JPS6166752A - Gel composition containing silicone oil - Google Patents
Gel composition containing silicone oilInfo
- Publication number
- JPS6166752A JPS6166752A JP59189995A JP18999584A JPS6166752A JP S6166752 A JPS6166752 A JP S6166752A JP 59189995 A JP59189995 A JP 59189995A JP 18999584 A JP18999584 A JP 18999584A JP S6166752 A JPS6166752 A JP S6166752A
- Authority
- JP
- Japan
- Prior art keywords
- silicone oil
- weight
- polyoxyalkylene
- modified
- gel composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 229920002545 silicone oil Polymers 0.000 title claims description 37
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002734 clay mineral Substances 0.000 claims abstract description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 239000003921 oil Substances 0.000 abstract description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 abstract description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 abstract description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- 238000013329 compounding Methods 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000003937 drug carrier Substances 0.000 abstract 1
- 150000003377 silicon compounds Chemical class 0.000 abstract 1
- 230000008719 thickening Effects 0.000 description 24
- 239000002537 cosmetic Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 239000001993 wax Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 239000006071 cream Substances 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- -1 octadecyldimethylbenzylammonium salt-modified montmorillonite Chemical class 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 239000003676 hair preparation Substances 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 2
- 150000002892 organic cations Chemical class 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 230000000475 sunscreen effect Effects 0.000 description 2
- 239000000516 sunscreening agent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical group CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
- Colloid Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は安定性、使用性に優れるシリコンオイルを含む
ゲル組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a gel composition containing silicone oil that is excellent in stability and usability.
［従来の技術］
従来、シリコンオイルはさまざまな製品に使用されてい
る。特に化粧料においては、シリコンオイルがなめらか
な使用性を持ち撥水性に優れており、また揮散性シリコ
ンオイルを配合すると当初のびがよく且つ塗布にともな
ってシリコンオイルが揮散してしまうので塗布後の化粧
くずれが少ないメーキャップ化粧料を製造することがで
きることから、のびの・よい使用感を求められるフェー
シャル化粧料や水はじきの性能を要求されるハンドクリ
ームや頭髪化粧料あるいはまたメーキャップ化粧料など
に配合が期待されてきた。また、シリコンオイルは皮膚
安全性が高いという化粧料原料としての条件も備えてい
る。[Prior Art] Silicone oil has conventionally been used in various products. Particularly in cosmetics, silicone oil is smooth to use and has excellent water repellency, and when volatile silicone oil is added, it spreads easily at the beginning, and the silicone oil evaporates as it is applied. Since it is possible to produce makeup cosmetics that do not cause makeup smearing, it can be incorporated into facial cosmetics that require a smooth and comfortable feel, hand creams and hair cosmetics that require water-repellent performance, and makeup cosmetics. has been expected. Silicone oil also has the requirements for being a cosmetic raw material, as it is highly safe for the skin.
［発明が解決しようとする問題点〕
しかしながら、シリコンオイルは安定な増粘系を得るの
が非常に困難であるという欠点を有しており、強く要望
されているにもかかわらず、このものを多量に配合し且
つ適当な粘度を有する組成物は得られていない。[Problems to be solved by the invention] However, silicone oil has the disadvantage that it is very difficult to obtain a stable thickening system, and despite strong demand, this oil has not been used. A composition containing a large amount and having an appropriate viscosity has not been obtained.
これまで、安定性良好なシリコンオイルの増粘系を得る
ためにはシリコンオイルをワックス類とともに固化する
方法や、シリカあるいは親油化処理したシリカで増粘す
るなどの方法がとられてきた。しかしながら、ワックス
類とともに固化する方法はのびが重くべたつ（といった
使用性上の欠点や、流動性がないため応用できる範囲が
限られている。また、シリカで増粘する方法は経時での
安定性が悪く、使用前によく振ることが必須であり好ま
しくない。Up to now, in order to obtain a highly stable silicone oil thickening system, methods have been used, such as solidifying silicone oil with waxes, or thickening it with silica or silica treated to make it lipophilic. However, the method of solidifying with waxes has disadvantages in usability, such as being difficult to spread and is sticky, and the range of application is limited due to lack of fluidity.Also, the method of thickening with silica is unstable over time. It is undesirable because it has poor properties and requires shaking well before use.
ｃ問題点を解決するための手段］
本発明者らは、こうした事情にかんがみ、シリコンオイ
ルの増粘法について鋭意研究を重ねた結果、シリコンオ
イルに特定のシリコン化合物と有機変性モンモリロナイ
トと水とを特定量配合することにより、任意の粘度を有
する経時安定性及び使用性が良好なゲル組成物が得られ
ることを見出し、この知見に基づいて本発明を完成する
に至った。c. Means for Solving Problems] In view of these circumstances, the inventors of the present invention have conducted intensive research on a method of thickening silicone oil, and as a result, they have developed a method of adding a specific silicone compound, organically modified montmorillonite, and water to silicone oil. It was discovered that by blending a specific amount, a gel composition having a desired viscosity and good stability over time and ease of use can be obtained, and based on this knowledge, the present invention was completed.
すなわち、本発明は、シリコンオイル、一般式（１）、
（ＩＩ）および（ＩＩＩ）で示されるポリオキシアルキ
レン変性オルガノポリシロキサンの一種または二種以上
、有機変性モンモリロナイト系粘土鉱物ならびに水を配
合することを特徴とするシリコンオイルを含むゲル組成
物を提供するものである。That is, the present invention provides silicone oil, general formula (1),
Provided is a gel composition containing silicone oil, characterized in that it contains one or more polyoxyalkylene-modified organopolysiloxanes represented by (II) and (III), an organically modified montmorillonite clay mineral, and water. It is something.
（一般式（１）、（ＩＴ）、（ＩＩＩ）中、Ｒはメチル
基または一部がフェニル基、Ｒ゛は水素または炭素数１
〜１２のアルキル基、ｐは１〜５の数、ｑは２〜３の数
、ｘ、ｍ、ｎは平均数でポリオキシアルキレン変性オル
ガノポリシロキサンが分子中にポリオキシアルキレン基
を２〜２０重量％含有し且つ該ポリオキシアルキレン変
性オルガノポリシロキサンの粘度が２５°Ｃにおいて５
〜３０００センチストークスになるような数値を表す。(In general formulas (1), (IT), and (III), R is a methyl group or partially a phenyl group, and R' is hydrogen or has 1 carbon number.
~12 alkyl groups, p is a number of 1 to 5, q is a number of 2 to 3, x, m, and n are average numbers, and the polyoxyalkylene-modified organopolysiloxane has 2 to 20 polyoxyalkylene groups in the molecule. % by weight and the viscosity of the polyoxyalkylene-modified organopolysiloxane is 5 at 25°C.
Expresses a value that is ~3000 centistokes.
） 以下、本発明の構成について詳述する。) Hereinafter, the configuration of the present invention will be explained in detail.
本発明で用いられるシリコンオイルは従来用いられてい
る周知のものを使用することができる。As the silicone oil used in the present invention, conventionally known silicone oils can be used.
たとえば、ジメチルポリシロキサン、メチルフェニルポ
リシロキサン、オクタメチルシクロテトラシロキサン、
デカメチルシクロペンタシロキサンなどが挙げられる。For example, dimethylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane,
Examples include decamethylcyclopentasiloxane.
これらの中から一種又は二種以上が任意に選択される。One or more types are arbitrarily selected from these.
配合量は通常本発明の組成物全量中の２０〜９０重量％
である。The blending amount is usually 20 to 90% by weight based on the total amount of the composition of the present invention.
It is.
本発明で用いられるポリオキシアルキレン変性オルガノ
ポリシロキサン（以下ポリエーテル変性シリコンと略記
する）は前記一般式（１）、（ＩＩ）および（Ｉ［［）
で表されるものであり、これらのうちの任意の一種又は
二種以上が選ばれて用いられる。The polyoxyalkylene-modified organopolysiloxane (hereinafter abbreviated as polyether-modified silicone) used in the present invention has the general formulas (1), (II) and (I[[)
These are represented by the following, and any one or more of these may be selected and used.
本発明の目的に合致した効果、すなわち経時安定性及び
使用性の良好なシリコン増粘効果を満足せしめるために
は、ポリエーテル変性シリコンはポリオキシアルキレン
基をその分子量に対して２〜１５重量％の割合で含有し
且つ２５℃においてそのもの自体の粘度が５〜３０００
センチストークスの範範囲に存する必要がある。すなわ
ち、ポリオキシアルキレン基のポリエーテル変性シリコ
ン全重量に対する割合が２重量％未満では増粘効果が十
分でなく、２０重量％を越えると経時安定性が悪くなる
。またポリエーテル変性シリコンの粘度が５センチスト
一クス未満では増粘効果が十分でなく、３０００センチ
ストークスを越えると使用感がべたつき好ましくない。In order to satisfy the effect consistent with the purpose of the present invention, that is, silicone thickening effect with good stability over time and usability, the polyether-modified silicone should contain 2 to 15% by weight of polyoxyalkylene groups based on its molecular weight. and has a viscosity of 5 to 3000 at 25°C.
It must be within the range of centistokes. That is, if the ratio of the polyoxyalkylene group to the total weight of the polyether-modified silicone is less than 2% by weight, the thickening effect will not be sufficient, and if it exceeds 20% by weight, the stability over time will deteriorate. Further, if the viscosity of the polyether-modified silicone is less than 5 centistokes, the thickening effect will not be sufficient, and if it exceeds 3000 centistokes, the feeling of use will be sticky, which is undesirable.
本範囲のゲル組成物に対するポリエーテル変性シリコン
の配合量は全量中の０．１から３０重量％の範囲で選択
されるが、好ましくは０．２〜２５重量％である。０．
１重量％未満では増粘効果が十分でなく経時安定性も悪
い。３０重量％を越えるとべたつきが感じられ、また化
粧もちも悪くなる。The blending amount of polyether-modified silicone in the gel composition of this range is selected in the range of 0.1 to 30% by weight based on the total amount, preferably 0.2 to 25% by weight. 0.
If it is less than 1% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 30% by weight, it will feel sticky and the makeup will not last long.
本発明で用いられる有機変性モンモリロナイト系粘土鉱
物はモンモリロナイト系粘土鉱物の結晶層間に介在する
水や交換性カチオンを有機極性化合物や有機カチオンで
置換したものであり、たとえば、ジオクタデシルジメチ
ルアンモニウム塩変性モンモリロナイト、オクタデシル
ジメチルベンジルアンモニウム塩変性モンモリロナイト
、ジオクタデシルジメチルアンモニウム塩変性モンモリ
ロナイトなどが挙げられる。これらの中から一種または
二種以上が任意に選択される。The organically modified montmorillonite clay mineral used in the present invention is a montmorillonite clay mineral in which water and exchangeable cations interposed between the crystal layers are replaced with an organic polar compound or an organic cation; for example, montmorillonite modified with dioctadecyldimethylammonium salt. , octadecyldimethylbenzylammonium salt-modified montmorillonite, dioctadecyldimethylammonium salt-modified montmorillonite, and the like. One or more types are arbitrarily selected from these.
配合量は本発明のゲル組成物全量中の０．１〜１５重量
％の範囲で選択されるが、好ましくは０．２〜１０重量
％である。０．１重量％未満では増粘効果が十分でなく
経時安定性も悪い。１５重量％を越えるとのびが重くな
り使用性が悪くなる。The blending amount is selected within the range of 0.1 to 15% by weight based on the total amount of the gel composition of the present invention, preferably 0.2 to 10% by weight. If it is less than 0.1% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 15% by weight, it becomes difficult to spread and the usability deteriorates.
本発明における水の配合量はゲル組成物全量中の０．２
〜８０重量％の範囲で選択されるが、好ましくは０．５
〜６０重量％である。０．２重量％未満では増粘効果が
十分でなく経時安定性も悪い。８０重量％を越えるとの
びが重くなり好ましくない。The amount of water in the present invention is 0.2 in the total amount of the gel composition.
-80% by weight, preferably 0.5% by weight
~60% by weight. If it is less than 0.2% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 80% by weight, it becomes difficult to spread, which is not preferable.
本発明のシリコン増粘組成物を応用した化粧料は、上記
の必須成分に加えて、必要に応じてワックス、油脂、保
湿剤、顔料、粉末、樹脂、香料、防腐剤等が配合される
。Cosmetics to which the silicone thickening composition of the present invention is applied contain, in addition to the above-mentioned essential ingredients, waxes, oils, humectants, pigments, powders, resins, perfumes, preservatives, etc., as necessary.
なお、さらにエタノール°、イソプロピルアルコール等
の低級アルコールやプロピレングリコール、ジプロピレ
ングリコール、■、３−ブチレングリコール等のグリコ
ール類を組成物全量に対して０．１〜１０重量％加える
とさらに増粘し安定性を向上させることができる。Furthermore, when 0.1 to 10% by weight of lower alcohols such as ethanol and isopropyl alcohol, and glycols such as propylene glycol, dipropylene glycol, and 3-butylene glycol are added to the total amount of the composition, the viscosity can be further increased. Stability can be improved.
［発明の効果］
本発明のシリコンオイルを含むゲル組成物は経時安定性
が良好で且つ使用に際してはのびがよくてべたつきがな
い良好な使用感触を有し、耐水性や経時の持ちにも優れ
たゲル組成物である。[Effects of the Invention] The gel composition containing the silicone oil of the present invention has good stability over time, and when used, it spreads well and has a good feel without stickiness, and has excellent water resistance and durability over time. It is a gel composition.
また、粘度すなわち流動性を自由にコントロールできる
ため、化粧料をはじめ、医薬品の基剤や自動車ワックス
、家具ワックスなど広い範囲にわたって使用することが
できる。In addition, because the viscosity, or fluidity, can be freely controlled, it can be used in a wide range of applications, including cosmetics, pharmaceutical bases, automobile wax, and furniture wax.
［実施例］
次に実施例によって本発明をさらに詳細に説明する。本
発明はこれにより限定されるものではない。配合量は重
量％である。[Example] Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereby. The blending amount is in weight%.
なお、実施例および比較例の緒特性についての試験法は
次の通り行ったものである。The test methods for the mechanical properties of Examples and Comparative Examples were as follows.
（１）安定性
サンプル管に試料を取り各温度条件に放置し、分離度で
評（ｉ（１力月後判定）。(1) Stability Take a sample in a sample tube and leave it at each temperature condition, and evaluate the degree of separation (i (judgment after 1 month).
評価基準 ○：分離なし △：１１５程度分離 Ｘ ： ２／３以上分離 （２）粘度 ブルックフィールド型粘度計にて測定（３０″Ｃ）。Evaluation criteria ○: No separation △: Separation of about 115 X: 2/3 or more separation (2) Viscosity Measured with a Brookfield viscometer (30″C).
（３）べたつきおよびのび 実使用試験による官能評価（パネル２０名）。(3) Stickiness and spreadability Sensory evaluation by practical use test (20 panelists).
評価基準 ○：べたつきなし、のびが軽い。Evaluation criteria ○: No stickiness, easy spread.
△：ややべたつく、のびが普通。△: Slightly sticky, spreads normally.
×：べたつく、のびか重い。×: Sticky, spreadable and heavy.
（以下余白）
（製法）
■〜■をホモディスパーにて攪拌し、日やけ用乳液を得
た。(Left below) (Manufacturing method) ① to ② were stirred in a homodisper to obtain a sunscreen emulsion.
表中に示した特性から、実施例１．２．３は経時安定性
及び使用性に優れていることが判る。From the characteristics shown in the table, it can be seen that Examples 1.2.3 are excellent in stability over time and usability.
（以下余白） （製法） ■〜■をホモディスパーにて攪拌し、クリームを得た。(Margin below) (Manufacturing method) ■~■ were stirred with a homodisper to obtain cream.
表中に示した特性から実施例４．５．６．７．８．９は
経時安定性および使用性に優れていることが判る。From the properties shown in the table, it can be seen that Example 4.5.6.7.8.9 is excellent in stability over time and usability.
（以下余白）
（製法）
■〜［相］をホモディスパーにて攪拌し、耐水性ファン
チージョンを得た。。(Left below) (Manufacturing method) Phases 1 to 1 were stirred in a homodisper to obtain a water-resistant fancijoon. .
表中に示した特性から実施例１０．１１．１２は経時安
定性および使用性に優れていることが判る。From the properties shown in the table, it can be seen that Examples 10, 11, and 12 are excellent in stability over time and usability.
また、海浜における実使用テスト（パネル２０名）によ
り耐水性ファンデーションとして十分な機能を有してお
り、化粧もちも良いことが確認された。In addition, actual use tests at the beach (20 panelists) confirmed that it has sufficient functionality as a water-resistant foundation and has good makeup retention.
（以下余白）
（肥沃）
■〜■をホモディスパーで攪拌し、耐水性アイライナー
を得た。(Left below) (Fertile) ① to ② were stirred with a homodisper to obtain a water-resistant eyeliner.
表中に示した特性から実施例１３．１４．１５．１６は
経時安定性および使用性に優れていることが判る。From the properties shown in the table, it can be seen that Examples 13, 14, 15, and 16 are excellent in stability over time and usability.
また、海浜における実使用テスト（パネル２０名）によ
り耐水性アイライナーとして十分な機能を有しており、
化粧もちも良いことがｆｉ！Ｅｌされた。In addition, it has sufficient functionality as a water-resistant eyeliner according to actual use tests at the beach (20 panelists).
The fact that my makeup lasts well is fi! It was El.
（以下余白）
（製法、）
■〜■をホモディスパーで攪拌し、つや出しクリームを
得た。(Left below) (Manufacturing method) ① to ② were stirred with a homodisper to obtain a glossy cream.
実施例１７．１８は化粧品だけでなく、家具のつや出し
クリームなどにも使用できることを実使用テストにて確
認した。It was confirmed through actual use tests that Examples 17 and 18 can be used not only for cosmetics but also for furniture polishing creams.
特許出願人 株式会社 資 生 堂
手続補正書く自発）
昭和６０年７月１０日
特許庁長官 宇 賀 道 部 殿
２、発明の名称
シリコンオイルを含むゲル組成物
３、補正をする者
事件との関係 特許出願人
４、補正の対象
明１１ＩＭの特許請求の範囲および発明の詳細な説明の
欄
５、 補正の内容
１、発明の名称
シリコンオイルを含むゲル組成物
２、特許請求の範囲
（１１シリコンオイル、一般式（１）、（ＩＩ）または
（［［）で示されるポリオキシアルキレン変性オルガノ
ポリシロキサンの一種または二種以上、有機変性モンモ
リロナイト系粘土鉱物ならびに水を配合することを特徴
とするシリコンオイルを含むゲル組成物。Patent applicant: Shiseido Co., Ltd. Voluntary amendment to the procedure) July 10, 1985 Michibe Uga, Commissioner of the Patent Office 2 Name of the invention: Gel composition containing silicone oil 3 Relationship with the case of the person making the amendment Patent Applicant 4, Subject of Amendment 11 IM Claims and Detailed Description of the Invention Column 5, Contents of Amendment 1, Name of Invention Gel Composition Containing Silicone Oil 2, Claims (11 IM) , one or more polyoxyalkylene-modified organopolysiloxanes represented by the general formula (1), (II) or ([[), an organically modified montmorillonite clay mineral, and water. A gel composition comprising.
（以下余白）
（一般式（１）、（ＩＩ）、（ＩＩＩ）中、Ｒはメチル
基または一部がフェニル基、Ｒ゛は水素または炭素数１
−１２のアルキル基、ｐは１〜５の数、ｑは２〜３の数
、ｘ、ｍ、ｎは平均数でポリオキシアルキレン変性オル
ガノポリシロキサンが分子中にポリオキシアルキレン基
を２〜２０重量％含有し且つ該ポリオキシアルキレン変
性オルガノポリシロキサンの粘度が２５℃において５〜
３０００センチストークスになるような数値を表す。）
３、発明の詳細な説明
［産業上の利用分野］
本発明は安定性、使用性に優れるシリコンオイルを含む
ゲル組成物に関する。(Left below) (In general formulas (1), (II), and (III), R is a methyl group or partially a phenyl group, and R' is hydrogen or has 1 carbon number.
-12 alkyl groups, p is a number from 1 to 5, q is a number from 2 to 3, x, m, and n are average numbers, and the polyoxyalkylene-modified organopolysiloxane has 2 to 20 polyoxyalkylene groups in the molecule. % by weight, and the viscosity of the polyoxyalkylene-modified organopolysiloxane is 5 to 5 at 25°C.
Represents a value that equals 3000 centistokes. ) 3. Detailed Description of the Invention [Industrial Application Field] The present invention relates to a gel composition containing silicone oil that is excellent in stability and usability.
［従来の技術］
従来、シリコンオイルはさまざまな製品に使用されてい
る。特に化粧料においては、シリコンオイルがなめらか
な使用性を持ち戻水性に優れており、また揮散性シリコ
ンオイルを配合すると当初のびがよく且つ塗布にともな
ってシリコンオイルが揮散してしまうので塗布後の化粧
くずれが少ないメーキャップ化粧料を製造することがで
きることから、のびのよい使用感を求められるフエーシ
ャル化粧料や水はじきの性能を要求されるハンドクリー
ムや頭髪化粧料あるいはまたメーキャップ化粧料などに
配合が期待されてきた。また、シリコンオイルは皮膚安
全性が高いという化粧料原料としての条件も備えている
。[Prior Art] Silicone oil has conventionally been used in various products. Particularly in cosmetics, silicone oil is smooth to use and has excellent water rehydration properties, and when volatile silicone oil is blended, it spreads easily at the beginning, but since the silicone oil evaporates as it is applied, Since it is possible to produce makeup cosmetics that do not smudge, it can be incorporated into facial cosmetics that require a long-wearing feel, hand creams and hair cosmetics that require water-repellent performance, and makeup cosmetics. It has been expected. Silicone oil also has the requirements for being a cosmetic raw material, as it is highly safe for the skin.
［発明が解決しようとする問題点］
しかしながら、シリコンオイルは安定な増粘系を得るの
が非常に困難であるという欠点を有しており、強く要望
されているにもかかわらず、このものを多量に配合し且
つ適当な粘度を有する組成６物は得られていない。[Problems to be Solved by the Invention] However, silicone oil has the disadvantage that it is very difficult to obtain a stable thickening system, and despite strong demands, this oil has not been used. Composition 6, which contains a large amount and has an appropriate viscosity, has not been obtained.
これまで、安定性良好なシリコンオイルの増粘系を得る
ためにはシリコンオイルをワックス類とともに固化する
方法や、シリカあるいは親油此処 理したシリカで増
粘するなどの方法がとられてきた。しかしながら、ワッ
クス類とともに固化する方法はのびが重くべたつくとい
った使用性上の欠点や、流’ｆｌｊ性がないため応用で
きる範囲が限られている。また、シリカで増粘する方法
は経時での安定性が悪く、使用前によく振ることが必須
であり好ましくない。Up to now, in order to obtain a highly stable silicone oil thickening system, methods have been used, such as solidifying silicone oil with waxes, or thickening it with silica or silica treated with lipophilic agents. However, the method of solidifying with waxes has disadvantages in usability such as being difficult to spread and is sticky, and lacks flowability, which limits the scope of its applicability. Further, the method of thickening with silica is not preferred because it has poor stability over time and requires shaking well before use.
［問題点を解決するための手段］
本発明者らは、こうした事情にかんがみ、シリコンオイ
ルの増粘法について鋭意研究を重ねた結果、シリコンオ
イルに特定のシリコン化合物と有機変性モンモリロナイ
トと水とを特定量配合することにより、任意の粘度を有
する経時安定性及び使用性が良好なゲル組成物が得られ
ることを見出し、この知見に基づいて本発明を完成する
に至った。[Means for Solving the Problems] In view of these circumstances, the present inventors have conducted intensive research on methods of thickening silicone oil, and as a result, they have developed a method of adding a specific silicone compound, organically modified montmorillonite, and water to silicone oil. It was discovered that by blending a specific amount, a gel composition having a desired viscosity and good stability over time and ease of use can be obtained, and based on this knowledge, the present invention was completed.
すなわち、本発明は、シリコンオイル、一般式（１）、
（ＩＩ）または（ＩＩＩ）で示されるポリオキシアルキ
レン変性オルガノポリシロキサンの一種または二種以上
、有機変性モンモリロナイト系粘土鉱物ならびに水を配
合することを特徴とするシリコンオイルを含むゲル組成
物を提供するものである。That is, the present invention provides silicone oil, general formula (1),
Provided is a gel composition containing silicone oil, which contains one or more polyoxyalkylene-modified organopolysiloxanes represented by (II) or (III), an organically modified montmorillonite clay mineral, and water. It is something.
（一般式（１）、（Ｕ＞、（ＩＩＩ）中、Ｒはメチル基
または一部がフェニル基、Ｒ゛は水素または炭素数１〜
１２のアルキル基、ｐは１〜５の数、ｑ ハ２〜３の数
、ｘ、ｍ、ｎは平均数でポリオキシアルキレン変性オル
ガノポリシロキサンが分子中にポリオキシアルキレン基
を２〜２０重量％含有し且つ該ポリオキシアルキレン変
性オルガノポリシロキサンの粘度が２５℃において５〜
３０００センチストークスになるような数値を表す。）
以下、本発明の構成について詳述する。(In general formulas (1), (U>, (III), R is a methyl group or partially a phenyl group, and R' is hydrogen or has 1 to 1 carbon atoms.
12 alkyl groups, p is a number from 1 to 5, q is a number from 2 to 3, x, m, and n are average numbers, and polyoxyalkylene-modified organopolysiloxane has 2 to 20 polyoxyalkylene groups in the molecule by weight % and the viscosity of the polyoxyalkylene-modified organopolysiloxane is 5 to 5 at 25°C.
Represents a value that equals 3000 centistokes. ) Hereinafter, the structure of the present invention will be explained in detail.
本発明で用いられるシリコンオイルは従来用いられてい
る周知のものを使用することができる。As the silicone oil used in the present invention, conventionally known silicone oils can be used.
たとえば、ジメチルポリシロキサン、メチルフェニルポ
リシロキサン、オクタメチルシクロテトラシロキサン、
デカメチルシクロペンタシロキサンなどが挙げられる。For example, dimethylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane,
Examples include decamethylcyclopentasiloxane.
これらの中から一種又は二種以上が任意に選択される。One or more types are arbitrarily selected from these.
配合量は通常本発明の組成物全量中の２０〜９０重量％
である。The blending amount is usually 20 to 90% by weight based on the total amount of the composition of the present invention.
It is.
本発明で用いられるポリオキシアルキレン変性オルガノ
ポリシロキサン（以下ポリエーテル変性シリコンと略記
する）は前記一般式（［）、（ＩＩ）または（ＩＩＩ）
で表されるものであり、これらのうちの任意の一種又は
二種以上が選ばれて用いられる。The polyoxyalkylene-modified organopolysiloxane (hereinafter abbreviated as polyether-modified silicone) used in the present invention has the general formula ([), (II) or (III).
These are represented by the following, and any one or more of these may be selected and used.
本発明の目的に合致した効果、すなわち経時安定性及び
使用性の良好なシリコン増粘効果を満足せしめるために
は、ポリエーテル変性シリコンはポリオキシアルキレン
基をその分子量に対して２〜２０重量％の割合で含有し
且つ２５℃においてそのもの自体の粘度が５〜３０００
センチストークスの範囲に存する必要がある。すなわち
、ポリオキシアルキレン基のポリエーテル変性シリコン
全重量に対する割合が２重量％未満では増粘効果が十分
でなく、２０重量％を越えるとその割合の増加に従って
経時安定性が悪くなっていく１頃向にある。またポリエ
ーテル変性シリコンの粘度が５センチスト一クス未満で
は増粘効果が十分でなく、３０００センチストークスを
越えると使用感がべたつき好ましくない。In order to satisfy the effect consistent with the purpose of the present invention, that is, the silicone thickening effect with good stability over time and ease of use, the polyether-modified silicone should contain 2 to 20% by weight of polyoxyalkylene groups based on its molecular weight. and has a viscosity of 5 to 3000 at 25°C.
It must be within the centistoke range. That is, if the ratio of polyoxyalkylene groups to the total weight of polyether-modified silicone is less than 2% by weight, the thickening effect will not be sufficient, and if it exceeds 20% by weight, the stability over time will deteriorate as the ratio increases. It's across the street. Further, if the viscosity of the polyether-modified silicone is less than 5 centistokes, the thickening effect will not be sufficient, and if it exceeds 3000 centistokes, the feeling of use will be sticky, which is undesirable.
本発明のゲル組成物に対するポリエーテル変性シリコン
の配合量は全量中の０．１から３０重量％の範囲で選択
されるが、好ましくは０．２〜２５重量％′である。０
．１重量％未満では増粘効果が十分でなく経時安定性も
悪い。３０重量％を越えるとべたつきが感じられ、また
化粧もちも悪くなる。The amount of polyether-modified silicone added to the gel composition of the present invention is selected within the range of 0.1 to 30% by weight, preferably 0.2 to 25% by weight. 0
．． If it is less than 1% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 30% by weight, it will feel sticky and the makeup will not last long.
本発明で用いられる有機変性モンモリロナイト系粘土鉱
物は粘土鉱物の結晶層間に介在する水や交換性カチオン
を有機極性化合物や有機カチオンで置換したものであり
、たとえば、ジオクタデシルジメチルアンモニウム塩変
性モンモリロナイト、オクタデシルジメチルベンジルア
ンモニウム塩変性モンモリロナイト、ジオクタデシルジ
メチルアンモニウム塩変性モンモリロナイトなどが挙げ
られる。これらの中から一種または二種以上が任意に選
択される。The organically modified montmorillonite clay mineral used in the present invention is a clay mineral in which water and exchangeable cations interposed between crystal layers are replaced with organic polar compounds or organic cations, such as dioctadecyl dimethyl ammonium salt modified montmorillonite, octadecyl Examples include dimethylbenzylammonium salt-modified montmorillonite and dioctadecyldimethylammonium salt-modified montmorillonite. One or more types are arbitrarily selected from these.
配合量は本発明のゲル組成物全量中の０．１〜１５重量
％の範囲で選択されるが、好ましくは０．２〜１０重量
％である。０．１重量％未満では増粘効果が十分でなく
経時安定性も悪い。１５ｉｉｆｆｉ％を越えるとのびが
重くなり使用性が悪くなる。The blending amount is selected within the range of 0.1 to 15% by weight based on the total amount of the gel composition of the present invention, preferably 0.2 to 10% by weight. If it is less than 0.1% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 15iiffi%, it becomes difficult to spread and the usability deteriorates.
本発明における水の配合量はゲル組成物全量中の０．２
〜８０重量％の範囲で選択されるが、好ましくは０．５
〜６０重量％である。０．２重量％未満では増粘効果が
十分でなく経時安定性も悪い。８０重量％を越えるとの
びが重くなり好ましくない。The amount of water in the present invention is 0.2 in the total amount of the gel composition.
-80% by weight, preferably 0.5% by weight
~60% by weight. If it is less than 0.2% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 80% by weight, it becomes difficult to spread, which is not preferable.
本発明のシリコン増粘組成物を応用した化粧料は、上記
の必須成分に加えて、必要に応じてワックス、油脂、保
湿剤、顔料、粉末、樹脂、香料、防腐剤等が配合される
。Cosmetics to which the silicone thickening composition of the present invention is applied contain, in addition to the above-mentioned essential ingredients, waxes, oils, humectants, pigments, powders, resins, perfumes, preservatives, etc., as necessary.
なお、さらにエタノール、イソプロピルアルコール等の
低級アルコールやプロピレングリコール、ジプロピレン
グリコール、１．３−フチレンクリコール等のグリコー
ル類を組成物全量に対して０．１〜１０重量％加えると
さらに増粘し安定性を向上させることができる。Furthermore, if 0.1 to 10% by weight of lower alcohols such as ethanol and isopropyl alcohol, and glycols such as propylene glycol, dipropylene glycol, and 1,3-phthylene glycol are added to the total amount of the composition, the viscosity will be further increased. Stability can be improved.
［発明の効果］
本発明のシリコンオイルを含むゲル組成物は経時安定性
が良好で且つ使用に際してはのびがよくてべたつきがな
い良好な使用感触を有し、耐水性や経時の持ちにも優れ
たゲル組成物である。[Effects of the Invention] The gel composition containing the silicone oil of the present invention has good stability over time, and when used, it spreads well and has a good feel without stickiness, and has excellent water resistance and durability over time. It is a gel composition.
また、粘度すなわち流動性を自由にコントロールできる
ため、化粧料をはじめ、医薬品の基剤や自動車ワックス
、家具ワックスなど広い範囲にわたって使用することが
できる。In addition, because the viscosity, or fluidity, can be freely controlled, it can be used in a wide range of applications, including cosmetics, pharmaceutical bases, automobile wax, and furniture wax.
［実施例］
次に実施例によって本発明をさらに詳細に説明する。本
発明はこれにより限定されるものではない。配合量は重
量％である。[Example] Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereby. The blending amount is in weight%.
なお、実施例および比較例の諸特性についての試験法は
次の通り行ったものである。The test methods for various properties of Examples and Comparative Examples were as follows.
（１１安定性
サンプル管に試料を取り各温度条件に放置し、分離度で
評価。(11 Stability: Take a sample in a sample tube and leave it at each temperature condition, and evaluate the degree of separation.
評価基準 ○：分離なし △：１１５程度分離 Ｘｌ／３以上分離 （２） 粘度 ブルックフィールド型粘度針にて測定（３０℃）。Evaluation criteria ○: No separation △: Separation of about 115 Separation of XL/3 or more (2) Viscosity Measured with a Brookfield type viscosity needle (30°C).
（３） べたつきおよびのび 実使用試験による官能評価（パネル２０名）。(3) Stickiness and spread Sensory evaluation by practical use test (20 panelists).
評価基準 Ｏ：べたつきなし、のびが軽い。Evaluation criteria O: No stickiness, easy spread.
Δ：ややべたつく、のびが普通。Δ: Slightly sticky, spreads normally.
×：へた・つく、のびか重い。×: Weak and stiff, slow and heavy.
（以下余白）
（製法）
■〜■をホモディスパーにて攪拌し、日やけ用乳液を得
た。(Left below) (Manufacturing method) ① to ② were stirred in a homodisper to obtain a sunscreen emulsion.
表中に示した特性から、実施例１．２．３は経時安定性
及び使用性に優れていることが判る。From the characteristics shown in the table, it can be seen that Examples 1.2.3 are excellent in stability over time and usability.
（以下余白） （製法） ■〜■をホモディスパーにて攪拌し、クリームを得た。(Margin below) (Manufacturing method) ■~■ were stirred with a homodisper to obtain cream.
表中に示した特性から実施例４．５．６．７．８．９は
経時安定性および使用性に優れていることが判る。From the properties shown in the table, it can be seen that Example 4.5.6.7.8.9 is excellent in stability over time and usability.
（以下余白ン
（製法）
■〜［相］をホモディスパーにて攪拌し、耐水性ファン
デーションを得た。(Manufacturing method) Phases 1 to 1 were stirred in a homodisper to obtain a water-resistant foundation.
表中に示した特性から実施例１０．１１．１２は経時
−安定性および使用性に優れていることが判る。From the characteristics shown in the table, Example 10.11.12
- It is found that the product has excellent stability and usability.
また、海浜における実使用テスト（パネル２０名）によ
り耐水性ファンデーションとして十分な機能を有してお
り、化粧もちも良いことが確認された。In addition, actual use tests at the beach (20 panelists) confirmed that it has sufficient functionality as a water-resistant foundation and has good makeup retention.
（以下余白）
（Ｍ法）
■〜■をホモディスパーで攪拌し、耐水性アイライナー
を得た。(The following is a blank space) (Method M) ① to ② were stirred with a homodisper to obtain a water-resistant eyeliner.
表中に示した特性から実施例１３．１４．１５．１６は
経時安定性および使用性に優れていることが判る。From the properties shown in the table, it can be seen that Examples 13, 14, 15, and 16 are excellent in stability over time and usability.
また、海浜における実使用テスト（パネル２０名）によ
り耐水性アイライナーとして十分な機能を有しており、
塗布後の乾燥が早く化粧もちも良いことが確認された。In addition, it has sufficient functionality as a water-resistant eyeliner according to actual use tests at the beach (20 panelists).
It was confirmed that the makeup dries quickly after application and has good makeup retention.
（以下余白）
（′Ｍ法）
■〜■をホモディスパーで攪拌し、つや出しクリームを
得た。(Left below) ('M method) ① to ② were stirred with a homodisper to obtain a glossy cream.
実施例１７．１８は化粧品だけでなく、家具のつや出し
クリームなどにも使用できることを実使用テストにて確
認した。It was confirmed through actual use tests that Examples 17 and 18 can be used not only for cosmetics but also for furniture polishing creams.
Claims (1)
（III）で示されるポリオキシアルキレン変性オルガノ
ポリシロキサンの一種または二種以上、有機変性モンモ
リロナイト系粘土鉱物ならびに水を配合することを特徴
とするシリコンオイルを含むゲル組成物。 ▲数式、化学式、表等があります▼（ I ） ▲数式、化学式、表等があります▼（II） ▲数式、化学式、表等があります▼（III） （一般式（ I ）、（II）、（III）中、Ｒはメチル基ま
たは一部がフェニル基、Ｒ′は水素または炭素数１〜１
２のアルキル基、ｐは１〜５の数、ｑは２〜３の数、ｘ
、ｍ、ｎは平均数でポリオキシアルキレン変性オルガノ
ポリシロキサンが分子中にポリオキシアルキレン基を２
〜２０重量％含有し且つ該ポリオキシアルキレン変性オ
ルガノポリシロキサンの粘度が２５℃において、５〜３
０００センチストークスになるような数値を表す。）(1) It is characterized by containing silicone oil, one or more polyoxyalkylene-modified organopolysiloxanes represented by general formulas (I), (II), and (III), an organically modified montmorillonite clay mineral, and water. A gel composition containing silicone oil. ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(III) (General formulas (I), (II), In (III), R is a methyl group or partially a phenyl group, and R' is hydrogen or has 1 to 1 carbon atoms.
2 alkyl group, p is a number from 1 to 5, q is a number from 2 to 3, x
, m, and n are the average numbers, and the polyoxyalkylene-modified organopolysiloxane has 2 polyoxyalkylene groups in its molecule.
~20% by weight, and the viscosity of the polyoxyalkylene-modified organopolysiloxane is 5 to 3 at 25°C.
000 centistokes. )
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59189995A JPS6166752A (en) | 1984-09-11 | 1984-09-11 | Gel composition containing silicone oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59189995A JPS6166752A (en) | 1984-09-11 | 1984-09-11 | Gel composition containing silicone oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6166752A true JPS6166752A (en) | 1986-04-05 |
| JPH0419269B2 JPH0419269B2 (en) | 1992-03-30 |
Family
ID=16250628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59189995A Granted JPS6166752A (en) | 1984-09-11 | 1984-09-11 | Gel composition containing silicone oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6166752A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61113646A (en) * | 1984-11-08 | 1986-05-31 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS61271030A (en) * | 1985-05-28 | 1986-12-01 | Shiseido Co Ltd | Oily gel composition |
| JPS6245656A (en) * | 1985-08-22 | 1987-02-27 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS62238212A (en) * | 1986-04-10 | 1987-10-19 | Shiseido Co Ltd | Makeup cosmetic |
| JPS63215615A (en) * | 1986-12-19 | 1988-09-08 | レブロン・コンシューマー・プロダクツ・コーポレーション | Cosmetic composition comprising pigment- containing water-in-oil type emulsion |
| JPS63275518A (en) * | 1987-05-08 | 1988-11-14 | Terumo Corp | Semisolid composition |
| JPH02115110A (en) * | 1988-10-25 | 1990-04-27 | Shin Etsu Chem Co Ltd | Material for cosmetic |
| FR2646346A1 (en) * | 1989-04-26 | 1990-11-02 | Thorel Jean | Composition for the topical deposition of a permeable and light-reflecting continuous film |
| JPH0344309A (en) * | 1989-06-29 | 1991-02-26 | Unilever Nv | Composition for beauty |
| JPH03115207A (en) * | 1989-09-28 | 1991-05-16 | Kobayashi Kose Co Ltd | Oily composition and cosmetic containing same |
| US5681551A (en) * | 1991-12-26 | 1997-10-28 | Kao Corporation | Oil-based solid cosmetic composition |
| JP2003160435A (en) * | 2001-11-21 | 2003-06-03 | Pola Chem Ind Inc | Gel composition |
| US6780402B1 (en) | 1995-07-28 | 2004-08-24 | L'oreal | Make-up compositions containing phenylated silicone oils, which are resistant to transfer and migration |
| JP2012012351A (en) * | 2010-07-02 | 2012-01-19 | Nikko Chemical Co Ltd | Water-in-oil type emulsifier composition and water-in-oil type emulsion composition using the composition, and cosmetic |
| US11248125B2 (en) * | 2017-06-01 | 2022-02-15 | The Johns Hopkins University | Coating system for aluminum-magnesium alloys |
-
1984
- 1984-09-11 JP JP59189995A patent/JPS6166752A/en active Granted
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61113646A (en) * | 1984-11-08 | 1986-05-31 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPH0349307B2 (en) * | 1985-05-28 | 1991-07-29 | Shiseido Co Ltd | |
| JPS61271030A (en) * | 1985-05-28 | 1986-12-01 | Shiseido Co Ltd | Oily gel composition |
| JPS6245656A (en) * | 1985-08-22 | 1987-02-27 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPH0554868B2 (en) * | 1985-08-22 | 1993-08-13 | Shiseido Co Ltd | |
| JPS62238212A (en) * | 1986-04-10 | 1987-10-19 | Shiseido Co Ltd | Makeup cosmetic |
| JPS63215615A (en) * | 1986-12-19 | 1988-09-08 | レブロン・コンシューマー・プロダクツ・コーポレーション | Cosmetic composition comprising pigment- containing water-in-oil type emulsion |
| JPH0572886B2 (en) * | 1987-05-08 | 1993-10-13 | Terumo Corp | |
| JPS63275518A (en) * | 1987-05-08 | 1988-11-14 | Terumo Corp | Semisolid composition |
| JPH02115110A (en) * | 1988-10-25 | 1990-04-27 | Shin Etsu Chem Co Ltd | Material for cosmetic |
| FR2646346A1 (en) * | 1989-04-26 | 1990-11-02 | Thorel Jean | Composition for the topical deposition of a permeable and light-reflecting continuous film |
| JPH0344309A (en) * | 1989-06-29 | 1991-02-26 | Unilever Nv | Composition for beauty |
| JPH0625051B2 (en) * | 1989-06-29 | 1994-04-06 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Beauty composition |
| JPH03115207A (en) * | 1989-09-28 | 1991-05-16 | Kobayashi Kose Co Ltd | Oily composition and cosmetic containing same |
| US5681551A (en) * | 1991-12-26 | 1997-10-28 | Kao Corporation | Oil-based solid cosmetic composition |
| US6780402B1 (en) | 1995-07-28 | 2004-08-24 | L'oreal | Make-up compositions containing phenylated silicone oils, which are resistant to transfer and migration |
| JP2003160435A (en) * | 2001-11-21 | 2003-06-03 | Pola Chem Ind Inc | Gel composition |
| JP2012012351A (en) * | 2010-07-02 | 2012-01-19 | Nikko Chemical Co Ltd | Water-in-oil type emulsifier composition and water-in-oil type emulsion composition using the composition, and cosmetic |
| US11248125B2 (en) * | 2017-06-01 | 2022-02-15 | The Johns Hopkins University | Coating system for aluminum-magnesium alloys |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0419269B2 (en) | 1992-03-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |