JPS6266560A - Nonaqueous electrolyte battery - Google Patents
Nonaqueous electrolyte batteryInfo
- Publication number
- JPS6266560A JPS6266560A JP60205560A JP20556085A JPS6266560A JP S6266560 A JPS6266560 A JP S6266560A JP 60205560 A JP60205560 A JP 60205560A JP 20556085 A JP20556085 A JP 20556085A JP S6266560 A JPS6266560 A JP S6266560A
- Authority
- JP
- Japan
- Prior art keywords
- positive
- positive electrode
- silicon
- corrosion
- stainless steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011255 nonaqueous electrolyte Substances 0.000 title claims abstract description 9
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 13
- 239000010703 silicon Substances 0.000 claims abstract description 13
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 13
- 239000011149 active material Substances 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 239000000470 constituent Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 12
- 230000007797 corrosion Effects 0.000 abstract description 9
- 238000005260 corrosion Methods 0.000 abstract description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003792 electrolyte Substances 0.000 abstract description 3
- 229910052744 lithium Inorganic materials 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 2
- 150000004820 halides Chemical class 0.000 abstract description 2
- 229910001507 metal halide Inorganic materials 0.000 abstract description 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- 150000004706 metal oxides Chemical class 0.000 abstract description 2
- 229910052708 sodium Inorganic materials 0.000 abstract description 2
- 239000011734 sodium Substances 0.000 abstract description 2
- 230000035945 sensitivity Effects 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 229910052759 nickel Inorganic materials 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/669—Steels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/117—Inorganic material
- H01M50/119—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Abstract
Description
【発明の詳細な説明】
（イ）産業上の利用分野
本発明はリチウム、ナトリウムなどの軽金属を活物質と
する負極と、金属の酸化物、ハロゲン化物などを活物質
とする正極と、非水電解液とを備えた電池に関する。DETAILED DESCRIPTION OF THE INVENTION (a) Industrial application field The present invention relates to a negative electrode using a light metal such as lithium or sodium as an active material, a positive electrode using a metal oxide or halide as an active material, and a non-aqueous The present invention relates to a battery equipped with an electrolyte.
（ロ）従来の技術
この種電源の缶材料としてはニッケル含有量が約３〜２
０重量％の所謂オーステナイト系ステンレス鋼が一般に
用いられているが、電池の保存中に特に正極に電気接続
された正極缶はその構成部材が電解液中に溶解し負極上
に析出して内部抵抗を増大させ、又極端な場合には穴あ
き現象を生じることがある。この原因はステンレス鋼に
倉まれるニッケル量に依存すると考えられニッケル量が
大なるほど顕著であった。(b) Conventional technology The can material for this type of power supply has a nickel content of approximately 3 to 2.
0% by weight so-called austenitic stainless steel is generally used, but during battery storage, the positive electrode can, which is electrically connected to the positive electrode, has its constituent members dissolved in the electrolyte and deposited on the negative electrode, increasing the internal resistance. and, in extreme cases, may cause a perforation phenomenon. The cause of this is thought to depend on the amount of nickel contained in the stainless steel, and was more pronounced as the amount of nickel increased.
そこで、例えば特公昭５５−１５０６７号公報に開示さ
れているように正極缶構成部材としてニッケルをほとん
ど含まず応力下での割れ感受性の少ないフェライト系ス
テンレス鋼を用いることが提案されたが、この場合にも
高温で長期間保存すると構成部材の溶解現象が認められ
た。Therefore, for example, as disclosed in Japanese Patent Publication No. 55-15067, it has been proposed to use ferritic stainless steel, which contains almost no nickel and is less susceptible to cracking under stress, as a component of the positive electrode can. However, when stored at high temperatures for long periods of time, melting of the constituent parts was observed.
さて、この種電源は従来の銀電池、アルカリ電池に比し
て自己放電が小さいため長期間の使用に耐えうるちので
あり、そのため最近では使用機器側のエレクトロニクス
の発戻と相撲って微小電流による長期に亘る放電特性の
安定性が求められるようになってきた。と仁゛で述べる
微小電流とは高々数μ＾であるがこのような微小電流放
電下において長期間安定した放電特性を得るためには電
池自身の高信頼性が要求される。Now, compared to conventional silver and alkaline batteries, this type of power supply has a smaller self-discharge and can withstand long-term use.As a result, recently, it has become possible to use a small current due to the regeneration of electronics in the equipment used. The stability of discharge characteristics over a long period of time is now required. The microcurrent referred to above is a few μ^ at most, but in order to obtain stable discharge characteristics for a long period of time under such microcurrent discharge, the battery itself is required to have high reliability.
（ハ）発明が解決しようとする問題点
本発明は高温での長期保存においても正極缶構成部材の
溶解（腐食）を抑制しうる非水電解液電池を提供するこ
とを目的とする。(c) Problems to be Solved by the Invention An object of the present invention is to provide a non-aqueous electrolyte battery that can suppress dissolution (corrosion) of positive electrode can components even during long-term storage at high temperatures.
（ニ）問題点を解決するための手段
本発明は正極缶構成部材として硅素を１．２〜５．０重
量％含有するフェライト系ステンレス鋼ヲ用いることを
特徴とする。(d) Means for Solving the Problems The present invention is characterized in that ferritic stainless steel containing 1.2 to 5.0% by weight of silicon is used as the positive electrode can component.
（ホ）作用
本発明によれば、詳細な機構については明らかではない
が、フェライト系ステンレス鋼に含有させた硅素が非水
電解液中において粒界腐食感受性を低下させる効果があ
り正極缶構成部材の腐蝕のの
発生を抑制しうる。尚、硅素−果は含有量が１．２〜５
．０重量％の時に顕著である。(E) Effect According to the present invention, although the detailed mechanism is not clear, silicon contained in ferritic stainless steel has the effect of reducing intergranular corrosion susceptibility in a non-aqueous electrolyte, and the positive electrode can component member The occurrence of corrosion can be suppressed. In addition, the content of silicon fruit is 1.2 to 5.
．． It is noticeable at 0% by weight.
（へ）実施例
以下本発明の一実施例を図面に基づき説明するに、第１
図において（１）はリチウム圧延板を所定形状に打抜い
た負極であってオーステナイト系ステンレス鋼（ＳＵＳ
３０４）よりなる負極缶（２）の内面に固着せる負極集
電体（３）に圧着されている。（４）は活物質としての
二酸化マンガンに、導電剤としてのカーボン粉末及び結
着剤としてのフ・ン素樹脂粉末を８５：１０：５の重量
比で混合し、この混合物を成型して得た正極であって、
本発明の要旨とする正極缶（５）の内面に固着せる正極
集電体（６）に圧接きれている。(v) Example Below, one example of the present invention will be explained based on the drawings.
In the figure, (1) is a negative electrode made by punching a lithium rolled plate into a predetermined shape, and is made of austenitic stainless steel (SUS).
304) is crimped to a negative electrode current collector (3) which is fixed to the inner surface of a negative electrode can (2). (4) is obtained by mixing manganese dioxide as an active material, carbon powder as a conductive agent, and fluorocarbon resin powder as a binder in a weight ratio of 85:10:5, and molding this mixture. a positive electrode,
It is pressed into contact with the positive electrode current collector (6) which is fixed to the inner surface of the positive electrode can (5), which is the gist of the present invention.
ここで正極缶（５）は鉄８０重量％、クロム１８重量％
、ニッケル０重量％及び硅素２重量％の組成からなるフ
ェライト系ステンレス鋼で構成されている。Here, the positive electrode can (5) is made of 80% iron and 18% chromium by weight.
, ferritic stainless steel with a composition of 0% by weight of nickel and 2% by weight of silicon.
尚、（７）は非水電解液を含浸せるセパレータ、（８）
は絶、縁バッキングである。In addition, (7) is a separator impregnated with a non-aqueous electrolyte, (8)
It is definitely a backing.
下表は各種正極缶を用いた電池を６０゛Ｃにおいて３ケ
月保存後、周波数Ｉ ＫＨｚで測定した内部インピーダ
ンスを比較したものであり、（Ａ）は本発明電池、＜Ｂ
）は硅素をほとんど含まないフェライト系ステンレス鋼
（ＳＵＳ４３０＞を正極缶に■いた第１の比較電池、（
Ｃ）はオーステナイト系不テンレス鋼（ＳＵＳ３０４）
を正極缶に用いた第２の比較電池の場合を夫々示す。The table below compares the internal impedance measured at a frequency of I KHz after storing batteries using various positive electrode cans at 60°C for 3 months.
) is the first comparative battery whose positive electrode can is made of ferritic stainless steel (SUS430), which contains almost no silicon, (
C) is austenitic non-stainless steel (SUS304)
The case of a second comparative battery using the same as the positive electrode case is shown below.
（ｎ ＝ ５ ）
上表より本発明電池によると高温、保存後の内部インピ
ーダンスは低く、且バラツキも小さいことがわかる。尚
、測定後の各電池の正極缶を走査型電子顕微鏡で観察し
たところ比較電池（Ｂ）（Ｃ）の正極缶では腐蝕が見ら
れたが、本発明電池（Ａ）の正極缶では腐蝕現象は認め
られなかった。(n = 5) From the above table, it can be seen that according to the battery of the present invention, the internal impedance after storage at high temperature is low and the variation is small. When the positive electrode cans of each battery were observed using a scanning electron microscope after the measurements, corrosion was observed in the positive electrode cans of comparative batteries (B) and (C), but no corrosion was observed in the positive electrode cans of the invention battery (A). was not recognized.
第２図は正極缶構成部材としてのフェライト系ステンレ
スに含有せる硅素の含有量と内部インピーダンスとの関
係を示す、尚、測定方法は硅素の含有量を種々変化させ
たフェライト系ステンレスを正極缶とせる電池を夫々５
ケづつ作成し、６０℃で３力月保存した後、周波数Ｉ
ＫＨ２で内部インピーダンスを測定した。Figure 2 shows the relationship between the internal impedance and the silicon content contained in ferritic stainless steel as a component of the positive electrode can. 5 batteries each
After storing at 60℃ for 3 months, frequency I
Internal impedance was measured with KH2.
第２図から硅素の含有量としては１．２〜５．０！ （
ｔ％の範囲が特に好ましいことがわかる。From Figure 2, the silicon content is 1.2 to 5.0! (
It can be seen that the range of t% is particularly preferable.
（ト）発明の効果
上述した如く、正極缶構成部材として硅素を１．２〜５
．０重量％含有せるフェライト系ステンレスものであり
、その工業的価値は極めて犬である。(g) Effects of the invention As mentioned above, the amount of silicon in the positive electrode can component is 1.2 to 5.
．． It is a ferritic stainless steel containing 0% by weight, and its industrial value is extremely high.
第１図は本発明電池の半断面図、第２図は正極缶を構成
するフェライト系ステンレス鋼の硅素の含有量と内部イ
ンピーダンスとの関係を示す図である。
（１）・・・負極、（２）・・・負極缶、（４）・・・
正極、（５）・・・正極缶、（７）・・・セパレータ、
（８）・・・絶縁バッキング。FIG. 1 is a half-sectional view of the battery of the present invention, and FIG. 2 is a diagram showing the relationship between the silicon content and internal impedance of the ferritic stainless steel constituting the positive electrode can. (1)... Negative electrode, (2)... Negative electrode can, (4)...
Positive electrode, (5)... Positive electrode can, (7)... Separator,
(8)...Insulating backing.
Claims (1)
極とを備え、正極缶構成部材として硅素を１．２〜５．
０重量％含有するフェライト系ステンレス鋼を用いるこ
とを特徴とする非水電解液電池。(1) Equipped with a negative electrode using a light metal as an active material, a non-aqueous electrolyte, and a positive electrode, and containing 1.2 to 5% silicon as a positive electrode can constituent member.
A non-aqueous electrolyte battery characterized by using ferritic stainless steel containing 0% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60205560A JP2594034B2 (en) | 1985-09-18 | 1985-09-18 | Non-aqueous electrolyte battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60205560A JP2594034B2 (en) | 1985-09-18 | 1985-09-18 | Non-aqueous electrolyte battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6266560A true JPS6266560A (en) | 1987-03-26 |
| JP2594034B2 JP2594034B2 (en) | 1997-03-26 |
Family
ID=16508914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60205560A Expired - Lifetime JP2594034B2 (en) | 1985-09-18 | 1985-09-18 | Non-aqueous electrolyte battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2594034B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11002826B2 (en) | 2016-05-18 | 2021-05-11 | Nec Corporation | Distributed-cooperative-information processing device, distributed-cooperative-information processing method, and recording medium |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58158856A (en) * | 1982-03-16 | 1983-09-21 | Fuji Elelctrochem Co Ltd | Nonaqueous electrolytic battery |
| JPS5919984A (en) * | 1982-07-26 | 1984-02-01 | Olympus Optical Co Ltd | Toner cleaning device |
-
1985
- 1985-09-18 JP JP60205560A patent/JP2594034B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58158856A (en) * | 1982-03-16 | 1983-09-21 | Fuji Elelctrochem Co Ltd | Nonaqueous electrolytic battery |
| JPS5919984A (en) * | 1982-07-26 | 1984-02-01 | Olympus Optical Co Ltd | Toner cleaning device |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11002826B2 (en) | 2016-05-18 | 2021-05-11 | Nec Corporation | Distributed-cooperative-information processing device, distributed-cooperative-information processing method, and recording medium |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2594034B2 (en) | 1997-03-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |