JPS63159309A - Hair cosmetic - Google Patents
Hair cosmeticInfo
- Publication number
- JPS63159309A JPS63159309A JP30942386A JP30942386A JPS63159309A JP S63159309 A JPS63159309 A JP S63159309A JP 30942386 A JP30942386 A JP 30942386A JP 30942386 A JP30942386 A JP 30942386A JP S63159309 A JPS63159309 A JP S63159309A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- group
- alkyl
- carbon atoms
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 10
- 150000002148 esters Chemical class 0.000 claims abstract description 10
- 239000000194 fatty acid Substances 0.000 claims abstract description 10
- 229930195729 fatty acid Natural products 0.000 claims abstract description 10
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 10
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 7
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 3
- 125000005843 halogen group Chemical group 0.000 claims abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 3
- 125000005526 alkyl sulfate group Chemical group 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 238000001035 drying Methods 0.000 abstract description 3
- 150000008051 alkyl sulfates Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- -1 mono long chain alkyl pentaethoxylated ammonium chloride Chemical class 0.000 description 10
- 230000003766 combability Effects 0.000 description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000003676 hair preparation Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 230000003719 hair strength Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 206010044625 Trichorrhexis Diseases 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 229960000735 docosanol Drugs 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DGSZGZSCHSQXFV-UHFFFAOYSA-N 2,3-bis(2-ethylhexanoyloxy)propyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(OC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DGSZGZSCHSQXFV-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Chemical class 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Chemical class 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Chemical class 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- PFKRTWCFCOUBHS-UHFFFAOYSA-N dimethyl(octadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH+](C)C PFKRTWCFCOUBHS-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- SFFVATKALSIZGN-UHFFFAOYSA-N hexadecan-7-ol Chemical compound CCCCCCCCCC(O)CCCCCC SFFVATKALSIZGN-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Chemical class 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229920000609 methyl cellulose Chemical class 0.000 description 1
- 239000001923 methylcellulose Chemical class 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- VLAQWJMMSTXOEI-UHFFFAOYSA-N tetracosyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCCCCCC VLAQWJMMSTXOEI-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は洗髪、乾燥後の毛髪に優れた腰の強さ。[Detailed description of the invention] [Industrial application field] The present invention provides excellent strength to the hair after washing and drying.
櫛通り性及びなめらかさを与える毛髪化粧料に関する。This invention relates to a hair cosmetic that provides combability and smoothness.
〔従来の技術及び発明が解決しようとする問題点］通常
、毛髪は、ヘアークリームやヘアーオイル等の動植物油
及び毛髪自身から分泌される皮脂等により覆われている
が、石ケンや合成洗剤等で洗髪すると、それらの油脂成
分は必要以上に除去されてしまう。そのため、洗髪後の
毛髪はなめらかさが失なわれ、パサパサした硬い感触と
なり、櫛通りが悪くなって裂毛や枝毛が生じやすくなっ
てしまう。[Prior art and problems to be solved by the invention] Normally, hair is covered with animal and vegetable oils such as hair creams and hair oils, as well as sebum secreted from the hair itself. When you wash your hair with it, those oils and fats are removed more than necessary. As a result, the hair after washing loses its smoothness, feels dry and stiff, and becomes difficult to comb, resulting in split ends and split ends.
従来このような不都合を解消するための毛髪化粧料とし
て、ステアリルジメチルアンモニウムクロライドやセチ
ルトリメチルアンモニウムクロライドに代表される第４
級アンモニウム塩と、セチルアルコール、ステアリルア
ルコール、ベヘニルアルコールなどの高級アルコールと
を有効成分とするものが提案されている。これら第４級
アンモニウム塩と高級アルコールとを有効成分とした毛
髪化粧料は毛髪に櫛通り性、柔軟性を付与する効果をあ
る程度有する÷反面、毛髪の腰がなくなり、ふくよかさ
やボリューム感に欠けた猫毛状になってしまい、その後
の毛髪処理（セット、ウェービング等）性が悪化するな
どの問題点を有している。Conventionally, as hair cosmetics to eliminate such inconveniences, hair cosmetics such as stearyldimethylammonium chloride and cetyltrimethylammonium chloride have been used.
It has been proposed that the active ingredients are a grade ammonium salt and a higher alcohol such as cetyl alcohol, stearyl alcohol, and behenyl alcohol. Hair cosmetics containing these quaternary ammonium salts and higher alcohols as active ingredients have the effect of imparting combability and flexibility to the hair to some extent, but on the other hand, the hair loses its elasticity and lacks fullness and volume. The problem is that the hair becomes cat-hair-like, and the subsequent hair treatment (setting, waving, etc.) becomes difficult.
又、毛髪に腰の強さを与える目的では、高分子物質を配
合した試みがなされているが、多くの場合は毛髪にある
程度の腰の強さは与えるものの、毛髪がごわついたりフ
レーキングをおこしたりあるいは物質特有の不快臭がす
るなど欠点を有している。In addition, attempts have been made to incorporate polymeric substances in order to give hair strength, but in many cases, although they do give some strength to the hair, they tend to cause stiffness or flaking of the hair. It has drawbacks such as causing a nuisance or emitting an unpleasant odor peculiar to the substance.
このため毛髪毛髪に腰の強さ、櫛通り性、なめらかさを
与えることのできる毛髪化粧料が強く要望されていた。For this reason, there has been a strong demand for hair cosmetics that can give hair strength, combability, and smoothness.
［問題点を解決するための手段］
本発明による毛髪化粧料は、一般式（Ｉ）で表わされる
第４級アンモニウム塩の１種又は２種以上を０．１〜１
０重量％と、炭素数が２０以上の１価及び１又は２価の
アルコールと脂肪酸とのエステルで３０℃で固体である
ものを１〜１０重量９６を含むことを特徴とするもので
ある。[Means for Solving the Problems] The hair cosmetic according to the present invention contains one or more quaternary ammonium salts represented by the general formula (I) in an amount of 0.1 to 1
It is characterized by containing 0% by weight and 1 to 10% by weight of esters of fatty acids and monohydric and monohydric or dihydric alcohols having 20 or more carbon atoms, which are solid at 30°C.
［式中、Ｒ１＋ Ｒ２、Ｒ３又はＲ４のうち、１個又は
２個は炭素数８〜２４の直鎖若しくは分枝鎖アルキル基
、ヒドロキシアルキル基又はＲｓ−（ＯＣＨ２ｃ ｈ２
） ａ （ここでＲ５は数８〜２４のアルキル基又は
ヒドロキシアルキル基を示し、ａは１〜１０の整数であ
る。）であり、他は炭素数１〜３のアルキル基、ベンジ
ル基又は子又はメチル基を示し、ｂは１〜５の整数であ
る。[In the formula, one or two of R1+ R2, R3 or R4 is a straight or branched alkyl group having 8 to 24 carbon atoms, a hydroxyalkyl group, or Rs-(OCH2c h2
) a (Here, R5 represents an alkyl group having 8 to 24 carbon atoms or a hydroxyalkyl group, and a is an integer of 1 to 10.), and the others are an alkyl group having 1 to 3 carbon atoms, a benzyl group, or a hydroxyalkyl group. or represents a methyl group, and b is an integer of 1 to 5.
）Ｘはハロゲン原子又は炭素数１若しくは２のアルキル
硫酸基である。］
本発明の第１の必須成分である一般式［Ｉ］で表わされ
る第４級アンモニウム塩の代表例として、モノ長鎖アル
キルトリメチルアンモニウムクロライド、ジ長鎖アルキ
ルジメチルアンモニウムクロライド、ジ長鎖アルキル−
ビス−（２−ヒドロキシエチル）アンモニウムクロライ
ド、ジ長鎖アルキルメチル（２−ヒドロキシエチル）ア
ンモニウムクロライド、モノ長鎖アルキルジメチル（２
−ヒドロキシエチル）アンモニウムクロライド、モノ長
鎖アルキルペンタエトキシ化アンモニウムクロライド、
ジ長鎖アルキルポリエトキシ化アンモニウムクロライド
を挙げることができる。これらは単独でも組み合わせて
も用いることができる。) X is a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms. ] Representative examples of the quaternary ammonium salt represented by the general formula [I], which is the first essential component of the present invention, include mono-long-chain alkyltrimethylammonium chloride, di-long-chain alkyldimethylammonium chloride, di-long-chain alkyl-
Bis-(2-hydroxyethyl)ammonium chloride, di-long-chain alkylmethyl(2-hydroxyethyl)ammonium chloride, mono-long-chain alkyldimethyl(2-hydroxyethyl)ammonium chloride,
-hydroxyethyl) ammonium chloride, mono long chain alkyl pentaethoxylated ammonium chloride,
Mention may be made of dilong-chain alkyl polyethoxylated ammonium chloride. These can be used alone or in combination.
第４級アンモニウム塩の配合量は０．１〜１０１０％で
あり、好ましくは０．１〜５重量％である。The content of the quaternary ammonium salt is 0.1 to 1010%, preferably 0.1 to 5% by weight.
０、１ｆｆ（ｆｕ％未満では本発明の効果が発揮されず
、１０重量％を超えると毛髪にべたつきが生じなめらか
さ櫛通り性が劣化する。If it is less than 0 or 1 ff (fu%), the effect of the present invention will not be exhibited, and if it exceeds 10% by weight, the hair will become sticky and the smoothness and combability will deteriorate.
本発明の第２の必須成分である３０℃で固体であるエス
テルの代表例としてモンタン酸セリル。Seryl montanate is a representative example of the ester that is solid at 30°C, which is the second essential component of the present invention.
ベヘニン酸テトラコシル，ヘブタコ酸エイコシル等を挙
げることができる。これらは単独でも組み合わせても用
いることができる。これらエステルの配合量は１〜１０
重量％であり１重量％未満では本発明の効果が発揮され
ず１０重量％を超えると毛髪が重くなり櫛通り性が劣化
する。Examples include tetracosyl behenate and eicosyl hebutacate. These can be used alone or in combination. The blending amount of these esters is 1 to 10
If it is less than 1% by weight, the effect of the present invention will not be exhibited, and if it exceeds 10% by weight, the hair will become heavy and the combability will deteriorate.
本発明組成物中には、その種類、使用目的等に応じ、本
発明の効果に影響を与えない範囲で、任意の他の成分を
配合することができる。このような任意の成分には、次
のものがある。The composition of the present invention may contain any other components depending on its type, purpose of use, etc., as long as it does not affect the effects of the present invention. Such optional ingredients include:
即ち流動パラフィン、ワセリン、固形パラフィン、スク
ワラン及びオレフィンオリゴマーなどの炭化水素；イソ
プロピルミリステート、イソプロピルパルミテート及び
２−エチルヘキサン酸トリグリセライドなどのエステル
：ツバキ油，オリーブ油，アボガド油．パーシック油等
の植物油：ベヘニルアルコール及びヘキシルデカノール
などの高級アルコール：グリセリル脂肪酸エステル、ソ
ルビタン脂肪酸エステル、ポリオキシエチレン脂肪酸エ
ステル、ポリグリセリン脂肪酸エステル及びポリオキシ
エチレンソルビタン脂肪酸エステルなどの乳化剤；メチ
ルセルロース、ヒドロキシエチルセルロース、ヒドロキ
シプロピルセルロース及びカチオン化セルロースなどの
セルロース誘導体；天然高分子類等の増粘剤；エチレン
グリコール、プロピレングリコール、１，３−ブチレン
ゲリコール、グリセリン及びツルビートルなどの保湿剤
；ポリエチレングリコール、高級脂肪酸エタノールアミ
ド、雲母チタン及び魚すン箔等のパール光沢付与剤；そ
の他溶剤、殺菌剤、キレート剤。Hydrocarbons such as liquid paraffin, vaseline, solid paraffin, squalane and olefin oligomers; esters such as isopropyl myristate, isopropyl palmitate and 2-ethylhexanoic acid triglyceride; camellia oil, olive oil, avocado oil. Vegetable oils such as persic oil; Higher alcohols such as behenyl alcohol and hexyldecanol; Emulsifiers such as glyceryl fatty acid esters, sorbitan fatty acid esters, polyoxyethylene fatty acid esters, polyglycerin fatty acid esters and polyoxyethylene sorbitan fatty acid esters; Methyl cellulose, hydroxyethyl cellulose, hydroxypropyl Cellulose derivatives such as cellulose and cationized cellulose; Thickeners such as natural polymers; Humectants such as ethylene glycol, propylene glycol, 1,3-butylene gellicol, glycerin, and sulfur beetles; Polyethylene glycol, higher fatty acid ethanolamide , mica titanium, and pearl luster imparting agents such as fish starch foil; other solvents, bactericidal agents, and chelating agents.
紫外線吸収剤１着色剤、香料などであり、これらの１種
又は２種以上を配合することができる。Ultraviolet absorber 1 Colorant, fragrance, etc., and one or more of these can be blended.
［発明の効果］ 本発明の毛髪化粧料によれば、例えば均一状態。[Effect of the invention] According to the hair cosmetic of the present invention, for example, the hair cosmetic can be in a uniform state.
不均一状態、乳化状態等のいずれの状態においても、ま
たすすぎを必要とするタイプ、しないタイプのいずれの
タイプにおいても、毛髪に腰の強さ、櫛通り性及びなめ
らかさを与えることができる。It can give the hair strength, combability and smoothness in any state such as a non-uniform state or an emulsified state, and whether it requires rinsing or not.
従ってヘアリンス剤、ヘアトリトートメント、ディスペ
ンサー型のヘアコンディイショナー、ヘローローション
など様々な用途手に用いることができる。Therefore, it can be used for various purposes such as hair rinse, hair treatment torment, dispenser type hair conditioner, and hello lotion.
［実施例］
次に本発明の実施例を示し、本発明の効果をより具体的
に説明する。なお各側の説明に先立ち、試験方法につい
て説明する。[Example] Next, Examples of the present invention will be shown to explain the effects of the present invention more specifically. Before explaining each side, we will explain the test method.
く腰の強さ〉
シャンプー処理された毛束（Ｉ０９，２００１）に試料
１９を直接塗布し、手で毛束全体に均一に伸ばした。次
いで約４０℃の湯で軽くすすいだ後、２５℃φ相対湿度
６５％の恒温恒湿雰囲気下で一昼夜放置乾燥した。Strength> Sample 19 was applied directly to the shampoo-treated hair bundle (I09, 2001) and spread evenly over the entire hair bundle by hand. Next, after rinsing lightly with hot water at about 40°C, it was left to dry overnight in a constant temperature and humidity atmosphere of 25°C and 65% relative humidity.
この毛束のしっとり感について、２０名の試験者により
官能評価した。毛束のしっとり感についての評価は、１
重量％のステアリルトリメチルアンモニウムクロライド
、３ｉＩｆｌｉｌ＜％のセチルアルコール。１０′ｆｒ
１ｍ％のプロピレングリコール及び水（残部）からなる
標準試料を用いて得た評価を基準とし、これとの比較に
よる下記５段階による評価で判定した。The moist feeling of this hair bundle was sensory evaluated by 20 testers. The evaluation for the moist feeling of the hair bundle is 1
wt% stearyltrimethylammonium chloride, 3iIflil<% cetyl alcohol. 10'fr
The evaluation was based on the evaluation obtained using a standard sample consisting of 1 m% propylene glycol and water (the remainder), and was compared with the evaluation using the following five steps.
◎：基準と比べてよい
Ｏ：基準と比べてややよい
Δ：基準と同等
×：基準と比べてやや劣る
××：基準と比べて劣る
くなめらかさ〉
前述の腰の強さと同様の評価方法、評価基準で判定した
。◎: Good compared to the standard O: Slightly better than the standard Δ: Equal to the standard ×: Slightly inferior compared to the standard , the evaluation criteria were used.
実施例１〜５及び比較例１〜８
第１表に示す組成の１３種の毛髪化粧料を調製し、その
効能を試験した。結果を同表に示す。なお表中の数字は
重量％を示す。Examples 1 to 5 and Comparative Examples 1 to 8 Thirteen types of hair cosmetics having the compositions shown in Table 1 were prepared and their efficacy was tested. The results are shown in the same table. Note that the numbers in the table indicate weight %.
この表から本発明の毛髪化粧料は第４級アンモニウム塩
、又はエステルのいずれかを欠いたもの（比較例１〜４
）、エステルの配合量が１重量％未満のもの（比較例５
）及び第４級アンモニウム塩の配合量が０．１重量％未
満のもの（比較例７）は、腰の強さ、なめらかさ及び櫛
通り性の全てにわたって所望の効果を得ることがないこ
とが分かる。又、エステルの配合量が１０重量％を超え
るもの（比較例６）、及び第４級アンモニウム塩の配合
量が１０重量％を超えるもの（比較例８）は、腰の強さ
は与えるものの反面なめらかさ、櫛通り準試料に比し乾
燥後の毛髪の腰の強さ、なめらかさおよび櫛通り性のい
ずれもがより優れていることが知見される。From this table, it can be seen that the hair cosmetics of the present invention lack either quaternary ammonium salt or ester (Comparative Examples 1 to 4).
), with an ester content of less than 1% by weight (Comparative Example 5)
) and quaternary ammonium salt in an amount of less than 0.1% by weight (Comparative Example 7), it may not be possible to obtain the desired effects in terms of stiffness, smoothness, and combability. I understand. In addition, those containing more than 10% by weight of ester (Comparative Example 6) and those containing more than 10% by weight of quaternary ammonium salt (Comparative Example 8) provide stiffness, but on the other hand, It is found that all of the stiffness, smoothness, and combability of the hair after drying are superior to the smoothness and combability quasi-samples.
Claims (1)
種又は２種以上を０．１〜１０重量％と、炭素数が２０
以上の１価及び１又は２価のアルコールと脂肪酸とのエ
ステルで３０℃で固体であるものを１〜１０重量％を含
むことを特徴とする毛髪化粧料。 ▲数式、化学式、表等があります▼（ I ） ［式中、Ｒ＿１、Ｒ＿２、Ｒ＿３又はＲ＿４のうち、１
個又は２個は炭素数８〜２４の直鎖若しくは分枝鎖アル
キル基、ヒドロキシアルキル基又はＲ＿５−（ＯＣＨ＿
２ＣＨ＿２）＿ａ（ここでＲ＿５は炭素数８〜２４のア
ルキル基又はヒドロキシアルキル基を示し、ａは１〜１
０の整数である。）であり、他は炭素数１〜３のアルキ
ル基、ベンジル基又は−（−ＣＨＣＨ＿２Ｏ）＿ｂＨ（
ここでＲ＿６は水素原子又はメチル基を示し、ｂは１〜
５の整数である。）Ｘはハロゲン原子又は炭素数１若し
くはＺのアルキル硫酸基である。］[Claims] One of the quaternary ammonium salts represented by the general formula (I)
Species or two or more species in an amount of 0.1 to 10% by weight and a carbon number of 20
A hair cosmetic comprising 1 to 10% by weight of the above-mentioned ester of monohydric and monohydric or dihydric alcohol and fatty acid, which is solid at 30°C. ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (I) [In the formula, 1 of R_1, R_2, R_3 or R_4
or 2 is a straight chain or branched alkyl group having 8 to 24 carbon atoms, a hydroxyalkyl group, or R_5-(OCH_
2CH_2)_a (here, R_5 represents an alkyl group or hydroxyalkyl group having 8 to 24 carbon atoms, and a is 1 to 1
It is an integer of 0. ), and the others are an alkyl group having 1 to 3 carbon atoms, a benzyl group, or -(-CHCH_2O)_bH(
Here, R_6 represents a hydrogen atom or a methyl group, and b is 1 to
It is an integer of 5. ) X is a halogen atom or an alkyl sulfate group having 1 or Z carbon atoms. ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30942386A JPS63159309A (en) | 1986-12-24 | 1986-12-24 | Hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30942386A JPS63159309A (en) | 1986-12-24 | 1986-12-24 | Hair cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63159309A true JPS63159309A (en) | 1988-07-02 |
Family
ID=17992825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30942386A Pending JPS63159309A (en) | 1986-12-24 | 1986-12-24 | Hair cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63159309A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0407040A2 (en) * | 1989-06-21 | 1991-01-09 | Colgate-Palmolive Company | Cationic surface active fibre conditioning compositions comprising compounds including long chain hydrocarbyl groups |
| EP0410567A2 (en) * | 1989-06-21 | 1991-01-30 | Colgate-Palmolive Company | Liquid dishwashing detergent composition |
| GR900100470A (en) * | 1989-06-21 | 1991-11-15 | Colgate Palmolive Co | Liquid detergent composition for dish washers |
| GR900100471A (en) * | 1989-06-21 | 1991-11-15 | Colgate Palmolive Co | Smoothing compositions for fibers |
| FR2940097A1 (en) * | 2008-12-19 | 2010-06-25 | Oreal | Cosmetic composition, useful for cosmetic treatment of keratin fibers, preferably hair, comprises polysaccharides of lambda carrageenan type and esters of fatty acid and fatty alcohol in a medium |
| JP2017507978A (en) * | 2014-03-21 | 2017-03-23 | ダウ グローバル テクノロジーズ エルエルシー | Hair oil conditioning agent |
-
1986
- 1986-12-24 JP JP30942386A patent/JPS63159309A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0407040A2 (en) * | 1989-06-21 | 1991-01-09 | Colgate-Palmolive Company | Cationic surface active fibre conditioning compositions comprising compounds including long chain hydrocarbyl groups |
| EP0410567A2 (en) * | 1989-06-21 | 1991-01-30 | Colgate-Palmolive Company | Liquid dishwashing detergent composition |
| EP0410567A3 (en) * | 1989-06-21 | 1991-09-04 | Colgate-Palmolive Company | Liquid dishwashing detergent composition |
| EP0407040A3 (en) * | 1989-06-21 | 1991-09-11 | Colgate-Palmolive Company | Cationic surface active fibre conditioning compositions comprising compounds including long chain hydrocarbyl groups |
| GR900100470A (en) * | 1989-06-21 | 1991-11-15 | Colgate Palmolive Co | Liquid detergent composition for dish washers |
| GR900100471A (en) * | 1989-06-21 | 1991-11-15 | Colgate Palmolive Co | Smoothing compositions for fibers |
| EP0559304A2 (en) * | 1989-06-21 | 1993-09-08 | Colgate-Palmolive Company | Liquid dishwashing detergent composition |
| EP0559304A3 (en) * | 1989-06-21 | 1994-03-09 | Colgate Palmolive Co | |
| FR2940097A1 (en) * | 2008-12-19 | 2010-06-25 | Oreal | Cosmetic composition, useful for cosmetic treatment of keratin fibers, preferably hair, comprises polysaccharides of lambda carrageenan type and esters of fatty acid and fatty alcohol in a medium |
| JP2017507978A (en) * | 2014-03-21 | 2017-03-23 | ダウ グローバル テクノロジーズ エルエルシー | Hair oil conditioning agent |
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