JPS6238381B2 - - Google Patents
Info
- Publication number
- JPS6238381B2 JPS6238381B2 JP59094242A JP9424284A JPS6238381B2 JP S6238381 B2 JPS6238381 B2 JP S6238381B2 JP 59094242 A JP59094242 A JP 59094242A JP 9424284 A JP9424284 A JP 9424284A JP S6238381 B2 JPS6238381 B2 JP S6238381B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- weight
- silicon
- polytrimethylvinylsilane
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 21
- 239000007789 gas Substances 0.000 claims description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 16
- 229910052710 silicon Inorganic materials 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000000962 organic group Chemical group 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000010408 film Substances 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 12
- 239000010703 silicon Substances 0.000 description 12
- 229920001197 polyacetylene Polymers 0.000 description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 230000035699 permeability Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- 230000006750 UV protection Effects 0.000 description 4
- 238000005266 casting Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- -1 acetylene compound Chemical class 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910021419 crystalline silicon Inorganic materials 0.000 description 2
- GCSJLQSCSDMKTP-UHFFFAOYSA-N ethenyl(trimethyl)silane Chemical compound C[Si](C)(C)C=C GCSJLQSCSDMKTP-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 150000000475 acetylene derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical class FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- DCGLONGLPGISNX-UHFFFAOYSA-N trimethyl(prop-1-ynyl)silane Chemical group CC#C[Si](C)(C)C DCGLONGLPGISNX-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/70—Polymers having silicon in the main chain, with or without sulfur, nitrogen, oxygen or carbon only
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Eyeglasses (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59094242A JPS60238352A (ja) | 1984-05-11 | 1984-05-11 | 気体透過性ポリマ−組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59094242A JPS60238352A (ja) | 1984-05-11 | 1984-05-11 | 気体透過性ポリマ−組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60238352A JPS60238352A (ja) | 1985-11-27 |
JPS6238381B2 true JPS6238381B2 (fr) | 1987-08-18 |
Family
ID=14104835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59094242A Granted JPS60238352A (ja) | 1984-05-11 | 1984-05-11 | 気体透過性ポリマ−組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60238352A (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1068661C (zh) * | 1996-02-02 | 2001-07-18 | 株式会社三协精机制作所 | 滑动轴承的安装方法 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4859215A (en) * | 1988-05-02 | 1989-08-22 | Air Products And Chemicals, Inc. | Polymeric membrane for gas separation |
US6372020B2 (en) * | 1999-08-26 | 2002-04-16 | Jae-Jin Hong | Oxygen enriching membrane |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5221021A (en) * | 1975-08-09 | 1977-02-17 | Kubota Ltd | Method of producing combined piles |
JPS5456985A (en) * | 1977-10-14 | 1979-05-08 | Mitsubishi Chem Ind Ltd | Gas-separaing membrane |
JPS6012104A (ja) * | 1983-06-29 | 1985-01-22 | Sanyo Chem Ind Ltd | 気体分離膜 |
-
1984
- 1984-05-11 JP JP59094242A patent/JPS60238352A/ja active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1068661C (zh) * | 1996-02-02 | 2001-07-18 | 株式会社三协精机制作所 | 滑动轴承的安装方法 |
Also Published As
Publication number | Publication date |
---|---|
JPS60238352A (ja) | 1985-11-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS6135803A (ja) | 複合中空糸 | |
JPS62225513A (ja) | ブロツク・グラフト共重合体及びその製造法 | |
JPH05279481A (ja) | フルオロシリコ−ンブロック共重合体およびその製造方法 | |
KR20130125224A (ko) | 사다리형 사이올계 실세스퀴옥산 고분자 및 이의 제조방법 | |
US4567245A (en) | Substituted polyacetylene copolymer | |
JPS6238381B2 (fr) | ||
Lee et al. | Thiol-ene photopolymerization of well-defined hybrid graft polymers from a ladder-like polysilsesquioxane | |
JPS6317282B2 (fr) | ||
Isobe et al. | Polymerization of 1‐(trimethylsilyl)‐1‐propyne homologs containing two silicon atoms by tantalum‐and niobium‐based catalysts | |
US4033731A (en) | Partially crosslinked silalactone polymers, their preparation and their use | |
JPS6367486B2 (fr) | ||
US5360869A (en) | Method of making fluorinated copolymers | |
US4833262A (en) | Oxygen permeable polymeric materials | |
Nagasaki et al. | Novel organosilicon‐containing polymers for an oxygen permselective membrane | |
US4126736A (en) | Anionically polymerized copolymers of methyl α-N-alkylacrylate and methyl methacrylate and method of making same | |
JP2006131805A (ja) | 脂環式ビニルエーテル共重合体 | |
JPS633644B2 (fr) | ||
JPH0326701B2 (fr) | ||
JPH0260925A (ja) | ブロック−グラフト共重合体およびその製造方法 | |
JPH0556768B2 (fr) | ||
KR20200078154A (ko) | 신규한 공중합체 및 이를 포함하는 광학용 물품 | |
Chujo et al. | Synthesis and application of polymerizable silicone oligomers from water glass | |
JPH0255100B2 (fr) | ||
Okubo et al. | Synthesis, hydrophilicity, and oxygen permeability of poly [(trimethylsilyl) propyne]‐gr‐poly (N, N‐dimethylacrylamide) | |
JPS61268745A (ja) | オルガノポリシロキサン−置換ポリアセチレン組成物 |