JPS608098B2 - Method and equipment for continuous production of milk chocolate - Google Patents

Method and equipment for continuous production of milk chocolate

Info

Publication number
JPS608098B2
JPS608098B2 JP51025642A JP2564276A JPS608098B2 JP S608098 B2 JPS608098 B2 JP S608098B2 JP 51025642 A JP51025642 A JP 51025642A JP 2564276 A JP2564276 A JP 2564276A JP S608098 B2 JPS608098 B2 JP S608098B2
Authority
JP
Japan
Prior art keywords
batch
continuously
sugar
mixing
thin layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP51025642A
Other languages
Japanese (ja)
Other versions
JPS51112560A (en
Inventor
アルミン・シユミツト
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MASHIINENFUABURIIKU YOTSUTO ESU PETSUHORUTO
Original Assignee
MASHIINENFUABURIIKU YOTSUTO ESU PETSUHORUTO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MASHIINENFUABURIIKU YOTSUTO ESU PETSUHORUTO filed Critical MASHIINENFUABURIIKU YOTSUTO ESU PETSUHORUTO
Publication of JPS51112560A publication Critical patent/JPS51112560A/ja
Publication of JPS608098B2 publication Critical patent/JPS608098B2/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/04Apparatus specially adapted for manufacture or treatment of cocoa or cocoa products
    • A23G1/042Manufacture or treatment of liquid, cream, paste, granule, shred or powder
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/04Apparatus specially adapted for manufacture or treatment of cocoa or cocoa products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/04Apparatus specially adapted for manufacture or treatment of cocoa or cocoa products
    • A23G1/10Mixing apparatus; Roller mills for preparing chocolate

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Confectionery (AREA)

Description

【発明の詳細な説明】 本発明はミルクチョコレートを連続的に製造するため、
樽妙された粉砕カカオニブは微細粉砕されかつ砂糖、レ
シチン、カカオバターおよび粉乳を添加しながら操和さ
れ、磨潰され、均質化されかつ精練される方法ならびに
この方法を実施するための装置に関する。
[Detailed Description of the Invention] The present invention continuously produces milk chocolate.
The present invention relates to a method in which milled ground cocoa nibs are finely ground and milled, milled, homogenized and refined with the addition of sugar, lecithin, cocoa butter and milk powder, and an apparatus for carrying out this method.

ミルクチョコレートに高度の味品質と純正さを与えるた
めには多大な機械費用と時間消費とが必要である、何と
なれば熔妙された破砕カカオニブの微細粉砕、カカオバ
ター、レシチン、砂糖および粉乳の混入、微細磨贋、す
べての成分の均質化および有害喚気の除去のような数加
工段階が必要であり、その場合材料をある加工段階の範
囲においてはバッチごとに処理することは不可避であり
、これは勿論希望される、材料処理の連続的実施に相反
するからである。
In order to give milk chocolate a high degree of taste quality and purity, great mechanical costs and time consumption are required, including the fine grinding of melted crushed cocoa nibs, cocoa butter, lecithin, sugar and milk powder. Several processing steps are necessary, such as contamination, micro-polishing, homogenization of all components and removal of noxious air, in which case it is unavoidable that the material is processed in batches within certain processing steps; This is of course contrary to the desired continuous material processing.

加工経過をおよび長いコンチェ内のタンブリング処理時
間を有利に構成しようという努力は既に行われている。
破砕カカオニブの微細粉砕の直後に有害香料および喚気
物質を駆逐するため連続的薄層処理(西ドイツ特許公報
1557184)の有利な作用を利用する準半連続的方
法によって、完成品の同じ品質を保持しながらコンチェ
内のタンブリング処理時間を約2独特間から8ないし1
幼時間に短縮することができたが、その場合破砕カカオ
ニブは工程順に従って次の機械または装置を通過しなけ
ればならない:予備粉砕機、微細粉砕機、薄層精練処理
装置、連続違和機、磨簿機およびコンチェである。理和
機の前で、すなわち可成り後で添加される粉乳によって
巳むを得ず取り込まれる水ーーこの水は最終成品の中に
は一定の%だけ含有することが許されるーーを再び許容
の率にまで駆逐しかつ同じく粉乳によって取り込まれる
望ましくない香料を駆逐するためにはコンチェ内のタン
ブリング処理はバッチ式に実施されなければならない。
Efforts have already been made to advantageously configure the processing sequence and the tumbling process time in long conches.
The same quality of the finished product is maintained by a quasi-semi-continuous process that takes advantage of the advantageous effect of a continuous thin layer treatment (German Patent Publication 1557184) to eliminate harmful flavorings and arousal substances immediately after the fine grinding of the crushed cocoa nibs. The tumbling process time within the conche varies from approximately 2 to 8 to 1
However, in that case, the crushed cocoa nibs must pass through the following machines or equipment according to the process order: pre-pulverizer, fine-pulverizer, thin-layer scouring equipment, continuous mixing machine, polishing machine, etc. They are a bookkeeping machine and a conche. The water that is inevitably introduced by the milk powder that is added before or after the processing machine, which is only allowed to be present in a certain percentage in the final product, is once again allowed. The tumbling process in the conch must be carried out batchwise in order to eliminate the undesirable flavors introduced by the milk powder.

全動力費用また機械の費用も、従釆の、ただし半連続式
である方法の場合には特に所要のコンチェ使用によって
相当に高い。一方では、比動力の上昇によって所要のコ
ンチェ内のタンブリング処理時間を減少することができ
ることが既に古くから知られているけれ共他方では比動
力(KW/〆)の本質的上昇は構造上の理由によって不
可能であることを知らなければならなかった。カカオ、
砂糖、粉乳およびカカオバターから成る中間材料を先づ
適当な装置によって液状化しかつ続いて薄層精練処理を
受けさせようという可能な方法も思わしい効果をもたら
さない。すなわち広汎な調査によると、かかる処理法は
可能ではあるけれども成果は僅少でありかつしたがって
経済的解決にはならないことが明らかにされた。チョコ
レートの感覚上の特性は薄層処理によって著しくポジチ
ーフの意味に変えられるけれ共、薄層−短時間処理によ
って経済的条件の下でかつ材料の品質損傷無いこ脱水お
よび粘度改良を所望の状態に蓬せさせることはできない
ことを証明することができた。これに対しては材料の中
に既に含まれている砂糖の大なる吸収能力が責任を有す
る。本発明は、今日普通の近代的な製造法に対して少な
くも同じ品質結果および同じ装入館力を有しながらより
僅少動力出費および機械費用で足り、バッチ式混合であ
るが加工工程を連続的に実施することができかつ均質化
過程は所要の、余剰水および有害香料の駆逐によって既
に広汎に軽減されているような方法を創造する課題を基
調とする。
The total power costs as well as the machine costs are considerably high, especially in the case of a subcontinuous, but semi-continuous process, due to the conche use required. On the one hand, it has already been known for a long time that the required tumbling time in conches can be reduced by increasing the specific power; on the other hand, the substantial increase in the specific power (KW/〆) is due to structural reasons. I had to know that it was impossible. cacao,
The possible method of first liquefying the intermediate material consisting of sugar, milk powder and cocoa butter by means of suitable equipment and subsequently subjecting it to a thin layer scouring treatment also does not give the desired effect. Extensive research has shown that although such treatments are possible, the results are marginal and therefore do not represent an economical solution. The sensory properties of chocolate can be significantly changed to a positive meaning by thin-layer treatment, while thin-layer and short-time treatments can achieve the desired dehydration and viscosity improvement under economic conditions and without damaging the quality of the material. I was able to prove that I couldn't let it fall. The large absorption capacity of the sugar already contained in the material is responsible for this. The present invention requires less power and machinery outlays with at least the same quality results and the same charging forces as compared to the modern manufacturing methods common today, and allows the process to be carried out continuously, although with batch mixing. This is based on the task of creating a process which can be carried out to a large extent and in which the homogenization process is already extensively alleviated by the elimination of the necessary excess water and harmful fragrances.

この課題は本発明による冒頭に掲げた種類の方法に基づ
き、連続的交互にバッチ混合またはバッチ操和を受ける
微細粉砕された破砕カカオニブに、この交互のバッチ加
工に際してカカオバターおよび粉乳が添加され、その場
合一つのバッチの混合または操和の間完成混合されたま
たは陸和された他のバッチは連続的に排出されかつ粉乳
を既に含有した材料は連続的に薄層精練機に供給されか
っこの薄層精練機において除湿および除塵のために薄層
精練処理を受け、その場合続いてカカオバター、レシチ
ンおよび砂糖が材料に添加されかつ連続的に交互のバッ
チ均質化を受け、一つのバッチの均質化の時間の間、他
のバッチの完成品は連続的に引き出されることによって
解決される。すなわちこの場合、水分と有害香料を有す
る粉乳がまだ除塵されていないかつ砂糖を混ぜられたカ
カオマスに添加されてこのカカオマスとともに共通して
薄層精練処理を受けることによって、そこから引出され
た材料は一方では既に粉乳を含んでいると共に他方では
余剰水および有害香料を既に広汎に除去されていること
が重要なことであり、この結果として引続く処理段階に
おいてはこれらの排除されるべき成分によっても早や負
荷されていないことになる。完全連続的処理の抵抗とな
る比較的長いコンチェ内のタンプリング処理時間または
精練時間はも早や不必要である。
The object is based on a method of the type mentioned at the outset according to the invention, in which finely ground, crushed cocoa nibs are subjected to continuous alternating batch mixing or batch manipulation, and during this alternating batch processing, cocoa butter and milk powder are added; In that case, during the mixing or working of one batch, the other batches which have been mixed or consolidated are continuously discharged and the material already containing milk powder is continuously fed into the laminar scouring machine. It is subjected to a thin layer scouring process for dehumidification and dust removal in a thin layer scouring machine, where the cocoa butter, lecithin and sugar are subsequently added to the material and subjected to continuous alternating batch homogenization, resulting in homogenization of one batch. During the oxidation time, the finished products of other batches are settled by being drawn out continuously. That is, in this case, the material extracted from the milk powder, which has moisture and harmful flavorings, is added to the cocoa mass which has not yet been dedusted and has been mixed with sugar and is commonly subjected to a thin layer scouring process together with this cocoa mass. It is important that, on the one hand, it already contains milk powder and, on the other hand, that it has already been extensively removed from excess water and harmful flavorings, so that in the subsequent processing steps, even these components to be excluded are It means that it is no longer under load. Relatively long tampling or scouring times in conches, which would hinder fully continuous processing, are no longer necessary.

この本発明による処理にとって必要な機械費用、すなわ
ちなお詳述される交互に稼動する2個のミキサーまたは
強力精練機は一見比較的大に見えるけれども、一方では
ミキサーはコンチェのようにはコスト的にまたは動力消
費上では大ではなく、他方では公知のおよび前述の半蓮
競的方法の場合、相応する全設備の連続的に作業する部
分が持続的に運転される時1個のコンチェだけでは不足
である。最後の精練段の後では材料は有利に静的ミキサ
ー(西ドイツ特許公報2130134)を通過させられ
る。本方法の実施のための装置は予備粉砕機、微細粉砕
機、2個の交互に稼動するミキサー、薄層精練処理装置
(西ドイツ特許公報1537184)、連続梶和機、砂
糖粉砕機、磨濃機、ボールミルなどおよび場合によって
は静的ミキサー(西ドイツ特許公報2130134)か
ら成っている。
Although the mechanical costs required for this process according to the invention, i.e. the two alternating mixers or high-power scouring machines described in further detail, seem relatively large at first glance, mixers, like conches, are cost-effective. or not large in terms of power consumption; on the other hand, in the case of the known and above-mentioned semi-competitive methods, one conch is not enough when the continuously working parts of the entire corresponding installation are operated continuously. It is. After the last scouring stage, the material is preferably passed through a static mixer (DE 21 30 134). The equipment for carrying out the process includes a pre-grinding mill, a fine grinding mill, two alternating mixers, a thin layer scouring device (West German Patent Publication No. 1537184), a continuous scouring machine, a sugar grinding machine, a polishing machine. , ball mills etc. and possibly static mixers (DE 2130134).

ミキサーにいたるまで公知のこの装置および機械の配設
は本発明により、薄層精練機には、交互に連続的に装入
可能および排出可能のミキサ−が前直されかつ相応して
作業しかつ形成されたミキサーが、連続理和機、および
磨潰機、ボールミルなどのような少なくも微細粉砕機を
中間接続して後直されているように配設される。
According to the invention, this arrangement of devices and machines, which is known up to the mixer, is such that the thin-layer scouring machine has mixers which can be charged and discharged in succession alternately and which work accordingly. The formed mixer is arranged to be rearranged with a continuous reducer and at least a fine grinder, such as an attritor, a ball mill, etc., interposed therebetween.

ミキサーは特に、混合要素および操和要素を具備した2
個の混合槽が装入導管および排出導管と切換可能の連結
されているように形成されており、その場合混合槽は荷
重表示要素の上に装置されている。
The mixer is in particular a two-piece mixer comprising a mixing element and a manipulating element.
A mixing tank is designed in switchable connection with the charging line and the discharge line, the mixing tank being arranged above the load indicating element.

連続理和機の代りに相応のミキサーを使用することもで
き、これは、装置の中には一つのミキサー型だけが使用
されるという利点を有する。味要求および品質要求に応
じて砂糖は微細磨債機(ローフー、ポールミルなど)の
前または後で添加されることができ、その場合砂糖は後
から添加される場合には勿論前もって最終微細度にされ
ていなければならず、ただしこれは味に対してある程度
の影響を及ぼすことがある、すなわち完全に挽き〈だか
れた砂糖は他の味ニュアンスを生ずるからである。出発
製品として利用されるカカオの産地と品種によってはカ
カオは強い酸性であることがあり、この場合にはその強
い酸性のカカオが望ましくない方法でミルク蛋白質と反
応し最終成品の味に対して不満足な結果を生ずるという
危険がある。
Instead of a continuous ricer, it is also possible to use a corresponding mixer, which has the advantage that only one mixer type is used in the device. Depending on the taste and quality requirements, the sugar can be added before or after the fine grinding machine (lohu, pole mill, etc.), in which case the sugar is of course brought to the final fineness beforehand if it is added later. However, this may have a certain influence on the taste, as fully ground sugar gives rise to other taste nuances. Depending on the origin and variety of cocoa used as the starting product, the cocoa may be highly acidic, which can react with milk proteins in an undesirable manner and result in an unsatisfactory taste of the final product. There is a danger that this could lead to negative consequences.

この難点に対しても本発明による方法は単一材料の案内
において僅かだけ相違して適応する有利な適用可能性を
提供しており、すなわちカカオバターおよび粉乳はバッ
チ混合またはバッチ操和を受けかつ混合および理和の間
一つのバッチは薄層精練機の第1段および第2段に供給
され、かつ同時に第3段には微細粉砕された破砕カカオ
ニブが連続的供給され、その場合レシチンおよび微細粉
砕された砂糖は、混合された、薄層精練機の中で脱水さ
れかつ有害喚気を除去された中間材料の中に混入されか
つ中間材料とともに理和されかつ続いて微細に磨潰され
かっこの中間材料はカカオマスと併せてカカオバターを
添加しながらバッチ混合またはバッチ損和を受け、その
場合一つのバッチの混合の間完成混合された他のバッチ
は連続的に排出されかつ次の加工に供給される。既に最
終微細度に粉砕された破砕カカオニブから、またはまだ
最終微細度には粉砕されていない破砕カカオニブから出
発するかに応じて、後者の場合には本方法は、カカオマ
スは薄層精練機の第3段階を通過後砂糖およびレシチン
と同時に「薄層精練機の第2段から連続的に搬出される
、カカオバターと粉乳とから成る材料に混合されかつ連
続的に理和されかつ続いて微細に磨潰されるように実施
され、また前者の場合には、最終微細度に粉砕されたカ
カオマスは薄層精練機の第3段を通過後カカオバター、
粉乳、砂糖およびレシチンから成り理和されたかつ微細
にすりつぶされた材料に連続的に供給されかっこの材料
とともに続いてバッチ混合またはバッチ操和を受けるよ
うに実施される。
Even in view of this drawback, the method according to the invention offers advantageous applicability with slightly different adaptation in the guidance of single ingredients, namely cocoa butter and milk powder subjected to batch mixing or batch manipulation. During mixing and consolidation, one batch is fed to the first and second stages of the thin layer smelter, and at the same time the third stage is continuously fed with finely ground and crushed cocoa nibs, in which case lecithin and finely ground cocoa nibs are continuously fed into the third stage. The ground sugar is mixed into the dehydrated and dehydrated intermediate material in a laminar scouring machine and is mixed with the intermediate material and subsequently ground to a fine grain to form parentheses. The intermediate material is subjected to batch mixing or batch loss with the addition of cocoa butter together with the cocoa mass, in which case during the mixing of one batch the finished mixed batch of the other batch is continuously discharged and fed to the next processing. be done. Depending on whether one starts from crushed cocoa nibs that have already been ground to the final fineness or from crushed cocoa nibs that have not yet been ground to the final fineness, in the latter case the method may After passing through the three stages, sugar and lecithin are mixed together with the material consisting of cocoa butter and milk powder, which is continuously discharged from the second stage of the thin layer scouring machine, and are continuously smelted and subsequently finely divided. In the former case, the cocoa mass ground to the final fineness is processed into cocoa butter after passing through the third stage of the thin layer scouring machine.
The process is such that the blended and finely ground ingredients consisting of milk powder, sugar and lecithin are continuously fed and subsequently subjected to batch mixing or batch manipulation with parenteral ingredients.

以下図面に表わされた実施例によって、本発明の方法、
その実施のための装置および本方法により達成可能の利
点を詳述する。
The method of the present invention will be explained below by way of an embodiment represented in the drawings.
The apparatus for its implementation and the advantages achievable by the method are detailed.

第1図によると熔妙されかつ予備破砕されたカカオニブ
は予備粉砕機1および微細粉砕機2の中で粉砕される。
According to FIG. 1, the melted and pre-crushed cocoa nibs are ground in a pre-mill 1 and a fine grinder 2.

微細粉砕機2から材料はミキサー3の混合槽9の中にい
たる、その場合同時に材料は他の混合槽内の材料の処理
の間連続的に夫々他の混合槽9から引き出される。微細
に磨潰されたカカオには図示されていない配量要素によ
ってカカオバターおよび粉乳が添加される。カカオ、カ
カオバターおよび粉乳から成りかつ混合完了された材料
は3個の薄層精練機から成る薄層精練処理装置4の中に
送られ、ここでカカオや粉乳が含んでいる余剰水および
有害香料が既に次の処理は不必要な位広汎に除去される
。混合槽から連続して排出される間に他の混合槽の中で
は既に混合が行われている。カカオバターおよびレシチ
ンの次の添加およびこれらとカカオとの混合は連続的に
作業する控和機5によって行われ、混合機の中へは砂糖
粉砕機6によって粉砕された砂糖をも添加することがで
きる。
From the fine grinder 2 the material passes into the mixing tank 9 of the mixer 3, with the material simultaneously being drawn off from each other mixing tank 9 continuously during the processing of the material in the other mixing tank. Cocoa butter and milk powder are added to the finely ground cocoa by means of dosing elements (not shown). The mixed material consisting of cocoa, cocoa butter and milk powder is sent into a thin layer scouring device 4 consisting of three thin layer scouring machines, where it removes excess water and harmful flavors contained in the cocoa and milk powder. But already the following processing is unnecessary and extensively eliminated. During the continuous discharge from the mixing tank, mixing is already taking place in other mixing tanks. The subsequent addition of cocoa butter and lecithin and their mixing with the cocoa takes place in a continuously working attenuator 5, into which it is also possible to add the ground sugar by means of a sugar grinder 6. can.

操和機5の代りに第4図による適当のミキサーを利用す
ることもできる。ただし既に所要に応じて最終微細度に
された砂糖をロール磨債機7を回避して(設備Dに)、
点線で示唆されている如くミキサー3「に入れることも
できる。
Instead of the mixer 5, a suitable mixer according to FIG. 4 can also be used. However, the sugar, which has already been made to the final fineness as required, bypasses the roll bonding machine 7 (to equipment D).
It can also be placed in mixer 3' as suggested by the dotted line.

すなわち砂糖は既に最終微細度に粉砕されているこの変
形の場合には操和機5を省略することができる。理和機
5から来る材料はロール磨債機7を経て同じく交互に稼
動するミキサー3′に達し、ミキサーからは、他の混和
槽9の中で処理時間の間完成品の連続的排出が行われる
。個々の装置および機械を通過した量は比較のため例と
してフローチャートによって表示されている。ミキサー
3′の後方にはなお静的ミキサー8が後直されている。
この方法によって達成可能の進歩を明瞭にするため第2
,3図には従来の方法と半連続的方法(両者とも公知)
が表わされている。比較する場合次のようになる。
Thus, in this variant, where the sugar has already been ground to the final fineness, the mixer 5 can be omitted. The material coming from the mixing machine 5 passes through a roll grinding machine 7 to a mixer 3' which also operates alternately, from which the finished product is continuously discharged during the processing time in another mixing tank 9. be exposed. The quantities passed through the individual devices and machines are shown by example flowcharts for comparison. A static mixer 8 is also mounted behind the mixer 3'.
In order to clarify the progress that can be achieved by this method, the second
, Figure 3 shows the conventional method and the semi-continuous method (both known).
is represented. The comparison will look like this:

例として次の処方が想定される。As an example, the following prescription is assumed.

12% カカオマス 18% カカオバター 50% 砂糖 20% 全粉乳 100% 原料チョコレート 4種の製造方法が比較される、すなわち 凶 従来の方法 【B)半連続的方法 【C)新しい方法 ■ 粉砕機6において砂糖を最終微細度に粉砕する新し
い方法。
12% Cocoa mass 18% Cocoa butter 50% Sugar 20% Whole milk powder 100% Four types of raw chocolate manufacturing methods are compared, namely: Conventional method [B) Semi-continuous method [C) New method ■ In crusher 6 A new method of grinding sugar to its final fineness.

新しい方法【C}によって作業する装置はれ/h=48
/日の袋入用に構成されている。
Equipment working according to the new method [C} / h = 48
Configured for /day bag storage.

設備■,(B}および【qは同一の1日生産量を有する
。装置■に比べて機械が節減(一)されまた余分(十)
に必要とされる関係は装置‘B} (一)8コンチェ・・・各コンチェの全充填量丸(十)
1薄層精練機4…各機1000k9/h装置【q(一)
3ロール磨濃・・・各機500k9/h(十)1薄層精
練機4・・・各機1000k9/h(一)50%操和容
器(t/hからa/hへ)(十)2ミキサー3,3′・
・・各機が/h(−)16コンチェ・・・各コンチェX
充填量(十)1静的ミキサー8・・・各ミキサー公/h
(十)1中圧質量ポンプ16…各ポンプ 公ノh 設備 皿 (一)6ロール磨濃・・・谷機500k9/h(十)1
薄層精練機16・・・各機公ノh(一)1混合機・・・
各機 t/h (十)2ミキサー3,3′…各ミキサー が/h (一)1コンチエ (十)1定置ミキサー8・・・各ミキサー公/h(十)
1中圧質量ポンプ16…各ポンプ a/h 投資費については次の関係が生ずる: A:B:C:D=3.4:2.7:1.6:1すなわち
例えば装置■は装置{D)に比べて3.4倍の投資費を
必要とするが、この場合風,‘B},〔CI,‘D’の
順序に減少するスペース費は顧慮されていない。
Equipment ■, (B} and [q have the same daily production volume. Compared with equipment ■, the machine is saved (1) and is redundant (10).
The relationship required for this is device 'B} (1) 8 conches...total filling amount of each conche (10 circles)
1 Thin layer scouring machine 4...Each machine 1000k9/h device [q (1)
3 roll scouring machines...500k9/h (10) each machine 1 thin layer scouring machine 4...1000k9/h (1) each machine 50% manipulation vessel (from T/H to A/H) (10) 2 mixer 3, 3'・
...Each machine has /h(-)16 conche...Each conche X
Filling amount (10) 1 Static mixer 8...Each mixer public/h
(10) 1 Medium pressure mass pump 16...Each pump common h Equipment Dish (1) 6 rolls Mano...Tani machine 500k9/h (10) 1
Thin layer scouring machine 16...Each machine public h(1)1 mixer...
Each machine t/h (10) 2 mixers 3, 3'...Each mixer/h (1) 1 Contier (10) 1 stationary mixer 8...Each mixer public/h (10)
1 medium pressure mass pump 16... each pump a/h The following relationship arises regarding investment costs: A: B: C: D = 3.4: 2.7: 1.6: 1 That is, for example, the device ■ is the device { It requires 3.4 times the investment cost compared to D), but in this case the space cost, which decreases in the order of wind, 'B}, [CI, 'D', is not taken into account.

動力費は次の如くになる。A:B:C:D=2.5:2
:1.7:1すなわち例えば装置弧の所要動力は装置D
}に比べて2.5倍高い。
The power cost will be as follows. A:B:C:D=2.5:2
:1.7:1 That is, for example, the required power of the device arc is device D
} is 2.5 times higher than

両方のミキサー3または3′は第4図により次の如く形
成されている。
The two mixers 3 or 3' are constructed as follows according to FIG.

優先的には混合槽9は夫々1対の相互係合した混合スク
リューコンベア10を有し、材料は麓梓機により回転さ
れてこの混合スクリューコンベアに対して圧迫される。
Preferentially, the mixing vessels 9 each have a pair of interengaging mixing screw conveyors 10 against which the material is rotated and compressed by a foot slender.

切換可能の導管1 1から交互に充填される両方の混合
槽9は架台15の中で圧力計13の上に装着されていて
、混合槽において夫々の全充填量に達する場合全組成の
配量は自動的に停止させられる。混合槽9の中で強力な
混合処理が行われている間他の混合槽9は連続的に排出
されることによって連続的全流週が保証されている。た
だしこれに対する基本前提は比較的短い滞留時間を可能
にする特に最終精練相における本方法により達成可能の
、余剰湿気および有害香料からの材料の負担軽減である
。実施例 第1図による装置Cにおけるチョコレート製造に対し破
砕カカオニブは公知の構造の衝撃−鱒断粉砕機上で粉砕
され、かつ240k9/hの流量で微細粉砕機(ボール
ミル)に達する。
The two mixing vessels 9, which are alternately filled from the switchable conduit 11, are mounted in a pedestal 15 on a pressure gauge 13, which allows the metering of the total composition when the respective full filling is reached in the mixing vessel. will be stopped automatically. While intensive mixing is taking place in one mixing tank 9, the other mixing tanks 9 are continuously drained, thereby ensuring a continuous full flow. The basic premise for this, however, is the unburdening of the material from excess moisture and harmful fragrances, which can be achieved with this method, especially in the final scouring phase, which allows relatively short residence times. EXAMPLE For the production of chocolate in apparatus C according to FIG. 1, the crushed cocoa nibs are crushed on an impact-trout crusher of known construction and reach a fine crusher (ball mill) at a flow rate of 240 k9/h.

その際微細粉砕機は約80℃の温度に保たれる。微細粉
砕機から流動的に引き出された材料は、120k9/h
で1混合槽の中に給入され、一方他の混合槽9からは既
に連続的に粉乳、カカオバターおよびカカオの混合され
た材料が引き出される(その場合運転開始の際の始動過
程は既に実施されていることを前提とする)。混合槽9
の中に交互に給入される流動性のカカオバター(100
k9/h)は約40℃の温度を、また粉乳は約20午0
の温度を有する。その場合各混合槽は公知の調節措置に
よって約50q0に保たれる。混合槽の中の滞留時間ま
たは他の混合槽の排出時間は夫々約1/少時間である。
The fine grinder is maintained at a temperature of approximately 80°C. The material drawn fluidly from the fine grinder is 120k9/h
is fed into one mixing tank 9, while a mixed material of milk powder, cocoa butter and cocoa is already continuously withdrawn from the other mixing tank 9 (in which case the start-up process during start-up has already been carried out). ). Mixing tank 9
Liquid cocoa butter (100%
k9/h) at a temperature of about 40℃, and powdered milk at a temperature of about 20:00.
has a temperature of Each mixing tank is then maintained at approximately 50 q0 by known regulating measures. The residence time in the mixing vessel or the discharge time of other mixing vessels is each approximately 1/min hour.

混合槽の中の加工要素10,14は約1肌/秒の回転速
度を有する。交互に連続的にミキサー3の混合槽9から
引き出される材料は連続的に薄層精練機4の3個の塔ま
たは段を通過するが、該薄層精練機の除達−および分離
要素は約13m/秒の回転速度で駆動される。この3段
階において温度は約90qoであり、その場合前もって
サーモスタットにより調整された加熱要素を通過する多
少加熱された空気によって自動的温度調整が行われる。
塔は給水されるダブルジャケットを備えており、ダブル
ジャケットは予熱のためにのみ使われる、すなわち熱は
その後で全体的に材料の磨擬および空気によって供給ま
たは生成されるからである。装置のこの部分から840
X9/hによって流出する材料は約60〜6y0に冷却
されかつ控和機5の中に達し、64k9/hの流動性の
カカオバターおよびレシチンを添加しながら、約50o
oを有する前もって粉砕された砂糖が粉砕機6から同じ
く連続的に狸和機に給入された後この操和機から約30
00の温度を有する材料が流出するようにこの狸和機5
は冷却される。その後で1904k9/hによって理和
機5から流出する材料は公知の構造の4個のチョコレー
ト磨造機に分配され、磨薄機を通過に際して材料は約2
5q0に冷却される。磨債機から材料は連続的にかつ交
互にミキサー3′の混合槽9の中に与えられるが、これ
らの混合槽はその外に交互に夫々48k9/hにより4
0qoのカカオバターおよびレシチンを連続的に装入さ
れる。混合槽の給水可能のダブルジャケットによる熱供
給および摩擦熱によって混合槽の中では約65ooの温
度が保たれかつ次いでポンプ16の圧力の下に公知の構
造の静的ミキサー8を連続通過して次の加工にいたる。
レシチンの添加量は装入材料の全量に対して全部で約0
.4%である。
The processing elements 10, 14 in the mixing tank have a rotational speed of approximately 1 skin/second. The material withdrawn from the mixing tank 9 of the mixer 3 in alternating succession passes continuously through the three columns or stages of the laminar scouring machine 4, the removal and separation elements of which are approximately It is driven at a rotational speed of 13 m/s. In these three stages, the temperature is approximately 90 qo, with automatic temperature adjustment being effected by slightly heated air passing through a heating element previously regulated by a thermostat.
The column is equipped with a water-fed double jacket, which is used only for preheating, since the heat is then supplied or generated entirely by material abrasion and air. 840 from this part of the device
The material flowing out by
From the mill 6, the pre-milled sugar having a milliliter of about 30 milligrams of
This Tanukiwa machine 5 so that material with a temperature of 0.00 flows out
is cooled. Thereafter, at 1904 k9/h, the material flowing out of the rice miller 5 is distributed to four chocolate grinders of known construction, and as it passes through the grinder, the material is approx.
Cooled to 5q0. From the abrasion machine the material is fed continuously and alternately into the mixing vessels 9 of the mixer 3', but these mixing vessels are alternately fed 4 times at a rate of 48k9/h each.
Continuously charged with 0 qo cocoa butter and lecithin. A temperature of about 65 oo is maintained in the mixing tank by means of the heat supply by the water-feedable double jacket of the mixing tank and by the frictional heat, and then under the pressure of the pump 16 passes continuously through a static mixer 8 of known construction. processing.
The amount of lecithin added is approximately 0 in total based on the total amount of charging material.
.. It is 4%.

第5図には強い酸性の破砕カカオニブに対するやや異つ
た方法のフローチャートが表わされている。
FIG. 5 depicts a flowchart of a slightly different method for highly acidic crushed cocoa nibs.

個々の機構と装置に対しては同じ引用番号が利用されて
いる。第1図の設備Cに対してこの場合一方はカカオバ
ターと粉乳および他方は破砕カカオニブは睦和機5にい
たるまでは別個に取扱われ、その場合カカオバターと粉
乳は第1および第2段17,18においてのみ薄層精練
機を通過しかつ粉砕された破砕カカオニブは別個に段1
9を通過することによって段19の中で放出される醸成
分がミルク蛋白質に対してネガチーフの作用を及ぼすこ
とはできない。粉入ーカカオバター混合物およびカカオ
マスは熱交換器20を経て操和機5などに達する。第6
図によるフローチャートは、この場合粉砕機1,2の中
で既に最終微細度に粉砕されたカカオマスは控和機5に
いたること無く直ちにミキサー3′に達し、一方操和機
5および磨簿機7を経てはカカオバター、粉乳、砂糖お
よびレシチンだけが送られる点のみが第5図とは異って
いる。
The same reference numbers are used for individual mechanisms and devices. In this case, for equipment C in FIG. , 18, the crushed cocoa nibs are passed through the laminar smelter and crushed separately in stage 1.
The brewing ingredients released in stage 19 by passing through step 9 cannot have any negative effect on the milk proteins. The flour-cocoa butter mixture and the cocoa mass pass through the heat exchanger 20 and reach the mixer 5 or the like. 6th
The illustrated flowchart shows that in this case the cocoa mass already crushed to the final fineness in the crushers 1 and 2 reaches the mixer 3' immediately without reaching the mixing machine 5, while the mixing machine 5 and the polishing machine 7 The only difference from FIG. 5 is that only cocoa butter, powdered milk, sugar and lecithin are sent through .

操和機と磨濃機の容量はこの場合相応して減少されるこ
とが可能である。
The capacity of the mixer and polisher can be correspondingly reduced in this case.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は全装置(装置CとD)のフローチャート、第2
図は公知の半連糠式方法に対する装置のフローチャート
(装置B)、第3図は別の従来の方法に対する装置のフ
ローチャート(装置A)、第4図はミキサーの断面図、
第5図は第1図に比べてやや変化した方法に対するフロ
ーチャート、第6図は第5図に比べてやや変化した方法
に対するフローチャートを示す。 図中符号、K−B:カカオバター、M−P:粉乳、Le
:レシチン、Zu:砂糖、k9:キログラム、h:時間
、Co:コンチェ、A,B,C,D:装置記号、ローマ
数字:加工される量に対し必要な機械の個数、3,3′
:ミキサー、4:薄層精練機、5:程和機、7:粉砕装
置(磨濃機、ボールミルなど)、8:静的ミキサー、9
:混合槽、11:装入導管、12:排出導管、17,1
8,19,20:薄層精練機の段。 互・逆′ 0一.2 〇99 付9.イ
Figure 1 is a flowchart of the entire device (devices C and D);
The figure is a flowchart of an apparatus for a known semi-continuous rice bran method (apparatus B), FIG. 3 is a flowchart of an apparatus for another conventional method (apparatus A), and FIG. 4 is a sectional view of the mixer.
FIG. 5 shows a flowchart for a method slightly different from that shown in FIG. 1, and FIG. 6 shows a flowchart for a method slightly different from that shown in FIG. Codes in the figure, KB: cocoa butter, M-P: milk powder, Le
: lecithin, Zu: sugar, k9: kilogram, h: time, Co: conche, A, B, C, D: equipment symbol, Roman numeral: number of machines required for the amount processed, 3, 3'
: mixer, 4: thin layer scouring machine, 5: tempering machine, 7: grinding device (polishing machine, ball mill, etc.), 8: static mixer, 9
: Mixing tank, 11: Charge conduit, 12: Discharge conduit, 17,1
8, 19, 20: stages of thin layer scouring machine. Reciprocal/reverse' 01. 2 〇99 Attached 9. stomach

Claims (1)

【特許請求の範囲】 1 ミルクチヨコレートの連続製造のため、焙炒された
破砕カカオニブは微細粉砕されかつカカオバター、レシ
チン、砂糖および粉乳を添加しながら捏和され、磨潰さ
れ、均質化されかつ精練される方法において、連続的に
交互にバツチ混合またはバツチ捏和を受ける微細粉砕さ
れた破砕カカオニブにはこの交互のバツチ加工に際して
カカオバターおよび粉乳が添加され、その場合一つのバ
ツチの処理の間完全に混合されたまたは捏和された他の
バツチは連続的に排出されかつ既に粉乳を含んでいる材
料は続いて、除湿および除塵のため薄層精練を受け、そ
の場合続いてカカオバター、レシチンおよび砂糖が材料
に添加されかつ材料は連続的に交互のバツチ毎に均質化
され、一つのバツチの均質化の時間の間他のバツチの完
成品は連続的に引き出されることを特徴とする方法。 2 特許請求の範囲第1項に記載の方法において、バツ
チ毎に均質化され、引き出された材料は続いて静的ミキ
サー8を通される方法。 3 特許請求の範囲第1項に記載の方法において、砂糖
は最終微細度に粉砕されかつ最終均質化相において添加
される方法。 4 連続的に交互にバツチ混合またはバツチ捏和を受け
る微細粉砕された破砕カカオニブにはこの交互のバツチ
加工に際してカカオバターおよび粉乳が添加され、その
場合一つのバツチの処理の間完全に混合されたまたは捏
和された他のバツチは連続的に排出されかつ既に粉乳を
含んでいる材料は続いて、除湿および除塵のため薄層精
練を受け、その場合続いてカカオバター、レシチンおよ
び砂糖が材料に添加されかつ材料は連続的に交互のバツ
チ均質化を受け、一つのバツチの均質化の時間の間他の
バツチの完成品は連続的に引き出される方法を実施する
ために、工程順に配列された予備粉砕機と微細粉砕機、
薄層精練機、混合装置と捏和装置、微細磨潰機と併列さ
れた砂糖粉砕機とから成る装置において、薄層精練装置
4には、交互に連続的に装入可能かつ排出可能のミキサ
ー3が前置されており、かつ交互に連続的に装入可能か
つ排出可能のミキサー3′が捏和装置5および磨潰機、
ボールミルなどのような粉砕装置7の下に後置されてい
ることを特徴とする前記装置。 5 特許請求の範囲第4項に記載の装置において、ミキ
サー3,3′は混合−または捏和要素10を具備した2
個の混合槽9から形成されており、混合槽は装入導管1
1および排出導管12と切換可能に連結されており、そ
の場合混合槽は圧力計13のような荷重表示要素の上に
装着されている前記装置。 6 特許請求の範囲第4又は第5項に記載の装置におい
て、連続的捏和機5の代りにミキサー3または3′が装
置の中に配置されている装置。 7 微細粉砕されかつカカオバター、レシチン、砂糖お
よび粉乳を添加しながら捏和され、磨潰され、均質化さ
れかつ精練される。 強い酸性の焙炒された粉砕カカオニブからミルクチヨコ
レートを連続的に製造する方法において、カカオバター
および粉乳はバツチ混合およびバツチ捏和を受け、かつ
一つのバツチは薄層精練機4の第1段と第2段17,1
8に供給され、薄層精練機には第3段19において微細
粉砕された破砕カカオニブが連続的に供給され、その場
合レシチンおよび微細粉砕された砂糖は、薄層精練機4
から搬出される中間材料と共に捏和され、かつ続いて微
細に磨潰されバツチごとに交互にバツチ混合またはバツ
チ捏和を受け、その場合一つのバツチの混合の間完成混
合された他のバツチは連続的に排出されかつ次の加工に
供給されることを特徴とする方法。8 特許請求の範囲
第7項に記載の方法において、カカオマスは薄層精練機
4の第3段19を通過後砂糖およびレシチンと同時に、
薄層精練機4の第2段18から連続的に搬出される、カ
カオバターおよび粉乳から成る材料に混合されかつ連続
的に捏和されかつ続いて微細に磨潰される方法。9 特
許請求の範囲第7項に記載の方法において、最終微細度
に粉砕されたカカオマスは薄層精練機4の第3段19を
通過後、カカオバター、粉乳、砂糖およびレシチンから
成りこねられかつ微細に磨潰された材料に供給されかつ
この材料と共に続いてバツチ混合またはバツチ捏和を受
ける方法。
[Claims] 1. For continuous production of milk chocolate, roasted and crushed cocoa nibs are finely ground and kneaded with the addition of cocoa butter, lecithin, sugar and milk powder, ground, homogenized and In the process of scouring, the finely ground crushed cocoa nibs which are subjected to continuous alternating batch mixing or batch kneading are added with cocoa butter and milk powder during this alternating batch processing, in which case during the processing of one batch The thoroughly mixed or kneaded batches are continuously discharged and the material already containing milk powder is subsequently subjected to a thin layer scouring for dehumidification and dust removal, in which case it is followed by cocoa butter, lecithin. and a method characterized in that sugar is added to the material and the material is continuously homogenized in alternating batches, and during the homogenization time of one batch the finished product of the other batch is continuously withdrawn. . 2. A method according to claim 1, in which the batchwise homogenized and drawn-out material is subsequently passed through a static mixer (8). 3. A method according to claim 1, in which the sugar is ground to a final fineness and added in the final homogenization phase. 4. The finely ground crushed cocoa nibs that are subjected to continuous alternating batch mixing or batch kneading are supplemented with cocoa butter and milk powder during this alternating batch processing, in which case they are thoroughly mixed during the processing of one batch. or other batches that have been kneaded are continuously discharged and the material already containing milk powder is subsequently subjected to a thin layer scouring for dehumidification and dust removal, in which case cocoa butter, lecithin and sugar are subsequently added to the material. The added materials were arranged in process order to carry out the method in which the materials were continuously subjected to alternating batch homogenization, and during the homogenization time of one batch the finished product of the other batch was continuously withdrawn. preliminary crusher and fine crusher,
In an apparatus consisting of a thin layer scouring machine, a mixing device and a kneading device, a fine grinder and a sugar grinder in parallel, the thin layer scouring device 4 includes a mixer that can be alternately and continuously charged and discharged. A mixer 3' is provided with a kneading device 5, a grinder,
Said device, characterized in that it is downstream of a grinding device 7, such as a ball mill or the like. 5. In the device according to claim 4, the mixer 3, 3' comprises two or more mixing or kneading elements 10.
The mixing tank is formed by a charging conduit 1.
1 and a discharge conduit 12, in which case the mixing tank is mounted on a load indicating element, such as a pressure gauge 13. 6. Apparatus according to claim 4 or 5, in which instead of the continuous kneader 5 a mixer 3 or 3' is arranged in the apparatus. 7 Finely ground and kneaded with the addition of cocoa butter, lecithin, sugar and milk powder, milled, homogenized and refined. In a process for continuously producing milk chocolate from roasted and ground cocoa nibs in strong acidity, cocoa butter and milk powder are subjected to batch mixing and batch kneading, and one batch is combined with the first stage of the thin layer scouring machine 4. 2nd stage 17,1
8, and the thin layer scouring machine is continuously fed with crushed cocoa nibs that have been finely ground in the third stage 19, in which case the lecithin and the finely ground sugar are fed to the thin layer scouring machine 4.
It is then kneaded together with the intermediate material being discharged from the batch, and is subsequently finely ground and subjected to alternating batch mixing or batch kneading, in which case during the mixing of one batch, the other batches are mixed as finished. A method characterized in that it is continuously discharged and fed to the next processing. 8 In the method according to claim 7, the cocoa mass, after passing through the third stage 19 of the thin layer scouring machine 4, simultaneously contains sugar and lecithin.
A method in which the material consisting of cocoa butter and milk powder, which is continuously discharged from the second stage 18 of the laminar scouring machine 4, is mixed and continuously kneaded and subsequently finely ground. 9 In the method according to claim 7, the cocoa mass ground to the final fineness is kneaded with cocoa butter, milk powder, sugar and lecithin after passing through the third stage 19 of the thin layer scouring machine 4. A method in which a finely ground material is fed and subsequently subjected to batch mixing or batch kneading with this material.
JP51025642A 1975-03-12 1976-03-11 Method and equipment for continuous production of milk chocolate Expired JPS608098B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2510708.8 1975-03-12
DE19752510708 DE2510708C3 (en) 1975-03-12 1975-03-12 Method and device for the continuous production of milk chocolate masses

Publications (2)

Publication Number Publication Date
JPS51112560A JPS51112560A (en) 1976-10-05
JPS608098B2 true JPS608098B2 (en) 1985-02-28

Family

ID=5941116

Family Applications (1)

Application Number Title Priority Date Filing Date
JP51025642A Expired JPS608098B2 (en) 1975-03-12 1976-03-11 Method and equipment for continuous production of milk chocolate

Country Status (14)

Country Link
JP (1) JPS608098B2 (en)
AT (1) AT347220B (en)
BR (1) BR7601520A (en)
CH (1) CH616316A5 (en)
CS (1) CS191295B2 (en)
DD (1) DD123570A5 (en)
DE (1) DE2510708C3 (en)
ES (1) ES446004A1 (en)
FR (1) FR2303484A1 (en)
GB (1) GB1540636A (en)
IT (1) IT1057028B (en)
NL (1) NL7602545A (en)
SU (1) SU639418A3 (en)
YU (2) YU61276A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD148491A1 (en) * 1979-12-29 1981-05-27 Klaus Berkes METHOD AND APPARATUS FOR CONTINUOUS PRODUCTION OF CHOCOLATE MEASURES
DE3416533A1 (en) * 1984-05-04 1985-11-07 F.B. Lehmann Maschinenfabrik Gmbh, 7080 Aalen METHOD AND DEVICE FOR THE PRODUCTION OF CHOCOLATE DIMENSIONS, COVERS, FAT Glazes AND THE LIKE
DE3417126A1 (en) * 1984-05-09 1985-11-14 Rudolf Dr. 7770 Überlingen Rapp METHOD AND DEVICE FOR THE CONTINUOUS REFINING OF ROLLING MATERIALS AS THE STARTING PRODUCT FOR CHOCOLATE
DE3566768D1 (en) * 1985-05-30 1989-01-19 Lehmann Maschf F B Process and apparatus for making chocolate stock, coatings, icings and the like
DE19721791A1 (en) * 1997-05-24 1998-11-26 Lipp Mischtechnik Gmbh Method and device for making chocolate
NZ531932A (en) * 2001-10-30 2006-02-24 Nestle Sa Manipulation of chocolate flavour

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2465828A (en) * 1947-05-19 1949-03-29 Paul F Beich Company Method of making chocolate confectioneries
DE1227771B (en) * 1963-12-19 1966-10-27 Miag Muehlenbau Plant for the production of chocolate mass
DE1266734B (en) * 1967-02-15 1968-04-25 Petzholdt Maschf J S Device for the continuous mixing, liquefying, refining and flavor intensification of chocolate masses in particular
BE794985A (en) * 1972-04-27 1973-05-29 Petzholdt Maschf J S VERTICAL MIXER
DD108451A1 (en) * 1972-11-23 1974-09-20

Also Published As

Publication number Publication date
SU639418A3 (en) 1978-12-25
DE2510708A1 (en) 1976-09-23
YU61276A (en) 1982-02-28
ATA151876A (en) 1978-04-15
NL7602545A (en) 1976-09-14
CS191295B2 (en) 1979-06-29
ES446004A1 (en) 1977-05-16
FR2303484A1 (en) 1976-10-08
IT1057028B (en) 1982-03-10
GB1540636A (en) 1979-02-14
DE2510708B2 (en) 1977-12-15
AT347220B (en) 1978-12-11
JPS51112560A (en) 1976-10-05
FR2303484B1 (en) 1981-04-17
DD123570A5 (en) 1977-01-05
DE2510708C3 (en) 1978-08-10
BR7601520A (en) 1976-09-14
YU43041B (en) 1989-02-28
YU229581A (en) 1983-12-31
CH616316A5 (en) 1980-03-31

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