JPS61251514A - 高純度希土類酸化物の回収方法 - Google Patents
高純度希土類酸化物の回収方法Info
- Publication number
- JPS61251514A JPS61251514A JP60092445A JP9244585A JPS61251514A JP S61251514 A JPS61251514 A JP S61251514A JP 60092445 A JP60092445 A JP 60092445A JP 9244585 A JP9244585 A JP 9244585A JP S61251514 A JPS61251514 A JP S61251514A
- Authority
- JP
- Japan
- Prior art keywords
- rare earth
- mol
- phosphor
- oxalic acid
- waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 19
- 229910001404 rare earth metal oxide Inorganic materials 0.000 title claims description 16
- 238000011084 recovery Methods 0.000 title description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 53
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 34
- 150000002910 rare earth metals Chemical class 0.000 claims description 23
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 21
- 239000002699 waste material Substances 0.000 claims description 21
- 235000006408 oxalic acid Nutrition 0.000 claims description 16
- 239000012535 impurity Substances 0.000 claims description 10
- -1 rare earth oxalate Chemical class 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000000243 solution Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000001054 red pigment Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052693 Europium Inorganic materials 0.000 description 1
- 241000283986 Lepus Species 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/14—Methods for preparing oxides or hydroxides in general
- C01B13/145—After-treatment of oxides or hydroxides, e.g. pulverising, drying, decreasing the acidity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Luminescent Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60092445A JPS61251514A (ja) | 1985-04-30 | 1985-04-30 | 高純度希土類酸化物の回収方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60092445A JPS61251514A (ja) | 1985-04-30 | 1985-04-30 | 高純度希土類酸化物の回収方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61251514A true JPS61251514A (ja) | 1986-11-08 |
| JPH0331644B2 JPH0331644B2 (enrdf_load_stackoverflow) | 1991-05-08 |
Family
ID=14054605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60092445A Granted JPS61251514A (ja) | 1985-04-30 | 1985-04-30 | 高純度希土類酸化物の回収方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61251514A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6110433A (en) * | 1994-12-20 | 2000-08-29 | Varta Batterie Aktiengesellschaft | Process for the recovery of metals from used nickel/metal/rare earth hydride storage batteries |
| EP1215260A3 (en) * | 2000-12-18 | 2004-03-03 | Osram Sylvania Inc. | Recovery of electroluminescent phosphor from encapsulated material |
| CN103131862A (zh) * | 2013-03-13 | 2013-06-05 | 龙南县中利再生资源开发有限公司 | 预处理分解法从荧光粉废料中提取高纯稀土氧化物 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5515987A (en) * | 1978-04-14 | 1980-02-04 | Sjeldne Jordarter Forskning | Production of yttrium oxide |
-
1985
- 1985-04-30 JP JP60092445A patent/JPS61251514A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5515987A (en) * | 1978-04-14 | 1980-02-04 | Sjeldne Jordarter Forskning | Production of yttrium oxide |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6110433A (en) * | 1994-12-20 | 2000-08-29 | Varta Batterie Aktiengesellschaft | Process for the recovery of metals from used nickel/metal/rare earth hydride storage batteries |
| EP1215260A3 (en) * | 2000-12-18 | 2004-03-03 | Osram Sylvania Inc. | Recovery of electroluminescent phosphor from encapsulated material |
| CN103131862A (zh) * | 2013-03-13 | 2013-06-05 | 龙南县中利再生资源开发有限公司 | 预处理分解法从荧光粉废料中提取高纯稀土氧化物 |
| CN103131862B (zh) * | 2013-03-13 | 2016-09-14 | 龙南县中利再生资源开发有限公司 | 预处理分解法从荧光粉废料中提取高纯稀土氧化物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0331644B2 (enrdf_load_stackoverflow) | 1991-05-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR910005048B1 (ko) | 폐 희토류 형광체로부터의 고순도 희토류 산화물의 회수방법 | |
| AU2010210215B2 (en) | Method for depositing metal ions | |
| KR950003421B1 (ko) | 암모늄 희토류 이중 옥살레이트의 제조방법 및 그것의 희토류 산화물의 제조에 관한 용도 | |
| AU2010205981B2 (en) | Application of aqueous solution of magnesium bicarbonate and/or calcium bicarbonate in the process of extraction separation and purification of metals | |
| KR101343166B1 (ko) | 할로포스페이트 및 하나 이상의 희토류 원소의 화합물을 함유하는 고체 혼합물로부터 희토류 원소를 회수하는 방법 | |
| US20140286841A1 (en) | Processes for recovering rare earth elements for aluminum-bearing materials | |
| CN102312098A (zh) | 一种从废弃荧光粉中分离提纯荧光级氧化钇和氧化铕的方法 | |
| WO2014023092A1 (zh) | 一种两代酸解分解废旧稀土发光材料的工艺 | |
| US20230323509A1 (en) | Weak Acid Lixiviants for Recovery of Alkaline Earth Metals | |
| JPS61251514A (ja) | 高純度希土類酸化物の回収方法 | |
| JPS62187112A (ja) | 希土類元素・鉄系磁石材料から希土類元素を回収する方法 | |
| CN105886761B (zh) | 从还原萃取提铕反萃余液中分离稀土和锌的方法 | |
| CN1194237A (zh) | 湿法脱除锑矿物中铅、砷、硒、锡、汞杂质制备工业纯硫化锑的工艺 | |
| CN110184460B (zh) | 一种氯化镨钕料液中除铝离子的方法 | |
| RU2424188C1 (ru) | Способ получения высокочистого фторида кальция | |
| CN116640936B (zh) | 一种生产高品位钒精矿的方法 | |
| CN1040745C (zh) | 稀土铵双草酸盐的生产方法 | |
| CA3092484C (en) | Method for removing fluoride from a zinc-containing solution or suspension, defluoridated zinc sulfate solution and use thereof, and method for producing zinc and hydrogen fluoride or hydrofluoric acid | |
| US3420860A (en) | Method of rare-earth metal recovery from orthovanadate compound | |
| JPH06329414A (ja) | 希土類フッ化物の製造方法 | |
| JP4322122B2 (ja) | 高純度ニオブ化合物及び／又はタンタル化合物の精製方法 | |
| ATE343653T1 (de) | Verfahren zur wiedergewinnung von nickel aus verbrauchten katalysatoren | |
| CN116162811B (zh) | 硫酸稀土浸出液除杂的方法 | |
| JP2001288460A (ja) | 希土類系蛍光体の製造方法 | |
| CN1331981C (zh) | 荧光级碳酸锶的制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |