JPS6227166B2 - - Google Patents
Info
- Publication number
- JPS6227166B2 JPS6227166B2 JP5084984A JP5084984A JPS6227166B2 JP S6227166 B2 JPS6227166 B2 JP S6227166B2 JP 5084984 A JP5084984 A JP 5084984A JP 5084984 A JP5084984 A JP 5084984A JP S6227166 B2 JPS6227166 B2 JP S6227166B2
- Authority
- JP
- Japan
- Prior art keywords
- fibers
- fiber
- aromatic
- gas
- vapor phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 claims description 57
- 239000007789 gas Substances 0.000 claims description 26
- 125000003118 aryl group Chemical group 0.000 claims description 18
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 14
- 239000012808 vapor phase Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 229910052786 argon Inorganic materials 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 238000001947 vapour-phase growth Methods 0.000 claims description 5
- 150000008065 acid anhydrides Chemical class 0.000 claims description 4
- 239000001307 helium Substances 0.000 claims description 4
- 229910052734 helium Inorganic materials 0.000 claims description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 45
- 150000008064 anhydrides Chemical class 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 14
- 229920000049 Carbon (fiber) Polymers 0.000 description 13
- 239000004917 carbon fiber Substances 0.000 description 13
- 230000000704 physical effect Effects 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 8
- 239000002134 carbon nanofiber Substances 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- CLYVDMAATCIVBF-UHFFFAOYSA-N pigment red 224 Chemical compound C=12C3=CC=C(C(OC4=O)=O)C2=C4C=CC=1C1=CC=C2C(=O)OC(=O)C4=CC=C3C1=C42 CLYVDMAATCIVBF-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 208000016853 pontine tegmental cap dysplasia Diseases 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 102100027617 DNA/RNA-binding protein KIN17 Human genes 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 101100398255 Homo sapiens KIN gene Proteins 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 125000006159 dianhydride group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- MZYHMUONCNKCHE-UHFFFAOYSA-N naphthalene-1,2,3,4-tetracarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=C(C(O)=O)C(C(O)=O)=C21 MZYHMUONCNKCHE-UHFFFAOYSA-N 0.000 description 2
- YTVNOVQHSGMMOV-UHFFFAOYSA-N naphthalenetetracarboxylic dianhydride Chemical compound C1=CC(C(=O)OC2=O)=C3C2=CC=C2C(=O)OC(=O)C1=C32 YTVNOVQHSGMMOV-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- -1 3,4,8,9 anthracenetetracarboxylic Chemical compound 0.000 description 1
- AIVVXPSKEVWKMY-UHFFFAOYSA-N 4-(3,4-dicarboxyphenoxy)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C(C(O)=O)=C1 AIVVXPSKEVWKMY-UHFFFAOYSA-N 0.000 description 1
- AVCOFPOLGHKJQB-UHFFFAOYSA-N 4-(3,4-dicarboxyphenyl)sulfonylphthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1S(=O)(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 AVCOFPOLGHKJQB-UHFFFAOYSA-N 0.000 description 1
- JVERADGGGBYHNP-UHFFFAOYSA-N 5-phenylbenzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(=O)O)=CC(C=2C=CC=CC=2)=C1C(O)=O JVERADGGGBYHNP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- WKDNYTOXBCRNPV-UHFFFAOYSA-N bpda Chemical compound C1=C2C(=O)OC(=O)C2=CC(C=2C=C3C(=O)OC(C3=CC=2)=O)=C1 WKDNYTOXBCRNPV-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- YOXXMDMFOHDKAE-UHFFFAOYSA-N perylene-1,6,7,12-tetracarboxylic acid Chemical compound C1(=CC=C2C=CC(=C3C=4C(=CC=C5C=CC(=C(C1=C23)C=45)C(=O)O)C(=O)O)C(=O)O)C(=O)O YOXXMDMFOHDKAE-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- JEVOQXUAWFYIBD-UHFFFAOYSA-N pyrene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C2C(C(=O)O)=CC3=CC=CC4=CC=C1C2=C34 JEVOQXUAWFYIBD-UHFFFAOYSA-N 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- LUEGQDUCMILDOJ-UHFFFAOYSA-N thiophene-2,3,4,5-tetracarboxylic acid Chemical compound OC(=O)C=1SC(C(O)=O)=C(C(O)=O)C=1C(O)=O LUEGQDUCMILDOJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Landscapes
- Inorganic Fibers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5084984A JPS60199919A (ja) | 1984-03-19 | 1984-03-19 | 炭素質繊維の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5084984A JPS60199919A (ja) | 1984-03-19 | 1984-03-19 | 炭素質繊維の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60199919A JPS60199919A (ja) | 1985-10-09 |
| JPS6227166B2 true JPS6227166B2 (enrdf_load_stackoverflow) | 1987-06-12 |
Family
ID=12870166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5084984A Granted JPS60199919A (ja) | 1984-03-19 | 1984-03-19 | 炭素質繊維の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60199919A (enrdf_load_stackoverflow) |
-
1984
- 1984-03-19 JP JP5084984A patent/JPS60199919A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60199919A (ja) | 1985-10-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5149584A (en) | Carbon fiber structures having improved interlaminar properties | |
| US5413866A (en) | High performance carbon filament structures | |
| US5618875A (en) | High performance carbon filament structures | |
| JPH0827279A (ja) | 新規炭素フィブリルを含む複合材料 | |
| AU4947390A (en) | Carbon fibrils and a catalytic vapor growth method for producing carbon fibrils | |
| KR100497766B1 (ko) | 미세 탄소 섬유와 그 제조 방법 및 그 미세 탄소 섬유를 함유하는 도전성 재료 | |
| KR100841275B1 (ko) | 기상법 탄소섬유, 그 제조방법, 및 탄소섬유를 함유하는복합재 | |
| JPH0536521B2 (enrdf_load_stackoverflow) | ||
| JPS6227166B2 (enrdf_load_stackoverflow) | ||
| JPS6221882B2 (enrdf_load_stackoverflow) | ||
| JPS58197314A (ja) | 繊維状炭素 | |
| US20030082093A1 (en) | Carbon fibrils and method for producing same | |
| JPH0356596B2 (enrdf_load_stackoverflow) | ||
| JPS6224522B2 (enrdf_load_stackoverflow) | ||
| JPS639044B2 (enrdf_load_stackoverflow) | ||
| JPS61132630A (ja) | 炭素質繊維 | |
| JP2005015339A (ja) | 微細炭素繊維及びその製造方法並びに該微細炭素繊維を含む導電性材料 | |
| JPS61275114A (ja) | グラフアイトの製造方法 | |
| JP2586054B2 (ja) | 気相成長炭素繊維の製造方法 | |
| JPH0114326B2 (enrdf_load_stackoverflow) | ||
| EP1154050A1 (en) | Carbon fibrils and method for producing same | |
| JPH0648870A (ja) | 炭素系シート状物およびその製造方法 | |
| JP2586055B2 (ja) | 気相成長炭素繊維の製造方法 | |
| JP2643984B2 (ja) | 炭素繊維成形断熱材の製造方法及び断熱材 | |
| JPH06146118A (ja) | 炭素繊維およびその製造方法 |