JPS61143757A - X-ray exposure mask - Google Patents

X-ray exposure mask

Info

Publication number
JPS61143757A
JPS61143757A JP59267949A JP26794984A JPS61143757A JP S61143757 A JPS61143757 A JP S61143757A JP 59267949 A JP59267949 A JP 59267949A JP 26794984 A JP26794984 A JP 26794984A JP S61143757 A JPS61143757 A JP S61143757A
Authority
JP
Japan
Prior art keywords
ray
pattern
mask
film
ray absorption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP59267949A
Other languages
Japanese (ja)
Inventor
Kazuhiro Tanaka
和裕 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP59267949A priority Critical patent/JPS61143757A/en
Publication of JPS61143757A publication Critical patent/JPS61143757A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/22Masks or mask blanks for imaging by radiation of 100nm or shorter wavelength, e.g. X-ray masks, extreme ultraviolet [EUV] masks; Preparation thereof

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Preparing Plates And Mask In Photomechanical Process (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)

Abstract

PURPOSE:To facilitate formation of a mask by forming plural X-ray absorption patterns on the same plane or in plural layers on an X-ray transmitting layer by using plural materials different from each other in X-ray absorbance in each wavelength. CONSTITUTION:The surface of a silicon substrate 1 is coated with a resin monomer and heat treated to form a polyimide film 8 serviceable as the X-ray transmitting layer, and a frame member 9 is bonded to the film 8, the silicon substrate 1 is removed by etching or the like, an X-ray absorption pattern 10 made of Si3N4 is formed by attaching an Si3N4 film to the film 8 and etching it. Then, a resist pattern 11 in complementary relation to a prescribed pattern is formed by coating the pattern 10 with a resist and irradiating it with an electron beam, and further, a metal 5 of an X-ray absorber is attached onto the pattern 11, and when the pattern 11 is peeled, the second X-ray absorption pattern 12 is formed on the first pattern 10, and thus, an exposure mask is formed.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、X線露光用マスクの吸収層/(ターンの構
成に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to the structure of an absorbing layer/(turn) of an X-ray exposure mask.

半導体集積回路等の半導体装置を製造する際、微細パタ
ーン形成のため写真製版技術は必要不可欠であり、最近
では電子ビームあるいはX線による露光装置の採用によ
り高精度の微細パターン形成が可能となっている。
When manufacturing semiconductor devices such as semiconductor integrated circuits, photolithography technology is indispensable for forming fine patterns, and recently it has become possible to form fine patterns with high precision by adopting exposure equipment that uses electron beams or X-rays. There is.

〔従来の技術〕[Conventional technology]

従来のX線3+1!光用マスクの作成方法の一例を第3
図(&)〜(d) ”k−照して説明する。まず、揖3
図(IL)のように(100)の面方位を持つシリコン
基板1に、膜厚3〜5 μmで7 X 10”on−”
以上のポロン濃度を持つエピタキシャル層2を形成する
。次に、熱酸化したエツチング1スク3tシリコン基板
1の裏面に約300OAの厚さに形成する。
Conventional X-ray 3+1! An example of how to create a light mask is shown in Part 3.
Figures (&) to (d) "k-"
As shown in the figure (IL), a 7 x 10"on-" film with a film thickness of 3 to 5 μm is placed on a silicon substrate 1 with a (100) plane orientation.
The epitaxial layer 2 having the above poron concentration is formed. Next, a thermally oxidized etching film 3t is formed on the back surface of the silicon substrate 1 to a thickness of about 300 OA.

次に、第3図<b>のよ5にエピタキシャル層20表面
にVジス)Y塗布した後、電子ビーム照射し75r定の
パターンと相補の関係のVレストパターン415r:形
成する。さらに、X線吸収体である金層Sfvレストパ
ターン4上に被着させる。その後。
Next, as shown in FIG. 3<b>, after coating the surface of the epitaxial layer 20 with V (di) Y, electron beam irradiation is performed to form a V rest pattern 415r complementary to the constant pattern 75r. Furthermore, it is deposited on the gold layer Sfv rest pattern 4 which is an X-ray absorber. after that.

/シストパターン4 Y tll雌すると、第3図(c
)のように所望のパターン6がエピタキシャル層2上に
形成される。このパターン6はX線吸収層となるもので
ある。
/ Cyst pattern 4 Y tll female, Figure 3 (c
) A desired pattern 6 is formed on the epitaxial layer 2. This pattern 6 becomes an X-ray absorption layer.

その後、エツチングマスク3tマスクとして第3 IN
 (d)のように、シリコン基板11a択エツチング−
ttiは、X@透過層(エピタキシャル層2)および支
愕体7が形成さiる。
After that, the 3rd IN was used as an etching mask 3t mask.
As shown in (d), the silicon substrate 11a is selectively etched.
In tti, an X@transmissive layer (epitaxial layer 2) and a supporting body 7 are formed.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

上記のよ5な従来のxhn光用マスクは、各工程に対し
て1枚ずつ複雑なプロセスを経て作成されており、マス
ク作成の工期か長く作成が容易ではなかった。また、X
線露光用マスクはサブミクロンのオーダでの微細パター
ン転写に使用され。
The above-mentioned conventional xhn light masks are made one by one through a complicated process for each step, and the mask making process takes a long time and is not easy to make. Also, X
Line exposure masks are used to transfer fine patterns on the order of submicrons.

パター7fgKN重ね合わせ精度向上のために高度な技
術が裂開されている。しかし、従来のX線露光用マスク
は上記のような作成方法のため、l工程に1枚のマスク
が必要であり、ウェハ転写時の東ね合わせ精度が十分で
はな(、精度よくサメミクロンパターンが転写されなか
った。
Putter 7fgKN Advanced technology has been developed to improve alignment accuracy. However, due to the manufacturing method of conventional X-ray exposure masks as described above, one mask is required for each process, and alignment accuracy during wafer transfer is not sufficient (i.e., shark micron patterns cannot be accurately fabricated). was not transcribed.

さらに、X線露光用マスク作成には厳しいVシストv−
ジョンが要求されるが、現偉時の膨潤などにより高精度
のマスクの作成が困難であった。
In addition, V cyst v-
However, it was difficult to create a high-precision mask due to swelling and other factors.

この発明は、上記のような従来の欠点を除去するためK
なさRfSもので、X線吸収特性の異なる物質yttX
線吸収層として形成し、マスク作成枚数の減少と重ね合
わせ精度の向上を図ったxiitt元用マスクを提供す
ることを目的としている。
In order to eliminate the above-mentioned conventional drawbacks, this invention
RfS material with different X-ray absorption characteristics yttX
It is an object of the present invention to provide a mask for xiitt which is formed as a line-absorbing layer and which reduces the number of masks to be produced and improves overlay accuracy.

〔問題点を解決するための手段〕[Means for solving problems]

この発明に係るX線露光用マスクは、X線透過層上に複
数の各波長におけるX線吸収率の異なる物質からなる複
数のxiパターンを形成したものである。
The X-ray exposure mask according to the present invention has a plurality of xi patterns made of substances having different X-ray absorption rates at a plurality of wavelengths formed on an X-ray transparent layer.

〔作用〕[Effect]

この発明においては、波長の異なるX4i!Jlヲ順次
照射すること釦よりXM吸収パターンのX線吸収率にし
たがった複数のX線吸収パターンが、1枚のX1sj!
光用マスク九よりウェハに転写されることKなる。
In this invention, X4i! Multiple X-ray absorption patterns according to the X-ray absorption rate of the XM absorption pattern are irradiated in sequence by pressing the button, and one sheet of X1sj!
The light is transferred from the optical mask 9 to the wafer.

〔実施例〕〔Example〕

第1図(1)〜(e)はこの発明の一実施例馨説明する
ための工程図である。まず、第1 囚(a) K示すよ
うにシリコン基板10表面に樹脂上/マーを回転塗布し
、さらに、熱処理を行ってX線透過層となるポリイミド
膜8yt形成する。次に、第1図(b)に示すように、
ポリイミド膜a上に枠部材9を接層等により固着させる
。次いで、シリコン基板1tエツチング等により除去し
fs後、藁1図(c)に示すようにポリイミド膜80表
面にSi3N、(輩化シリコン)からなる第1のX線吸
収パターン10’t’形成する。第1のX線吸収パター
ン10は。
FIGS. 1(1) to 1(e) are process diagrams for explaining one embodiment of the present invention. First, as shown in Figure 1 (a) K, a resin coating material is spin-coated on the surface of the silicon substrate 10, and then heat treatment is performed to form a polyimide film 8yt that will become an X-ray transparent layer. Next, as shown in Figure 1(b),
The frame member 9 is fixed onto the polyimide film a by a contact layer or the like. Next, the silicon substrate 1t is removed by etching or the like, and after fs, a first X-ray absorbing pattern 10't' made of Si3N (polymerized silicon) is formed on the surface of the polyimide film 80 as shown in Fig. 1(c). . The first X-ray absorption pattern 10 is.

例えばCVD法により被膜形成後、Pj′I望パターン
を電子ビーム描画した後、エツチングすることにより形
成される。しかる後、フジスト塗布後、電子ビーム照射
し、て所定のパターンと相補の関係のVレストパターン
11Y:第1図(d)に示すように形成する。さらに、
X線吸収体である金層5馨第1図(d)に示すようにレ
ジストパターン11上に被着させる。その後、Vシスト
パターン11を制能すると、第1図(e)に示すように
g2のX線吸収パターン12が、5t3N、かもなる第
1のX線吸収パターン10上く形成され、この発明のX
線露光用マスクが作成される。
For example, it is formed by forming a film by CVD, drawing a desired Pj'I pattern with an electron beam, and then etching. Thereafter, after applying fujisto, electron beam irradiation is performed to form a V rest pattern 11Y complementary to a predetermined pattern as shown in FIG. 1(d). moreover,
A gold layer 5 serving as an X-ray absorber is deposited on the resist pattern 11 as shown in FIG. 1(d). Thereafter, when the V cyst pattern 11 is controlled, an X-ray absorption pattern 12 of g2 is formed on the first X-ray absorption pattern 10 of 5t3N as shown in FIG. X
A line exposure mask is created.

次に、この発明により作成されたX線露光用マスクの転
写方法について説明する。まず、X線源Va長4.37
 AノPd L、線とすると、XrIM透過層のX騨減
波は約0.06 dB/μmであり、第1のX線吸収層
である第1のXIvj吸収パターン10のX紛減我は0
.3dB/μmであり、第2のX線吸収層である第2の
X線吸収パターン12のX!1減放は206B/μmで
あるため、第2のXi吸収パターン12のみがウェハに
転写される。
Next, a method of transferring an X-ray exposure mask produced according to the present invention will be explained. First, the X-ray source Va length is 4.37
Assuming that AnoPdL is a line, the X wave attenuation of the XrIM transmission layer is approximately 0.06 dB/μm, and the X wave attenuation of the first XIvj absorption pattern 10, which is the first X-ray absorption layer, is 0
.. 3 dB/μm, and the X! of the second X-ray absorption pattern 12 which is the second X-ray absorption layer is 3 dB/μm. Since one emission reduction is 206 B/μm, only the second Xi absorption pattern 12 is transferred to the wafer.

次に、XM源を波長44AのCk、I!111とすると
Next, the XM source is connected to Ck, I! of wavelength 44A! If it is 111.

X線透過層のX線減衰は1 dB/μmであり、第1の
X線吸収層である第1のX線吸収パターン10のX線減
衰は80dB/μm%第2のX線吸収層である第2のX
#!吸収パターン12のX線減衰は100dB/μmと
なり、第1.第2のX線吸収パターン10.12がウェ
ハに転写される。
The X-ray attenuation of the X-ray transmission layer is 1 dB/μm, and the X-ray attenuation of the first X-ray absorption pattern 10 which is the first X-ray absorption layer is 80 dB/μm%. some second X
#! The X-ray attenuation of the absorption pattern 12 is 100 dB/μm, and the first. A second X-ray absorption pattern 10.12 is transferred to the wafer.

なお、上記実施例では、X線透過層としてポリイミド、
X線吸収層としてSi3N、およびAuの場合について
述べたが、これに限定されるものではなく、X線源の波
長′It変化させ、X@吸収に差の生じる物質であれば
何種類でも、また、どのような組み合わせでもよい。ま
た、上記実施例では。
In the above embodiment, the X-ray transparent layer is made of polyimide,
Although we have described the case of Si3N and Au as the X-ray absorption layer, it is not limited to this, but any number of materials can be used as long as the wavelength 'It of the X-ray source is changed and the X@ absorption differs. Further, any combination may be used. Moreover, in the above embodiment.

X線波長4.37 AのPd L、線と44人のCk5
線について述べたが、これ以外の波長の組み合わせでも
よい。
X-ray wavelength 4.37 A Pd L, line and 44 Ck5
Although the wavelengths have been described above, other combinations of wavelengths may be used.

また、X線g元用マスクの構造については、ボリイミド
@8に枠部材9Y固着させた[k11九ついて述べたが
、これ以外でもよい。また、Xi吸収層については2種
類のX線吸収率の異なる物質について述べたが、2種類
以上の物質でもよい。
Regarding the structure of the X-ray g source mask, the frame member 9Y is fixed to the polyimide@8 [k119], but other structures may be used. Furthermore, although two types of materials with different X-ray absorption rates have been described for the Xi absorption layer, two or more types of materials may be used.

また、第2のX線吸収層である第2のX線吸収パターン
12として、第1のX線吸収パターン10にパターニン
グする例について述べたが、側部あるいは第2図に示す
よ51C同一平面上に形成してもよい。
In addition, although an example has been described in which the second X-ray absorption pattern 12, which is the second X-ray absorption layer, is patterned on the first X-ray absorption pattern 10, the side part or the same plane as 51C as shown in FIG. It may be formed on top.

さらに、上記実施例では、波長によりX線吸収率の異な
る物質によりX線吸収パターンを形成した例について述
べたが、同一波長でX線吸収率の異なる物質でX線吸収
パターンを構成してもよ(。
Furthermore, in the above embodiment, an example was described in which an X-ray absorption pattern was formed using a material with different X-ray absorption rates depending on the wavelength. Yo(.

この場合にはX線照射の強度変化により異徨物質による
異種パターンが形成できる。
In this case, different patterns can be formed by foreign substances due to changes in the intensity of X-ray irradiation.

〔発明の効果〕〔Effect of the invention〕

この発明は以上説明したとおり、X線透過層上に複数の
各波長によりX線吸収率の異なる物質で複数のX恵吸収
パターンwrrfJ一平面上または複数層状に形b5.
LYXMg充用マスクを形成したので。
As explained above, this invention has a plurality of X-ray absorption patterns wrrfJ formed on one plane or in multiple layers using a plurality of materials having different X-ray absorptivity depending on each wavelength on an X-ray transmission layer.
Because I formed a mask filled with LYXMg.

このX線露光用マスクを用いてウェハにマスクパターン
の転写を行えば、1枚のX線露光用マスクにより2工程
分のXW4露光用マスクが代用でき、作成方法も容易と
なり工期も短くなると同時に、コストダウンにもつなが
る。その上、X線露光用マスクの作成を同時Icu複数
工程分について作成可能なため、マスク精度の著しい向
上が期待でき、また、ウェハ転写は同一マスクを使用し
転写するため、ウェハ転写の7ライメントが不要で、ア
ライメント精度の著しい向上が期待できる。また。
By using this X-ray exposure mask to transfer a mask pattern onto a wafer, one X-ray exposure mask can replace the XW4 exposure mask for two processes, making it easier to create and shortening the construction period. , which also leads to cost reduction. Furthermore, since it is possible to create X-ray exposure masks for multiple ICU processes at the same time, a significant improvement in mask accuracy can be expected.In addition, since the same mask is used for wafer transfer, seven alignments of wafer transfer can be achieved. is not required, and a significant improvement in alignment accuracy can be expected. Also.

これまでのX線g党によるサグミクロンパターン形成の
精度低下は、X線露光用マスクとウェハ転写時のアライ
メント精度によるものであったが。
The decrease in accuracy of sag micron pattern formation using X-ray beams so far has been due to the alignment accuracy between the X-ray exposure mask and the wafer transfer.

この発明によりこれらの大きな問題点は一挙に解決され
サグミクロンパターン形成が容易となつ、精度の向上が
可能となる効果が得られる。
The present invention solves these major problems all at once, making it easier to form a sag-micron pattern, and making it possible to improve accuracy.

【図面の簡単な説明】[Brief explanation of drawings]

第1図(息)〜(e)はこの発明の一実施例を示すX線
露光用マスクの製造工程l説明するための断面図、第2
図はこの発明の他の実施例χ示すX線露光用マスクの断
面図、第3図Cm)〜(d)は従来のX線j!元用マス
クの製造工8を説明するための断面図である。 図において、1はシリコン基板、2はエピタキシャル層
、5は金層、8はポリイミド膜、9は枠部材、10は第
1のXPs吸収パターン、11はノジストパターン、1
2は第2のX脚吸収パターンである。 なお、各因中同−符号は同一または相轟部分を示す。 代理人 大岩 増雄 (外2名) 第1図 (a) 8:ポリイしく贋 (b) 9:砕郁廿 第1図 (C) 12:萬2の入−σλνぐターン 第2図 第3図 (a) 第3図 忙) 手続補正書(自発) 1、事件の表示   特願昭5O−2B7841]号2
、発明の名称   X kQ 78光用マスク3、補正
をする者 事件との関係 特許出願人 住 所    東京都千代田区丸の内二丁目2番3号名
 称  (601)三菱電機株式会社5、補正の対象 明細書の特許請求の範囲の欄および発明の詳細な説明の
櫃 6、補正の内容 (1)明細書の特許請求の範囲を別紙のように補正する
。 (2)明細書第4頁2行の「複数の各波長における」を
削除する。 (3)同じく第7頁18行の「複数の各波長により」を
削除する。 (4)同じく第8頁3行の「2工程分」を、「複数工程
分」と補正する。 以上 2、特許請求の範囲 X線透過層上に  の  −に゛けるX線吸収率の異な
る物質で複数のX線吸収パターンを同一工面上または複
数層状に形成したことを特徴とするX線露光用マスク。
1(b) to 1(e) are cross-sectional views for explaining the manufacturing process l of an X-ray exposure mask showing one embodiment of the present invention;
The figure is a sectional view of an X-ray exposure mask showing another embodiment χ of the present invention, and FIGS. FIG. 2 is a cross-sectional view for explaining a manufacturing process 8 of the original mask. In the figure, 1 is a silicon substrate, 2 is an epitaxial layer, 5 is a gold layer, 8 is a polyimide film, 9 is a frame member, 10 is a first XPs absorption pattern, 11 is a nodist pattern, 1
2 is the second X-leg absorption pattern. Note that the same symbols in each factor indicate the same or similar parts. Agent: Masuo Oiwa (2 others) Figure 1 (a) 8: Polii Shikaku Fake (b) 9: Ikuji Figure 1 (C) 12: Man 2 entry - σλν turn 2 Figure 3 (a) Figure 3) Procedural amendment (spontaneous) 1. Indication of case Patent application No. 5O-2B7841] No. 2
, Title of the invention Claims column of the specification and Detailed Description of the Invention Box 6, Contents of amendment (1) The claims of the specification are amended as shown in the attached sheet. (2) Delete "at each of a plurality of wavelengths" in line 2 of page 4 of the specification. (3) Also delete "by each of a plurality of wavelengths" on page 7, line 18. (4) Similarly, "2 steps" on page 8, line 3, is corrected to "multiple steps." 2. Claims X-ray exposure characterized in that a plurality of X-ray absorption patterns are formed on the same surface or in a plurality of layers using materials having different X-ray absorption rates in - on the X-ray transmission layer. mask.

Claims (1)

【特許請求の範囲】[Claims] X線透過層上に複数の各波長におけるX線吸収率の異な
る物質で複数のX線吸収パターンを同一平面上または複
数層状に形成したことを特徴とするX線露光用マスク。
1. An X-ray exposure mask characterized in that a plurality of X-ray absorption patterns are formed on the same plane or in a plurality of layers using materials having different X-ray absorption rates at a plurality of wavelengths on an X-ray transmission layer.
JP59267949A 1984-12-17 1984-12-17 X-ray exposure mask Pending JPS61143757A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59267949A JPS61143757A (en) 1984-12-17 1984-12-17 X-ray exposure mask

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59267949A JPS61143757A (en) 1984-12-17 1984-12-17 X-ray exposure mask

Publications (1)

Publication Number Publication Date
JPS61143757A true JPS61143757A (en) 1986-07-01

Family

ID=17451834

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59267949A Pending JPS61143757A (en) 1984-12-17 1984-12-17 X-ray exposure mask

Country Status (1)

Country Link
JP (1) JPS61143757A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4895779A (en) * 1986-09-20 1990-01-23 Mitsubishi Denki Kabushiki Kaisha Method of forming a T shaped control electrode through an X-ray mask
JPH09306807A (en) * 1996-05-14 1997-11-28 Canon Inc Manufacture of x-ray exposing mask structure

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5789221A (en) * 1980-11-25 1982-06-03 Seiko Epson Corp Multiple mask

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5789221A (en) * 1980-11-25 1982-06-03 Seiko Epson Corp Multiple mask

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4895779A (en) * 1986-09-20 1990-01-23 Mitsubishi Denki Kabushiki Kaisha Method of forming a T shaped control electrode through an X-ray mask
JPH09306807A (en) * 1996-05-14 1997-11-28 Canon Inc Manufacture of x-ray exposing mask structure

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