JPS62106839A - シ−ト・ケイ酸塩の水性懸濁液の調製方法 - Google Patents
シ−ト・ケイ酸塩の水性懸濁液の調製方法Info
- Publication number
- JPS62106839A JPS62106839A JP26088386A JP26088386A JPS62106839A JP S62106839 A JPS62106839 A JP S62106839A JP 26088386 A JP26088386 A JP 26088386A JP 26088386 A JP26088386 A JP 26088386A JP S62106839 A JPS62106839 A JP S62106839A
- Authority
- JP
- Japan
- Prior art keywords
- ammonium
- cation
- film
- silicate
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims description 25
- 239000000725 suspension Substances 0.000 title claims description 11
- 238000002360 preparation method Methods 0.000 title description 5
- 238000000034 method Methods 0.000 claims description 32
- 235000019354 vermiculite Nutrition 0.000 claims description 32
- 150000001768 cations Chemical class 0.000 claims description 31
- 229910052902 vermiculite Inorganic materials 0.000 claims description 31
- 239000010455 vermiculite Substances 0.000 claims description 31
- 238000005342 ion exchange Methods 0.000 claims description 21
- -1 guanidine cation Chemical class 0.000 claims description 20
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 14
- HPNMFZURTQLUMO-UHFFFAOYSA-O diethylammonium Chemical compound CC[NH2+]CC HPNMFZURTQLUMO-UHFFFAOYSA-O 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 14
- 239000010445 mica Substances 0.000 claims description 13
- 229910052618 mica group Inorganic materials 0.000 claims description 13
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 11
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000013078 crystal Substances 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 9
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 8
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 claims description 6
- 239000007900 aqueous suspension Substances 0.000 claims description 5
- WEHWNAOGRSTTBQ-UHFFFAOYSA-O dipropylazanium Chemical compound CCC[NH2+]CCC WEHWNAOGRSTTBQ-UHFFFAOYSA-O 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 claims description 5
- 229910052615 phyllosilicate Inorganic materials 0.000 claims description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000006185 dispersion Substances 0.000 description 37
- 239000000243 solution Substances 0.000 description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 18
- 229910052744 lithium Inorganic materials 0.000 description 18
- 230000008961 swelling Effects 0.000 description 15
- 239000011734 sodium Substances 0.000 description 13
- 229910052708 sodium Inorganic materials 0.000 description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 150000004760 silicates Chemical class 0.000 description 12
- 239000011521 glass Substances 0.000 description 10
- 229960004198 guanidine Drugs 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 238000005341 cation exchange Methods 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 4
- HDITUCONWLWUJR-UHFFFAOYSA-N diethylazanium;chloride Chemical compound [Cl-].CC[NH2+]CC HDITUCONWLWUJR-UHFFFAOYSA-N 0.000 description 4
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- 229910052627 muscovite Inorganic materials 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000007970 homogeneous dispersion Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052628 phlogopite Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- PJJJBBJSCAKJQF-UHFFFAOYSA-N guanidinium chloride Chemical compound [Cl-].NC(N)=[NH2+] PJJJBBJSCAKJQF-UHFFFAOYSA-N 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 241000234282 Allium Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-O butylazanium Chemical compound CCCC[NH3+] HQABUPZFAYXKJW-UHFFFAOYSA-O 0.000 description 1
- ICXXXLGATNSZAV-UHFFFAOYSA-N butylazanium;chloride Chemical compound [Cl-].CCCC[NH3+] ICXXXLGATNSZAV-UHFFFAOYSA-N 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229960000789 guanidine hydrochloride Drugs 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-O propan-1-aminium Chemical compound CCC[NH3+] WGYKZJWCGVVSQN-UHFFFAOYSA-O 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- DTPQZKZONQKKSU-UHFFFAOYSA-N silver azanide silver Chemical compound [NH2-].[Ag].[Ag].[Ag+] DTPQZKZONQKKSU-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- 239000007962 solid dispersion Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Landscapes
- Colloid Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79472485A | 1985-11-04 | 1985-11-04 | |
| US794724 | 1985-11-04 | ||
| US913391 | 1986-10-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62106839A true JPS62106839A (ja) | 1987-05-18 |
| JPH0341407B2 JPH0341407B2 (OSRAM) | 1991-06-24 |
Family
ID=25163472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26088386A Granted JPS62106839A (ja) | 1985-11-04 | 1986-11-04 | シ−ト・ケイ酸塩の水性懸濁液の調製方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62106839A (OSRAM) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007277078A (ja) * | 2006-03-11 | 2007-10-25 | National Institute Of Advanced Industrial & Technology | 変性粘土を用いた膜 |
| JP2012176398A (ja) * | 2011-01-31 | 2012-09-13 | Sumitomo Chemical Co Ltd | 分散液の製造方法および無機層状化合物のイオン交換方法 |
| JP2014111531A (ja) * | 2007-11-13 | 2014-06-19 | Tomoegawa Paper Co Ltd | 粘土薄膜及びその製造方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59169924A (ja) * | 1983-02-25 | 1984-09-26 | インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− | 固体のバ−ミキユライト生成物の製造法 |
| JPS59223218A (ja) * | 1983-06-01 | 1984-12-15 | Toray Ind Inc | 無機・有機複合体のゾルおよびそれを原料とするフイルム |
-
1986
- 1986-11-04 JP JP26088386A patent/JPS62106839A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59169924A (ja) * | 1983-02-25 | 1984-09-26 | インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− | 固体のバ−ミキユライト生成物の製造法 |
| JPS59223218A (ja) * | 1983-06-01 | 1984-12-15 | Toray Ind Inc | 無機・有機複合体のゾルおよびそれを原料とするフイルム |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007277078A (ja) * | 2006-03-11 | 2007-10-25 | National Institute Of Advanced Industrial & Technology | 変性粘土を用いた膜 |
| JP2014111531A (ja) * | 2007-11-13 | 2014-06-19 | Tomoegawa Paper Co Ltd | 粘土薄膜及びその製造方法 |
| JP2012176398A (ja) * | 2011-01-31 | 2012-09-13 | Sumitomo Chemical Co Ltd | 分散液の製造方法および無機層状化合物のイオン交換方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0341407B2 (OSRAM) | 1991-06-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1284406C (en) | Suspensions of sheet silicate materials and products made therefrom | |
| Huang et al. | Vibrational spectroscopic studies of layered silicates | |
| Weiss | Mica-type layer silicates with alkylammonium ions | |
| Tan et al. | A novel method to prepare chitosan/montmorillonite nanocomposites in the presence of hydroxy-aluminum oligomeric cations | |
| Aly et al. | Polymer and water quality effects on flocculation of montmorillonite | |
| JPH10510236A (ja) | アルミノ−シリケート誘導体の製造方法 | |
| JPS5891033A (ja) | ゼオライトＮｕ−１０の製造方法 | |
| US4929431A (en) | Process for producing amorphous aluminosilicates | |
| CN102259881A (zh) | 一种由钙基膨润土制备高粘度有机膨润土的方法 | |
| DE2839830A1 (de) | Hydrophile, silanbehandelte zeolithmaterialien | |
| US4715987A (en) | Method of treating phyllosilicates | |
| Jemima et al. | Sorption properties of organo modified montmorillonite clay for the reclamation of chromium (VI) from waste water | |
| JPS62106839A (ja) | シ−ト・ケイ酸塩の水性懸濁液の調製方法 | |
| Van Reeuwijk et al. | Potassium fixation by amorphous aluminosilica gels | |
| DE2927444A1 (de) | Alkalicalciumsilikate und verfahren zu deren herstellung | |
| CA1241506A (en) | Flocced mineral materials and water-resistant articles made therefrom | |
| DE69406655T2 (de) | Amorphes Aluminosilikat und Verfahren zu seiner Herstellung | |
| RU2520434C1 (ru) | Способ очистки немодифицированного бентонита на основе монтмориллонита | |
| JPH0761927B2 (ja) | 抗菌剤 | |
| EP1645544B1 (de) | Papierherstellung mit modifizierten Schichtsilikaten als Mikropartikel | |
| Keymirov | Water purification of ions of heavy metals by montmorillonite modified with polyamine | |
| JPH01128809A (ja) | ひる石の表層剥離方法 | |
| JPH08268711A (ja) | 改質層状ケイ酸塩の製造方法 | |
| JP3362423B2 (ja) | 層間化合物陽イオン交換体の製造方法 | |
| JPH09235116A (ja) | 新規な層状ケイ酸塩及びその製造法 |