KR100779287B1 - Cosmetic compositions for hair conditioning - Google Patents

Abstract

The present invention relates to a composition for hair conditioning,

The composition comprises (i) at least one polyalcohol selected from propylene glycol and 1,3-butylene glycol and glycerin, (ii) at least one lower alcohol selected from methanol, ethanol, isopropanol, and (iii) C ₁₂ At least one fatty alcohol having a carbon in the range from -C ₂₂ , (iv) at least one cationic surfactant selected from quaternary ammonium salts,

In the case of hair treatment, the force required to comb the hair bundles is relatively less than that of the conventional emulsion-type composition, the softness of the hair is excellent, and the temperature is increased when the composition is applied to the hair (when in contact with water). Aesthetic effect due to exothermic reaction), and the feeling of conditioning in dry hair after treatment is relatively excellent, and also has the effect that can be useful in the manufacture of a spray or mousse-type conditioner in a low viscosity solution state.

Hair conditioning

Description

Hair Conditioning Composition {COSMETIC COMPOSITIONS FOR HAIR CONDITIONING}

The present invention relates to a composition for hair conditioning, and more particularly, exhibits excellent hair conditioning effect, of course, does not require heating at the time of manufacture, and has a low viscosity (50 CP or less as measured by Brookfield viscometer at 25 ° C). , Preferably 20 to 50 CP) relates to a composition for convenient hair conditioning.

Consumers' preferences and needs for conditioning products that improve the appearance and feel of hair and make them easier to care for are increasing day by day. These products are particularly necessary for the treatment of hair damaged by dyeing, perm and combing. Damaged hair, when wet or dry, has severe hair stiffness and stiffness and is difficult to manage due to lack of gloss and has a poor appearance.

Therefore, the hair conditioning compositions not only minimize the tangling and soften the hair in wet hair, but also prevent the hair from being blown by static electricity in dry hair, and improve the texture of the hair, making hair care easier and easier to see. To have a good appearance.

Hair conditioning products having the above functions generally have an emulsion form, and in order to impart this function, generally, cationic surfactants and long-chain quaternary ammonium compounds, higher alcohols, and silicones and humectants are the main components, It replenishes the hair's oil after shampooing, giving the hair a conditioning effect.

Here, cationic surfactants are normally deposited on the hair by the interaction of cations and anions by supplying cationic surfactants to the surface of the net negatively charged hair in an aqueous composition with a neutral pH value to prevent hair damage and static electricity generation. In addition, it is used to provide the softness of the hair after rinsing and drying, and to reduce the tangling.

In addition, silicone is used to artificially give sebum-like feel to reduce the stiffness of hair due to the removal of sebum after shampooing, to give softness and shine to dry hair.

Existing conditioners, which have a function suitable for rinsing compositions, ie, hair, which are then left in place for a suitable period of time and then rinsed with water, have been formulated by O / W (Oil-in-Water) or W / O (Water- in-Oil) type of emulsion, which not only limits the formulation and use of the product, but also requires a lot of time in preparation, requires a heating process, and entails manufacturing difficulties due to high viscosity. Had a disadvantage.

In general, silicone oil and polymer silicone (gum) give gloss and flexibility to the hair and provide softness to the hair after drying. However, in spite of these excellent properties, silicone is limited in its use due to lack of moisturizing properties and poor compatibility with other ingredients, and it accumulates in the hair and degrades the softness of hair when used for a long time, and prevents ash from dust and sebum. There is a problem of accelerating contamination. In addition, there is also a problem of reducing the smoothness of the hair during rinsing, and increase the tangling.

The present invention relates to hair protective cosmetics, in particular cosmetic compositions, preferably rinsing compositions which provide improved hair conditioning properties, ie compositions suitable for rinsing with water after being added to the hair and then left for a suitable time.

The hair conditioner composition according to the present invention exhibits excellent hair conditioning effect compared to the conventional conditioner in the form of an emulsion, and does not require manufacturing heat treatment and has a low viscosity (50 when measured with a Brookfield viscometer at 25 ° C.). It is below CP, preferably 20-50 CP), which not only facilitates the manufacture, but also provides the advantage of providing a conditioner for spray and mousse formulations as it is in liquid form.

Accordingly, it is an object of the present invention to provide a hair conditioning lotion for rinsing after application to hair.

It is another object of the present invention to provide a hair protection composition which improves the feel of hair in both wet and dry conditions and has aesthetic appearance.

Yet another object of the present invention is to provide a composition which can be easily applied to hair because it is a liquid having a low viscosity.

It is a further object of the present invention to provide a hair protection composition which exhibits an excellent hair conditioning effect compared to products in the conventional emulsion form.                         

It is a further object of the present invention to provide a method for improving the manufacturing difficulties due to the heating or high viscosity which is inevitably involved in the production of products in the form of conventional emulsions in the form of liquid solutions.

Still another object of the present invention is to provide a composition that exhibits a better conditioning effect without using a nonvolatile silicone oil that has been generally used in conventional hair protection conditioners.

The present invention does not use non-volatile silicone oil and polymer silicone (gum) generally used in existing conditioners, thereby minimizing hair entanglement during rinsing and improving softness after drying.

In addition, the present invention is in the form of a hair conditioner in the form of a solution in which fatty substances and cationic surfactants are dissolved in alcohols and glycols, unlike conventional emulsion-type conditioners, superior to conventional emulsion-type hair conditioners. In addition to providing an effect, the present invention provides the advantages of time in manufacturing and convenience in the manufacturing process, and also enables the manufacture of a conditioner in the form of a spray or a mousse as a liquid.

The present invention provides an aqueous liquid hair cosmetic composition having excellent hair conditioning effect and reducing tangling in the wet state, comprising: (a) at least one organic solvent or polymer thereof selected from polyalcohols having two or more hydroxy; 90% by weight, (b) 0.1 to 90% by weight of one or more lower alcohols or polar organic solvents having one hydroxy having 6 or less carbon atoms, (c) 0.1 to 1 or more fatty alcohols having carbon in the range of C ₁₂ to C ₂₂ 20% by weight, (d) 0.1-20% by weight of one or more cationic surfactants selected from quaternary ammonium salts, and (e) the balance consists of water, characterized in that the pH range is 3-8.

Hereinafter, the present invention will be described in detail, and each component and the like will be described in order.

-Organic solvent-

An organic solvent that mixes well with water and has one or more hydroxy groups, which acts as a carrier of the conditioning component and some can act as a moisturizer.

Such solvents include lower alcohols having 6 or less carbon atoms and having one hydroxy (e.g. ethanol, propanol, isopropanol, butanol), alcohols having two or more hydroxys (e.g. ethylene glycol, propylene glycol, 1, 3-butylene glycol, isoprene glycol, glycerol), polymers of two or more hydroxy alcohols (e.g. diethylene glycol, dipropylene glycol, diglycerol, polyethylene glycol), glycol ethers (e.g. ethylene glycol monoethyl ether , Diethylene glycol monoethyl ether, diethylene glycol monomethyl ether) and the like.

One or more of the above solvents used in the present invention may be mixed, and can be used in the range of 0.1 to 90% by weight, preferably, in the range of 1 to 50% by weight.

Oils or fats

Fatty substances commonly used for hair treatment include alkyl alcohols or higher alcohols having straight or branched alkylene groups, hydrocarbons such as paraffin or petrolatum, lanolin derivatives, higher fatty acids or higher fatty acid ethers, animal or vegetable fats or oils, and the like. .

Preferably the fatty acid has 12 to 24 saturated or unsaturated carbons, and the higher alcohols have straight or branched alkyl or alkenyl groups having 12 to 26 carbons, preferably 14 to 18 carbons.

One or more of the above fat components used in the present invention may be used in combination, and may be used in the range of 0.1 to 30% by weight, and preferably used in the range of 0.1 to 20% by weight.

Quaternary Ammonium Salts

Preferred quaternary ammonium salts of the present invention have the following structural formula (1).

[Formula 1]

_{[R 1 R 2 R 3 R} 4 N] + X -

(Wherein R _1, R ₂ , R ₃ , R ₄ may be the same or different, respectively.)

One higher alkyl in R usually has 10-30 carbons, and the remaining three lower alkyls have 1-4 carbons.                     

Quaternary ammonium salts with two higher alkyls consist of lower alkyl with two R having 10-30 carbons and the remaining two R having 1-4 carbons.

Quaternary ammonium salts with three higher alkyls have three R groups with 10-30 carbons, and one alkyl group consists of lower alkyl with 1-4 carbons.

X is a salt-forming anion that is halogen (e.g. chlorine, bromine), acetate, citrate, lactate, glycolate, phosphate nitrate, sulfate, alkylsulfate radicals and the like. Lower alkyl usually has 1 to 3 or 4 carbon atoms, preferably has 1 or 2 carbon atoms, more preferably methyl, and higher alkyl has 10 to 30 carbon atoms, preferably 12 It has -22 carbon atoms, More preferably, it is 14-22 carbon atoms. The anion is preferably halogen such as chlorine, bromine or iodine, chlorine and bromine are preferred, and chlorine is more preferred.

The number of lower alkyls is preferably 2-3, and the number of higher alkyls is usually 1-2. Most preferred higher alkyl is cetyl and stearyl and most preferred lower alkyl is methyl.

The quaternary ammonium salts used in the present invention may be used in combination with one or more, and may be used in the range of 0.1 to 20% by weight, preferably in the range of 0.1 to 10% by weight.

-Other Ingredients-                     

In addition to the ingredients mentioned above, other additional ingredients may be added which impart a conditioning effect to the hair. These additional ingredients may include moisturizers, emollients, inorganic salts, fragrances, dyes, pH adjusters, ingredients that protect and soften hair, such as proteins or volatile silicones. Usually used in the range of less than 5% by weight per component, the sum of these components is usually used in the range of 5 to 10% by weight.

- How to use -

The hair protection composition of the present invention is used in the same manner as the hair protection composition, which is usually in the form of a rinse, to provide conditioning and damage prevention effects.

The composition is used by washing the hair with shampoo and then evenly applying about 5g to 30g evenly to the hair in a state in which proper moisture is present in the hair.

Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples.

Examples 1-5: Conditioning Composition for Liquid Hair

This example describes a method for preparing a liquid hair conditioning composition of the present invention comprising a lower alcohol as an organic solvent, a higher alcohol as a conditioning agent, and a quaternary ammonium salt. The composition component and the composition amount are shown in Table 1 below.

Furtherance Example 1 (% by weight) Example 2 (% by weight) Example 3 (% by weight) Example 4 (% by weight) Example 5 (% by weight) ethanol 60% 50% 45% 45% 50% Propylene glycol 20% 25% 30% - - 1,3-butylene glycol - - - 35% 40% Cetyltrimethyl ammonium chloride 3 5% 1.5% 2 % 3% 3% Dimethyl distearyl ammonium chloride 0.1% 0.1% - - - Behenyltrimethyl ammonium chloride - 0.2% 0.2% - - Lauryl Alcohol - - 3% One % Myristyl Alcohol 6% 5% 5% 4 % 5% Cetyl alcohol 3% 3% - 2 % 3% Stearyl alcohol One % One % - - - incense A reasonable amount A reasonable amount A reasonable amount A reasonable amount A reasonable amount dyes A reasonable amount A reasonable amount A reasonable amount A reasonable amount A reasonable amount water Residual amount Residual amount Residual amount Residual amount Residual amount Viscosity 25 cp 30 cp 30 cp 40 cp 40 cp

The present compositions according to the above Examples 1 to 5 are prepared by the method of dissolving each composition component in an organic solvent, there is a feature that can be prepared at room temperature (about 25 ℃). Higher alcohols of _C18 or higher may facilitate the preparation with slight warming. In the organic solvent (lower alcohol) of less than 50% by weight, C ₁₆ alone is difficult to dissolve more than 1%, and when added simultaneously with C ₁₄ can accelerate dissolution and increase the amount of dissolution.

Example 6 and Comparative Example 1 Conditioning Compositions for Hair in Liquid and Existing Emulsion Types

In order to find out the conditioning effect by comparing the liquid composition mentioned in the present invention with a conventional emulsion type product, the amount of cationic surfactants and higher alcohols, which have a major effect on the conditioning of hair, was compared with Example 6 and Comparative Example 1. The same was done for the other components, and the appropriate amount was used to make each formulation. In Comparative Example 2, the same components as in Comparative Example 1 were used, but silicone oil was added to determine the effect thereof.

Furtherance Example 6 * Comparative Example 1 ** Comparative Example 2 *** ethanol 60 Propylene glycol 20 1.5 1.5 Cetyltrimethyl ammonium chloride 4 4 4 Myristyl Alcohol 5 5 5 Cetyl alcohol 2 2 2 Pantenol 0.05 0.05 0.05 Dimethicone oil - - One Ceteareth-20 - 0.2 0.2 Citric acid A reasonable amount A reasonable amount A reasonable amount antiseptic - A reasonable amount A reasonable amount incense 0.5 0.5 0.5 dyes A reasonable amount A reasonable amount A reasonable amount water Residual amount Residual amount Residual amount

*: Composition of the present invention

**: Conventional emulsion composition

***: Existing emulsion type composition (containing dimethicone oil)

Test Example 1: Performance Test

Comparative tests were performed on the evaluation items shown in Table 3 below by using the liquid hair conditioning composition of the present invention prepared in Example 6 and Comparative Example 1 and Comparative Example 2 and the conventional emulsion composition for hair conditioning. The lowest score was 1 and the highest score was 5. The test results are shown in Table 1 below.

Item Example 6 Comparative Example 1 Comparative Example 2 Early experience 3.5 3.5 3.5 Soft when using 4.2 3.5 3 Hair softness after use 4 3 3.5 burnish 4.5 3.5 3.5 Moisturizing 4 3 3

As a result of the test, the composition of Example 6 according to the present invention was evaluated to be relatively superior in feeling and gloss, moisture retention, etc. than Comparative Example 1 and Comparative Example 2.

When treating the hair with the hair conditioning composition of the present invention, the force required to comb the hair bundle is relatively less than that of the conventional emulsion-type composition, the softness of the hair is excellent, and the composition is applied to the hair. Aesthetic effects due to elevated temperature (by exothermic reaction upon contact with water) and conditioning in dry hair after treatment are also relatively good, and are also useful for the manufacture of spray or mousse-type conditioners in low viscosity solutions. There is an effect that can be used.

Claims (2)

Composition for hair conditioning consisting of: (a) ethylene glycol, propylene glycol, 1,3-butylene glycol, isoprene glycol, glycerol, diethyl glycol, dipropylene glycol, diglycerol, polyethylene glycol, ethylene glycol monoethyl ether, diethylene glycol monoethyl ether, di 0.1 to 90% by weight of one or two or more organic solvents selected from the group consisting of ethylene glycol monomethyl ether, (b) 0.1 to 90% by weight of a lower alcohol or a polar organic solvent having 1 hydroxy of 1 to 6 carbon atoms, (c) 0.1 to 20% by weight of fatty alcohol having carbon in the range of C ₁₂ to C ₂₂ , (d) 0.1-20% by weight of cationic surfactant of the quaternary ammonium salt of formula 1:  [Formula 1] _{[R 1 R 2 R 3 R} 4 N] + X - Wherein R ₁ , R ₂ , R ₃ , and R ₄ may be the same or different, respectively, wherein R ₁ is a higher alcohol having 10 to 30 carbon atoms, and R ₂ , R ₃ , R ₄ is lower alkyl having 1 to 4 carbon atoms, or ; R ₁ and R ₂ are higher alcohols having 10 to 30 carbon atoms, and R ₃ and R ₄ are lower alkyl having 1 to 4 carbon atoms; or R ₁ to R ₃ are higher alcohols having 10 to 30 carbon atoms, and R ₄ is lower alkyl having 1 to 4 carbon atoms, X is a salt-forming anion selected from the group consisting of halogen, acetate, citrate, lactate, glycolate, phosphate nitrate, sulfate, alkylsulfate radicals; And (e) water to balance. delete