JPS61142739A - Manufacture of semiconductor device - Google Patents

Manufacture of semiconductor device

Info

Publication number
JPS61142739A
JPS61142739A JP26441984A JP26441984A JPS61142739A JP S61142739 A JPS61142739 A JP S61142739A JP 26441984 A JP26441984 A JP 26441984A JP 26441984 A JP26441984 A JP 26441984A JP S61142739 A JPS61142739 A JP S61142739A
Authority
JP
Japan
Prior art keywords
film
metal
layer
substrate
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP26441984A
Other languages
Japanese (ja)
Inventor
Shigeya Mori
森 重哉
Shohei Shima
昇平 嶋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP26441984A priority Critical patent/JPS61142739A/en
Publication of JPS61142739A publication Critical patent/JPS61142739A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

PURPOSE:To implement a highly reliable electrode, by forming a high melting point metal layer on an insulating film and on the surface of a contact hole part, thereafter forming a nitride metal from the surface of the metal by heat treatment, forming silicide at the interface of the metal and a substrate, and then forming a wiring metal on the nitride metal. CONSTITUTION:A diffused layer 2 is formed on an Si substrate, and a P-N junction is formed. Then, an oxide film 3 is provided on the surface of the Si substrate. A contact hole is provided in the oxide film 3 on the diffused layer 2. Ti is deposited on the entire surface, and a Ti film 4 is formed. Then, the substrate 1 is heated, and a titanium nitride film 6 is formed on the surface of the Ti film 4. At the same time, a titanium silicide layer 5 is formed at the interface between the Ti film 4 and the substrate Si. An Al wiring metal film 7 is formed on the entire surface of the titanium nitride film 6. Thereafter, the Al wiring metal film 7 and the Ti film 4 are continuously etched, and a wiring pattern is formed. In this multilayer structure, resistance becomes low. Since the titanium nitride layer 6 is formed, high contact resistance with the Al wiring metal layer 7 can be prevented.

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明は、半導体装置の製造方法に関し、特に基体と配
線金属の間に珪化金属、高融点金属、窒化金属の層を介
在させた信頼性の高い電極の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a method for manufacturing a semiconductor device, and in particular to a method for manufacturing a semiconductor device, in particular a method for improving reliability by interposing a layer of a metal silicide, a high melting point metal, or a metal nitride between a substrate and a wiring metal. This invention relates to a method for manufacturing high-quality electrodes.

〔発明の技術的背景とその問題点〕[Technical background of the invention and its problems]

一般に、半導体基体上に形成される配線金属としては、
アルミニウム又はアルミニウムーシリコン合金が用いら
れている。しかし、アルミニウムを配線金属として用い
九場合、通常の素子製造工程における熱処理にともなう
温度上昇により、浅い不純物拡散層を有するトランジス
タま九はICにおいては、アルミニウムと基板シリコン
との反応によるアルミニウムの基板シリコンへの侵入が
この浅い拡散層による接合を破壊する恐れがある。
In general, wiring metals formed on semiconductor substrates include:
Aluminum or aluminum-silicon alloys are used. However, when aluminum is used as a wiring metal, transistors with shallow impurity diffusion layers due to the temperature rise associated with heat treatment in the normal device manufacturing process are difficult to manufacture. There is a risk that the intrusion into the shallow diffusion layer may destroy the junction formed by this shallow diffusion layer.

上記の如きアルミニウムとシリコンとの反応を防止する
手段として、従来アルミニウム配線層と基板シリコンと
の間に、チタン、モリブデン、タングステン等の高融点
金属層を設けることが行なわれている。
As a means for preventing the reaction between aluminum and silicon as described above, conventionally, a high melting point metal layer such as titanium, molybdenum, tungsten, etc. is provided between the aluminum wiring layer and the silicon substrate.

しかし、この方法においては高融点金属と配線材料であ
るアルミニウム、および基板を構成するシリコンとが低
温で反応しtす、高融点金属表面が酸化されfclpし
て電極特性の安定性に対して問題があう九〇 〔発明の目的〕 本発明は上記の様な従来技術の欠点を改良したもので、
安定で低抵抗のコンタクト電極を有する半導体装置を提
供することを目的とする。
However, in this method, the high melting point metal, aluminum that is the wiring material, and silicon that makes up the substrate react at low temperatures, and the surface of the high melting point metal is oxidized and fclp, which causes problems with the stability of the electrode characteristics. 90 [Object of the Invention] The present invention improves the drawbacks of the prior art as described above.
An object of the present invention is to provide a semiconductor device having a stable and low-resistance contact electrode.

〔発明の概要〕[Summary of the invention]

上記目的を達成せしめる九め、本発明の半導体装置の製
造方法によれば、絶縁膜上およびコンタクト開孔部表面
上に高融点金属層を形成後、窒素雰囲気中で熱処理(例
えば400〜800℃)して金属表面を窒化金属にする
と共に金属と半導体界面をシリサイド化し、次に上記窒
化金属上に配線金属を形成して配線路を形成する。
Ninth to achieve the above object, according to the method of manufacturing a semiconductor device of the present invention, after forming a high melting point metal layer on the insulating film and the surface of the contact opening, heat treatment (for example, 400 to 800 ° C. ) to make the metal surface a metal nitride and silicide the interface between the metal and the semiconductor, and then form a wiring metal on the metal nitride to form a wiring path.

〔発明の効果〕〔Effect of the invention〕

本発明により、電極配線の低抵抗化が達成され、アルミ
ニウムと高融点金属との反応が抑えられ高温熱処理にお
いても安定した電極特性を維持できる信頼性の高い電極
を実現できる。
According to the present invention, it is possible to achieve a low resistance of electrode wiring, to suppress the reaction between aluminum and a high-melting point metal, and to realize a highly reliable electrode that can maintain stable electrode characteristics even during high-temperature heat treatment.

〔発明の実施例〕[Embodiments of the invention]

以下、本発明の詳細を一実施例に従って説明する。第1
図(a)〜(d)は、本発明てよる半導体装置の製造方
法の一実施例を示す工程断面図である。先ず通常の方法
によυシリコン基体1に所定不純物を拡散して拡散層2
を形成してPN接合を形成する。次にシリコン基板10
表面にシリコン酸化膜3を設け、更にフォトレジスト法
により拡散層2上のシリコン酸化膜3を選択的に除去し
てシリコン酸化膜3にコンタクトホールを設ける。
Hereinafter, details of the present invention will be explained according to one embodiment. 1st
Figures (a) to (d) are process cross-sectional views showing one embodiment of the method for manufacturing a semiconductor device according to the present invention. First, a predetermined impurity is diffused into the υ silicon substrate 1 using a normal method to form a diffusion layer 2.
is formed to form a PN junction. Next, the silicon substrate 10
A silicon oxide film 3 is provided on the surface, and the silicon oxide film 3 on the diffusion layer 2 is selectively removed using a photoresist method to form a contact hole in the silicon oxide film 3.

次に、通常のスパッタリング装置で全面にチタン(Ti
)をスパッタリングによシ被着し、500〜zoooi
のチタン膜4を形成する。
Next, the entire surface is coated with titanium (Ti) using a normal sputtering device.
) by sputtering, and
A titanium film 4 is formed.

次に、この基板lを400〜800℃で約30分糧度窒
素雰囲気中で加熱処理してチタン膜4の表面にチタンナ
イトライド膜6を形成せしめると同時にチタン膜4と基
板シリフンの界面にチタンシリサイド層5を形成せしめ
る。
Next, this substrate 1 is heat-treated at 400 to 800°C for about 30 minutes in a nitrogen atmosphere to form a titanium nitride film 6 on the surface of the titanium film 4, and at the same time to form a titanium nitride film 6 at the interface between the titanium film 4 and the substrate silicon. A titanium silicide layer 5 is formed.

次にこのチタンナイトライド膜6上全面に、通常のスパ
ッタリング法により、厚さ8000にのアルミニウム配
線金属膜7を形成する。
Next, an aluminum wiring metal film 7 having a thickness of 8000 mm is formed on the entire surface of the titanium nitride film 6 by a normal sputtering method.

ソノ後エツチングによりアルミニウム配線金属膜7とそ
の下のチタン膜4を連続的にエツチングし配線パター/
を形成する。
After etching, the aluminum wiring metal film 7 and the titanium film 4 underneath are continuously etched to form a wiring pattern/
form.

このようにシリコン基板上にチタンシリサイド層5、チ
タン層4、チタンナイトライド層6、アルミニウム配線
金属層7の多層構造にすることにより、チタン、アルミ
ニウム配線金属層の二層構造よシ低抵抗にな夛、またチ
タン層4とアルミニウム配線金属層7がチタンナイトラ
イド層6により分離されているためチタン層4とアルミ
ニウム配線金属層7の反応がおさえられる。さらにチタ
ンナイトライド層6を形成したことにより、チタン層4
0表面酸化がおさえられ、表面酸化膜によるアルミニウ
ム配線金属層7との高接触抵抗化が防止できる。
By creating a multilayer structure of the titanium silicide layer 5, titanium layer 4, titanium nitride layer 6, and aluminum wiring metal layer 7 on the silicon substrate in this way, the resistance is lower than that of the two-layer structure of titanium and aluminum wiring metal layers. Moreover, since the titanium layer 4 and the aluminum wiring metal layer 7 are separated by the titanium nitride layer 6, the reaction between the titanium layer 4 and the aluminum wiring metal layer 7 is suppressed. Furthermore, by forming the titanium nitride layer 6, the titanium layer 4
0 surface oxidation is suppressed, and high contact resistance with the aluminum wiring metal layer 7 due to the surface oxide film can be prevented.

なお、シリコン基板1上に形成する高融点金属層4は、
チタンに限る必要がなく、モリブデン、タングステン、
タンタルを用いても同様の効果が期待できる。またチタ
ン層の厚さは数百え程度あれば良〈実施例に示し北範囲
が適当である。アルミニウム配線金属膜7は、実施例の
如(8000Aの厚さにする必要はなく、配線の電流容
量などによシ適宜変えてかまわない。ま几配線材料とし
てアルミニウム以外の例えばアルミニウムシリサイド等
のものを用いてもよい。基板1はシリコy&c限らずG
aAsで構成してもよいし、 8o8構造であってもよ
い。
Note that the high melting point metal layer 4 formed on the silicon substrate 1 is
There is no need to limit it to titanium, but molybdenum, tungsten,
A similar effect can be expected by using tantalum. Further, the thickness of the titanium layer should be about several hundred digits (the northern range shown in the example is suitable). The aluminum wiring metal film 7 does not need to have a thickness of 8000 A as in the embodiment, and may be changed as appropriate depending on the current capacity of the wiring, etc. The wiring material may be made of a material other than aluminum, such as aluminum silicide, etc. The substrate 1 may be made of not only silico Y&C but also G
It may be composed of aAs or may have an 8o8 structure.

以上説明した如く、本発明は半導体装置の電極部分に低
抵抗のコンタクトを形成することができ、tx高融点金
属と配線金属の反応がかさえられ、この構造にするとと
くより信頼性を向上させることができる。
As explained above, the present invention makes it possible to form a low-resistance contact in the electrode portion of a semiconductor device, suppresses the reaction between the tx high melting point metal and the wiring metal, and particularly improves reliability with this structure. be able to.

【図面の簡単な説明】[Brief explanation of drawings]

第1図(a)〜(d)は本発明の一実施例を示す製造工
程断面図である。 1・・・シリコン半導体基板、2・・・不純物拡散層、
3・・・二酸化シリコン膜、4・・・チタン層、5・・
・チタンシリサイド膜、6・・・チタンナイトライド0
膜、7・・・アルミニウム配線金属膜。
FIGS. 1(a) to 1(d) are sectional views showing manufacturing steps of an embodiment of the present invention. 1... Silicon semiconductor substrate, 2... Impurity diffusion layer,
3... Silicon dioxide film, 4... Titanium layer, 5...
・Titanium silicide film, 6...Titanium nitride 0
Film, 7... Aluminum wiring metal film.

Claims (1)

【特許請求の範囲】[Claims]  基体の半導体表面に絶縁膜を形成し前記半導体表面に
達する所要コンタクトホールを上記絶縁膜に形成する工
程と、上記絶縁膜上および上記コンタクトホールに露出
する上記半導体表面上に高融点金属膜を形成する工程と
、窒素雰囲気中で熱処理することにより上記金属表面を
窒化化合物に変換するとともに、上記金属と上記半導体
界面に金属シリサイド膜を形成する工程と、上記窒化化
合物上に配線層を形成する工程とを有することを特徴と
する半導体装置の製造方法。
forming an insulating film on the semiconductor surface of the base body and forming a required contact hole in the insulating film reaching the semiconductor surface; and forming a high melting point metal film on the insulating film and on the semiconductor surface exposed to the contact hole. a step of converting the metal surface into a nitride compound by heat treatment in a nitrogen atmosphere and forming a metal silicide film at the interface between the metal and the semiconductor; and a step of forming a wiring layer on the nitride compound. A method for manufacturing a semiconductor device, comprising:
JP26441984A 1984-12-17 1984-12-17 Manufacture of semiconductor device Pending JPS61142739A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26441984A JPS61142739A (en) 1984-12-17 1984-12-17 Manufacture of semiconductor device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26441984A JPS61142739A (en) 1984-12-17 1984-12-17 Manufacture of semiconductor device

Publications (1)

Publication Number Publication Date
JPS61142739A true JPS61142739A (en) 1986-06-30

Family

ID=17402908

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26441984A Pending JPS61142739A (en) 1984-12-17 1984-12-17 Manufacture of semiconductor device

Country Status (1)

Country Link
JP (1) JPS61142739A (en)

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61183942A (en) * 1985-02-08 1986-08-16 Fujitsu Ltd Manufacture of semiconductor device
JPS61212041A (en) * 1985-03-18 1986-09-20 Hitachi Ltd Formation of metal silicide electrode and wiring
JPS6232610A (en) * 1985-08-05 1987-02-12 Fujitsu Ltd Manufacture of semiconductor device
JPS6384024A (en) * 1986-09-26 1988-04-14 Seiko Epson Corp Manufacture of semiconductor device
JPS63175420A (en) * 1987-01-14 1988-07-19 Nec Corp Manufacture of semiconductor device
JPS63193522A (en) * 1987-02-05 1988-08-10 Nec Corp Manufacture of semiconductor device
EP0279588A2 (en) * 1987-02-19 1988-08-24 Advanced Micro Devices, Inc. Contact in a contact hole in a semiconductor and method of producing same
US4811078A (en) * 1985-05-01 1989-03-07 Texas Instruments Incorporated Integrated circuit device and process with tin capacitors
US4811076A (en) * 1985-05-01 1989-03-07 Texas Instruments Incorporated Device and process with doubled capacitors
JPH01298765A (en) * 1988-05-27 1989-12-01 Fujitsu Ltd Semiconductor device and manufacture thereof
US4890141A (en) * 1985-05-01 1989-12-26 Texas Instruments Incorporated CMOS device with both p+ and n+ gates
US4894693A (en) * 1985-05-01 1990-01-16 Tigelaar Howard L Single-polysilicon dram device and process
JPH02238246A (en) * 1989-03-09 1990-09-20 Tokyo Gas Co Ltd Hot-water/water supply device
US4960732A (en) * 1987-02-19 1990-10-02 Advanced Micro Devices, Inc. Contact plug and interconnect employing a barrier lining and a backfilled conductor material
JPH04296020A (en) * 1991-03-25 1992-10-20 Nec Corp Semiconductor device and manufactuer thereof
JPH0582772A (en) * 1991-09-20 1993-04-02 Mitsubishi Electric Corp Semiconductor device and its manufacture
US5371041A (en) * 1988-02-11 1994-12-06 Sgs-Thomson Microelectronics, Inc. Method for forming a contact/VIA
US5374592A (en) * 1992-09-22 1994-12-20 Sgs-Thomson Microelectronics, Inc. Method for forming an aluminum metal contact
US5395795A (en) * 1991-04-09 1995-03-07 Samsung Electronics Co., Ltd. Method for fabricating a semiconductor device
US5472912A (en) * 1989-11-30 1995-12-05 Sgs-Thomson Microelectronics, Inc. Method of making an integrated circuit structure by using a non-conductive plug
US5658828A (en) * 1989-11-30 1997-08-19 Sgs-Thomson Microelectronics, Inc. Method for forming an aluminum contact through an insulating layer
US5930673A (en) * 1990-11-05 1999-07-27 Stmicroelectronics, Inc. Method for forming a metal contact
US6242811B1 (en) 1989-11-30 2001-06-05 Stmicroelectronics, Inc. Interlevel contact including aluminum-refractory metal alloy formed during aluminum deposition at an elevated temperature
US6271137B1 (en) 1989-11-30 2001-08-07 Stmicroelectronics, Inc. Method of producing an aluminum stacked contact/via for multilayer
US6278150B1 (en) 1996-09-05 2001-08-21 Mitsubishi Denki Kabushiki Kaisha Conductive layer connecting structure and method of manufacturing the same
US6287963B1 (en) 1990-11-05 2001-09-11 Stmicroelectronics, Inc. Method for forming a metal contact
US6617242B1 (en) * 1989-11-30 2003-09-09 Stmicroelectronics, Inc. Method for fabricating interlevel contacts of aluminum/refractory metal alloys

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61183942A (en) * 1985-02-08 1986-08-16 Fujitsu Ltd Manufacture of semiconductor device
JPS61212041A (en) * 1985-03-18 1986-09-20 Hitachi Ltd Formation of metal silicide electrode and wiring
US4811078A (en) * 1985-05-01 1989-03-07 Texas Instruments Incorporated Integrated circuit device and process with tin capacitors
US4894693A (en) * 1985-05-01 1990-01-16 Tigelaar Howard L Single-polysilicon dram device and process
US4890141A (en) * 1985-05-01 1989-12-26 Texas Instruments Incorporated CMOS device with both p+ and n+ gates
US4811076A (en) * 1985-05-01 1989-03-07 Texas Instruments Incorporated Device and process with doubled capacitors
JPS6232610A (en) * 1985-08-05 1987-02-12 Fujitsu Ltd Manufacture of semiconductor device
JPS6384024A (en) * 1986-09-26 1988-04-14 Seiko Epson Corp Manufacture of semiconductor device
JPS63175420A (en) * 1987-01-14 1988-07-19 Nec Corp Manufacture of semiconductor device
JPS63193522A (en) * 1987-02-05 1988-08-10 Nec Corp Manufacture of semiconductor device
EP0279588A2 (en) * 1987-02-19 1988-08-24 Advanced Micro Devices, Inc. Contact in a contact hole in a semiconductor and method of producing same
US4960732A (en) * 1987-02-19 1990-10-02 Advanced Micro Devices, Inc. Contact plug and interconnect employing a barrier lining and a backfilled conductor material
US5371041A (en) * 1988-02-11 1994-12-06 Sgs-Thomson Microelectronics, Inc. Method for forming a contact/VIA
US5512516A (en) * 1988-05-27 1996-04-30 Fujitsu Limited Contact structure for connecting an electrode to a semiconductor device and a method of forming the same
US5384485A (en) * 1988-05-27 1995-01-24 Fujitsu Limited Contact structure for connecting an electrode to a semiconductor
JPH01298765A (en) * 1988-05-27 1989-12-01 Fujitsu Ltd Semiconductor device and manufacture thereof
JPH02238246A (en) * 1989-03-09 1990-09-20 Tokyo Gas Co Ltd Hot-water/water supply device
US5658828A (en) * 1989-11-30 1997-08-19 Sgs-Thomson Microelectronics, Inc. Method for forming an aluminum contact through an insulating layer
US5472912A (en) * 1989-11-30 1995-12-05 Sgs-Thomson Microelectronics, Inc. Method of making an integrated circuit structure by using a non-conductive plug
US6617242B1 (en) * 1989-11-30 2003-09-09 Stmicroelectronics, Inc. Method for fabricating interlevel contacts of aluminum/refractory metal alloys
US5976969A (en) * 1989-11-30 1999-11-02 Stmicroelectronics, Inc. Method for forming an aluminum contact
US6242811B1 (en) 1989-11-30 2001-06-05 Stmicroelectronics, Inc. Interlevel contact including aluminum-refractory metal alloy formed during aluminum deposition at an elevated temperature
US6271137B1 (en) 1989-11-30 2001-08-07 Stmicroelectronics, Inc. Method of producing an aluminum stacked contact/via for multilayer
US6287963B1 (en) 1990-11-05 2001-09-11 Stmicroelectronics, Inc. Method for forming a metal contact
US5930673A (en) * 1990-11-05 1999-07-27 Stmicroelectronics, Inc. Method for forming a metal contact
JPH04296020A (en) * 1991-03-25 1992-10-20 Nec Corp Semiconductor device and manufactuer thereof
US5395795A (en) * 1991-04-09 1995-03-07 Samsung Electronics Co., Ltd. Method for fabricating a semiconductor device
JPH0582772A (en) * 1991-09-20 1993-04-02 Mitsubishi Electric Corp Semiconductor device and its manufacture
US5374592A (en) * 1992-09-22 1994-12-20 Sgs-Thomson Microelectronics, Inc. Method for forming an aluminum metal contact
US6433435B2 (en) 1993-11-30 2002-08-13 Stmicroelectronics, Inc. Aluminum contact structure for integrated circuits
US6278150B1 (en) 1996-09-05 2001-08-21 Mitsubishi Denki Kabushiki Kaisha Conductive layer connecting structure and method of manufacturing the same

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