JPS6117843B2 - - Google Patents
Info
- Publication number
- JPS6117843B2 JPS6117843B2 JP53165995A JP16599578A JPS6117843B2 JP S6117843 B2 JPS6117843 B2 JP S6117843B2 JP 53165995 A JP53165995 A JP 53165995A JP 16599578 A JP16599578 A JP 16599578A JP S6117843 B2 JPS6117843 B2 JP S6117843B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- rubber
- composition
- mixture
- terpolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 68
- 229920000642 polymer Polymers 0.000 claims description 68
- 239000000178 monomer Substances 0.000 claims description 36
- 229920001971 elastomer Polymers 0.000 claims description 33
- 239000005060 rubber Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- 238000000465 moulding Methods 0.000 claims description 17
- 150000002825 nitriles Chemical class 0.000 claims description 17
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 13
- 229920001897 terpolymer Polymers 0.000 claims description 13
- 239000011159 matrix material Substances 0.000 claims description 11
- 150000008064 anhydrides Chemical class 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 8
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000012986 chain transfer agent Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 230000009477 glass transition Effects 0.000 claims description 5
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims description 4
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 4
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- FRQQKWGDKVGLFI-UHFFFAOYSA-N 2-methylundecane-2-thiol Chemical compound CCCCCCCCCC(C)(C)S FRQQKWGDKVGLFI-UHFFFAOYSA-N 0.000 claims description 2
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 claims 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 18
- 238000004132 cross linking Methods 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 229920001169 thermoplastic Polymers 0.000 description 8
- 238000007792 addition Methods 0.000 description 7
- 239000000306 component Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 5
- 239000004416 thermosoftening plastic Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 238000003856 thermoforming Methods 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- OMNYXCUDBQKCMU-UHFFFAOYSA-N 2,4-dichloro-1-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C(Cl)=C1 OMNYXCUDBQKCMU-UHFFFAOYSA-N 0.000 description 1
- SZSWKGVWJBZNIH-UHFFFAOYSA-N 2-chloro-1-ethenyl-4-methylbenzene Chemical compound CC1=CC=C(C=C)C(Cl)=C1 SZSWKGVWJBZNIH-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- HIIRHFCETUWEJE-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol;terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1.CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O HIIRHFCETUWEJE-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 241000873911 Gracilaria dura Species 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N aconitic acid Chemical class OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- VUKHQPGJNTXTPY-UHFFFAOYSA-N but-2-enylbenzene Chemical compound CC=CCC1=CC=CC=C1 VUKHQPGJNTXTPY-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005094 computer simulation Methods 0.000 description 1
- 239000000039 congener Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- WOLATMHLPFJRGC-UHFFFAOYSA-N furan-2,5-dione;styrene Chemical compound O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 WOLATMHLPFJRGC-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 238000011090 industrial biotechnology method and process Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920003246 polypentenamer Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 238000010104 thermoplastic forming Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/948,122 US4223096A (en) | 1977-12-27 | 1978-10-02 | Rubber-modified terpolymer with improved molding characteristics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5548213A JPS5548213A (en) | 1980-04-05 |
| JPS6117843B2 true JPS6117843B2 (es) | 1986-05-09 |
Family
ID=25487312
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16599578A Granted JPS5548213A (en) | 1978-10-02 | 1978-12-26 | Molding polymer composition |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4223096A (es) |
| EP (1) | EP0009529B1 (es) |
| JP (1) | JPS5548213A (es) |
| AU (1) | AU520534B2 (es) |
| BR (1) | BR7808511A (es) |
| CA (1) | CA1107884A (es) |
| DE (1) | DE2861983D1 (es) |
| ES (1) | ES476335A1 (es) |
| IT (1) | IT1102787B (es) |
| MX (2) | MX151395A (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4404322A (en) * | 1981-01-28 | 1983-09-13 | Denki Kagaku Kogyo Kabushiki Kaisha | Heat resistant resin composition |
| US4311806A (en) * | 1981-03-17 | 1982-01-19 | Monsanto Company | Polyblends of PVC and styrene-maleic anhydride-rubber copolymers |
| US4336354A (en) * | 1981-03-26 | 1982-06-22 | Atlantic Richfield Company | Method of preparing styrene-maleic anhydride molding composition |
| US4439571A (en) * | 1981-09-24 | 1984-03-27 | Monsanto Company | Thermally stabilized polymers |
| US4397975A (en) * | 1981-11-25 | 1983-08-09 | Monsanto Company | Heat stabilized polymers |
| US4387191A (en) * | 1982-03-25 | 1983-06-07 | Monsanto Company | Heat stabilized polymers |
| US4542189A (en) * | 1983-09-26 | 1985-09-17 | The Standard Oil Company | Process for the preparation of novel rubber-modified thermoplastic resin compositions using multiple feed streams |
| US4692498A (en) * | 1983-09-26 | 1987-09-08 | The Standard Oil Company | Novel rubber-modified thermoplastic resin compositions |
| DE3481310D1 (de) * | 1983-11-15 | 1990-03-15 | Dainippon Ink & Chemicals | Waermebestaendiges schlagfestes styrolharz, dessen herstellungsverfahren und dieses styrolharz enthaltende zusammensetzung. |
| DE3505778A1 (de) * | 1985-02-20 | 1986-08-21 | Bayer Ag, 5090 Leverkusen | Schwefelhaltige pfropfprodukte |
| US4765607A (en) * | 1985-03-08 | 1988-08-23 | Mars, Incorporated | Stacker apparatus |
| US4877826A (en) * | 1988-10-05 | 1989-10-31 | The Dow Chemical Company | Weatherable styrenic polymer blend comprising polyalkylene glycol |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2858281A (en) * | 1954-01-22 | 1958-10-28 | Goodrich Co B F | Insoluble, acid and alkali-resistant carboxylic polymers |
| US3267061A (en) * | 1962-06-18 | 1966-08-16 | Union Carbide Corp | Freeze-thaw stable styrene butadiene maleic acid interpolymer latex and paints |
| US3676526A (en) * | 1967-06-02 | 1972-07-11 | Eugene G Sommerfeld | Polymeric dispersion of a diene-acrylonitrite graft copolymer with a different graft copolymer |
| US3919354A (en) * | 1972-09-08 | 1975-11-11 | Dow Chemical Co | Impact resistant polymers of a resinous copolymer of an alkenyl aromatic monomer and unsaturated dicarboxylic anhydride |
| DE2329585C2 (de) * | 1973-06-09 | 1984-01-05 | Bayer Ag, 5090 Leverkusen | Polycarbonat-Formmassen |
| US4108925A (en) * | 1974-11-25 | 1978-08-22 | General Electric Company | Thermoplastic molding compositions of rubber modified copolymers of a vinyl aromatic compound and an α,β-unsaturated cyclic anhydride |
| GB1524433A (en) * | 1975-03-26 | 1978-09-13 | Bayer Ag | Continuous bulk polymerisation process |
| IT1043117B (it) * | 1975-10-03 | 1980-02-20 | Snam Progetti | Resine antiurto e metodo per la loro areparazione |
| JPS52112692A (en) * | 1976-03-19 | 1977-09-21 | Toyo Soda Mfg Co Ltd | Method for carboxylation of ethylene-vinyl acetate copolymers |
| US4097551A (en) * | 1976-12-20 | 1978-06-27 | Arco Polymers, Inc. | Rubber modified dicarboxylic acid copolymer blends |
-
1978
- 1978-10-02 US US05/948,122 patent/US4223096A/en not_active Expired - Lifetime
- 1978-12-26 JP JP16599578A patent/JPS5548213A/ja active Granted
- 1978-12-26 BR BR7808511A patent/BR7808511A/pt unknown
- 1978-12-26 ES ES476335A patent/ES476335A1/es not_active Expired
- 1978-12-27 IT IT31345/78A patent/IT1102787B/it active
- 1978-12-27 CA CA318,621A patent/CA1107884A/en not_active Expired
- 1978-12-27 EP EP78300908A patent/EP0009529B1/en not_active Expired
- 1978-12-27 DE DE7878300908T patent/DE2861983D1/de not_active Expired
- 1978-12-28 AU AU42922/78A patent/AU520534B2/en not_active Expired
-
1979
- 1979-01-03 MX MX176148A patent/MX151395A/es unknown
- 1979-01-03 MX MX797621U patent/MX4143E/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX151395A (es) | 1984-11-14 |
| IT7831345A0 (it) | 1978-12-27 |
| IT1102787B (it) | 1985-10-07 |
| JPS5548213A (en) | 1980-04-05 |
| DE2861983D1 (en) | 1982-09-16 |
| MX4143E (es) | 1982-01-06 |
| CA1107884A (en) | 1981-08-25 |
| AU4292278A (en) | 1980-04-17 |
| US4223096A (en) | 1980-09-16 |
| EP0009529A1 (en) | 1980-04-16 |
| EP0009529B1 (en) | 1982-07-28 |
| ES476335A1 (es) | 1979-07-01 |
| BR7808511A (pt) | 1980-05-20 |
| AU520534B2 (en) | 1982-02-04 |
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