JPS63189471A - Readily water-dispersible powder - Google Patents

Readily water-dispersible powder

Info

Publication number
JPS63189471A
JPS63189471A JP62021248A JP2124887A JPS63189471A JP S63189471 A JPS63189471 A JP S63189471A JP 62021248 A JP62021248 A JP 62021248A JP 2124887 A JP2124887 A JP 2124887A JP S63189471 A JPS63189471 A JP S63189471A
Authority
JP
Japan
Prior art keywords
powder
water
alkali metal
acid
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62021248A
Other languages
Japanese (ja)
Inventor
Ikuo Takagishi
郁夫 高岸
Toshinobu Kosaka
小坂 敏信
Katsuhiko Kawabata
克彦 川端
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pentel Co Ltd
Original Assignee
Pentel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pentel Co Ltd filed Critical Pentel Co Ltd
Priority to JP62021248A priority Critical patent/JPS63189471A/en
Publication of JPS63189471A publication Critical patent/JPS63189471A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/56Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms

Abstract

PURPOSE:To obtain the titled powder, readily wettable with water, hardly settling and suitable as water-based ink for writing utensils, liquid cosmetic, liquid painting material, water-based magnetic ink, etc., by adsorbing an alkali metal silicate on the surface thereof. CONSTITUTION:The aimed powder obtained by adsorbing an alkali metal silicate, e.g. sodium salt of metasilicic acid, orthosilicic acid, disilicic acid, tetrasilicic acid, etc., on the surface of powder, e.g. organic or inorganic pigment, metal, metal oxide, extender pigment, resin powder, etc. Furthermore, the amount of the alkali metal silicate is preferably 5-200pts.wt. based on 100pts.wt. powder.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、水に対して濡れ易く、かつ沈降し難い水易分
散性粉体に関し、更に詳細には、筆記具用水性インキ、
液状化粧料1g、状描画材。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a water-dispersible powder that is easily wetted by water and is difficult to settle, and more particularly relates to a water-based ink for writing instruments,
1g of liquid cosmetics, shape drawing material.

水性磁性インキ、ジェットプリンター用を含む記録液等
粉体を水に分散させて用いる物に好適に用いることがで
きろ水易分散性粉体に関するものである。
The present invention relates to a water-easily dispersible powder that can be suitably used in water-based magnetic inks, recording liquids including those for jet printers, and other products in which the powder is dispersed in water.

(従来の技術) 従来、筆記用水性インキ、液状化粧料、液状描画材、水
性磁性インキ、ジェットプリンター用を含む記録液を製
造する場合2着色剤、添加剤等として用いる粉体を水に
分散して用いている。製造時、粉体を水に濡れ易くする
ためには。
(Prior art) Conventionally, when manufacturing water-based writing inks, liquid cosmetics, liquid drawing materials, water-based magnetic inks, and recording liquids including those for jet printers, powders used as colorants, additives, etc. are dispersed in water. It is used as To make powder more easily wetted by water during manufacturing.

界面活性剤を添加し、粉体の濡れ性を向上する方法が最
も一般的であり、又、水に濡れた粉体の沈降を防ぐため
には、ゼラチン等の水溶性高分子等による保護コロイド
作用を用いる方法が一般的であるが、従来は前記2つの
方法を併用して粉体を分散していた。
The most common method is to add a surfactant to improve the wettability of powder, and to prevent sedimentation of powder wet with water, the protective colloid effect of water-soluble polymers such as gelatin is used. Generally, the above two methods have been used in combination to disperse the powder.

(発明が解決しようとする問題点) しかし々がら、従来の界面活性剤及び水溶性高分子を添
加する方法により粉体を分散させようとする場合、十分
な分散性、即ち、良好な蘭れ及び良好な非沈降性を得る
ためには、前記界面活性剤及び水溶性高分子の多量を要
することが多く、この結果 ■ 界面活性剤を多量に用いた場合1表面張力が低くな
りすぎ、筆跡、菫布跡、印字跡等ににじみが発生する。
(Problems to be Solved by the Invention) However, when trying to disperse powder by the conventional method of adding surfactants and water-soluble polymers, it is difficult to obtain sufficient dispersibility, that is, good dispersion. In order to obtain good non-sedimentation properties, a large amount of the above-mentioned surfactant and water-soluble polymer is often required. As a result, if a large amount of surfactant is used, the surface tension becomes too low, resulting in poor handwriting. , bleeding occurs on violet marks, printing marks, etc.

■ 水溶性高分子を多量に用いた場合、粘度が高くなり
すぎ、ペン先やノズルよりのインキの吐出、筆等による
*布時のタッチが悪くなる といった問題点を有していた。
■ When a large amount of water-soluble polymer is used, the viscosity becomes too high, leading to problems such as ink being ejected from the pen tip or nozzle and poor touch when using a brush or the like.

(問題点を解決するだめの手段) そこで本発明は上記問題点に鑑み、粉体自体に、水に濡
れ易く、かつ、沈降し難い性質を付与すべくなされたも
のであって2表面にケイ酸のアルカリ金属塩を吸着処理
してなることを特徴とする水易分散性粉体を要旨とする
ものである。
(Means for Solving the Problems) In view of the above-mentioned problems, the present invention has been devised to impart properties to the powder itself that make it easy to get wet with water and prevent it from settling. The gist of this invention is a water-readily dispersible powder which is produced by adsorption treatment of an alkali metal salt of an acid.

以下1本発明の詳細な説明する。Hereinafter, one aspect of the present invention will be explained in detail.

粉体は、筆記具用水性インキ、液状化粧料。The powder is water-based ink for writing instruments and liquid cosmetics.

液状描画材、水性磁性インキ、ジェットプリンター用を
含む記録液等に通常用いられている。
It is commonly used in liquid drawing materials, water-based magnetic inks, recording liquids including those for jet printers, etc.

有機又は無機顔料、金属又は釡属酸化物1体質顔料、樹
脂粉等が使用可能であるが、この粉体は、前記した用途
に合わせ市販されているものをそのまま或いは後述する
ような方法によって凝集を解きほぐし1微細粒子として
用いても良い。
Organic or inorganic pigments, metal or matrix oxide monolithic pigments, resin powders, etc. can be used, but these powders may be commercially available as they are or agglomerated by the method described below. It may also be used as fine particles after being loosened.

本発明の骨子である。上記粉体表面に吸着させるケイ酸
のアルカリ金属塩とは、具体的には。
This is the gist of the present invention. Specifically, the alkali metal salt of silicic acid to be adsorbed onto the surface of the powder is as follows.

メタケイ酸、オルトケイ酸、ニケイ酸、西ケイ酸のリチ
ウム、ナトリウム、カリウム塩でろり。
Contains lithium, sodium, and potassium salts of metasilicic acid, orthosilicic acid, disilicate acid, and silicic acid.

その使用量は粉体100重量部に対し1重袖部以上であ
れば良いが、5〜200重量部が将に好ましい。
The amount used may be at least 1 part by weight per 100 parts by weight of the powder, but 5 to 200 parts by weight is particularly preferred.

次に、粉体表面にケイ酸のアルカリ金属塩を吸着処理す
る方法について述べると、ケイ酸のアルカリ金属塩水溶
液中に被処理粉体を加え。
Next, a method for adsorbing an alkali metal salt of silicic acid onto the surface of a powder is described. The powder to be treated is added to an aqueous solution of an alkali metal salt of silicic acid.

30分〜数時間攪拌・混合した後、−過、乾探すればよ
く、更に微粒子粉体にして処理する場合には、被処理粉
体を三本ロールミル又はサンドミル等の分散機で分散し
、その粒子径を微細化した分散液中にケイ酸アルカリ金
属塩又はその水溶液を添加し、30分〜数時間攪拌・混
合した後、−過、乾嫌する方法によってもよい。
After stirring and mixing for 30 minutes to several hours, it is sufficient to filter and dry the mixture.If the powder is to be further processed into fine particles, the powder to be processed is dispersed using a dispersing machine such as a three-roll mill or a sand mill. Alternatively, an alkali metal silicate or an aqueous solution thereof may be added to a dispersion having a fine particle size, stirred and mixed for 30 minutes to several hours, and then filtered and dried.

尚、処理時、粉体がケイ酸のアルカリ金属塩水浴液に濡
れ難かったり1分散機で微細化する時分散し難かったり
した場合には、少量の界面活性剤を加えてもよく、更に
効果を上げるために攪拌・混合中加熱を行なっても良い
During treatment, if the powder is difficult to wet with the silicic acid alkali metal salt bath solution or difficult to disperse when finely divided using a dispersion machine, a small amount of surfactant may be added to further improve the effect. Heating may be performed during stirring and mixing to increase the temperature.

(作用ン 本発明に係る2表面にケイ酸のアルカリ金属塩を吸着処
理した粉体が、水に対して濡れ易く。
(Action: 2) The powder according to the present invention, whose surface has been treated with adsorption of an alkali metal salt of silicic acid, is easily wetted by water.

かつ、沈降し難い性質を有するのかについては定かでは
ないが、粉体の表面にケイ酸のアルカリ塩が吸着・fi
覆することにより、粉体の表面の親水性が増大するため
と考察される。
In addition, although it is not certain whether the powder has the property of being difficult to settle, the alkali salt of silicic acid is adsorbed onto the surface of the powder.
It is considered that this is because the hydrophilicity of the surface of the powder increases by inverting the powder.

(実施例〉 以下1本発明を実施例にて詳細に説明するが。(Example> The present invention will be explained in detail below using examples.

以後の記載において「部」とあるのは特にことわらない
眠り「i置部」を示す。
In the following description, the term "part" indicates the sleep "i-place part" unless otherwise specified.

実施例1 メタケイ酸ナトリウム        20部弁柄  
             10部水        
                  100 部メタ
ケイ鈑ナトリウムを水に溶解させ、この水溶液に攪拌し
ながら弁柄を加え、更に1時間攪拌・混合した後−過、
乾味して水易分散性表面処理弁柄粉体を得た。
Example 1 Sodium metasilicate 20 parts Bengara
10 parts water
Dissolve 100 parts of sodium metasilicate in water, add Bengara to this aqueous solution while stirring, stir and mix for an additional hour, and then filtrate.
After drying, a water-easily dispersible surface-treated Bengara powder was obtained.

実施例2 オルトケイ酸カリウム        4部ニソコール
NP−10(ポリオキ ンエチレンノニルフェニルエー チル、日光ケミカルノー。掬製)    0.2 部赤
色226号           20部水     
                     ioo 
 部上記成分中、赤色226号以外の各成分を混合・攪
拌・溶解し、これに赤色226号を加え1時間攪拌・混
合した後、−過、転線して水易分散性表面処理赤色22
6最初体を得た。
Example 2 Potassium orthosilicate 4 parts Nisocol NP-10 (Polyoxine ethylene nonylphenyl ethyl, manufactured by Nikko Chemical No. Kiki) 0.2 parts Red No. 226 20 parts Water
ioo
Of the above components, each component other than Red No. 226 was mixed, stirred, and dissolved, and Red No. 226 was added to this and stirred and mixed for 1 hour.
6 I got my first body.

実施例3 ニケイ酸リチウム          8部透明性黒酸
化鉄          10部水         
                 100 部ニケイ
酸リチウムを水に溶解させ、この水溶液に透明注黒板化
扶を加え、90°Cに加熱しながら6時間攪拌・混合し
室温迄放冷した鎌、濾過、乾燥して水易分故性表面処理
透明性黒酸化鉄粉体を得た。   ′ 実施例4 四ケイ酸ナトリウム        15部ナイロン粉
(東し111      10部水         
                  100 部門ケ
イ酸ナトリウムを水に4解させ、この水d液にナイロン
粉を加え、2時間撹拌・混合したffl+1濾過、乾燥
して水易分散性表面処理処ナイロン粉体を得た。
Example 3 Lithium disilicate 8 parts Transparent black iron oxide 10 parts Water
Dissolve 100 parts of lithium disilicate in water, add a transparent chalkboard to this aqueous solution, stir and mix while heating to 90°C for 6 hours, cool to room temperature, filter, dry and dissolve in water. A transparent black iron oxide powder with surface treatment was obtained. ' Example 4 Sodium tetrasilicate 15 parts Nylon powder (Higashi 111 10 parts water
100 Division Sodium silicate was dissolved in water, nylon powder was added to this aqueous d solution, stirred and mixed for 2 hours, ffl+1 filtration, and dried to obtain water-easily dispersible surface-treated nylon powder.

実施例5 ケイ酸ナトリウム          25部ウオッチ
ングレッド        20部水        
                  100 部ウオ
ッチングレッドと水とを30分間攪拌・混合した後、サ
ンドミルで2時間分散、微、細化したものにケイ酸ナト
リウムを加え30分攪拌・混合して、更に遠心分離機に
て分離した沈殿物を乾燥し水易分散性表面処理ウオッチ
ングレッド粉体を得た。
Example 5 Sodium silicate 25 parts Watching red 20 parts Water
After stirring and mixing 100 parts of watching red and water for 30 minutes, they were dispersed for 2 hours in a sand mill, finely ground, added sodium silicate, stirred and mixed for 30 minutes, and then separated using a centrifuge. The precipitate was dried to obtain a water-easily dispersible surface-treated watching red powder.

比較例1〜5 実施例1〜5に用いた粉体の未処理のものを比較例1〜
5とした。
Comparative Examples 1 to 5 Untreated powders used in Examples 1 to 5 were used in Comparative Examples 1 to 5.
I gave it a 5.

(発明の効果) 前記実施例1〜5及び比較例1〜4の粉体各10部を水
100部に加え攪拌・混合し分散液としたもの、及び、
比・収例5の粉体20部と水100部とを30分攪拌・
混合した後、サンドミルで2時間分散微細化して分散液
としたものについて試験を行なった。
(Effect of the invention) 10 parts each of the powders of Examples 1 to 5 and Comparative Examples 1 to 4 were added to 100 parts of water and stirred and mixed to form a dispersion, and
Ratio/Yield 20 parts of the powder of Example 5 and 100 parts of water were stirred for 30 minutes.
After mixing, the mixture was dispersed and finely dispersed in a sand mill for 2 hours to obtain a dispersion liquid, which was then tested.

結果を表に示す。The results are shown in the table.

※1濡れ・・・粉体を水に添加した時の粉体の儒れ具合
を観察し評価した。
*1 Wetness: Evaluated by observing the degree of crumbling of the powder when it was added to water.

○:すぐ濡れる Δ:濡れる迄時間がかかる ×:mれない X2沈降度・・・各分散液について攪拌・混合を行なっ
た後、試験管に入れ5分間静置し。
○: Gets wet easily Δ: Takes time to get wet ×: Doesn't get wet

粉体の沈降娑を観察し評価した。The sedimentation of the powder was observed and evaluated.

○:沈降少ない Δ;半分位沈降 ×:全部沈降 以上詳細に説明したように1本発明に係る水易分散性粉
体は、水に対する濡れ易さ及び水に濡らした粉体の耐沈
降性が向上しているので。
○: Less sedimentation Δ; Half sedimentation ×: Total sedimentation or more As explained in detail, the water-ready dispersible powder according to the present invention has a high wettability with water and a high sedimentation resistance of the powder when wetted with water. Because it's improving.

該粉体を、筆記具用水性インキ、液状化粧料。The powder is used as water-based ink for writing instruments and liquid cosmetics.

液状描画材、水性磁性インキ、ジェットプリンター用を
含む記録液等に適用する場合、未処理の粉体を用いる場
合に比べ、界面活性剤や水溶性高分子の使用が不要とな
る。もしくはその使用址を低く押さえることができるの
で1表面張力の低下や粘度の上昇が少なく、前述したに
じみや吐出、タッチの不良が発生しないのみならず、上
記各種の製品特有の性質を向上する為の各種の防カビ剤
、防錆剤、浸透剤、凍結防止剤。
When applied to liquid drawing materials, water-based magnetic inks, recording liquids for jet printers, etc., there is no need to use surfactants or water-soluble polymers compared to when using untreated powder. Or, since the usage area can be kept low, 1 there is less decrease in surface tension and increase in viscosity, which not only prevents the aforementioned bleeding, discharge, and touch defects, but also improves the properties specific to the various products mentioned above. Various mold inhibitors, rust inhibitors, penetrants, and antifreeze agents.

保湿剤、粘度調整剤等の添加剤の使用が限定されないと
いう利点も生じる非常に優れたものである。
This is an excellent product that has the advantage that the use of additives such as humectants and viscosity modifiers is not limited.

Claims (1)

【特許請求の範囲】[Claims] 表面にケイ酸のアルカリ金属塩を吸着処理してなること
を特徴とする水易分散性粉体。
A water easily dispersible powder characterized by having its surface adsorbed with an alkali metal salt of silicic acid.
JP62021248A 1987-01-31 1987-01-31 Readily water-dispersible powder Pending JPS63189471A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62021248A JPS63189471A (en) 1987-01-31 1987-01-31 Readily water-dispersible powder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62021248A JPS63189471A (en) 1987-01-31 1987-01-31 Readily water-dispersible powder

Publications (1)

Publication Number Publication Date
JPS63189471A true JPS63189471A (en) 1988-08-05

Family

ID=12049759

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62021248A Pending JPS63189471A (en) 1987-01-31 1987-01-31 Readily water-dispersible powder

Country Status (1)

Country Link
JP (1) JPS63189471A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277580A (en) * 2014-10-27 2015-01-14 合肥旭阳铝颜料有限公司 Luminescent aluminum pigment for waterborne ink and preparation method of luminescent aluminum pigment
CN104312219A (en) * 2014-10-20 2015-01-28 合肥旭阳铝颜料有限公司 Water-based aluminum pigment for ink and preparation method thereof
CN104341801A (en) * 2014-09-29 2015-02-11 合肥旭阳铝颜料有限公司 Fireproof aluminum pigment and preparation method thereof
CN104341803A (en) * 2014-10-25 2015-02-11 合肥旭阳铝颜料有限公司 High-temperature-resistant aluminum pigment and preparation method thereof
CN104371408A (en) * 2014-10-27 2015-02-25 合肥旭阳铝颜料有限公司 Luminous aluminum pigment for water-based paint and preparation method of luminous aluminum pigment

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104341801A (en) * 2014-09-29 2015-02-11 合肥旭阳铝颜料有限公司 Fireproof aluminum pigment and preparation method thereof
CN104312219A (en) * 2014-10-20 2015-01-28 合肥旭阳铝颜料有限公司 Water-based aluminum pigment for ink and preparation method thereof
CN104341803A (en) * 2014-10-25 2015-02-11 合肥旭阳铝颜料有限公司 High-temperature-resistant aluminum pigment and preparation method thereof
CN104277580A (en) * 2014-10-27 2015-01-14 合肥旭阳铝颜料有限公司 Luminescent aluminum pigment for waterborne ink and preparation method of luminescent aluminum pigment
CN104371408A (en) * 2014-10-27 2015-02-25 合肥旭阳铝颜料有限公司 Luminous aluminum pigment for water-based paint and preparation method of luminous aluminum pigment

Similar Documents

Publication Publication Date Title
JP5399997B2 (en) Modified carbon products for inks and coatings with free groups
EP2831181B1 (en) Oxidized carbon blacks treated with polyetheramines and coating compositions comprising same
JPH05194892A (en) Liquid ink composition
JP4189258B2 (en) Modified carbon black dispersion and water-based ink containing the same
JP4713710B2 (en) Aqueous carbon black dispersion, production method thereof and use thereof
JP6031175B2 (en) Titanium dioxide pigment, method for producing the same, and printing ink composition
JPH06128517A (en) Ink and coloring agent for ink
CN107652777A (en) A kind of environment-friendly aqueous nanometer is modified ink-jet ink and its preparation method and application
JPH1160231A (en) Amorphous silica particle having dual structure, its production and use
JP2018188518A (en) Pigment composition and aqueous ink composition for inkjet
JPS62177070A (en) Coloring solution
JP6697532B2 (en) Pigment composition and aqueous ink composition for inkjet
JPS63189471A (en) Readily water-dispersible powder
JPH0345112B2 (en)
JP3646506B2 (en) Surface-treated carbon black, method for producing the same, and dispersion using the same
JP2010532398A (en) Dioxazine-based pigment formulation
US2479836A (en) Finishing of pigments
JP5037958B2 (en) Water-based ballpoint pen ink composition
JP2002294133A (en) Aqueous pigment dispersion and ink composition
JP2000345086A (en) Aqueous ink composition
JP2008195837A (en) Surface treated carbon black and its manufacturing method, water dispersion formed by dispersing same, and cosmetic, ink and coating containing the dispersion
JP2000345085A (en) Aqueous ink composition
JPH11256068A (en) Carbon black dispersion
JP2000017189A (en) Aqueous carbon black dispersion and aqueous ink using the same
JP4699830B2 (en) Aqueous silica slurry with excellent storage stability