JPS6254878B2 - - Google Patents
Info
- Publication number
- JPS6254878B2 JPS6254878B2 JP55141115A JP14111580A JPS6254878B2 JP S6254878 B2 JPS6254878 B2 JP S6254878B2 JP 55141115 A JP55141115 A JP 55141115A JP 14111580 A JP14111580 A JP 14111580A JP S6254878 B2 JPS6254878 B2 JP S6254878B2
- Authority
- JP
- Japan
- Prior art keywords
- electrolyte
- anode
- anolyte
- anolyte compartment
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003792 electrolyte Substances 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 17
- 239000006260 foam Substances 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 229910017052 cobalt Inorganic materials 0.000 claims description 12
- 239000010941 cobalt Substances 0.000 claims description 12
- 238000005363 electrowinning Methods 0.000 claims description 12
- 238000000605 extraction Methods 0.000 claims description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 11
- 239000004088 foaming agent Substances 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000008396 flotation agent Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA337,248A CA1125228A (en) | 1979-10-10 | 1979-10-10 | Process for electrowinning nickel or cobalt |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5662980A JPS5662980A (en) | 1981-05-29 |
| JPS6254878B2 true JPS6254878B2 (US07498051-20090303-C00003.png) | 1987-11-17 |
Family
ID=4115315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14111580A Granted JPS5662980A (en) | 1979-10-10 | 1980-10-08 | Electrolytic recovery of nickel or cobalt |
Country Status (11)
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1181035A (en) * | 1982-02-04 | 1985-01-15 | Albert J. Alakas | Electrode container for electrolytic cells |
| US4600483A (en) * | 1984-11-19 | 1986-07-15 | Chevron Research Company | Electrolytic reduction of cobaltic ammine |
| GB2250515B (en) * | 1990-11-27 | 1994-09-28 | Rhone Poulenc Chemicals | Controlling acid misting during electrolytic recovery of metals |
| JP2526734B2 (ja) * | 1991-11-22 | 1996-08-21 | 住友金属鉱山株式会社 | 金属電解採取方法に用いる不溶性アノ―ドボックス |
| JP2751900B2 (ja) * | 1995-11-28 | 1998-05-18 | 住友金属鉱山株式会社 | 金属電解採取方法 |
| US6428604B1 (en) | 2000-09-18 | 2002-08-06 | Inco Limited | Hydrometallurgical process for the recovery of nickel and cobalt values from a sulfidic flotation concentrate |
| US6391170B1 (en) | 2000-12-01 | 2002-05-21 | Envirotech Pumpsystems, Inc. | Anode box for electrometallurgical processes |
| US7378011B2 (en) * | 2003-07-28 | 2008-05-27 | Phelps Dodge Corporation | Method and apparatus for electrowinning copper using the ferrous/ferric anode reaction |
| US20060021880A1 (en) * | 2004-06-22 | 2006-02-02 | Sandoval Scot P | Method and apparatus for electrowinning copper using the ferrous/ferric anode reaction and a flow-through anode |
| US7393438B2 (en) * | 2004-07-22 | 2008-07-01 | Phelps Dodge Corporation | Apparatus for producing metal powder by electrowinning |
| EP1712660A1 (de) * | 2005-04-12 | 2006-10-18 | Enthone Inc. | Unlösliche Anode |
| BRPI0604853B1 (pt) * | 2006-10-27 | 2016-03-08 | Vale Do Rio Doce Co | método para produção de cobalto metálico a partir de refinado de extração por solventes de níquel |
| US20080308429A1 (en) * | 2007-06-18 | 2008-12-18 | Cvrd Inco Limited | Method for improving cathode morphology |
| MX2010001916A (es) * | 2007-08-23 | 2010-03-11 | Fernando Penna Wittig | Sistema de control de neblina auxiliado con cerramientos de salida lateral en las celdas de electroobtencion o electrorrefinacion de metal. |
| AU2009206007B8 (en) * | 2008-01-17 | 2012-05-17 | Freeport Mcmoran Corporation | Method and apparatus for electrowinning copper using an atmospheric leach with ferrous/ferric anode reaction electrowinning |
| JP2009203487A (ja) * | 2008-02-26 | 2009-09-10 | Nippon Mining & Metals Co Ltd | 隔膜電解による金属電解採取方法 |
| FI122595B (fi) * | 2009-02-03 | 2012-04-13 | Outotec Oyj | Menetelmä metallin elektrolyyttiseksi talteenottamiseksi ja elektrolyysijärjestelmä |
| US8980068B2 (en) * | 2010-08-18 | 2015-03-17 | Allen R. Hayes | Nickel pH adjustment method and apparatus |
| FI123851B (en) * | 2012-02-08 | 2013-11-15 | Outotec Oyj | Cathode frame and use of cathode frame |
| US10106903B2 (en) * | 2016-03-08 | 2018-10-23 | Uchicago Argonne, Llc | Consumable anode and anode assembly for electrolytic reduction of metal oxides |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US415576A (en) * | 1889-11-19 | Werner siemens | ||
| FR1384780A (fr) * | 1963-11-27 | 1965-01-08 | Nickel Le | Procédé de raffinage électrolytique d'un alliage de nickel, en vue de l'obtention de nickel pur électrolytique |
| CA1020115A (en) * | 1973-02-09 | 1977-11-01 | Victor A. Ettel | Air sparging electrowinning cell |
| GB1478502A (en) * | 1974-11-25 | 1977-07-06 | Falconbridge Nickel Mines Ltd | Electrowinning metal from chloride solution |
| CA1062653A (en) * | 1976-07-02 | 1979-09-18 | Robert W. Elliott | Electrowinning of sulfur-containing nickel |
-
1979
- 1979-10-10 CA CA337,248A patent/CA1125228A/en not_active Expired
-
1980
- 1980-08-18 US US06/178,819 patent/US4288305A/en not_active Expired - Lifetime
- 1980-08-25 ZA ZA00805241A patent/ZA805241B/xx unknown
- 1980-08-28 AU AU61842/80A patent/AU530960B2/en not_active Ceased
- 1980-08-28 ZW ZW202/80A patent/ZW20280A1/xx unknown
- 1980-09-24 DE DE8080303346T patent/DE3062835D1/de not_active Expired
- 1980-09-24 EP EP80303346A patent/EP0027322B1/en not_active Expired
- 1980-10-03 FI FI803147A patent/FI64817C/fi not_active IP Right Cessation
- 1980-10-08 JP JP14111580A patent/JPS5662980A/ja active Granted
- 1980-10-09 NO NO803017A patent/NO154465C/no unknown
- 1980-10-10 ZM ZM89/80A patent/ZM8980A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0027322B1 (en) | 1983-04-20 |
| NO154465C (no) | 1986-09-24 |
| NO154465B (no) | 1986-06-16 |
| FI64817C (fi) | 1984-01-10 |
| AU530960B2 (en) | 1983-08-04 |
| ZW20280A1 (en) | 1981-01-14 |
| CA1125228A (en) | 1982-06-08 |
| NO803017L (no) | 1981-04-13 |
| AU6184280A (en) | 1981-04-16 |
| FI803147L (fi) | 1981-04-11 |
| US4288305A (en) | 1981-09-08 |
| FI64817B (fi) | 1983-09-30 |
| EP0027322A1 (en) | 1981-04-22 |
| JPS5662980A (en) | 1981-05-29 |
| ZA805241B (en) | 1981-09-30 |
| DE3062835D1 (en) | 1983-05-26 |
| ZM8980A1 (en) | 1981-11-23 |
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