JPS6123927B2 - - Google Patents
Info
- Publication number
- JPS6123927B2 JPS6123927B2 JP55037374A JP3737480A JPS6123927B2 JP S6123927 B2 JPS6123927 B2 JP S6123927B2 JP 55037374 A JP55037374 A JP 55037374A JP 3737480 A JP3737480 A JP 3737480A JP S6123927 B2 JPS6123927 B2 JP S6123927B2
- Authority
- JP
- Japan
- Prior art keywords
- polyacrylamide
- weight
- silicon dioxide
- temperature
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 113
- 229920002401 polyacrylamide Polymers 0.000 claims description 112
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 57
- 239000000377 silicon dioxide Substances 0.000 claims description 56
- 235000012239 silicon dioxide Nutrition 0.000 claims description 56
- -1 dimethylsilyl groups Chemical group 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 21
- 238000006116 polymerization reaction Methods 0.000 claims description 20
- 239000000126 substance Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 16
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 10
- 239000001913 cellulose Substances 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 125000005625 siliconate group Chemical group 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 8
- 235000019441 ethanol Nutrition 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- 230000009471 action Effects 0.000 claims description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 235000010981 methylcellulose Nutrition 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 95
- 239000011541 reaction mixture Substances 0.000 description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 66
- 239000000243 solution Substances 0.000 description 59
- 238000003756 stirring Methods 0.000 description 52
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 46
- 229920000642 polymer Polymers 0.000 description 25
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 23
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 23
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 23
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 18
- 229920000742 Cotton Polymers 0.000 description 17
- 238000010186 staining Methods 0.000 description 17
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 16
- 235000011114 ammonium hydroxide Nutrition 0.000 description 16
- 238000012360 testing method Methods 0.000 description 12
- 239000004698 Polyethylene Substances 0.000 description 10
- 235000011837 pasties Nutrition 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 238000005299 abrasion Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 230000000007 visual effect Effects 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 238000005498 polishing Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000001953 sensory effect Effects 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 3
- 230000033116 oxidation-reduction process Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- ZPUCINDJVBIVPJ-LJISPDSOSA-N cocaine Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- GBPOWOIWSYUZMH-UHFFFAOYSA-N sodium;trihydroxy(methyl)silane Chemical compound [Na+].C[Si](O)(O)O GBPOWOIWSYUZMH-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3737480A JPS56133307A (en) | 1980-03-24 | 1980-03-24 | Manufacture of polyacrylamide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3737480A JPS56133307A (en) | 1980-03-24 | 1980-03-24 | Manufacture of polyacrylamide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56133307A JPS56133307A (en) | 1981-10-19 |
| JPS6123927B2 true JPS6123927B2 (cs) | 1986-06-09 |
Family
ID=12495734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3737480A Granted JPS56133307A (en) | 1980-03-24 | 1980-03-24 | Manufacture of polyacrylamide |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56133307A (cs) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016098269A1 (ja) * | 2014-12-17 | 2016-06-23 | 三菱レイヨン株式会社 | アクリルアミド水溶液及びアクリルアミド系重合体の製造方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003277416A (ja) * | 2002-03-22 | 2003-10-02 | Daiyanitorikkusu Kk | 糖類を含むアクリルアミド水溶液 |
| JP5197974B2 (ja) * | 2007-03-09 | 2013-05-15 | 花王株式会社 | 繊維の残香性付与剤 |
| CN102690381A (zh) * | 2012-06-21 | 2012-09-26 | 河南省科学院高新技术研究中心 | 一种分子量为5000-20000的超低分子量聚丙烯酰胺制备方法 |
-
1980
- 1980-03-24 JP JP3737480A patent/JPS56133307A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016098269A1 (ja) * | 2014-12-17 | 2016-06-23 | 三菱レイヨン株式会社 | アクリルアミド水溶液及びアクリルアミド系重合体の製造方法 |
| JP6020741B1 (ja) * | 2014-12-17 | 2016-11-02 | 三菱レイヨン株式会社 | アクリルアミド水溶液及びアクリルアミド系重合体の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56133307A (en) | 1981-10-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Latta | Improved tactile and sorption properties of polyester fabrics through caustic treatment | |
| AU750776B2 (en) | Method for treating cellulosic shaped bodies | |
| EP2243870B1 (en) | An antistatic acrylic fiber and a method for manufacturing the same | |
| US3717689A (en) | Process for improving the antistatic properties of hydrophobic synthetic fibers | |
| JPS6123927B2 (cs) | ||
| JP2018104850A (ja) | セルロース系繊維用染料固着剤 | |
| US2390032A (en) | Treatment of cellulosic fibers | |
| US2416272A (en) | Treating jute fibers | |
| JP5696944B2 (ja) | 発色性に優れた制電性アクリル繊維およびその製造方法 | |
| GB2060659A (en) | Method of Producing Polyacrylamide | |
| JPS642713B2 (cs) | ||
| CS224714B1 (cs) | Způsob výroby pólyakrylamidu | |
| JPH0559664A (ja) | 繊維製品の樹脂加工方法 | |
| JPH11247067A (ja) | ポリエステル系合成繊維製品の親水化加工方法 | |
| JPS6032752B2 (ja) | アクリロニトリル系合成繊維の処理方法 | |
| Balmforth et al. | The Dyeing of Cellulose Acetate with Water‐soluble (Solacet) Dyes | |
| JP3947595B2 (ja) | エマルジョンポリマーによる繊維材料の仕上加工法 | |
| SU953047A1 (ru) | Шлихта дл пр жи из смеси полиэфирных и целлюлозных волокон | |
| Gibson et al. | Pad‐Batch Dyeing of Wool Fabric—Development of an Industrial Process | |
| JPS6316514B2 (cs) | ||
| JPH0860546A (ja) | コラーゲン含有糊剤 | |
| JP3277174B2 (ja) | 合成繊維及び製造方法 | |
| Landolt | WEST RIDING, SCOTTISH and MANCHESTER SECTIONS | |
| JP3593846B2 (ja) | 繊維布帛の仕上げ加工方法 | |
| McCleary | Fundamentals of the dyeing of cellulosic fibers |