JPS6248714B2 - - Google Patents

Info

Publication number

JPS6248714B2

JPS6248714B2 JP10373679A JP10373679A JPS6248714B2 JP S6248714 B2 JPS6248714 B2 JP S6248714B2 JP 10373679 A JP10373679 A JP 10373679A JP 10373679 A JP10373679 A JP 10373679A JP S6248714 B2 JPS6248714 B2 JP S6248714B2

Authority

JP

Japan

Prior art keywords

iron

added

water

metal

reaction

Prior art date

1979-08-15

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

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• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 28
• 238000006243 chemical reaction Methods 0.000 claims description 22
• 239000000203 mixture Substances 0.000 claims description 15
• 229910052742 iron Inorganic materials 0.000 claims description 12
• 239000003999 initiator Substances 0.000 claims description 10
• -1 hydroxylamine inorganic acid salt Chemical class 0.000 claims description 8
• 229910052751 metal Inorganic materials 0.000 claims description 8
• 239000002184 metal Substances 0.000 claims description 8
• 229910044991 metal oxide Inorganic materials 0.000 claims description 8
• 150000004706 metal oxides Chemical class 0.000 claims description 8
• 239000010949 copper Substances 0.000 claims description 6
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
• 229910052802 copper Inorganic materials 0.000 claims description 4
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
• 239000001301 oxygen Substances 0.000 claims description 3
• 229910052760 oxygen Inorganic materials 0.000 claims description 3
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
• VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
• 229910052791 calcium Inorganic materials 0.000 claims description 2
• 239000011575 calcium Substances 0.000 claims description 2
• 229910052804 chromium Inorganic materials 0.000 claims description 2
• 239000011651 chromium Substances 0.000 claims description 2
• 229910017052 cobalt Inorganic materials 0.000 claims description 2
• 239000010941 cobalt Substances 0.000 claims description 2
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
• 229910052749 magnesium Inorganic materials 0.000 claims description 2
• 239000011777 magnesium Substances 0.000 claims description 2
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
• 150000002739 metals Chemical class 0.000 claims description 2
• 229910052759 nickel Inorganic materials 0.000 claims description 2
• 239000004480 active ingredient Substances 0.000 claims 2
• 230000020169 heat generation Effects 0.000 description 10
• QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 6
• 239000005751 Copper oxide Substances 0.000 description 6
• 229910000431 copper oxide Inorganic materials 0.000 description 6
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
• 239000000463 material Substances 0.000 description 3
• 229910001510 metal chloride Inorganic materials 0.000 description 3
• 229910001006 Constantan Inorganic materials 0.000 description 2
• WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 2
• 239000003795 chemical substances by application Substances 0.000 description 2
• 238000007254 oxidation reaction Methods 0.000 description 2
• 239000000843 powder Substances 0.000 description 2
• 150000003839 salts Chemical class 0.000 description 2
• 239000013535 sea water Substances 0.000 description 2
• 239000004698 Polyethylene Substances 0.000 description 1
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
• 229910052783 alkali metal Inorganic materials 0.000 description 1
• 150000001340 alkali metals Chemical class 0.000 description 1
• 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
• 229910052799 carbon Inorganic materials 0.000 description 1
• ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
• 239000008187 granular material Substances 0.000 description 1
• 229910021645 metal ion Inorganic materials 0.000 description 1
• 229910000510 noble metal Inorganic materials 0.000 description 1
• 239000004745 nonwoven fabric Substances 0.000 description 1
• 230000003647 oxidation Effects 0.000 description 1
• 229920000573 polyethylene Polymers 0.000 description 1
• 238000007789 sealing Methods 0.000 description 1
• 239000000741 silica gel Substances 0.000 description 1
• 229910002027 silica gel Inorganic materials 0.000 description 1
• 229910052717 sulfur Inorganic materials 0.000 description 1
• 239000011593 sulfur Substances 0.000 description 1
• 239000002023 wood Substances 0.000 description 1