JPS63121244A - Flexible thin type battery - Google Patents

Flexible thin type battery

Info

Publication number
JPS63121244A
JPS63121244A JP61267928A JP26792886A JPS63121244A JP S63121244 A JPS63121244 A JP S63121244A JP 61267928 A JP61267928 A JP 61267928A JP 26792886 A JP26792886 A JP 26792886A JP S63121244 A JPS63121244 A JP S63121244A
Authority
JP
Japan
Prior art keywords
laminated
electrolyte
impregnated
heat
negative electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61267928A
Other languages
Japanese (ja)
Inventor
Jun Kiyoshige
清重 潤
Susumu Ushiama
牛尼 進
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dai Nippon Printing Co Ltd
Original Assignee
Dai Nippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Nippon Printing Co Ltd filed Critical Dai Nippon Printing Co Ltd
Priority to JP61267928A priority Critical patent/JPS63121244A/en
Publication of JPS63121244A publication Critical patent/JPS63121244A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/04Cells with aqueous electrolyte
    • H01M6/06Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H01M6/12Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with flat electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/552Terminals characterised by their shape
    • H01M50/553Terminals adapted for prismatic, pouch or rectangular cells
    • H01M50/557Plate-shaped terminals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/547Terminals characterised by the disposition of the terminals on the cells
    • H01M50/548Terminals characterised by the disposition of the terminals on the cells on opposite sides of the cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/16Cells with non-aqueous electrolyte with organic electrolyte

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Primary Cells (AREA)

Abstract

PURPOSE:To form flexible metal thin film collectors which can be mounted after being arbitrarily bent depending on the shape of the internal space of a device by allocating laminated materials of said collectors oppositely to each other and intervening a positive electrode, a separator impregnated with electrolyte and a negative electrode between them. CONSTITUTION:A heat resistant and organic solvent resistant plastic film 14 on one surface of aluminum foil 13 and a thermal adhesion type resin film 12 on the other surface thereof are laminated. On the latter, two sheets of materials 1 laminated with metal thin film collector 11 having leading wires 5, 6 are allocated oppositely to each other, and intervening a positive electrode 3, a separator 2 impregnated with electrolyte and a negative electrode 4, between them and a heat sealing process is applied thereafter to form the battery in the caption. By the arrangement, since a flexible metal thin film is used in collectors of both electrodes and all other sheathing materials are flexible, it is possible to bend them in an arbitrary shape.

Description

【発明の詳細な説明】[Detailed description of the invention]

R皿り■旬 [産業上の利用分野] 本発明は、フレキシブルな薄型電池に関する。 この電池は、電気および電子搬器の内部の空間に、その
形状に応じて任意に曲げて装填することができる。
R Plate ■ Shun [Field of Industrial Application] The present invention relates to a flexible thin battery. This battery can be bent and loaded into the internal space of the electric/electronic carrier depending on its shape.

【従来の技術】[Conventional technology]

各種電気および電子機器の小型化、薄型化傾向に対応す
るため、厚ざ1s以下の薄型電池が好んで使用されてい
る。 薄型電池の代表的なものには、正極としてMnO
2、負極として金属リチウムまたは1−i−A1合金を
用い、電解質には1−iC,l) 04を有v!!溶媒
に溶解させた非水系の電解液を用いた、扁平薄型リチウ
ム電池がある。 この扁平薄型リチウム電池は、両極集電体として、Fe
、AI、Ntなとの金属板を使用し、この集電体を同時
に外装材に兼用しているので、フレキシブルではない。  薄型電池をフレキシブルにつくることができれば、こ
れを電気および電子機器の内部の空間に、その形状に応
じて任意に曲げて装填することができ、機器を小型化す
るのに有利である。 このためフレキシブル薄型電池の
開発が試みられている。 (発明が解決しようとする問題点) 本発明の目的は、こうした試みのひとつとして、フレキ
シブルな薄型電池を提供することにある。 及皿五璽感 [問題点を解決するための手段] 本発明のフレキシブル薄型電池は、図面に示すように、
アルミ箔13の一方の面に耐熱耐有機溶剤性プラスチッ
クフィルム14、他方の面に熱接着性樹脂のフィルム1
2をそれぞれ貼り合わせ、後者の上にリード5(6)を
有する金属薄膜の集電体11を積層してなる積層材1を
二枚対向させて、その間に正極3、電解質を含浸させた
セパレーター2および負極4を挾んでヒートシールして
構成したものである。 本発明のフレキシブル薄型電池の代表的な態様は、正極
としてMnO2、負極としてLi、電解質を含浸させた
セパレーターとしてLiC,!!04をプロピレンカー
ボネートに溶解した電解液をポリプロピレン不織布に含
浸させたものを使用した薄型リチウム電池である。 アルミ箔は、電解液の漏出を防ぎ、電池に防湿性を付与
するために使用するもので、フレキシビリティ−を考慮
して、厚さ7〜20μ程度が好ましい。 耐熱耐有機溶剤性プラスチックフィルムは、アルミ箔を
保護するためのもので、熱接着性樹脂のフィルムより融
点が高いプラスチック、代表的にはポリエステル、ナイ
ロン、ポリプロピレン、ポリカーボネートなどのフィル
ムを使用する。 厚さは、8〜40μ程度が好適である
。 熱接着性樹脂のフィルムは、ヒートシールにより電池を
封止するためのもので、アルミ箔や集電体との熱接着が
可能で、非水電解液に対して安定なことが要求される。  このような性質をもった材料としては、エチレン−ア
クリル酸エチル共重合体に、グラフト重合によりカルボ
キシル基、ヒドロキシ基またはアセトキシ基などを与え
たものが好適である。 そのほか、エチレン−(メタ)
アクリル酸共重合体やアイオノマーのように、本来分子
中にカルボキシル基などを有するもの、エチレン−酢酸
ビニル共重合体ケン化物や、ポリエチレン、ポリプロピ
レン、エチレン−αオレフィン共重合体またはエチレン
−(メタ)アクリル酸メチルまたはエチルエステル共重
合体に無水マレイン酸などをグラフト重合させて上記の
官能基を与えたものなどが使用できる。 フィルムの厚
さは、10〜40μ程度が好適である。 金属薄膜でリードを有する集電体を形成するには、熱接
着性樹脂のフィルムにニッケル、ステンレスなどの厚さ
10〜20μ程度の金属箔をラミネートし、その上にレ
ジスト層を設け、エツチングを行なった後、レジスト層
を剥離する方法をとるとよい。 アルミ箔と耐熱耐有機溶剤性プラスチックフィルムとの
貼り合わせは、ウレタン系、ポリエステル系、エポキシ
系などの接着剤を用いることにより、容易に実施できる
。 アルミ箔と熱接着性樹脂のフィルムおよび熱接着性
樹脂のフィルムと金属薄膜との積層は、熱接着により行
なうことができる。 [作 用] 本発明のフレキシブル薄型電池は、両極の集電体として
、フレキシブルな金属薄膜を使用し、かつその他の外装
材料も全部フレキシブルなものを使用しているので、自
由な形状に曲げることができる。 熱接着性樹脂のフィルムは、それ自体および金属への熱
接着性がすぐれているので、ヒートシールにより完全な
封止ができる。 [実施例] 厚さ7μのA、ll箔の一方の面に、厚さ12μのポリ
エチレンテレフタレートフィルムをウレタン系接着剤を
用いて貼り合わせ、他方の面に、エチレン−アクリル酸
エチル共重合体フィルム30μを熱接着し、その上に厚
さ10μのNi箔を熱接着したフィルムを2枚用意した
。 次に、熱硬化型インキ「エツチングレジストX−77J
  (太陽インキ製造)を用いて、一方のフィルムのN
1箔上に正極用の集電体のパターンを、他方のフィルム
のNi薄箔上負極用の集電体のパターンを、いずれもリ
ードの形状とともにシルクスクリーン印刷し、熱硬化さ
せエツチングレジスト層を形成した。 塩化第二鉄溶液に浸漬するエツチングの俊、カセイソー
ダ溶液で洗浄してレジスト層を剥離し、正極および負極
のリードを有する集電体を形成した積層材をつくった。 この積層材を用いて、図面に示す構造のフレキシブル薄
型電池を製作した。 セパレーターとしてポリプロピレ
ン不織布を用い、これに、電解質としてL i CD 
O4のプロピレンカーボネート溶液を含浸させた。 正
極にはMnO2を、負極にはl−i箔を使用した。 このフレキシブル薄型電池は、きわめて柔軟性に富み、
電池しての性能も従来のものと変らなかった。 発明の効果 本発明のフレキシブル薄型電池は、きわめて柔軟性に富
み、電気および電子搬器の内部空間に、その形状に応じ
て任意に曲げて装填することができる。 もらろん、機
器の外部に貼りつけて使用することもできる。 このよ
うにして、機器類の小型化、軽足化に役立つ。
2. Description of the Related Art In order to respond to the trend toward miniaturization and thinning of various electrical and electronic devices, thin batteries with a thickness of 1 s or less are preferably used. Typical thin batteries include MnO as the positive electrode.
2. Metal lithium or 1-i-A1 alloy is used as the negative electrode, and 1-iC,l) 04 is used as the electrolyte. ! There are flat, thin lithium batteries that use a non-aqueous electrolyte dissolved in a solvent. This flat thin lithium battery uses Fe as the bipolar current collector.
, AI, Nt, etc., and this current collector is also used as an exterior material, so it is not flexible. If a thin battery can be made flexibly, it can be bent and loaded into the internal space of electrical and electronic equipment according to its shape, which is advantageous for downsizing the equipment. For this reason, attempts are being made to develop flexible thin batteries. (Problems to be Solved by the Invention) An object of the present invention is to provide a flexible thin battery as one of such attempts. [Means for solving the problem] As shown in the drawings, the flexible thin battery of the present invention has the following features:
A heat-resistant and organic solvent-resistant plastic film 14 is placed on one side of the aluminum foil 13, and a heat-adhesive resin film 1 is placed on the other side.
2 are laminated together, and a metal thin film current collector 11 having leads 5 (6) is laminated on the latter, and two laminated materials 1 are placed facing each other, and between them, a positive electrode 3 and a separator impregnated with an electrolyte are formed. 2 and a negative electrode 4 are sandwiched and heat-sealed. A typical embodiment of the flexible thin battery of the present invention includes MnO2 as the positive electrode, Li as the negative electrode, and LiC as the electrolyte-impregnated separator! ! This is a thin lithium battery using a polypropylene nonwoven fabric impregnated with an electrolytic solution in which 04 is dissolved in propylene carbonate. The aluminum foil is used to prevent electrolyte leakage and provide moisture resistance to the battery, and in consideration of flexibility, the thickness is preferably about 7 to 20 μm. Heat-resistant and organic solvent-resistant plastic films are used to protect aluminum foil, and are typically made of plastics with a higher melting point than thermoadhesive resin films, such as polyester, nylon, polypropylene, and polycarbonate. The thickness is preferably about 8 to 40 microns. The thermoadhesive resin film is used to seal the battery by heat-sealing, and is required to be able to be thermally bonded to aluminum foil or a current collector, and to be stable with respect to non-aqueous electrolytes. As a material having such properties, it is preferable to use an ethylene-ethyl acrylate copolymer to which a carboxyl group, hydroxyl group, or acetoxy group is added by graft polymerization. In addition, ethylene-(meth)
Those that inherently have carboxyl groups in their molecules, such as acrylic acid copolymers and ionomers, saponified ethylene-vinyl acetate copolymers, polyethylene, polypropylene, ethylene-α-olefin copolymers, or ethylene-(meth) A methyl acrylate or ethyl ester copolymer graft-polymerized with maleic anhydride or the like to provide the above-mentioned functional groups can be used. The thickness of the film is preferably about 10 to 40 microns. To form a current collector with leads using a thin metal film, laminate a metal foil of nickel, stainless steel, or the like with a thickness of about 10 to 20 μm on a thermoadhesive resin film, provide a resist layer on top of it, and perform etching. After this, it is preferable to take a method of peeling off the resist layer. The aluminum foil and the heat-resistant, organic solvent-resistant plastic film can be easily bonded together using a urethane-based, polyester-based, or epoxy-based adhesive. The aluminum foil and the thermoadhesive resin film and the thermoadhesive resin film and the metal thin film can be laminated by thermal adhesion. [Function] The flexible thin battery of the present invention uses a flexible metal thin film as the current collector of both electrodes, and all other exterior materials are also flexible, so it can be bent into any shape. I can do it. The thermoadhesive resin film has excellent thermal adhesion to itself and to metals, so complete sealing can be achieved by heat sealing. [Example] A 12μ thick polyethylene terephthalate film was attached to one side of a 7μ thick A, ll foil using a urethane adhesive, and an ethylene-ethyl acrylate copolymer film was attached to the other side. Two films were prepared by thermally bonding a 30μ thick film and thermally bonding a 10μ thick Ni foil thereon. Next, we applied the thermosetting ink “Etching Resist X-77J”.
(Taiyo Ink Manufacture) was used to remove the N of one film.
A pattern of a current collector for the positive electrode is printed on one foil, and a pattern of a current collector for the negative electrode is printed on the Ni thin foil of the other film, along with the shape of the leads, and then heat cured to form an etching resist layer. Formed. The resist layer was removed by etching by immersion in a ferric chloride solution and cleaning with a caustic soda solution, thereby producing a laminated material in which a current collector having positive and negative electrode leads was formed. Using this laminated material, a flexible thin battery having the structure shown in the drawings was manufactured. A polypropylene nonwoven fabric was used as a separator, and Li CD was used as an electrolyte.
It was impregnated with a solution of O4 in propylene carbonate. MnO2 was used for the positive electrode, and li foil was used for the negative electrode. This flexible thin battery is extremely flexible,
The performance of the battery was also the same as the conventional one. Effects of the Invention The flexible thin battery of the present invention is extremely flexible and can be bent and loaded into the internal space of an electric/electronic carrier according to its shape. Of course, it can also be used by pasting it on the outside of the device. In this way, it helps to make equipment smaller and lighter.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は、本発明のフレキシブル薄型電池の構造を示す拡
大断面図である。 1・・・積層材 11・・・集電体 12・・・熱接着性樹脂のフィルム 13・・・アルミ箔 14・・・耐熱耐有機溶剤性プラスチックフィルム2・
・・電解質を含浸させたセパレーター3・・・正 極 4・・・負 極 5.6・・・リード
The drawing is an enlarged sectional view showing the structure of the flexible thin battery of the present invention. 1... Laminated material 11... Current collector 12... Heat-adhesive resin film 13... Aluminum foil 14... Heat-resistant and organic solvent-resistant plastic film 2.
...Separator impregnated with electrolyte 3...Positive electrode 4...Negative electrode 5.6...Lead

Claims (2)

【特許請求の範囲】[Claims] (1)アルミ箔の一方の面に耐熱耐有機溶剤性プラスチ
ックフィルム、他方の面に熱接着性樹脂のフィルムをそ
れぞれ貼り合わせ、後者の上にリードを有する金属薄膜
の集電体を積層してなる積層材を二枚対向させて、その
間に正極、電解質を含浸させたセパレーターおよび負極
を挾んでヒートシールして構成したフレキシブル薄型電
池。
(1) A heat-resistant, organic solvent-resistant plastic film is pasted on one side of aluminum foil, and a heat-adhesive resin film is pasted on the other side, and a metal thin film current collector with leads is laminated on top of the latter. A flexible thin battery constructed by placing two laminated materials facing each other, sandwiching a positive electrode, an electrolyte-impregnated separator, and a negative electrode between them and heat-sealing them.
(2)正極としてMnO_2、負極としてLi、電解質
を含浸させたセパレーターとしてLiClO_4をプロ
ピレンカーボネートに溶解した電解液をポリプロピレン
不織布に含浸させたものを使用した薄型リチウム電池で
ある特許請求の範囲第1項に記載のフレキシブル薄型電
池。
(2) Claim 1 which is a thin lithium battery using MnO_2 as a positive electrode, Li as a negative electrode, and a polypropylene nonwoven fabric impregnated with an electrolytic solution prepared by dissolving LiClO_4 in propylene carbonate as a separator impregnated with an electrolyte. Flexible thin battery described in .
JP61267928A 1986-11-11 1986-11-11 Flexible thin type battery Pending JPS63121244A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61267928A JPS63121244A (en) 1986-11-11 1986-11-11 Flexible thin type battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61267928A JPS63121244A (en) 1986-11-11 1986-11-11 Flexible thin type battery

Publications (1)

Publication Number Publication Date
JPS63121244A true JPS63121244A (en) 1988-05-25

Family

ID=17451557

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61267928A Pending JPS63121244A (en) 1986-11-11 1986-11-11 Flexible thin type battery

Country Status (1)

Country Link
JP (1) JPS63121244A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000340187A (en) * 1999-05-26 2000-12-08 Dainippon Printing Co Ltd Packaging material for polymer battery
EP1331677A2 (en) * 2002-01-21 2003-07-30 Nec Tokin Corporation Battery and electric double layer capacitor
EP1180806A3 (en) * 2000-08-18 2003-11-26 Sony Corporation Secondary cell and method for preparation thereof
EP1391947A1 (en) * 2002-06-15 2004-02-25 VARTA Microbattery GmbH Galvanic element with a thin and flexible housing
JP2009238463A (en) * 2008-03-26 2009-10-15 Nec Corp Flat battery
JP2011222771A (en) * 2010-04-09 2011-11-04 Jsr Corp Power storage device, device module and manufacturing method thereof
KR101323812B1 (en) * 2011-02-28 2013-10-31 스템코 주식회사 Thin film battery using flexible metal clad laminate, Apparatus for manufacturing for the same, and Manufacturing method for the same
CN105470414A (en) * 2014-09-30 2016-04-06 松下知识产权经营株式会社 Pouch-type battery and method of manufacturing the same
JP2016072209A (en) * 2014-09-30 2016-05-09 パナソニックIpマネジメント株式会社 Pouch battery and method of manufacturing the same
JPWO2021145345A1 (en) * 2020-01-17 2021-07-22

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4736146B2 (en) * 1999-05-26 2011-07-27 大日本印刷株式会社 Polymer battery packaging materials
JP2000340187A (en) * 1999-05-26 2000-12-08 Dainippon Printing Co Ltd Packaging material for polymer battery
EP1180806A3 (en) * 2000-08-18 2003-11-26 Sony Corporation Secondary cell and method for preparation thereof
EP1331677A2 (en) * 2002-01-21 2003-07-30 Nec Tokin Corporation Battery and electric double layer capacitor
EP1331677A3 (en) * 2002-01-21 2005-07-20 Nec Tokin Corporation Battery and electric double layer capacitor
US6998190B2 (en) 2002-01-21 2006-02-14 Nec Tokin Corporation Battery having a sheet current collector fluid-tightly separating basic cells
EP1391947A1 (en) * 2002-06-15 2004-02-25 VARTA Microbattery GmbH Galvanic element with a thin and flexible housing
JP2009238463A (en) * 2008-03-26 2009-10-15 Nec Corp Flat battery
JP2011222771A (en) * 2010-04-09 2011-11-04 Jsr Corp Power storage device, device module and manufacturing method thereof
KR101323812B1 (en) * 2011-02-28 2013-10-31 스템코 주식회사 Thin film battery using flexible metal clad laminate, Apparatus for manufacturing for the same, and Manufacturing method for the same
CN105470414A (en) * 2014-09-30 2016-04-06 松下知识产权经营株式会社 Pouch-type battery and method of manufacturing the same
JP2016072209A (en) * 2014-09-30 2016-05-09 パナソニックIpマネジメント株式会社 Pouch battery and method of manufacturing the same
US9859535B2 (en) 2014-09-30 2018-01-02 Panasonic Intellectual Property Management Co., Ltd. Pouch-type battery and method of manufacturing the same
JPWO2021145345A1 (en) * 2020-01-17 2021-07-22
WO2021145345A1 (en) * 2020-01-17 2021-07-22 富士フイルム株式会社 Non-aqueous electrolyte secondary battery, current collector and method for producing same

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