JPS6067487A - 不斉基を有する光学活性有機錫化合物 - Google Patents
不斉基を有する光学活性有機錫化合物Info
- Publication number
- JPS6067487A JPS6067487A JP17680183A JP17680183A JPS6067487A JP S6067487 A JPS6067487 A JP S6067487A JP 17680183 A JP17680183 A JP 17680183A JP 17680183 A JP17680183 A JP 17680183A JP S6067487 A JPS6067487 A JP S6067487A
- Authority
- JP
- Japan
- Prior art keywords
- optically active
- organotin compound
- octyl
- compound containing
- asymmetric group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title claims description 10
- -1 2-octyl Chemical group 0.000 abstract description 9
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract description 4
- 150000001299 aldehydes Chemical class 0.000 abstract description 4
- 238000006717 asymmetric allylation reaction Methods 0.000 abstract description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052794 bromium Inorganic materials 0.000 abstract description 4
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 4
- 150000002576 ketones Chemical class 0.000 abstract description 3
- 238000006293 aldehyde allylation reaction Methods 0.000 abstract description 2
- ODOPKAJVFRHHGM-UHFFFAOYSA-N phenyltin Chemical compound [Sn]C1=CC=CC=C1 ODOPKAJVFRHHGM-UHFFFAOYSA-N 0.000 abstract description 2
- ZSPTYLOMNJNZNG-UHFFFAOYSA-N 3-Buten-1-ol Chemical compound OCCC=C ZSPTYLOMNJNZNG-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 abstract 1
- NFHRNKANAAGQOH-UHFFFAOYSA-N triphenylstannane Chemical compound C1=CC=CC=C1[SnH](C=1C=CC=CC=1)C1=CC=CC=C1 NFHRNKANAAGQOH-UHFFFAOYSA-N 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 150000003606 tin compounds Chemical class 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 238000011914 asymmetric synthesis Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- 239000007818 Grignard reagent Substances 0.000 description 1
- HJPOKQICBCJGHE-UHFFFAOYSA-J [C+4].[Cl-].[Cl-].[Cl-].[Cl-] Chemical compound [C+4].[Cl-].[Cl-].[Cl-].[Cl-] HJPOKQICBCJGHE-UHFFFAOYSA-J 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- GMDGXJQUWIQOLE-UHFFFAOYSA-N prop-2-enylborane Chemical class BCC=C GMDGXJQUWIQOLE-UHFFFAOYSA-N 0.000 description 1
- WLHPCEJPGLYEJZ-UHFFFAOYSA-N prop-2-enyltin Chemical compound [Sn]CC=C WLHPCEJPGLYEJZ-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17680183A JPS6067487A (ja) | 1983-09-24 | 1983-09-24 | 不斉基を有する光学活性有機錫化合物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17680183A JPS6067487A (ja) | 1983-09-24 | 1983-09-24 | 不斉基を有する光学活性有機錫化合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6067487A true JPS6067487A (ja) | 1985-04-17 |
| JPS6225676B2 JPS6225676B2 (enrdf_load_stackoverflow) | 1987-06-04 |
Family
ID=16020077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17680183A Granted JPS6067487A (ja) | 1983-09-24 | 1983-09-24 | 不斉基を有する光学活性有機錫化合物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6067487A (enrdf_load_stackoverflow) |
-
1983
- 1983-09-24 JP JP17680183A patent/JPS6067487A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6225676B2 (enrdf_load_stackoverflow) | 1987-06-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Brown et al. | Hydroboration. 62. Monoisopinocampheylborane; an excellent chiral hydroborating agent for trans-disubstituted and trisubstituted alkenes. Evidence for a strong steric dependence in such asymmetric hydroborations | |
| Sommer et al. | Stereochemistry of asymmetric silicon. XVI. Transition metal catalyzed substitution reactions of optically active organosilicon hydrides | |
| JPS584748A (ja) | エナミンまたはイミンの製造方法 | |
| Bhatt | B-bromo-9-borabicyclo [3.3. 1] nonane. A convenient and selective reagent for ether cleavage | |
| Hagelee et al. | Boron Compounds. XLIV The Influence of Silicon on the Formation of (Z/E)-Tetrasubstituted Ethylenes via 1-Alkynylborates2 | |
| JPS6067487A (ja) | 不斉基を有する光学活性有機錫化合物 | |
| Ohshita et al. | Silicon-carbon unsaturated compounds. 26. Photochemical behavior of 1, 4-and 1, 5-bis (pentamethyldisilanyl) naphthalene | |
| Lautens et al. | A route to 1, 1-diorganometallic species via the claisen rearrangement of functionalized γ-hydroxyvinylstannanes | |
| JPS5817175B2 (ja) | エ−テルカゴウブツノセイゾウホウ | |
| EP0238826B1 (en) | 1,1-dichloro-1,2,2-trimethyl-2-phenyldisilane and method for producing the same | |
| Sakurai et al. | Conformationally stable 1-substituted 1-methyl-4-t-butyl-1-silacyclohexanes, a new organosilicon system suitable for stereochemical studies. | |
| JPH10130289A (ja) | ルテニウム−ジアミン錯体及びこれを触媒とする光学 活性アルコール類の製造方法 | |
| El-Hiti et al. | Preparation and use of sterically hindered organobis (2, 4, 6-triisopropylphenyl) hydroborates and their polystyrene derivatives for the diastereoselective reduction of ketones | |
| JPS6067486A (ja) | 不斉基を有する光学活性有機錫化合物 | |
| US4716240A (en) | 1,2-dichloro-1,2,2-trimethyl-1-phenyldisilane and method for producing the same | |
| Matsumoto et al. | Reductive coupling of 2, 2-dibromo-1, 1, 1, 3, 3, 3-hexaalkyltrisilanes. A novel route to persilylcyclotetrasilanes of the type [(R1R2R3Si) 2Si] 4 | |
| Nishiyama et al. | Silver-induced allylation of. beta.-bromo ethers with allylsilanes | |
| JPH0499740A (ja) | ２―ヒドロキシ―２，５，５，９―テトラメチルデカリルエタノールの製造法 | |
| JPS5944315B2 (ja) | ２−ペンチニルエ−テルの製造法 | |
| JP4807549B2 (ja) | シロキサン類，シラノール類及びシラン類，並びにその製造方法 | |
| US3219682A (en) | Method of producing cyclic ethyleneboronates | |
| JP2736916B2 (ja) | シベトンの製造法 | |
| EP0385368B1 (en) | Novel optically active compound | |
| JP4618781B2 (ja) | 新規プロリン誘導体、その製造方法、及びそれを用いた光学活性二級アルコール化合物の製造方法 | |
| JP2004323445A (ja) | 光学活性なスルホキシド化合物の製造方法 |