JPS60500261A - Single-layer wear-resistant coating for metal cutting tools - Google Patents
Single-layer wear-resistant coating for metal cutting toolsInfo
- Publication number
- JPS60500261A JPS60500261A JP50327883A JP50327883A JPS60500261A JP S60500261 A JPS60500261 A JP S60500261A JP 50327883 A JP50327883 A JP 50327883A JP 50327883 A JP50327883 A JP 50327883A JP S60500261 A JPS60500261 A JP S60500261A
- Authority
- JP
- Japan
- Prior art keywords
- metal cutting
- coating
- layer wear
- cutting tools
- resistant coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physical Vapour Deposition (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Drilling Tools (AREA)
- Chemical Vapour Deposition (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Knives (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるため要約のデータは記録されません。 (57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 金属切削工具の単−鳴耐、摩耗性被膜 技術分野 本発明は一般に金属切削に関し、特に金属切削工具の単一層耐摩耗性被膜に関す る。[Detailed description of the invention] Ring-resistant, abrasion-resistant coating for metal cutting tools Technical field FIELD OF THE INVENTION This invention relates generally to metal cutting, and more particularly to single layer wear resistant coatings for metal cutting tools. Ru.
背景技術 現代の金属切削における主要方向の一つは金属切削工具の化学成分の改良による それら工具の耐摩耗性被膜の性能特性における改良にある。Background technology One of the main directions in modern metal cutting is through the improvement of the chemical composition of metal cutting tools. The improvement lies in the performance characteristics of the wear-resistant coatings of these tools.
従来ではC,N、Oの群から選択された元素とハフニウムの実質的化合物である 単一層耐摩耗性被膜が知られている(米国特許第4.1.69,913号CJ! 、428−217 1979年参照)。Conventionally, it is a substantial compound of hafnium and an element selected from the group of C, N, and O. Single layer abrasion resistant coatings are known (US Pat. No. 4.1.69,913 CJ!). , 428-217, 1979).
しかしながら、ハフニウムイオンの高質量によって上記被膜は実際的に超硬(c ement、=d carbide )金属切削工具にのみ応用される。However, the high mass of hafnium ions makes the coating practically superhard (c element, = d carbide) Applicable only to metal cutting tools.
従来のもう一つの金属切削工具の単一層の耐摩耗性被膜(米国特許第4.264 ,682号 Cム428− :336.1981年参照)は炭素及び/又は窒素 と第■族(その1つがハフニウム)の2つの遷移金属の化合物の固溶体であるこ とが知られている。Another conventional metal cutting tool single-layer wear-resistant coating (U.S. Pat. No. 4.264 , No. 682, CM 428-: 336, 1981) is carbon and/or nitrogen. It is a solid solution of a compound of two transition metals of group III and group III (one of which is hafnium). is known.
その被膜は炭素及び/又は窒素との一部の化合物を作る他の■族遷移金属として チタンを含有する。The coating may form some compounds with carbon and/or nitrogen as well as other Group II transition metals. Contains titanium.
しかし彦がら、前記被膜は比較的に高いレベルの2 固有の自由エネルギーをその特徴とし、機械加工されている材料と被膜の相互作 用を招き被膜の耐摩耗性に悪い影響を力える。However, Hikohara found that the coating had a relatively high level of 2 Characterized by inherent free energy, the interaction between the material being machined and the coating is This can lead to corrosion and have a negative effect on the abrasion resistance of the coating.
発明の開示 本発明の第1の目的は被膜の耐摩耗性を与える一部の固溶体で窒素及び/又は炭 素との化合物としてハフニ・ラムを有する、窒素及び/又は炭素との化合物の形 で第■族の遷移金属を含む金属切削工具の単一層耐摩耗性被膜を提供することに ある。Disclosure of invention The first object of the present invention is to use some solid solutions of nitrogen and/or charcoal to provide the coating with wear resistance. Forms of compounds with nitrogen and/or carbon that have hafni ram as a compound with the element To provide a single-layer wear-resistant coating for metal cutting tools containing Group II transition metals. be.
上記目的は1つの金属がハフニウムである2つの第■族遷移金属と、炭素及び/ 又は窒素の化合物の固溶体である金属切削工具の単一層耐摩耗性被膜において、 本発明では前記金属切削工具の単一層耐摩耗性被膜がジルコニウムを他の■族遷 移金属として炭素及び/又は窒素との化合物の形で含有することによって達成さ れる。The above purpose is to prepare two Group I transition metals, one of which is hafnium, and carbon and/or carbon. or in a single-layer wear-resistant coating for metal cutting tools that is a solid solution of nitrogen compounds; In the present invention, the single-layer wear-resistant coating of the metal cutting tool combines zirconium with other group This is achieved by including the transition metal in the form of a compound with carbon and/or nitrogen. It will be done.
本発明は該被膜の固有の自由エネルギーのレベルを低下させる手段であり、それ によって耐摩耗性を増大させる。The present invention is a means of reducing the level of intrinsic free energy of the coating; increases wear resistance.
本発明を実施するための最良の形態単一層耐摩耗性被膜は金属切削工具に次のよ うに適用せしめられる0 これ迄用いられた工具合金から作られた金属切削工具を真空下に載置し、ノ・フ ニウムとジルコニウムを蒸発し且つイオン化させる。次に該工具の基地金属を予 備加熱し、その加工面をジルコ壬つムとノ・フニウムで衝突させて洗浄する。次 に炭素及び/又は窒素を添加し・・フニウムとジルコニウムに反応させそれらの 化合物の固溶体を形成する。その固溶体が該工具面に単一層耐摩耗性被膜となる 。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A single layer wear resistant coating is applied to a metal cutting tool as follows. 0 applied to sea urchin A metal cutting tool made from the tool alloy used up to now was placed under vacuum and Evaporate and ionize the nium and zirconium. Next, prepare the base metal of the tool. The machined surface is heated and cleaned by colliding with zircon and no-funium. Next Add carbon and/or nitrogen to the... to react with hunium and zirconium and their Form a solid solution of the compound. The solid solution forms a single layer wear-resistant coating on the tool surface. .
本発明をより理解させるために実際の実施態様の例示を以下示す。Examples of actual embodiments are provided below to provide a better understanding of the invention.
実施例1 以下の成分係 CMn Si Cr W V Mo Feの鋼からなる予め洗浄された径0.5 wnの20個のドリルを特定の容器に載置しジルコニウムとハフニウムが管部 から彦るカソードも配設されている真空チャンバー内に装入する。次に1.33 X10 Paの圧力にチャンバー内を減圧し、ジルコニウムとノヘフニウムが蒸 発且つイオン化するように電気アークを当てる。Example 1 Ingredients below Pre-cleaned diameter 0.5 made of CMn Si Cr W V Mo Fe steel 20 wn drills were placed in a specific container, and zirconium and hafnium were placed in the tube part. The empty cathode is placed in a vacuum chamber in which it is also placed. Next 1.33 Reduce the pressure inside the chamber to a pressure of X10 Pa, and zirconium and nohefnium evaporate. Apply an electric arc so that it emits and ionizes.
正に帯電したジルコニウムとハフニウノ・イオンを加速するために負の電圧をド リルにかけ、次に洗浄とその]二具の基地金属を予熱するため該ドリル加工面を 前記金属のイオンと衝突させる。次に、ドリルに印加した電圧を下げ、窒素を真 空チャンバー内に入れ、ハフニウムとジルコニウムと反応させその結果、該ドリ ルの加工面に単一層耐摩耗性被膜を形成する。該被膜は窒素とハフニウム、ジル コニウム化合物の固溶体からなる。A negative voltage is applied to accelerate the positively charged zirconium and hafniuno ions. The drilled surface is then cleaned and preheated to preheat the base metal of the two tools. Collision with ions of the metal. Next, reduce the voltage applied to the drill and remove the nitrogen. placed in an empty chamber and reacted with hafnium and zirconium, resulting in the Forms a single layer wear-resistant coating on the machined surface of the tool. The coating consists of nitrogen, hafnium, and zirconium. Consists of a solid solution of conium compounds.
このようにして得られた被膜を、以下の成分:At−5,Ti、残部のチタン− アルミニウム合金に、次の切削条件。The film thus obtained was coated with the following components: At-5, Ti, and the remainder was titanium. The following cutting conditions were applied to the aluminum alloy.
S = 0.0 8 van/回転 V=7.5 m/分 ここで、Sは加工されるチタン合金内へのドリル供給速度であり、■はドリル回 転速度である;の下で直立ドリルプレスで冷却剤(10%水溶性エマルジョン) を十分に供給して、157深さに穴をあけることにより耐摩耗(耐久性)のため にテストした。S = 0.0 8 van/rotation V=7.5 m/min Here, S is the drill supply speed into the titanium alloy to be machined, and ■ is the drill rotation speed. coolant (10% aqueous emulsion) in an upright drill press at a rolling speed of For wear resistance (durability) by providing sufficient supply of tested.
ドリルは金属音を発し始めた時、切れが悪くなったと考える。テスト結果は本被 膜の寿命が被膜をし々いドリルと比べて平均で8分から24分に増加することを 示した。When a drill starts to make a metallic sound, it is assumed that it has become dull. The test results will not be published. We found that the lifespan of the membrane increased from 8 minutes to 24 minutes on average compared to a drill that drilled the coating steadily. Indicated.
実施例2 実施例1で説明した単一層耐摩耗性被膜をつけたドリルを使用した。ドリルに対 する電圧低下と同時にわずかのアセチレンを真空チャンバーに入れ、その結果炭 化アセチ1/ンはハフニウムとジルコニウノ、と反応し、炭素とハフニウム及び ジルコニウノ・の固溶体からなる被膜をドリルの加工表面に形成する。Example 2 A drill with a single layer wear resistant coating as described in Example 1 was used. against drill A small amount of acetylene is introduced into the vacuum chamber at the same time as the voltage drops, resulting in carbon Acetylene reacts with hafnium and zirconium, forming carbon with hafnium and A coating made of a solid solution of zirconia is formed on the drill surface.
該被膜を実施例1のように耐摩耗性のテストをした。The coating was tested for abrasion resistance as in Example 1.
テスト結果はドリルの寿命は被膜しないドリルと比べて平均で8分から30分に 増大−することを示した。Test results show that drills last an average of 8 minutes to 30 minutes compared to uncoated drills. It was shown that the amount increases.
実施例3 実施例」で説明した単一層耐び耗被膜をつけたドリルを使用した。ドリルに印加 した電圧を下げると同時にアセチレンと窒素の混合物を真空チャンバーに通し、 炭素と窒素がハフニウムとジルコニウムと反応し、窒素と炭素とのハフニウム及 びジルコニウム化合物からなる被膜をドリルの加工面に形成する。Example 3 A drill with a single layer wear-resistant coating as described in "Examples" was used. applied to drill At the same time, a mixture of acetylene and nitrogen is passed through the vacuum chamber. Carbon and nitrogen react with hafnium and zirconium, and nitrogen and carbon react with hafnium and zirconium. A coating consisting of a zirconium compound and a zirconium compound is formed on the machined surface of the drill.
該被膜を実施例1のように耐摩耗性のテストをした。The coating was tested for abrasion resistance as in Example 1.
そのテスト結果は被膜ドリルの寿命は被膜しない1゛リルと比べて8分から35 分に増大することを示した。The test results showed that coated drills lasted 8 minutes to 35 minutes compared to uncoated drills. It was shown that the amount increases with time.
本発明は摩擦、高温、高圧又は腐食媒体下で動作する種々の作業性を良化するた めにも利用される一産業゛上の利用可能性 本発明は構造用あるいは難削材料の機械加工、特にチタン基台金の機械加二りに 適用しうるものである。The present invention improves the performance of various workpieces operating under friction, high temperature, high pressure or corrosive media. Possibility of application in an industry that can also be used for The present invention is suitable for machining of structural or difficult-to-cut materials, especially machining of titanium base metals. It is applicable.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU823511568A SU1128618A1 (en) | 1982-10-10 | 1982-10-10 | Material of wear-resistant coating of metal-cutting tool |
SU3511568/18 | 1982-10-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS60500261A true JPS60500261A (en) | 1985-02-28 |
Family
ID=21035727
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50327883A Pending JPS60500261A (en) | 1982-10-10 | 1983-08-25 | Single-layer wear-resistant coating for metal cutting tools |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPS60500261A (en) |
AU (1) | AU2073683A (en) |
DE (1) | DE3390292T1 (en) |
FI (1) | FI842315A (en) |
GB (1) | GB2137665A (en) |
NL (1) | NL8320316A (en) |
NO (1) | NO842235L (en) |
SE (1) | SE8403054L (en) |
SU (1) | SU1128618A1 (en) |
WO (1) | WO1984001587A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0280553A (en) * | 1988-09-16 | 1990-03-20 | Shimadzu Corp | Manufacture of thin film |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2612204A1 (en) * | 1987-03-12 | 1988-09-16 | Vac Tec Syst | METHOD AND APPARATUS FOR VACUUM ELECTRIC ARC PLASMA DEPOSITION OF DECORATIVE COATINGS AND WEAR RESISTANT COATINGS |
DE3728420A1 (en) * | 1987-08-26 | 1989-03-09 | Detlev Dipl Phys Dr Repenning | METHOD FOR PRODUCING LAYERS WITH HIGHLY HARD AND / OR LOW-FRICTION PROPERTIES |
DE3741127A1 (en) * | 1987-12-04 | 1989-06-15 | Repenning Detlev | METHOD FOR PRODUCING HEAT-STABLE LAYERS WITH HIGH-HARD AND / OR LOW-FRICTION PROPERTIES |
AU8971698A (en) | 1997-06-21 | 1999-01-04 | Reinhard Vorrink | Tyre trim ring, especially for automobile wheels |
JP4824989B2 (en) * | 2005-11-02 | 2011-11-30 | 株式会社神戸製鋼所 | Hard coating |
BRPI0618596B1 (en) * | 2005-11-17 | 2018-03-06 | Boehlerit Gmbh & Co. Kg | PROCESS FOR COATING A TOOL OR PART OF A TOOL, APPLIED TO AN OBJECT, WITH AT LEAST ONE LAYER OF TITANIUM CARBONITRET, AND TOOL OR PART OF THE TOOL |
RU2676718C1 (en) * | 2018-01-22 | 2019-01-10 | Общество с ограниченной ответственностью "Сборные конструкции инструмента, фрезы Москвитина" | Cutting tool for handling products made of hard-to-cut materials and cutting plate therefor |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1352241A (en) * | 1971-04-13 | 1974-05-08 | Wilkinson Sword Ltd | Razor blades |
DE2525185C3 (en) * | 1975-06-06 | 1986-04-17 | Fried. Krupp Gmbh, 4300 Essen | Hard metal body |
FR2357321A1 (en) * | 1976-07-05 | 1978-02-03 | Stellram Sa | Wear resistant hard metal article - coated with adherent layers of carbide, nitride, oxide, etc. |
-
1982
- 1982-10-10 SU SU823511568A patent/SU1128618A1/en active
-
1983
- 1983-08-25 JP JP50327883A patent/JPS60500261A/en active Pending
- 1983-08-25 NL NL8320316A patent/NL8320316A/en unknown
- 1983-08-25 GB GB08413858A patent/GB2137665A/en not_active Withdrawn
- 1983-08-25 WO PCT/SU1983/000032 patent/WO1984001587A1/en active Application Filing
- 1983-08-25 DE DE19833390292 patent/DE3390292T1/en not_active Withdrawn
- 1983-08-25 AU AU20736/83A patent/AU2073683A/en not_active Abandoned
-
1984
- 1984-06-04 NO NO842235A patent/NO842235L/en unknown
- 1984-06-06 SE SE8403054A patent/SE8403054L/en not_active Application Discontinuation
- 1984-06-07 FI FI842315A patent/FI842315A/en not_active Application Discontinuation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0280553A (en) * | 1988-09-16 | 1990-03-20 | Shimadzu Corp | Manufacture of thin film |
Also Published As
Publication number | Publication date |
---|---|
GB2137665A (en) | 1984-10-10 |
AU2073683A (en) | 1984-05-04 |
GB8413858D0 (en) | 1984-07-04 |
FI842315A0 (en) | 1984-06-07 |
WO1984001587A1 (en) | 1984-04-26 |
NO842235L (en) | 1984-06-04 |
SE8403054D0 (en) | 1984-06-06 |
FI842315A (en) | 1984-06-07 |
DE3390292T1 (en) | 1985-01-10 |
SE8403054L (en) | 1984-06-06 |
SU1128618A1 (en) | 1987-03-07 |
NL8320316A (en) | 1984-09-03 |
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