JPS6349164A - Aqueous solution deodorant - Google Patents
Aqueous solution deodorantInfo
- Publication number
- JPS6349164A JPS6349164A JP61191297A JP19129786A JPS6349164A JP S6349164 A JPS6349164 A JP S6349164A JP 61191297 A JP61191297 A JP 61191297A JP 19129786 A JP19129786 A JP 19129786A JP S6349164 A JPS6349164 A JP S6349164A
- Authority
- JP
- Japan
- Prior art keywords
- aqueous solution
- aqueous
- solution
- deodorizing
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007864 aqueous solution Substances 0.000 title claims description 11
- 239000002781 deodorant agent Substances 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 11
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 4
- 229960001763 zinc sulfate Drugs 0.000 claims description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 239000003002 pH adjusting agent Substances 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 2
- 230000001877 deodorizing effect Effects 0.000 description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 16
- 239000000126 substance Substances 0.000 description 14
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 9
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 9
- 235000019645 odor Nutrition 0.000 description 9
- 229910021529 ammonia Inorganic materials 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 4
- 238000004332 deodorization Methods 0.000 description 4
- 239000010806 kitchen waste Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000005273 aeration Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 239000001744 Sodium fumarate Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- MSJMDZAOKORVFC-SEPHDYHBSA-L disodium fumarate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C\C([O-])=O MSJMDZAOKORVFC-SEPHDYHBSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- -1 etc. Chemical compound 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 229940005573 sodium fumarate Drugs 0.000 description 1
- 235000019294 sodium fumarate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- RZLVQBNCHSJZPX-UHFFFAOYSA-L zinc sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Zn+2].[O-]S([O-])(=O)=O RZLVQBNCHSJZPX-UHFFFAOYSA-L 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明：よ、便槽、厨芥、ヘドロ、畜舎などの悪臭発生
源に直接散布して使用するのに適した水溶液脱臭剤に関
する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an aqueous deodorizing agent suitable for use by spraying directly onto sources of bad odors such as toilet tanks, kitchen waste, sludge, and livestock sheds.
昭和４０年代中頃までの高度成長期における悪臭問題は
比較的高温度で大規模な悪臭の発生源、例えば石油化学
工場、バルブ工場等に原因をなすものが大多数を占めて
いたが、昭和４６年に悪臭防止法が施行されて後工業的
脱臭装置が種々開発されるなど、工業的脱臭の技術が進
歩し、大規模発生源における悪臭問題の比重は低下して
いった。During the period of high economic growth up to the mid-1960s, the majority of odor problems were caused by relatively high temperature, large-scale odor sources, such as petrochemical plants and valve factories. With the advancement of industrial deodorization technology, such as the enactment of the Offensive Odor Prevention Act in 1998 and the development of various post-industrial deodorization devices, the proportion of offensive odor problems at large-scale sources has decreased.
最近は生活環境をより快適にという追求から、小規模・
間欠的な悪臭の発生源、例えば厨芥、汲み取り式トイレ
等に対しても対応が迫られるようになってきた。その対
応策として居住空間側よりも悪臭発生源及びその近傍に
おいて悪臭防止手段を講じる方が効率が高いことは当然
である。このような理由で厨芥、便槽等に直接撒布する
液状の脱臭剤が最近使用されろようになってきているが
、これらは速効性であり、且つ比較的安価に使用できる
ものでなければならない。Recently, in pursuit of a more comfortable living environment, small-scale
It has become necessary to deal with sources of intermittent bad odors, such as kitchen waste and pump-out toilets. As a countermeasure against this problem, it is natural that it is more efficient to take measures to prevent bad odor at the source of the odor and its vicinity, rather than on the living space side. For this reason, liquid deodorizers that are sprayed directly onto kitchen waste, toilet bowls, etc. have recently come into use, but these must be fast-acting and relatively inexpensive to use. .
〔発明が解決しようとする問題点］
悪臭物質と呼ばれるものは、化学構造的に広い範囲に及
んでいるが、アンモニア、アミン、硫化水素など代表的
なものは、かなり強いアルカリ性か又は酸性の物質であ
る。従って悪臭物質と反対のｐＨ挙動を示す物質を用い
て中和することによりその悪臭を除去することができる
。[Problems to be solved by the invention] Malodorous substances have a wide range of chemical structures, but representative ones such as ammonia, amines, and hydrogen sulfide are fairly strong alkaline or acidic substances. It is. Therefore, the malodor can be removed by neutralizing it with a substance that exhibits a pH behavior opposite to that of the malodorous substance.
この中和方法による脱臭は、悪臭物質のｐＨ挙動が一方
に集まっているとき効果があるが、悪臭の発生が多くの
物質が混在したものである場合、単なる中和方法による
脱臭は効果が不十分であったり、却って成る種の悪臭を
強める効果をもたらしたりすることが多い。Deodorization by this neutralization method is effective when the pH behavior of malodorous substances is concentrated on one side, but if the malodor is caused by a mixture of many substances, deodorization by simple neutralization is ineffective. It is often sufficient, or even has the effect of intensifying the odor of the seeds.
上記悪臭物質のうち、アルカリ性物質の代表的なものが
アンモニアであり、一方、硫化水素は酸性物質である。Among the malodorous substances mentioned above, ammonia is a typical alkaline substance, while hydrogen sulfide is an acidic substance.
この両物質に脱臭効果のある撒布用脱臭剤を得ることが
出来れば、それは広い範囲の悪臭源に有効な脱臭剤と考
えられる。If it is possible to obtain a spray deodorizer that has deodorizing effects on both of these substances, it will be considered an effective deodorizer for a wide range of malodor sources.
本発明者らは、悪臭物質の代表といえるアンモニアと硫
化水素の両方の脱臭に効果があり、かつ安価に製造可能
な撒布用脱臭剤を得るため鋭意研究を行った。その結果
、硫酸アルミニウム、硫酸亜鉛等の金属強酸塩の水溶液
に金属錯体形成剤とｐＨＪＩ整剤を含有し、そのｐＨを
５〜９に調整したものが優れた性能を有するものである
ことを見出し、本発明に到達した。The present inventors conducted extensive research in order to obtain a deodorizing agent for spraying that is effective in deodorizing both ammonia and hydrogen sulfide, which can be said to be representative malodorous substances, and can be manufactured at low cost. As a result, they found that an aqueous solution of strong metal salts such as aluminum sulfate and zinc sulfate containing a metal complex forming agent and a pHJI regulator and adjusting the pH to 5 to 9 had excellent performance. , arrived at the present invention.
本発明は、アルカリ金属及びアルカリ止金属を除く金属
の強酸塩と、錯体形成剤と、溶液のｐｌｌを５〜９の範
囲に調整するのに必要なｐＨ調整剤とを含有することを
特徴とする水溶液脱臭剤に関するものである。The present invention is characterized in that it contains a strong acid salt of a metal other than an alkali metal and an alkali stopping metal, a complex forming agent, and a pH adjusting agent necessary to adjust the PLL of the solution to a range of 5 to 9. This invention relates to an aqueous deodorizing agent.
本発明に使用する金属の強酸塩とは、アルミニウム、亜
鉛、鉄、銅、マンガン、コバルト、ニッケルなどの硫酸
塩、硝酸塩及び塩化物などであり、特に硫酸アルミニウ
ム、硫酸亜鉛が適当なものである。これらの金属強酸塩
の水溶液はアンモニアに対して強い防臭効果を示し、そ
の脱臭速度は速やかである。これら金属の強酸塩は、例
えば１０％？８ ／Ｆｉ、におけるｐｌｌは２〜４程度
の酸性であり、アンモニアに対する親和性は一種の中和
反応によるものと考えられる。The strong acid salts of metals used in the present invention include sulfates, nitrates, and chlorides of aluminum, zinc, iron, copper, manganese, cobalt, nickel, etc., and aluminum sulfate and zinc sulfate are particularly suitable. . Aqueous solutions of these strong metal salts exhibit strong deodorizing effects against ammonia, and their deodorizing speed is rapid. The strong acid salts of these metals are, for example, 10%? pll in 8/Fi is about 2 to 4 acidic, and the affinity for ammonia is thought to be due to a kind of neutralization reaction.
一般にこれら金属の強酸塩の水溶液は、アルカリ性であ
るアンモニアには脱臭効果があるが、酸性物質である硫
化水素には銅塩などの一部金属塩を除いては脱臭効果を
有しない。しかしながら、水溶液にｐＨ調整剤、即ちこ
の場合は水酸化ナトリウムなどのアルカリを加えること
によりｐｕを５〜９、好ましくは７〜８に調整して得ら
れる水溶液は、硫化水素に対し脱臭効果を有する。とこ
ろが、多くの金属の強酸塩にアルカリを加えてｐＨを中
性側に移動させようとすると、金属水酸化物などの形で
沈澱する傾向がある。Generally, aqueous solutions of strong acid salts of these metals have a deodorizing effect on ammonia, which is alkaline, but do not have a deodorizing effect on hydrogen sulfide, which is an acidic substance, except for some metal salts such as copper salts. However, the aqueous solution obtained by adjusting the PU to 5 to 9, preferably 7 to 8 by adding a pH adjuster, that is, an alkali such as sodium hydroxide in this case, to the aqueous solution has a deodorizing effect on hydrogen sulfide. . However, when an alkali is added to strong acid salts of many metals in an attempt to shift the pH to the neutral side, metal hydroxides tend to precipitate.
沈澱を形成したものは撒布用に不適当であるか、又は効
果を大幅に減少させる。これに対し、水溶液中に錯体形
成能のある物質を加えておくと、ｐＨを移動させても沈
澱を防止して安定な溶解状態を保つようになり、目的の
水溶液を得ることができる。錯体形成剤としては、オキ
シカルボン酸、多価カルボン酸又はそれらのアルカリ塩
、例えばクエン酸ナトリウム、酒石酸ナトリウム、フマ
ール酸ナトリウムなどを使用することができる。Those that form a precipitate are unsuitable for spraying or greatly reduce effectiveness. On the other hand, if a substance capable of forming a complex is added to an aqueous solution, precipitation will be prevented and a stable dissolution state will be maintained even if the pH is changed, making it possible to obtain the desired aqueous solution. As the complex forming agent, oxycarboxylic acids, polycarboxylic acids, or alkali salts thereof, such as sodium citrate, sodium tartrate, sodium fumarate, etc. can be used.
本発明の水溶液脱臭剤は脱臭効果が迅速であり、且つ悪
臭ガスに対する通用範囲が広いため、複数の悪臭ガスを
発生する実際の発生源である便槽、厨芥、ヘドロ、下水
などに対して有効である。即ち本発明の水溶液脱臭剤を
対象に直接撒布することにより、迅速な消臭効果が得ら
れる。The aqueous solution deodorizer of the present invention has a quick deodorizing effect and has a wide range of applications against malodorous gases, so it is effective against actual sources of multiple malodorous gases such as toilet tanks, kitchen waste, sludge, and sewage. It is. That is, by directly spraying the aqueous deodorizing agent of the present invention on a target, a rapid deodorizing effect can be obtained.
本発明の脱臭剤は、特に金属塩として硫酸アルミニウム
或いは硫酸亜鉛を用いた場合、水溶液自体及びそれが付
着乾燥したものも無色であり、周辺や作業者の衣服など
を汚染することがない。これらを用いた水溶液脱臭剤は
、繊維等に含浸乾燥したものも無色であると共に、アン
モニア、硫化水素に対する消臭能力を発揮するので、種
々の多孔体に含浸乾燥させて固形脱臭剤として使用する
ことも可能である。In the deodorizing agent of the present invention, especially when aluminum sulfate or zinc sulfate is used as the metal salt, the aqueous solution itself and the dried product to which it is attached are colorless, and do not contaminate the surrounding area or the clothes of workers. Aqueous deodorizing agents using these materials are colorless when impregnated into fibers, etc. and dried, and also exhibit deodorizing ability against ammonia and hydrogen sulfide, so they can be used as solid deodorizing agents by impregnating and drying them into various porous bodies. It is also possible.
以下に実施例を挙げて本発明を説明するが、本発明はこ
れにより限定されるものではない。The present invention will be explained below with reference to Examples, but the present invention is not limited thereto.
実施例１
硫酸アルミニウム１８水塩４ｇ、硫酸亜鉛７水塩０．５
ｇ、クエン酸ナトリウム２ｇに水酸化ナトリウム１ｇを
蒸留水１９２．５ｇに溶かした溶液（ｐＨ＝６．５）を
加え、全量２００ｇの溶液を調製した。Example 1 4 g of aluminum sulfate 18 hydrate, 0.5 g of zinc sulfate heptahydrate
A solution of 1 g of sodium hydroxide dissolved in 192.5 g of distilled water (pH = 6.5) was added to 2 g of sodium citrate to prepare a total solution of 200 g.
上記溶液３０ｇを洗気ビンに取り、４３〜４８ｐｐｍの
硫化水素ガスを含有する窒素ガスを０．２５７！／分の
速度で通気し、通気開始一定時間後での溶液中を通過し
てきたガス中の硫化水素ガス濃度を検知管を用いて測定
した。Take 30 g of the above solution in a washing bottle and add 0.257 g of nitrogen gas containing 43 to 48 ppm of hydrogen sulfide gas. Aeration was carried out at a rate of 1/min, and the concentration of hydrogen sulfide gas in the gas passing through the solution was measured using a detection tube after a certain period of time after the start of aeration.
対照溶液として蒸留水を用い同様の測定を行った。その
結果は次の表１の通りである。Similar measurements were performed using distilled water as a control solution. The results are shown in Table 1 below.
表１ 硫化水素に対する本発明溶液の効果実施例２
実施例１で調製した溶液１７０ｇを洗気びんに取り、９
００ｐｐｍのアンモニアガスを含有する空気を１１／分
の速度で通気し、通気開始一定時間後での溶液中を通過
してきたガス中のアンモニアガス濃度を検知管によって
測定した。Table 1 Effect of the solution of the present invention on hydrogen sulfide Example 2 170 g of the solution prepared in Example 1 was placed in an air washing bottle,
Air containing 00 ppm of ammonia gas was aerated at a rate of 11/min, and the concentration of ammonia gas in the gas that had passed through the solution after a certain time after the start of aeration was measured using a detection tube.
対照溶液として蒸留水を用い同様の測定を行った。その
結果は次の表２の通りである。Similar measurements were performed using distilled water as a control solution. The results are shown in Table 2 below.
Claims (1)
塩と、錯体形成剤と、溶液のｐＨを５〜９の範囲に調整
するのに必要なｐＨ調整剤とを含有することを特徴とす
る水溶液脱臭剤。 ２ アルカリ金属及びアルカリ土金属を除く金属の強酸
塩が硫酸アルミニウム又は硫酸亜鉛である特許請求の範
囲第１項記載の水溶液脱臭剤。 ３ 錯体形成剤がオキシカルボン酸又は多価カルボン酸
又はそれらの塩である特許請求の範囲第１項又は第２項
記載の水溶液脱臭剤。[Claims] 1. Contains a strong acid salt of a metal other than alkali metals and alkaline earth metals, a complex forming agent, and a pH adjusting agent necessary to adjust the pH of the solution to a range of 5 to 9. An aqueous deodorizer featuring: 2. The aqueous solution deodorizer according to claim 1, wherein the strong acid salt of a metal other than alkali metals and alkaline earth metals is aluminum sulfate or zinc sulfate. 3. The aqueous deodorizer according to claim 1 or 2, wherein the complex forming agent is an oxycarboxylic acid, a polycarboxylic acid, or a salt thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61191297A JPS6349164A (en) | 1986-08-15 | 1986-08-15 | Aqueous solution deodorant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61191297A JPS6349164A (en) | 1986-08-15 | 1986-08-15 | Aqueous solution deodorant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6349164A true JPS6349164A (en) | 1988-03-01 |
Family
ID=16272218
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61191297A Pending JPS6349164A (en) | 1986-08-15 | 1986-08-15 | Aqueous solution deodorant |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6349164A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002024237A1 (en) * | 2000-09-21 | 2002-03-28 | Withgaia Co., Ltd. | Liquid deodorant composition and method for use thereof |
-
1986
- 1986-08-15 JP JP61191297A patent/JPS6349164A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002024237A1 (en) * | 2000-09-21 | 2002-03-28 | Withgaia Co., Ltd. | Liquid deodorant composition and method for use thereof |
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