JPS63121244A - Flexible thin type battery - Google Patents
Flexible thin type batteryInfo
- Publication number
- JPS63121244A JPS63121244A JP61267928A JP26792886A JPS63121244A JP S63121244 A JPS63121244 A JP S63121244A JP 61267928 A JP61267928 A JP 61267928A JP 26792886 A JP26792886 A JP 26792886A JP S63121244 A JPS63121244 A JP S63121244A
- Authority
- JP
- Japan
- Prior art keywords
- laminated
- electrolyte
- impregnated
- heat
- negative electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010408 film Substances 0.000 claims abstract description 18
- 239000011888 foil Substances 0.000 claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003792 electrolyte Substances 0.000 claims abstract description 8
- 239000010409 thin film Substances 0.000 claims abstract description 7
- 239000002648 laminated material Substances 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- 239000002985 plastic film Substances 0.000 claims abstract description 6
- 229920006255 plastic film Polymers 0.000 claims abstract description 6
- 238000007789 sealing Methods 0.000 claims abstract description 5
- -1 polypropylene Polymers 0.000 claims description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000004840 adhesive resin Substances 0.000 claims description 3
- 229920006223 adhesive resin Polymers 0.000 claims description 3
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 3
- 239000008151 electrolyte solution Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 abstract description 7
- 239000011347 resin Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 2
- 239000011255 nonaqueous electrolyte Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000379 polypropylene carbonate Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
- H01M6/12—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with flat electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/552—Terminals characterised by their shape
- H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
- H01M50/557—Plate-shaped terminals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/547—Terminals characterised by the disposition of the terminals on the cells
- H01M50/548—Terminals characterised by the disposition of the terminals on the cells on opposite sides of the cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Primary Cells (AREA)
Abstract
Description
R皿り■旬
[産業上の利用分野]
本発明は、フレキシブルな薄型電池に関する。
この電池は、電気および電子搬器の内部の空間に、その
形状に応じて任意に曲げて装填することができる。R Plate ■ Shun [Field of Industrial Application] The present invention relates to a flexible thin battery. This battery can be bent and loaded into the internal space of the electric/electronic carrier depending on its shape.
各種電気および電子機器の小型化、薄型化傾向に対応す
るため、厚ざ1s以下の薄型電池が好んで使用されてい
る。 薄型電池の代表的なものには、正極としてMnO
2、負極として金属リチウムまたは1−i−A1合金を
用い、電解質には1−iC,l) 04を有v!!溶媒
に溶解させた非水系の電解液を用いた、扁平薄型リチウ
ム電池がある。
この扁平薄型リチウム電池は、両極集電体として、Fe
、AI、Ntなとの金属板を使用し、この集電体を同時
に外装材に兼用しているので、フレキシブルではない。
薄型電池をフレキシブルにつくることができれば、こ
れを電気および電子機器の内部の空間に、その形状に応
じて任意に曲げて装填することができ、機器を小型化す
るのに有利である。 このためフレキシブル薄型電池の
開発が試みられている。
(発明が解決しようとする問題点)
本発明の目的は、こうした試みのひとつとして、フレキ
シブルな薄型電池を提供することにある。
及皿五璽感
[問題点を解決するための手段]
本発明のフレキシブル薄型電池は、図面に示すように、
アルミ箔13の一方の面に耐熱耐有機溶剤性プラスチッ
クフィルム14、他方の面に熱接着性樹脂のフィルム1
2をそれぞれ貼り合わせ、後者の上にリード5(6)を
有する金属薄膜の集電体11を積層してなる積層材1を
二枚対向させて、その間に正極3、電解質を含浸させた
セパレーター2および負極4を挾んでヒートシールして
構成したものである。
本発明のフレキシブル薄型電池の代表的な態様は、正極
としてMnO2、負極としてLi、電解質を含浸させた
セパレーターとしてLiC,!!04をプロピレンカー
ボネートに溶解した電解液をポリプロピレン不織布に含
浸させたものを使用した薄型リチウム電池である。
アルミ箔は、電解液の漏出を防ぎ、電池に防湿性を付与
するために使用するもので、フレキシビリティ−を考慮
して、厚さ7〜20μ程度が好ましい。
耐熱耐有機溶剤性プラスチックフィルムは、アルミ箔を
保護するためのもので、熱接着性樹脂のフィルムより融
点が高いプラスチック、代表的にはポリエステル、ナイ
ロン、ポリプロピレン、ポリカーボネートなどのフィル
ムを使用する。 厚さは、8〜40μ程度が好適である
。
熱接着性樹脂のフィルムは、ヒートシールにより電池を
封止するためのもので、アルミ箔や集電体との熱接着が
可能で、非水電解液に対して安定なことが要求される。
このような性質をもった材料としては、エチレン−ア
クリル酸エチル共重合体に、グラフト重合によりカルボ
キシル基、ヒドロキシ基またはアセトキシ基などを与え
たものが好適である。 そのほか、エチレン−(メタ)
アクリル酸共重合体やアイオノマーのように、本来分子
中にカルボキシル基などを有するもの、エチレン−酢酸
ビニル共重合体ケン化物や、ポリエチレン、ポリプロピ
レン、エチレン−αオレフィン共重合体またはエチレン
−(メタ)アクリル酸メチルまたはエチルエステル共重
合体に無水マレイン酸などをグラフト重合させて上記の
官能基を与えたものなどが使用できる。 フィルムの厚
さは、10〜40μ程度が好適である。
金属薄膜でリードを有する集電体を形成するには、熱接
着性樹脂のフィルムにニッケル、ステンレスなどの厚さ
10〜20μ程度の金属箔をラミネートし、その上にレ
ジスト層を設け、エツチングを行なった後、レジスト層
を剥離する方法をとるとよい。
アルミ箔と耐熱耐有機溶剤性プラスチックフィルムとの
貼り合わせは、ウレタン系、ポリエステル系、エポキシ
系などの接着剤を用いることにより、容易に実施できる
。 アルミ箔と熱接着性樹脂のフィルムおよび熱接着性
樹脂のフィルムと金属薄膜との積層は、熱接着により行
なうことができる。
[作 用]
本発明のフレキシブル薄型電池は、両極の集電体として
、フレキシブルな金属薄膜を使用し、かつその他の外装
材料も全部フレキシブルなものを使用しているので、自
由な形状に曲げることができる。
熱接着性樹脂のフィルムは、それ自体および金属への熱
接着性がすぐれているので、ヒートシールにより完全な
封止ができる。
[実施例]
厚さ7μのA、ll箔の一方の面に、厚さ12μのポリ
エチレンテレフタレートフィルムをウレタン系接着剤を
用いて貼り合わせ、他方の面に、エチレン−アクリル酸
エチル共重合体フィルム30μを熱接着し、その上に厚
さ10μのNi箔を熱接着したフィルムを2枚用意した
。
次に、熱硬化型インキ「エツチングレジストX−77J
(太陽インキ製造)を用いて、一方のフィルムのN
1箔上に正極用の集電体のパターンを、他方のフィルム
のNi薄箔上負極用の集電体のパターンを、いずれもリ
ードの形状とともにシルクスクリーン印刷し、熱硬化さ
せエツチングレジスト層を形成した。
塩化第二鉄溶液に浸漬するエツチングの俊、カセイソー
ダ溶液で洗浄してレジスト層を剥離し、正極および負極
のリードを有する集電体を形成した積層材をつくった。
この積層材を用いて、図面に示す構造のフレキシブル薄
型電池を製作した。 セパレーターとしてポリプロピレ
ン不織布を用い、これに、電解質としてL i CD
O4のプロピレンカーボネート溶液を含浸させた。 正
極にはMnO2を、負極にはl−i箔を使用した。
このフレキシブル薄型電池は、きわめて柔軟性に富み、
電池しての性能も従来のものと変らなかった。
発明の効果
本発明のフレキシブル薄型電池は、きわめて柔軟性に富
み、電気および電子搬器の内部空間に、その形状に応じ
て任意に曲げて装填することができる。 もらろん、機
器の外部に貼りつけて使用することもできる。 このよ
うにして、機器類の小型化、軽足化に役立つ。2. Description of the Related Art In order to respond to the trend toward miniaturization and thinning of various electrical and electronic devices, thin batteries with a thickness of 1 s or less are preferably used. Typical thin batteries include MnO as the positive electrode.
2. Metal lithium or 1-i-A1 alloy is used as the negative electrode, and 1-iC,l) 04 is used as the electrolyte. ! There are flat, thin lithium batteries that use a non-aqueous electrolyte dissolved in a solvent. This flat thin lithium battery uses Fe as the bipolar current collector.
, AI, Nt, etc., and this current collector is also used as an exterior material, so it is not flexible. If a thin battery can be made flexibly, it can be bent and loaded into the internal space of electrical and electronic equipment according to its shape, which is advantageous for downsizing the equipment. For this reason, attempts are being made to develop flexible thin batteries. (Problems to be Solved by the Invention) An object of the present invention is to provide a flexible thin battery as one of such attempts. [Means for solving the problem] As shown in the drawings, the flexible thin battery of the present invention has the following features:
A heat-resistant and organic solvent-resistant plastic film 14 is placed on one side of the aluminum foil 13, and a heat-adhesive resin film 1 is placed on the other side.
2 are laminated together, and a metal thin film current collector 11 having leads 5 (6) is laminated on the latter, and two laminated materials 1 are placed facing each other, and between them, a positive electrode 3 and a separator impregnated with an electrolyte are formed. 2 and a negative electrode 4 are sandwiched and heat-sealed. A typical embodiment of the flexible thin battery of the present invention includes MnO2 as the positive electrode, Li as the negative electrode, and LiC as the electrolyte-impregnated separator! ! This is a thin lithium battery using a polypropylene nonwoven fabric impregnated with an electrolytic solution in which 04 is dissolved in propylene carbonate. The aluminum foil is used to prevent electrolyte leakage and provide moisture resistance to the battery, and in consideration of flexibility, the thickness is preferably about 7 to 20 μm. Heat-resistant and organic solvent-resistant plastic films are used to protect aluminum foil, and are typically made of plastics with a higher melting point than thermoadhesive resin films, such as polyester, nylon, polypropylene, and polycarbonate. The thickness is preferably about 8 to 40 microns. The thermoadhesive resin film is used to seal the battery by heat-sealing, and is required to be able to be thermally bonded to aluminum foil or a current collector, and to be stable with respect to non-aqueous electrolytes. As a material having such properties, it is preferable to use an ethylene-ethyl acrylate copolymer to which a carboxyl group, hydroxyl group, or acetoxy group is added by graft polymerization. In addition, ethylene-(meth)
Those that inherently have carboxyl groups in their molecules, such as acrylic acid copolymers and ionomers, saponified ethylene-vinyl acetate copolymers, polyethylene, polypropylene, ethylene-α-olefin copolymers, or ethylene-(meth) A methyl acrylate or ethyl ester copolymer graft-polymerized with maleic anhydride or the like to provide the above-mentioned functional groups can be used. The thickness of the film is preferably about 10 to 40 microns. To form a current collector with leads using a thin metal film, laminate a metal foil of nickel, stainless steel, or the like with a thickness of about 10 to 20 μm on a thermoadhesive resin film, provide a resist layer on top of it, and perform etching. After this, it is preferable to take a method of peeling off the resist layer. The aluminum foil and the heat-resistant, organic solvent-resistant plastic film can be easily bonded together using a urethane-based, polyester-based, or epoxy-based adhesive. The aluminum foil and the thermoadhesive resin film and the thermoadhesive resin film and the metal thin film can be laminated by thermal adhesion. [Function] The flexible thin battery of the present invention uses a flexible metal thin film as the current collector of both electrodes, and all other exterior materials are also flexible, so it can be bent into any shape. I can do it. The thermoadhesive resin film has excellent thermal adhesion to itself and to metals, so complete sealing can be achieved by heat sealing. [Example] A 12μ thick polyethylene terephthalate film was attached to one side of a 7μ thick A, ll foil using a urethane adhesive, and an ethylene-ethyl acrylate copolymer film was attached to the other side. Two films were prepared by thermally bonding a 30μ thick film and thermally bonding a 10μ thick Ni foil thereon. Next, we applied the thermosetting ink “Etching Resist X-77J”.
(Taiyo Ink Manufacture) was used to remove the N of one film.
A pattern of a current collector for the positive electrode is printed on one foil, and a pattern of a current collector for the negative electrode is printed on the Ni thin foil of the other film, along with the shape of the leads, and then heat cured to form an etching resist layer. Formed. The resist layer was removed by etching by immersion in a ferric chloride solution and cleaning with a caustic soda solution, thereby producing a laminated material in which a current collector having positive and negative electrode leads was formed. Using this laminated material, a flexible thin battery having the structure shown in the drawings was manufactured. A polypropylene nonwoven fabric was used as a separator, and Li CD was used as an electrolyte.
It was impregnated with a solution of O4 in propylene carbonate. MnO2 was used for the positive electrode, and li foil was used for the negative electrode. This flexible thin battery is extremely flexible,
The performance of the battery was also the same as the conventional one. Effects of the Invention The flexible thin battery of the present invention is extremely flexible and can be bent and loaded into the internal space of an electric/electronic carrier according to its shape. Of course, it can also be used by pasting it on the outside of the device. In this way, it helps to make equipment smaller and lighter.
図面は、本発明のフレキシブル薄型電池の構造を示す拡
大断面図である。
1・・・積層材
11・・・集電体
12・・・熱接着性樹脂のフィルム
13・・・アルミ箔
14・・・耐熱耐有機溶剤性プラスチックフィルム2・
・・電解質を含浸させたセパレーター3・・・正 極
4・・・負 極
5.6・・・リードThe drawing is an enlarged sectional view showing the structure of the flexible thin battery of the present invention. 1... Laminated material 11... Current collector 12... Heat-adhesive resin film 13... Aluminum foil 14... Heat-resistant and organic solvent-resistant plastic film 2.
...Separator impregnated with electrolyte 3...Positive electrode 4...Negative electrode 5.6...Lead
Claims (2)
ックフィルム、他方の面に熱接着性樹脂のフィルムをそ
れぞれ貼り合わせ、後者の上にリードを有する金属薄膜
の集電体を積層してなる積層材を二枚対向させて、その
間に正極、電解質を含浸させたセパレーターおよび負極
を挾んでヒートシールして構成したフレキシブル薄型電
池。(1) A heat-resistant, organic solvent-resistant plastic film is pasted on one side of aluminum foil, and a heat-adhesive resin film is pasted on the other side, and a metal thin film current collector with leads is laminated on top of the latter. A flexible thin battery constructed by placing two laminated materials facing each other, sandwiching a positive electrode, an electrolyte-impregnated separator, and a negative electrode between them and heat-sealing them.
を含浸させたセパレーターとしてLiClO_4をプロ
ピレンカーボネートに溶解した電解液をポリプロピレン
不織布に含浸させたものを使用した薄型リチウム電池で
ある特許請求の範囲第1項に記載のフレキシブル薄型電
池。(2) Claim 1 which is a thin lithium battery using MnO_2 as a positive electrode, Li as a negative electrode, and a polypropylene nonwoven fabric impregnated with an electrolytic solution prepared by dissolving LiClO_4 in propylene carbonate as a separator impregnated with an electrolyte. Flexible thin battery described in .
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61267928A JPS63121244A (en) | 1986-11-11 | 1986-11-11 | Flexible thin type battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61267928A JPS63121244A (en) | 1986-11-11 | 1986-11-11 | Flexible thin type battery |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63121244A true JPS63121244A (en) | 1988-05-25 |
Family
ID=17451557
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61267928A Pending JPS63121244A (en) | 1986-11-11 | 1986-11-11 | Flexible thin type battery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63121244A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000340187A (en) * | 1999-05-26 | 2000-12-08 | Dainippon Printing Co Ltd | Packaging material for polymer battery |
EP1331677A2 (en) * | 2002-01-21 | 2003-07-30 | Nec Tokin Corporation | Battery and electric double layer capacitor |
EP1180806A3 (en) * | 2000-08-18 | 2003-11-26 | Sony Corporation | Secondary cell and method for preparation thereof |
EP1391947A1 (en) * | 2002-06-15 | 2004-02-25 | VARTA Microbattery GmbH | Galvanic element with a thin and flexible housing |
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1986
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JP2009238463A (en) * | 2008-03-26 | 2009-10-15 | Nec Corp | Flat battery |
JP2011222771A (en) * | 2010-04-09 | 2011-11-04 | Jsr Corp | Power storage device, device module and manufacturing method thereof |
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US9859535B2 (en) | 2014-09-30 | 2018-01-02 | Panasonic Intellectual Property Management Co., Ltd. | Pouch-type battery and method of manufacturing the same |
JPWO2021145345A1 (en) * | 2020-01-17 | 2021-07-22 | ||
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