JPS6151548B2 - - Google Patents

Info

Publication number
JPS6151548B2
JPS6151548B2 JP53164435A JP16443578A JPS6151548B2 JP S6151548 B2 JPS6151548 B2 JP S6151548B2 JP 53164435 A JP53164435 A JP 53164435A JP 16443578 A JP16443578 A JP 16443578A JP S6151548 B2 JPS6151548 B2 JP S6151548B2
Authority
JP
Japan
Prior art keywords
layer
mil
bag
food
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP53164435A
Other languages
Japanese (ja)
Other versions
JPS54100475A (en
Inventor
Hatsuchinzu Oruson Robaato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of JPS54100475A publication Critical patent/JPS54100475A/en
Publication of JPS6151548B2 publication Critical patent/JPS6151548B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D31/00Bags or like containers made of paper and having structural provision for thickness of contents
    • B65D31/02Bags or like containers made of paper and having structural provision for thickness of contents with laminated walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/08Dimensions, e.g. volume
    • B32B2309/10Dimensions, e.g. volume linear, e.g. length, distance, width
    • B32B2309/105Thickness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • B32B2323/043HDPE, i.e. high density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/46Bags

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Bag Frames (AREA)
  • Wrappers (AREA)

Description

【発明の詳細な説明】 本発明は、異なつた熱可塑性樹脂から成形した
2つのフイルム層から成る熱可塑性フイルムラミ
ネート材から作つた熱可塑性袋状構造体に関す
る。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a thermoplastic pouch-like structure made from a thermoplastic film laminate consisting of two film layers molded from different thermoplastic resins.

従来、ポリエチレン製袋(bag)は、食物の貯
蔵用に、そして、特に、冷凍食品の貯蔵用に使用
されてきた。そのような食品収容体としての袋
は、後で再加熱することのある食品を包装したま
まで貯蔵するのに特に都合がよい。そのため、低
密度、すなわち0.91〜0.93g/c.c.のポリエチレン
からそのような食品貯蔵用の袋が大量に製造され
ている。しかし、再加熱のためには、食品をその
ような低密度ポリエチレン袋から取り出さなけれ
ばならない。100℃(212〓)以下の温度で部分的
に溶融し、調理容器の表面に付着してしまう傾向
があるからである。
Traditionally, polyethylene bags have been used for food storage, and in particular for frozen food storage. Such food containers are particularly advantageous for storing food products in their packaging that may be reheated later. Therefore, such food storage bags are manufactured in large quantities from polyethylene of low density, i.e. 0.91-0.93 g/cc. However, for reheating, the food must be removed from such low density polyethylene bags. This is because it tends to partially melt at temperatures below 100°C (212°C) and adhere to the surface of the cooking container.

低密度ポリエチレン製袋の上記の欠点を除去す
るために、“沸騰”用袋として高温で使用する袋
には、例えばポリエチレンンテレフタレートのよ
うなポリエステル製袋を使う試みが行行なわれて
きた。しかし、そのようなポリエステルフイルム
は封止することが困難であるばかりでなく、より
重要なことであるが、使い捨て用の袋として使用
するには余り高価すぎる。
In order to eliminate the above-mentioned disadvantages of low density polyethylene bags, attempts have been made to use polyester bags, such as polyethylene terephthalate, in bags used at high temperatures as "boiling" bags. However, such polyester films are not only difficult to seal, but more importantly, they are too expensive to be used as disposable bags.

本発明は、貯蔵期間中食品を収容しておくため
に使用できるばかりでなく、最も重要なことであ
るが、食卓に供するために加熱する期間中にもそ
の食品を収容しておくために使用できる、安価な
熱可塑性袋を提供する。本発明にる袋状構造体は
2層のラミネート構造を有しており、袋の内側の
層、つまり食品と接触している表面層はポリエチ
レン、好ましくは高密度エチレンコポリマーから
構成される。一方、袋ラミネート材の外側の層、
つまり調理用容器と直接に接触する袋の表面は比
較的薄いポリプロピレンフイルムの層から成る。
この外側のポリプロピレンフイルムの層の存在に
よつて、内側のより熱的に弱いポリエチレン層は
調理用の容器の表面と接触することがなく、その
ため袋自体はより高い温度にも耐えることができ
る。ポリプロピレン層は、150℃以上の融解点ま
たは粘着点を有するため、安定であつて、食品を
再加熱している間にあつても容器側壁などに付着
することがない。明らかに、食品を収容している
袋は、再加熱を行なつている間は、水などの流体
中に浸漬させておくものである。したがつて、本
発明は、食品の最適の貯蔵、収容用のラミネート
材製の袋を提供するものであつて、該袋内の食品
は袋から取り出すことなく再加熱ができるもので
ある。本発明に係る袋は、高密度エチレン/アル
フア―オレフインコポリマーの内側フイルム層と
ポリプロピレンフイルムの外側層とから成る2層
ラミネート材から構成される。この高密度エチレ
ンコポリマーは、好ましくは、少量の、例えば10
%以下の、例えばオクテン―1のように3〜10個
の炭素原子を有する別種のアルフア―オレフイン
と共重合化したエチレンである。
The present invention can be used to keep food contained not only during storage, but most importantly, during heating for consumption. To provide affordable thermoplastic bags. The bag-like structure according to the invention has a two-layer laminate structure, the inner layer of the bag, ie the surface layer in contact with the food product, being composed of polyethylene, preferably a high-density ethylene copolymer. Meanwhile, the outer layer of bag laminate material,
That is, the surface of the bag that comes into direct contact with the cooking container consists of a relatively thin layer of polypropylene film.
Due to the presence of this outer polypropylene film layer, the inner, more thermally weak polyethylene layer does not come into contact with the surface of the cooking container, so that the bag itself can withstand higher temperatures. Since the polypropylene layer has a melting point or sticking point of 150° C. or higher, it is stable and does not adhere to the side walls of the container even while the food is being reheated. Obviously, the bag containing the food product is to be submerged in a fluid, such as water, during the reheating process. Accordingly, the present invention provides a bag made of laminate material for optimal storage and containment of food, and the food inside the bag can be reheated without being removed from the bag. The bag of the present invention is constructed from a two-layer laminate consisting of an inner film layer of high density ethylene/alpha-olefin copolymer and an outer layer of polypropylene film. This high density ethylene copolymer is preferably used in small amounts, e.g.
% or less of ethylene copolymerized with another type of alpha-olefin having 3 to 10 carbon atoms, such as octene-1.

実施例 チユーブ状の熱可塑性ラミネート材は慣用のイ
ンフレートチユーブ状フイルム共押出し法によつ
て製造した。そのチユーブ状の内側層は1.0ミル
厚さの高密度ポリエチレンコポリマー層から成
り、外側層は0.2ミル厚さのポリプロピレンから
成るものであつた。この連続したラミネート材チ
ユーブは続いて、当業界での周知の方法で袋状構
造体とした。上記の高密度ポリエチレンコポリマ
ーはエチレンと約3重量%のオクテン―1とのコ
ポリマーであつた。この樹脂は製造者によつてア
ラトン(Alathon)7810と呼ばれているものであ
つて、4.3/1の膨張比で押出した1.25ミルのフイ
ルムについて、以下のような代表的物理的特性を
有する。
EXAMPLES Tubular thermoplastic laminates were manufactured by a conventional blown tube film coextrusion process. The tubular inner layer consisted of a 1.0 mil thick layer of high density polyethylene copolymer and the outer layer consisted of a 0.2 mil thick polypropylene layer. This continuous laminate tube was then formed into a bag-like structure using methods well known in the art. The high density polyethylene copolymer described above was a copolymer of ethylene and about 3% by weight octene-1. This resin is called Alathon 7810 by the manufacturer and has the following typical physical properties for a 1.25 mil film extruded at a 4.3/1 expansion ratio.

密度 0.945g/c.c. メルトインデツクス 0.25g/10分 引張降伏(MD) 3000psi (TD) 3100psi 伸び(MD) 660% (2インチ/分) 730% 割線モジユラス(MD) 80M psi (TD) 82M psi エルメンドルフ引裂(MD) 45gm/ミル (TD) 247gm/ミル スペンサー衝撃 2.8インチ・ポンド/ミル (Spencer Impact) 落槍(Dart Drop)(26インチ) 115gm/ミル 引裂き(MD) 3.2Kg力 ASTM D―2582(TD) 3.7Kg力 プロピレンの外側層は、製造者によつてテナイ
ト(Tenite)612Fと呼ばれ、以下のような代表
的物理的特性を有する樹脂で構成した。
Density 0.945g/cc Melt Index 0.25g/10min Tensile Yield (MD) 3000psi (TD) 3100psi Elongation (MD) 660% (2 inches/min) 730% Secant Modulus (MD) 80M psi (TD) 82M psi Elmendorf Tear (MD) 45 gm/mil (TD) 247 gm/mil Spencer Impact 2.8 in. lb/mil Dart Drop (26 in.) 115 gm/mil Tear (MD) 3.2 Kg force ASTM D-2582 ( TD) 3.7Kg Force The propylene outer layer was constructed from a resin called Tenite 612F by the manufacturer and having the following typical physical properties:

密度 0.902g/c.c. 流れ特性 4.5g/10分 引張り降伏 5000psi ビガー軟化点 145℃ 高密度エチレン―オクテン―1コポリマー層お
よびポリプロピレン層を一体的に接合して構成し
た2層ラミネート材フイルムは以下の物理的特性
を有した。
Density 0.902 g/cc Flow properties 4.5 g/10 minutes Tensile yield 5000 psi Vigor Softening point 145°C A two-layer laminate film made by integrally bonding a high-density ethylene-octene-1 copolymer layer and a polypropylene layer has the following physical properties. It had certain characteristics.

フイルム厚さ 1.20ミル 膨張比 2.5/1 引張降伏(MD) 3200psi (TD) 3400psi 伸び(MD) 525% (TD) 850% エルメンドルフ引裂(MD) 24gm/ミル (TD) 477gm/ミル モジユラス(MD) 80M psi (TD) 105M psi 本発明にあつては内側の高密度ポリエチレンコ
ポリマー層の厚さを約0.5ミルから約3.0ミルまで
の間で変えることができ、好ましくは、その厚さ
は1.0ミルである。一方、外側のポリプロピレン
の層は約0.1ミルから約3.0ミルまでの間で変える
ことができ、好ましくはその厚さは約0.2ミルで
ある。
Film Thickness 1.20 Mil Expansion Ratio 2.5/1 Tensile Yield (MD) 3200psi (TD) 3400psi Elongation (MD) 525% (TD) 850% Elmendorf Tear (MD) 24gm/mil (TD) 477gm/mil Modulus (MD) 80M psi (TD) 105M psi In the present invention, the thickness of the inner high density polyethylene copolymer layer can vary from about 0.5 mil to about 3.0 mil, preferably the thickness is 1.0 mil. The outer polypropylene layer, on the other hand, can vary from about 0.1 mil to about 3.0 mil, and preferably has a thickness of about 0.2 mil.

Claims (1)

【特許請求の範囲】 1 外層がポリプロピレンの連続層からなり、内
層が、約10重量%以下のオクテン―1を含みかつ
密度が0.945グラム/c.c.の高密度エチレン―オ
クテン―1コポリマーの連続層からなる熱可塑性
樹脂製ラミネートから作られる、二層同時押出熱
可塑性ラミネート袋。 2 ポリプロピレン層の厚さが0.1ないし0.2ミル
であり、そしてコポリマー層の厚さが0.5ないし
3ミルである、特許請求の範囲第1項に記載の熱
可塑性ラミネート袋。
[Claims] 1. The outer layer is a continuous layer of polypropylene, and the inner layer is a continuous layer of a high density ethylene-octene-1 copolymer containing less than about 10% by weight of octene-1 and having a density of 0.945 grams/ cc3 . A two-layer co-extruded thermoplastic laminate bag made from a thermoplastic laminate consisting of. 2. The thermoplastic laminate bag of claim 1, wherein the polypropylene layer has a thickness of 0.1 to 0.2 mil and the copolymer layer has a thickness of 0.5 to 3 mil.
JP16443578A 1977-12-27 1978-12-26 Thermoplastic resin bag Granted JPS54100475A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US86508877A 1977-12-27 1977-12-27

Publications (2)

Publication Number Publication Date
JPS54100475A JPS54100475A (en) 1979-08-08
JPS6151548B2 true JPS6151548B2 (en) 1986-11-10

Family

ID=25344683

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16443578A Granted JPS54100475A (en) 1977-12-27 1978-12-26 Thermoplastic resin bag

Country Status (8)

Country Link
JP (1) JPS54100475A (en)
BE (1) BE873112A (en)
CA (1) CA1113898A (en)
DE (1) DE2855053A1 (en)
FR (1) FR2413853A7 (en)
GB (1) GB2011317B (en)
IT (1) IT7823615V0 (en)
NL (1) NL7812412A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4390385A (en) 1980-05-23 1983-06-28 W. R. Grace & Co., Cryovac Div. Heat sealable, multi-ply polypropylene film
US4439478A (en) * 1980-05-23 1984-03-27 W. R. Grace & Co., Cryovac Division Heat sealable, multi-ply polypropylene film
US4903859B1 (en) * 1988-09-23 2000-04-18 Better Agricultural Goals Inc Container for flowable materials
US5288531A (en) * 1991-08-09 1994-02-22 The Dow Chemical Company Pouch for packaging flowable materials

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5189579A (en) * 1975-02-04 1976-08-05 SHOKUHINHOSOYO FUKURO
JPS5268279A (en) * 1975-12-04 1977-06-06 Toyobo Co Ltd Composite films of polypropylene withexcellent processability

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5189579A (en) * 1975-02-04 1976-08-05 SHOKUHINHOSOYO FUKURO
JPS5268279A (en) * 1975-12-04 1977-06-06 Toyobo Co Ltd Composite films of polypropylene withexcellent processability

Also Published As

Publication number Publication date
GB2011317A (en) 1979-07-11
DE2855053A1 (en) 1979-07-05
FR2413853A7 (en) 1979-07-27
NL7812412A (en) 1979-06-29
CA1113898A (en) 1981-12-08
BE873112A (en) 1979-06-27
JPS54100475A (en) 1979-08-08
GB2011317B (en) 1982-03-10
IT7823615V0 (en) 1978-12-21

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