JPS62281950A - Deodorant - Google Patents
DeodorantInfo
- Publication number
- JPS62281950A JPS62281950A JP61124351A JP12435186A JPS62281950A JP S62281950 A JPS62281950 A JP S62281950A JP 61124351 A JP61124351 A JP 61124351A JP 12435186 A JP12435186 A JP 12435186A JP S62281950 A JPS62281950 A JP S62281950A
- Authority
- JP
- Japan
- Prior art keywords
- ppm
- ammonia
- initial concentration
- deodorizing
- hydrogen sulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002781 deodorant agent Substances 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 150000002736 metal compounds Chemical class 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
- 230000001877 deodorizing effect Effects 0.000 description 10
- 229910021529 ammonia Inorganic materials 0.000 description 9
- 230000008929 regeneration Effects 0.000 description 9
- 238000011069 regeneration method Methods 0.000 description 9
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000019645 odor Nutrition 0.000 description 5
- 239000011790 ferrous sulphate Substances 0.000 description 4
- 235000003891 ferrous sulphate Nutrition 0.000 description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 244000144972 livestock Species 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000010806 kitchen waste Substances 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
３、発明の詳細な説明
〔産業上の利用分野〕
本発明は、便槽、下水、厨芥、ヘドロ、畜舎などの悪臭
発生源に水溶液にして、直接散布して使用するのに適し
た脱臭剤に関するもので、更に詳しくは、Ａｌ、 Ｃｕ
ｔ Ｚｎｌ Ｍｇ からなる群から選ばれた金属元素
を含む金属化合物からなる脱臭剤に関するものである。[Detailed Description of the Invention] 3. Detailed Description of the Invention [Field of Industrial Application] The present invention is an aqueous solution that can be used by spraying it directly onto sources of odor such as toilet tanks, sewage, kitchen waste, sludge, and livestock sheds. Regarding deodorizing agents suitable for
The present invention relates to a deodorizing agent made of a metal compound containing a metal element selected from the group consisting of tZnlMg.
生活環境において、発生する悪臭を除去することは環境
改善の一つの手段であり、種々の方法が用いられている
。BACKGROUND ART Removing bad odors that occur in living environments is one means of improving the environment, and various methods are used.
一つは居住空間側に悪臭除去手段を設けるもので、空調
手段と組み合わせたもの、室内に静置して使用するもの
、エアゾルとして散布するものがあるが、これらの方法
は効率としては良くない。One is to install a means to remove bad odors in the living space, and there are methods that combine it with air conditioning means, methods that leave it standing indoors, and methods that spray it as an aerosol, but these methods are not very efficient. .
これに対し、悪臭発生源そのもの及びその近傍において
悪臭除去手段１Ｆｒ：講じる方が、悪臭除去の効率は良
好となる。この念め、便槽、下水、厨芥、ヘドロ、畜舎
などに直接散布する形式の脱臭剤が最近多く使用される
ようになってきている。On the other hand, if the malodor removal means 1Fr is provided at the source of the malodor itself and in its vicinity, the efficiency of malodor removal will be better. To keep this in mind, deodorizers that are sprayed directly onto toilet tanks, sewage, kitchen waste, sludge, livestock barns, etc. have recently come into widespread use.
このような散布形式で使用する脱臭剤は、悪臭源である
化学物質と反応することにより、脱臭効果を発揮するも
ので、反応速度が早いために無機物質が主として使用さ
れておシ、特に水溶液が使用されている。Deodorizers used in this type of spraying exhibit a deodorizing effect by reacting with chemical substances that are the source of bad odors, and because the reaction rate is fast, inorganic substances are mainly used, especially in aqueous solutions. is used.
現在、このタイプの脱臭剤でよく利用されているのは硫
酸第１鉄水溶液である。これに関しては特開昭５９−１
３２９３７号公報等に開示されている。Currently, ferrous sulfate aqueous solution is commonly used as this type of deodorizer. Regarding this, JP-A-59-1
It is disclosed in Japanese Patent No. 32937 and the like.
硫酸第１鉄はその使用に対して、毒性の問題がなく、ア
ンモニヤ、アミンに対し、速やかに反応してその臭気を
除去する能力があることが知られている。Ferrous sulfate has no toxicity problems when used, and is known to have the ability to quickly react with ammonia and amines and remove their odors.
しかしながら、硫酸第１鉄に関しては、その水溶液の飛
沫が住居、衣服、その他の物品に付着すると、それが乾
燥した後に黄褐色〜黒褐色に着色して生活環境を損ねる
という欠点を有している。However, ferrous sulfate has the disadvantage that when droplets of its aqueous solution adhere to houses, clothes, and other articles, the droplets dry and turn yellowish brown to blackish brown, impairing the living environment.
これはいわゆる鉄サビの色で人間に対し、きわめて不快
な感じを与える。This is the color of so-called iron rust, and it gives humans an extremely unpleasant feeling.
本発明者らは、対象とする悪臭物質の適用範囲が広く、
かつ、水溶液の飛沫が付着しても着色しない散布用の脱
臭剤を得るため、いろいろ研究を行なった。その結果、
Ａｌ、 Ｃｕｔ Ｚｎｌ Ｍｇ からなる群から選ばれ
た金属元素全含むイオン比金属化合物がすぐれた性能を
有するものであることを見い出し、本発明に到達した。The present inventors have a wide range of application to malodorous substances,
In addition, we conducted various studies in order to obtain a deodorizing agent that can be sprayed and does not become colored even when splashed with aqueous solution. the result,
The inventors have discovered that an ionic ratio metal compound containing all metal elements selected from the group consisting of Al and Cut Znl Mg has excellent performance, and has arrived at the present invention.
Ａｌ、 Ｃｕ、 Ｚｎ、 Ｍｇ からなる群から選ばれ
た金属元素を含む金属化合物とは、ＡＬ＋ Ｃｕｔ Ｚ
ｎｌ Ｎ１ｇ からなる群から選ばれ比金属元素の硫酸
塩、塩化物、硝酸塩、炭酸塩等である。A metal compound containing a metal element selected from the group consisting of Al, Cu, Zn, and Mg is AL+ Cut Z.
sulfates, chlorides, nitrates, carbonates, etc. of specific metal elements selected from the group consisting of nl N1g.
これらの化合物は水溶性であり、水浴液とじて散布する
のに都合よく、更に、無色または白色あるいは淡色であ
って、かつ、脱臭作用はアンモニヤ、硫化水素等に対し
て、硫酸第１鉄とほぼ同等またはそれ以上の能力を有し
ている。These compounds are water-soluble and can be conveniently sprayed in a water bath, and are colorless, white, or light-colored, and have a deodorizing effect similar to that of ferrous sulfate against ammonia, hydrogen sulfide, etc. They have almost the same or greater ability.
本発明になる脱臭剤は、悪臭ガスを発生する便槽、下水
、厨芥、ヘドロ、畜舎などに水溶液又は粉末状で直接散
布して脱臭効果を発揮する。The deodorizing agent of the present invention exerts its deodorizing effect by directly spraying it in an aqueous solution or powder form onto toilet tanks, sewage, kitchen garbage, sludge, livestock sheds, etc. that generate malodorous gases.
また、本脱臭剤は、水溶液自体及びそれが付着乾燥した
ものは無色で之は白色あるいは淡色で、周辺や衣服など
を汚染しないか不快感を与えることがない。In addition, the aqueous solution itself and the dried product of this deodorizing agent are colorless, white or light in color, and do not contaminate the surrounding area or clothes, or cause discomfort.
繊維等に含浸乾燥したものも無色または白色あるいは淡
色であるとともにアンモニヤ、硫化水素等に対する消臭
能力も発揮するので、種々の多孔体に含浸乾燥させて固
形脱臭剤として使用することも可能でおる。When impregnated into fibers and dried, it is colorless, white, or light-colored, and also exhibits deodorizing ability against ammonia, hydrogen sulfide, etc., so it can also be used as a solid deodorizer by impregnating and drying it into various porous materials. .
本発明の脱臭剤を吸着型の脱臭能力を示す活性炭、ゼオ
ライトなどと組み合わせて使用することも可能である。It is also possible to use the deodorizer of the present invention in combination with activated carbon, zeolite, etc. that exhibit adsorption type deodorizing ability.
実施例１
ｚｎｃｔｚ （平均粒度５０μ）のサンプル４．０ ｇ
をＮＦシート（徳山曹達■製、通気性ＰＰクート）で包
装したものをデシケータ中に放置し、アンモニヤまたは
硫化水素濃度の経時変化を測定した。Example 1 4.0 g sample of znctz (average particle size 50μ)
was wrapped in an NF sheet (manufactured by Tokuyama Soda ■, breathable PP Kut) and left in a desiccator, and changes in ammonia or hydrogen sulfide concentration over time were measured.
アンモニヤの場合 初濃度Ｃｏ＝３７０ｐｐｍ。In the case of ammonia Initial concentration of Co = 370 ppm.
４時間復製度Ｃ＝１５ｐｐｍ、 Ｃ７０ｏ ＝ ０．０４ 硫化水素の場合 初濃度 Ｃ＝２５ｐｐｍ、 ４時間復製度Ｃ＝Ｏｐｐｍ。4-hour regeneration degree C = 15 ppm, C70o = 0.04 For hydrogen sulfide Initial concentration C=25ppm, 4-hour regeneration degree C=Oppm.
Ｃ／Ｃｏ＝０
比較例ｌ
ＦｅＳＯ４・７Ｈ２０（平均粒度１２ｏμ）のサンプル
について実施例１と同様のやり方で実験した。C/Co=0 Comparative Example 1 An experiment was conducted in the same manner as in Example 1 using a sample of FeSO4.7H20 (average particle size 12 μm).
アンモニヤの場合
初濃度Ｃｏ＝４５０ ｐ ｐｍ、
４時間復製度Ｃ＝８ｐｐｍ、 Ｃ／Ｃｏ＝０．０２硫
化水素の場合
初濃度 Ｃｏ＝３６ｐｐｍ。In case of ammonia, initial concentration Co = 450 ppm, 4-hour regeneration degree C = 8 ppm, C/Co = 0.02 In case of hydrogen sulfide, initial concentration Co = 36 ppm.
４時間復製度 Ｃ＝２９ ｐ ｐｍ、
Ｃ７０ｏ ＝ ０．８０
実施例２
Ａｔｚ（ＳＯａ）ｓ”ＨｚＯ（平均粒度４０μ）のサン
プルについて実施例１と同様のやシ方で実験した。4-hour regeneration degree C = 29 ppm, C70o = 0.80 Example 2 An experiment was conducted in the same manner as in Example 1 using a sample of Atz(SOa)s''HzO (average particle size 40μ).
アンモニヤの場合 初濃度 Ｃｏ＝２９０ＰＰｍ− ４時間復製度 Ｃ＝９ｐｐｍ。In the case of ammonia Initial concentration Co=290PPm- 4-hour regeneration degree C=9ppm.
Ｃ／Ｃｏ＝０．０３ 硫化水素の場合 初濃度 Ｃｏ＝３７ｐｐｍ。C/Co=0.03 For hydrogen sulfide Initial concentration Co = 37 ppm.
４時間復製度 Ｃ＝３０ｐｐｍ。4-hour regeneration degree C = 30 ppm.
Ｃ７０ｏ ＝ ０．８０
実施例３
ＭｇＣｌ２（平均粒度７０μ）のサンプルについて実施
例１と同様のや）方でアンモニヤの場合を実験した。C70o = 0.80 Example 3 The case of ammonia was tested in the same way as in Example 1 for a sample of MgCl2 (average particle size 70μ).
初濃度 Ｃｏ＝４３０ｐｐｍ。Initial concentration Co = 430 ppm.
４時間復製度 Ｃ＝２０ｐｐｍ、
Ｃ／Ｃｏ ＝ ０．０５
実施例４
ＣｕＳ０４（平均粒度４０μ）のサンプルについて実施
例１と同様のやり方で硫化水素の場合を実験した。4-hour regeneration degree C = 20 ppm, C/Co = 0.05 Example 4 The case of hydrogen sulfide was tested in the same manner as in Example 1 using a sample of CuS04 (average particle size 40 μ).
初濃度 ＣＯ＝１９ｐＰｍ、
４時間復製度 Ｃ＝２ｐｐｍ、
Ｃ／Ｃ０＝０．１１
比較例２
Ｎａ ２ Ｓｏａ （平均粒度９０μ）のサンプルにつ
いて実施例１と同様のやシ方でアンモニヤの場合を実験
した。Initial concentration CO = 19 pPm, 4-hour regeneration degree C = 2 ppm, C/C0 = 0.11 Comparative Example 2 An experiment was conducted using ammonia in the same manner as in Example 1 for a sample of Na 2 Soa (average particle size 90 μ). did.
初濃度 Ｃｏ＝３７０ｐｐｍ。Initial concentration Co = 370 ppm.
４時間復製度 Ｃ＝３４０ｐｐｍ、 Ｃ／ＣＯ＝ ０．９２4-hour regeneration degree C=340ppm, C/CO=0.92
Claims (1)
素を含む金属化合物からなる脱臭剤。A deodorizer made of a metal compound containing a metal element selected from the group consisting of Al, Cu, Zn, and Mg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61124351A JPS62281950A (en) | 1986-05-29 | 1986-05-29 | Deodorant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61124351A JPS62281950A (en) | 1986-05-29 | 1986-05-29 | Deodorant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62281950A true JPS62281950A (en) | 1987-12-07 |
Family
ID=14883229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61124351A Pending JPS62281950A (en) | 1986-05-29 | 1986-05-29 | Deodorant |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62281950A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006026305A1 (en) * | 2006-06-02 | 2007-12-06 | Barnickel, Thomas C. | Composition, useful for neutralizing or removing odor of biological origin, comprises water-soluble -magnesium salt and -aluminum salt |
| EP2559445A1 (en) | 2011-08-17 | 2013-02-20 | Thomas C. Barnickel | Compound for neutralising odours and use of same |
| DE102012101867A1 (en) | 2012-03-06 | 2013-09-12 | Thomas C. Barnickel | Composition useful for preparing aqueous solution for neutralizing odor of biological origin on surface, preferably household surface made of e.g. plastic, comprises mixture of aluminum sulfate and sodium chloride |
| JP2015043868A (en) * | 2013-08-28 | 2015-03-12 | Ｊｆｅミネラル株式会社 | Agent for inhibiting generation of ammonia gas, and method for inhibiting generation of ammonia gas |
-
1986
- 1986-05-29 JP JP61124351A patent/JPS62281950A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006026305A1 (en) * | 2006-06-02 | 2007-12-06 | Barnickel, Thomas C. | Composition, useful for neutralizing or removing odor of biological origin, comprises water-soluble -magnesium salt and -aluminum salt |
| DE102006026305B4 (en) * | 2006-06-02 | 2009-12-31 | Barnickel, Thomas C. | Odor neutralizing composition |
| EP2559445A1 (en) | 2011-08-17 | 2013-02-20 | Thomas C. Barnickel | Compound for neutralising odours and use of same |
| DE102012101867A1 (en) | 2012-03-06 | 2013-09-12 | Thomas C. Barnickel | Composition useful for preparing aqueous solution for neutralizing odor of biological origin on surface, preferably household surface made of e.g. plastic, comprises mixture of aluminum sulfate and sodium chloride |
| JP2015043868A (en) * | 2013-08-28 | 2015-03-12 | Ｊｆｅミネラル株式会社 | Agent for inhibiting generation of ammonia gas, and method for inhibiting generation of ammonia gas |
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