JPS6242851B2 - - Google Patents
Info
- Publication number
- JPS6242851B2 JPS6242851B2 JP53083893A JP8389378A JPS6242851B2 JP S6242851 B2 JPS6242851 B2 JP S6242851B2 JP 53083893 A JP53083893 A JP 53083893A JP 8389378 A JP8389378 A JP 8389378A JP S6242851 B2 JPS6242851 B2 JP S6242851B2
- Authority
- JP
- Japan
- Prior art keywords
- organic phase
- gallium
- aqueous
- solution
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012074 organic phase Substances 0.000 claims description 61
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 55
- 229910052733 gallium Inorganic materials 0.000 claims description 55
- 238000000034 method Methods 0.000 claims description 41
- 239000000243 solution Substances 0.000 claims description 30
- 239000008346 aqueous phase Substances 0.000 claims description 25
- 239000002253 acid Substances 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 22
- 239000011734 sodium Substances 0.000 claims description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 19
- 229910052708 sodium Inorganic materials 0.000 claims description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 18
- 238000000605 extraction Methods 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical class C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims description 10
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 9
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 9
- FNXKBSAUKFCXIK-UHFFFAOYSA-M sodium;hydrogen carbonate;8-hydroxy-7-iodoquinoline-5-sulfonic acid Chemical class [Na+].OC([O-])=O.C1=CN=C2C(O)=C(I)C=C(S(O)(=O)=O)C2=C1 FNXKBSAUKFCXIK-UHFFFAOYSA-M 0.000 claims description 8
- 239000012298 atmosphere Substances 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 6
- 238000004131 Bayer process Methods 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000011260 aqueous acid Substances 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims 6
- 238000004519 manufacturing process Methods 0.000 claims 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical group [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 239000011356 non-aqueous organic solvent Substances 0.000 claims 1
- 238000011084 recovery Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 150000004325 8-hydroxyquinolines Chemical class 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 239000003637 basic solution Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000000622 liquid--liquid extraction Methods 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000000638 solvent extraction Methods 0.000 description 3
- 125000003158 alcohol group Chemical group 0.000 description 2
- -1 alkenyl 8-hydroxyquinoline Chemical compound 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 1
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/36—Heterocyclic compounds
- C22B3/362—Heterocyclic compounds of a single type
- C22B3/364—Quinoline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7721607A FR2397464A2 (fr) | 1977-07-13 | 1977-07-13 | Procede de recuperation du gallium de solutions tres basiques par extraction liquide/liquide |
| KR7803585A KR810001297B1 (ko) | 1977-07-13 | 1978-12-07 | 갈륨 추출 방법 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5440212A JPS5440212A (en) | 1979-03-29 |
| JPS6242851B2 true JPS6242851B2 (enrdf_load_stackoverflow) | 1987-09-10 |
Family
ID=26220127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8389378A Granted JPS5440212A (en) | 1977-07-13 | 1978-07-10 | Liquiddliquid extraction for recovering gallium from high basic solutions |
Country Status (10)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01117370U (enrdf_load_stackoverflow) * | 1988-01-29 | 1989-08-08 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2460276A1 (fr) * | 1979-07-03 | 1981-01-23 | Rhone Poulenc Ind | Procede de traitement de melanges d'oxydes de terres rares et de gallium |
| FR2532296B1 (fr) * | 1982-08-26 | 1985-06-07 | Rhone Poulenc Spec Chim | Procede d'extraction du gallium a l'aide d'hydroxyquinoleines substituees et de composes organophosphores |
| SE8206378L (sv) * | 1982-11-10 | 1984-05-11 | Sverker Hogberg | Nya kelatbildande kinolinforeningar |
| SE8206377A0 (sv) * | 1982-11-10 | 1984-05-11 | Madan Khorshed | Nya kelatbildande biskinolinföreningar |
| CH655710A5 (de) * | 1983-11-17 | 1986-05-15 | Sulzer Ag | Verfahren zur fluessig-fluessig-extraktion von gallium aus natriumaluminatloesung mit hilfe eines organischen extraktionsmittels. |
| CH656643A5 (de) * | 1983-11-29 | 1986-07-15 | Sulzer Ag | Verfahren zur fluessig-fluessig-extraktion von gallium aus basischen, waessrigen loesungen mit hilfe eines organischen extraktionsmittels. |
| DE3508041A1 (de) * | 1985-03-07 | 1986-09-11 | Preussag Ag Metall, 3380 Goslar | Verfahren zur fluessig-fluessig-extraktion von gallium, germanium oder indium aus waessrigen loesungen |
| NO158028C (no) * | 1985-12-16 | 1988-06-29 | Elkem As | Utvinning av gallium. |
| US5016092A (en) * | 1989-11-17 | 1991-05-14 | Rca Licensing Corporation | Control circuitry for an adaptive multistandard video comb filter |
| FR2670803B1 (fr) * | 1990-12-19 | 1993-03-19 | Rhone Poulenc Chimie | Procede d'extraction de gallium avec de l'hydroxyquinoleine substituee. |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR952976A (fr) * | 1947-08-25 | 1949-11-28 | Alais & Froges & Camarque Cie | Procédé d'extraction de la galline des produits alumineux |
| US3214239A (en) * | 1962-07-02 | 1965-10-26 | Kerr Mc Gee Oil Ind Inc | Recovery of metal values from aqueous solution by solvent extraction with an organo phosphorus extractant |
| US3971843A (en) * | 1974-07-12 | 1976-07-27 | Rhone-Poulenc Industries | Process for liquid/liquid extraction of gallium |
-
1977
- 1977-07-13 FR FR7721607A patent/FR2397464A2/fr active Granted
-
1978
- 1978-06-27 EP EP78400035A patent/EP0000457B1/fr not_active Expired
- 1978-07-10 JP JP8389378A patent/JPS5440212A/ja active Granted
- 1978-07-11 GR GR56752A patent/GR66020B/el unknown
- 1978-07-11 FI FI782222A patent/FI68087C/fi not_active IP Right Cessation
- 1978-07-12 IT IT50271/78A patent/IT1105093B/it active
- 1978-07-12 CA CA000307275A patent/CA1117767A/fr not_active Expired
- 1978-07-12 AU AU37963/78A patent/AU517726B2/en not_active Expired
- 1978-07-13 ES ES471694A patent/ES471694A1/es not_active Expired
- 1978-12-07 KR KR7803585A patent/KR810001297B1/ko not_active Expired
-
1979
- 1979-03-28 ES ES479022A patent/ES479022A1/es not_active Expired
- 1979-03-28 ES ES479023A patent/ES479023A1/es not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01117370U (enrdf_load_stackoverflow) * | 1988-01-29 | 1989-08-08 |
Also Published As
| Publication number | Publication date |
|---|---|
| ES471694A1 (es) | 1979-10-01 |
| ES479022A1 (es) | 1979-07-01 |
| CA1117767A (fr) | 1982-02-09 |
| FI68087B (fi) | 1985-03-29 |
| EP0000457A1 (fr) | 1979-01-24 |
| JPS5440212A (en) | 1979-03-29 |
| FI68087C (fi) | 1985-07-10 |
| KR810001297B1 (ko) | 1981-10-13 |
| FR2397464A2 (fr) | 1979-02-09 |
| FR2397464B2 (enrdf_load_stackoverflow) | 1980-01-18 |
| FI782222A7 (fi) | 1979-01-14 |
| IT7850271A0 (it) | 1978-07-12 |
| ES479023A1 (es) | 1979-07-01 |
| AU517726B2 (en) | 1981-08-20 |
| GR66020B (enrdf_load_stackoverflow) | 1981-01-13 |
| IT1105093B (it) | 1985-10-28 |
| EP0000457B1 (fr) | 1982-06-02 |
| AU3796378A (en) | 1980-01-17 |
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