adds a certain amount of predetermined hydrophilic fine powder to the negative electrode active material paste, and in order to compensate for the decreased conductivity between particles and between the active material and the lattice due to the addition of this amount. It is characterized by adding a certain amount of conductive fine powder to improve the hydrophilicity and liquid absorption of the negative electrode plate.
作用
本発明による負極板は、電解液に対する親水性が向上す
るため、長期保存中に電解液中の水分が電槽壁を拡散減
少し、電解液量が所定量より減少した場合においても１
親水性に優れるためガラスマットより電解液の供給を受
け、充分に電解液を保持出来る能力を有するものである
。Function The negative electrode plate according to the present invention has improved hydrophilicity with respect to the electrolyte, so even when the water in the electrolyte diffuses through the wall of the battery cell during long-term storage and the amount of the electrolyte decreases below a predetermined amount,
Because of its excellent hydrophilicity, it receives the electrolyte from the glass mat and has the ability to sufficiently hold the electrolyte.
このため、長期保存後の問題点の１つである負極板中の
電解液充填率の低下による容量の低下を抑制することが
出来る。Therefore, it is possible to suppress a decrease in capacity due to a decrease in the electrolyte filling rate in the negative electrode plate, which is one of the problems after long-term storage.
実施例
以下、本発明の一実施例を説明する。従来のペースト処
方によって製作した負極板を人、および親水性の微粉末
として１次粒子の平均粒径が約１６μｍの５ｉ０２を人
の処方に対して重量比で０．６％および導電性の微粉末
として平均粒径が５μｍのグラフ１イトカーボンを同じ
＜０．３％添加して製作した負極板Ｂを用いて、電圧１
２ｖ、容量２．ｏＡｈの電池人およびＢを製作した。EXAMPLE An example of the present invention will be described below. A negative electrode plate manufactured using a conventional paste formulation was used, and a hydrophilic fine powder containing 5i02 with an average primary particle diameter of approximately 16 μm was added at a weight ratio of 0.6% to the human formulation, and a conductive fine powder was added. Using negative electrode plate B manufactured by adding <0.3% of graphite carbon with an average particle size of 5 μm as a powder, a voltage of 1
2v, capacity 2. I made oAh's battery man and B.
この電池の製作条件は、負極板の添加剤を除いてはすべ
て同一条件で実施した。This battery was manufactured under the same conditions except for the additive for the negative electrode plate.
製作した電池の初期容量および常温で２年間放置後の容
量の残存率と充電後の回復率の評価を行った。The initial capacity of the produced battery, the remaining capacity after being left at room temperature for two years, and the recovery rate after charging were evaluated.
その結果を次表に示す。The results are shown in the table below.
（以下余 白） なお充放電条件は次の通υである。(Left below) The charging and discharging conditions are as follows.
（１）充電条件
定電圧充電；充電電流＝８００ｍ人
設定電圧＝ １４．７ Ｖ
充電時間＝６時間
（２）放電条件
放電電流＝１．０人
カット電圧＝１０．５Ｖ
発明の効果
表に示したように本発明を密閉形鉛蓄電池に適用するこ
とにより、長期保存後の自己放電を抑制し、残存率を高
めるとともに充電後の回復率を大幅に向上させることが
出来るものである。(1) Charging conditions Constant voltage charging; Charging current = 800 m person Setting voltage = 14.7 V Charging time = 6 hours (2) Discharging conditions Discharging current = 1.0 person Cut voltage = 10.5 V As shown in the effect table of the invention As described above, by applying the present invention to a sealed lead-acid battery, it is possible to suppress self-discharge after long-term storage, increase the survival rate, and significantly improve the recovery rate after charging.
Claims (4)
成される鉛蓄電池であって、前記負極板には親水性の微
粉末および導電性の微粉末を添加したことを特徴とする
鉛蓄電池。(1) A lead-acid battery comprising a positive electrode plate, a negative electrode plate, a separator, and an electrolytic solution, wherein a hydrophilic fine powder and a conductive fine powder are added to the negative electrode plate.
０．０１〜３．０％であり、導電性の微粉末の添加量が
０．０１〜３．０％である特許請求の範囲第１項記載の
鉛蓄電池。(2) A patent in which the amount of hydrophilic fine powder added is 0.01 to 3.0% by weight of the total amount of active materials, and the amount of conductive fine powder added is 0.01 to 3.0%. A lead-acid battery according to claim 1.
ＴｉＯ＿２、希土類元素の酸化物またはこれらの混合物
であり、導電性の微粉末がカーボンである特許請求の範
囲第１項記載の鉛蓄電池。(3) Hydrophilic fine powder is SiO_2, Al_2O_3,
The lead-acid battery according to claim 1, wherein the conductive fine powder is carbon, which is TiO_2, an oxide of a rare earth element, or a mixture thereof.
の微粉末の粒径が２００μｍ以下である特許請求の範囲
第１項記載の鉛蓄電池。(4) The lead-acid battery according to claim 1, wherein the hydrophilic fine powder has a particle size of 200 μm or less, and the conductive fine powder has a particle size of 200 μm or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61164910A JPS6319764A (en) | 1986-07-14 | 1986-07-14 | Lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61164910A JPS6319764A (en) | 1986-07-14 | 1986-07-14 | Lead-acid battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6319764A true JPS6319764A (en) | 1988-01-27 |
Family
ID=15802181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61164910A Pending JPS6319764A (en) | 1986-07-14 | 1986-07-14 | Lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6319764A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101841032A (en) * | 2010-05-27 | 2010-09-22 | 江苏华富控股集团有限公司 | Method for preparing negative plate of lead storage battery |
| CN104743644A (en) * | 2013-12-27 | 2015-07-01 | 日本华尔卡工业株式会社 | Electrode film for water treatment and its preparation method and use |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5569970A (en) * | 1978-11-22 | 1980-05-27 | Japan Storage Battery Co Ltd | Enclosed type lead storage battery |
| JPS5828179A (en) * | 1981-08-13 | 1983-02-19 | Yuasa Battery Co Ltd | Lead storage battery |
-
1986
- 1986-07-14 JP JP61164910A patent/JPS6319764A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5569970A (en) * | 1978-11-22 | 1980-05-27 | Japan Storage Battery Co Ltd | Enclosed type lead storage battery |
| JPS5828179A (en) * | 1981-08-13 | 1983-02-19 | Yuasa Battery Co Ltd | Lead storage battery |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101841032A (en) * | 2010-05-27 | 2010-09-22 | 江苏华富控股集团有限公司 | Method for preparing negative plate of lead storage battery |
| CN104743644A (en) * | 2013-12-27 | 2015-07-01 | 日本华尔卡工业株式会社 | Electrode film for water treatment and its preparation method and use |
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