JPH07237010A - Surface coated cutting tool with excellent wear resistance - Google Patents

Surface coated cutting tool with excellent wear resistance

Info

Publication number
JPH07237010A
JPH07237010A JP5267394A JP5267394A JPH07237010A JP H07237010 A JPH07237010 A JP H07237010A JP 5267394 A JP5267394 A JP 5267394A JP 5267394 A JP5267394 A JP 5267394A JP H07237010 A JPH07237010 A JP H07237010A
Authority
JP
Japan
Prior art keywords
layer
cutting tool
coated cutting
hard coating
cutting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5267394A
Other languages
Japanese (ja)
Inventor
Munenori Kato
宗則 加藤
Hironori Yoshimura
寛範 吉村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP5267394A priority Critical patent/JPH07237010A/en
Publication of JPH07237010A publication Critical patent/JPH07237010A/en
Pending legal-status Critical Current

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  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Physical Vapour Deposition (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

PURPOSE:To provide a surface coated cutting tool with a long service life and excellent wear resistance. CONSTITUTION:With WC group hard metal or TiCN group cermet as a base body, a hard coating layer is formed on the surface to form a surface coated cutting tool. The hard coating layer has at least one layer out of a (Ti, Al, Cr) C layer, a (Ti, Al, Cr) N layer and a (Ti, Al, Cr) CN layer as an essential constituent layer, and at least one layer out of a metal Ti layer, a TiC layer, a TiN layer and a TiCN layer is further laminated as occasion calls.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、従来よりも使用寿命
の長い耐摩耗性に優れた表面被覆切削工具に関するもの
である。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surface-coated cutting tool which has a longer service life and is superior in wear resistance than ever before.

【0002】[0002]

【従来の技術】従来、炭化タングステン(以下、WCで
示す)基超硬合金または炭窒化チタン(以下、TiCN
で示す)基サーメットを基体とし、その表面にTiの炭
化物(以下、TiCで示す)、Tiの窒化物(以下、T
iNで示す)およびTiの炭窒化物(以下、TiCNで
示す)のうちの1種の単層または2種以上の複層からな
る硬質被覆層を化学蒸着法(CVD法)や物理蒸着法
(PVD法)を用いて形成してなる表面被覆切削工具は
知られている。
2. Description of the Related Art Conventionally, tungsten carbide (hereinafter referred to as WC) based cemented carbide or titanium carbonitride (hereinafter referred to as TiCN).
Base) cermet as a substrate, and on its surface Ti carbide (hereinafter referred to as TiC) and Ti nitride (hereinafter referred to as T
iN) and Ti carbonitrides (hereinafter TiCN), a hard coating layer composed of one single layer or two or more multiple layers is formed by a chemical vapor deposition method (CVD method) or a physical vapor deposition method (CVD method). A surface-coated cutting tool formed by using the PVD method) is known.

【0003】しかし、これら表面被覆切削工具では工具
寿命が十分でないために、WC基超硬合金またはTiC
N基サーメットの表面に、TiとAlの複合炭化物固溶
体(以下、(Ti,Al)Cで示す)、TiとAlの複
合窒化物固溶体(以下、(Ti,Al)Nで示す)、T
iとAlの複合炭窒化物固溶体(以下、(Ti,Al)
CNで示す)のうちの1種の単層または2種以上の複層
からなる硬質被覆層を形成してなる表面被覆切削工具が
提案されている(特公平4−53642号公報参照)。
そして硬質被覆層の厚さは0.5〜10μmの範囲内に
あることが好ましいとされている。
However, since these surface-coated cutting tools have insufficient tool life, WC-based cemented carbide or TiC is used.
On the surface of the N-based cermet, a composite carbide solid solution of Ti and Al (hereinafter represented by (Ti, Al) C), a composite nitride solid solution of Ti and Al (hereinafter represented by (Ti, Al) N), T
Composite carbonitride solid solution of i and Al (hereinafter, (Ti, Al)
(Referred to as CN), a surface-coated cutting tool formed by forming a hard coating layer composed of one type of single layer or two or more types of multilayers has been proposed (see Japanese Patent Publication No. 4-53642).
And it is said that the thickness of the hard coating layer is preferably in the range of 0.5 to 10 μm.

【0004】[0004]

【発明が解決しようとする課題】しかし、近年、切削機
械の自動化および省力化に伴って切削工具の交換回数を
減らすべく使用寿命の長い表面被覆切削工具が求められ
ているが、上記従来の表面被覆切削工具ではかかる要求
をみたすことができなかった。
However, in recent years, there has been a demand for a surface-coated cutting tool having a long service life in order to reduce the number of times of exchanging the cutting tool with the automation and labor saving of the cutting machine. Coated cutting tools have not been able to meet these requirements.

【0005】[0005]

【課題を解決するための手段】そこで、本発明者等は、
かかる観点から、使用寿命の一層長い表面被覆切削工具
を得るべく研究を行った結果、TiとAlとCrの複合
炭化物固溶体(以下、(Ti,Al,Cr)Cで示
す)、TiとAlとCrの複合窒化物固溶体(以下、
(Ti,Al,Cr)Nで示す)、およびTiとAlと
Crの複合炭窒化物固溶体(以下、(Ti,Al,C
r)CNで示す)のうちの1種の単層または2種以上の
複層からなる硬質被覆層を必須構成層とする表面被覆切
削工具は、従来よりも工具寿命が延命化されるという知
見を得たのである。
Therefore, the present inventors have
From this point of view, as a result of research to obtain a surface-coated cutting tool having a longer service life, a composite carbide solid solution of Ti, Al, and Cr (hereinafter referred to as (Ti, Al, Cr) C), Ti and Al Cr composite nitride solid solution (hereinafter,
(Indicated by (Ti, Al, Cr) N), and a composite carbonitride solid solution of Ti, Al, and Cr (hereinafter (Ti, Al, C)
r) The surface-coated cutting tool having a hard coating layer consisting of one single layer or two or more multi-layers of CN) as an indispensable constituent layer has a longer tool life than before. Is obtained.

【0006】この発明は、かかる知見に基づいてなされ
たものであって、WC基超硬合金またはTiCN基サー
メットを基体とし、その表面に硬質被覆層を形成してな
る表面被覆切削工具において、上記硬質被覆層は、(T
i,Al,Cr)C層、(Ti,Al,Cr)N層、
(Ti,Al,Cr)CN層のうちの少なくとも1層を
必須構成層とし、必要に応じてさらに、金属Ti層、T
iC層、TiN層およびTiCN層のうちの少なくとも
1層を積層させてなる、表面被覆切削工具に特徴を有す
るものである。
The present invention has been made on the basis of such findings, and in a surface-coated cutting tool comprising a WC-based cemented carbide or TiCN-based cermet as a substrate and a hard coating layer formed on the surface thereof, The hard coating layer is (T
i, Al, Cr) C layer, (Ti, Al, Cr) N layer,
At least one of the (Ti, Al, Cr) CN layers is an essential constituent layer, and if necessary, a metal Ti layer, T
It is characterized by a surface-coated cutting tool formed by laminating at least one layer of an iC layer, a TiN layer and a TiCN layer.

【0007】上記硬質被覆層の長さは0.5〜10μm
の範囲内にあることが好ましく、この厚さは従来の表面
被覆切削工具における硬質被覆層の厚さと同じである。
The length of the hard coating layer is 0.5 to 10 μm.
, Which is the same as the thickness of the hard coating layer in conventional surface-coated cutting tools.

【0008】[0008]

【実施例】【Example】

実施例1 重量%で(以下%は重量%を示す)、WC−9%Co−
8%TiC−10%TaCからなる組成のWC基超硬合
金およびTiCN−12%Co−8%Mo−6%Ni−
15%WC−10%TaCからなる組成のTiCN基サ
ーメットで構成され、かつJIS・SNGN432に則
した形状を有する切削チップを用意した。
Example 1 In% by weight (hereinafter,% indicates% by weight), WC-9% Co-
WC-based cemented carbide having a composition of 8% TiC-10% TaC and TiCN-12% Co-8% Mo-6% Ni-
A cutting tip composed of a TiCN-based cermet having a composition of 15% WC-10% TaC and having a shape conforming to JIS SNGN432 was prepared.

【0009】これら切削チップを公知のイオンプレーテ
ィング装置内に装入し、下記の方法で表1および表2に
示される本発明表面被覆切削工具(以下、本発明切削工
具という)1〜18および従来表面被覆切削工具(以
下、従来切削工具という)1〜7を作製した。
These cutting tips are placed in a known ion plating apparatus, and the surface-coated cutting tools of the present invention (hereinafter referred to as the cutting tools of the present invention) 1 to 18 shown in Tables 1 and 2 by the following method and Conventional surface-coated cutting tools (hereinafter referred to as conventional cutting tools) 1 to 7 were produced.

【0010】(a) (Ti,Al,Cr)C層、(T
i,Al,Cr)N層および(Ti,Al,Cr)CN
層形成方法。
(A) (Ti, Al, Cr) C layer, (T
i, Al, Cr) N layer and (Ti, Al, Cr) CN
Layer forming method.

【0011】上記イオンプレーティング装置内に置かれ
たるつぼ内にTi−30%Al−20%Cr合金を入
れ、こ状態で、まず装置内の真空度を5×10-5torrの
雰囲気とすると共に、切削チップを500℃に加熱し、
ついで切削チップに−1000Vの電位をかけ、装置内
にArガスを流通させて切削チップの表面を十分に洗浄
した後、Ar脱気し、引続いてるつぼ内のTi−30%
Al−20%Cr合金に電子ビームを照射してこれを溶
融し、蒸発させ、同時に切削チップへの負荷電位を−7
00Vとすると共に、N2 および/またはC2 2 (ア
セチレン)からなる反応ガスを200cc/min の割合で
流して、切削チップの表面に(Ti,Al,Cr)C
層、(Ti,Al,Cr)N層および(Ti,Al,C
r)CN層を蒸着させることにより形成した。
A Ti-30% Al-20% Cr alloy is placed in a crucible placed in the above ion plating apparatus, and in this state, the degree of vacuum in the apparatus is first set to an atmosphere of 5 × 10 -5 torr. Along with heating the cutting tip to 500 ° C,
Then, an electric potential of -1000 V was applied to the cutting tip, Ar gas was circulated in the device to sufficiently clean the surface of the cutting tip, and then degassing was performed for Ar, and subsequently Ti-30% in the crucible was used.
The Al-20% Cr alloy is irradiated with an electron beam to melt and vaporize it, and at the same time, the load potential on the cutting tip is set to -7.
The reaction gas consisting of N 2 and / or C 2 H 2 (acetylene) was made to flow at a rate of 200 cc / min while being set to 00 V, and the (Ti, Al, Cr) C
Layer, (Ti, Al, Cr) N layer and (Ti, Al, C)
r) Formed by depositing a CN layer.

【0012】(b) (Ti,Al)C層、(Ti,A
l)N層および(Ti,Al)CN層の形成方法。
(B) (Ti, Al) C layer, (Ti, A)
l) Method for forming N layer and (Ti, Al) CN layer.

【0013】上記(a)で述べたイオンプレーティング
装置内のるつぼ内にTi−Al合金を入れる以外は上記
(a)と全く同じ方法で形成した。
It was formed in exactly the same manner as in (a) above, except that a Ti--Al alloy was placed in the crucible in the ion plating apparatus described in (a) above.

【0014】(c) TiC層、TiN層、TiCN層
の形成方法。
(C) Method of forming TiC layer, TiN layer, TiCN layer.

【0015】上記(a)で述べたイオンプレーティング
装置内のるつぼ内にTiを入れる以外は上記(a)と全
く同じ方法で形成した。
It was formed by the same method as in the above (a) except that Ti was put in the crucible in the ion plating apparatus described in the above (a).

【0016】(d) Ti層 上記(a)で述べたイオンプレーティング装置内のるつ
ぼ内にTiを入れ、反応ガスを流すことなく真空雰囲気
中で溶融、蒸発させる以外は上記(a)と全く同じ方法
で形成した。
(D) Ti layer Except for (a), except that Ti is put in the crucible in the ion plating apparatus described in (a) above and is melted and evaporated in a vacuum atmosphere without flowing a reaction gas. It was formed in the same way.

【0017】上記本発明切削工具1〜18および従来切
削工具1〜7について、 被削材:SNCM439(硬さ:HB 240)丸棒、 切削速度:210m/min 、 送り:0.3mm/rev.、 切込み:2mm、 切削時間:20min.、 の条件で鋼の連続切削試験、並びに、 被削材:SNCM439(硬さ:HB 290)の角材、 切削速度:150m/min 、 送り:0.3mm/rev.、 切込み:3mm、 切削時間:3min.、 の条件で鋼の断続切削試験をそれぞれ行ない、前者の連
続切削試験では、切刃の逃げ面摩耗幅とすくい面摩耗深
さを測定し、また後者の断面切削試験では、10個の試
験切刃のうちの欠損発生数を測定した。これらの測定結
果を表3および表4に示した。
Regarding the cutting tools 1 to 18 of the present invention and the conventional cutting tools 1 to 7, the work material: SNCM439 (hardness: H B 240) round bar, cutting speed: 210 m / min, feed: 0.3 mm / rev ., cut: 2 mm cutting time:. 20min continuous cutting test of steel, the conditions and, workpiece: SNCM439 (hardness: H B 290) square bar of cutting speed: 150 meters / min, feed: 0. 3mm / rev., Depth of cut: 3mm, Cutting time: 3min., The intermittent cutting test of steel is performed respectively. In the former continuous cutting test, the flank wear width and rake face wear depth of the cutting edge are measured. In the latter cross-section cutting test, the number of occurrences of defects in 10 test cutting edges was measured. The results of these measurements are shown in Tables 3 and 4.

【0018】[0018]

【表1】 [Table 1]

【0019】[0019]

【表2】 [Table 2]

【0020】[0020]

【表3】 [Table 3]

【0021】[0021]

【表4】 [Table 4]

【0022】表1〜表4に示される結果から、本発明切
削工具1〜21は、従来切削工具と比較して特に連続切
削に対して優れた特性を示すことがわかる。
From the results shown in Tables 1 to 4, it can be seen that the cutting tools 1 to 21 of the present invention exhibit excellent characteristics particularly in continuous cutting as compared with the conventional cutting tools.

【0023】実施例2 実施例1で用いたWC基超硬合金と同じ成分組成のWC
基超硬合金からなり、直径:10mmφ×長さ:66mmの
寸法をもった2枚刃エンドミルを用意した。これを実施
例1で用いたと同じイオンプレーティング装置に装入
し、硬質被覆層形成時の2枚刃エンドミルへの負荷電位
を−300Vとする以外は、実施例1で実施した条件と
同じ条件で2枚刃エンドミルの表面にそれぞれ表5に示
される組成および平均層厚を有する硬質被覆層を蒸着
し、これにより本発明切削工具22〜28および従来切
削工具8〜14を作製した。
Example 2 WC having the same composition as the WC-based cemented carbide used in Example 1
A two-blade end mill made of a base cemented carbide and having a diameter of 10 mmφ and a length of 66 mm was prepared. This was charged in the same ion plating apparatus as used in Example 1, and the same load conditions as in Example 1 except that the load potential to the two-blade end mill at the time of forming the hard coating layer was set to -300V. A hard coating layer having the composition and the average layer thickness shown in Table 5 was vapor-deposited on the surface of the two-blade end mill, and thereby cutting tools 22 to 28 of the present invention and conventional cutting tools 8 to 14 were produced.

【0024】これら本発明切削工具22〜28および従
来切削工具8〜14についても 被削材:S45C(硬さ:HB 220)、 切削速度:100m/min 、 送り:0.03mm/刃、 切込み:5mm、 切削油:水溶性、 の条件で切削試験を行ない、切刃外周の逃げ面摩耗幅が
0.3mmに至るまでの切削長さを測定し、この結果を表
5に示した。
Also for these cutting tools 22 to 28 of the present invention and conventional cutting tools 8 to 14, work material: S45C (hardness: H B 220), cutting speed: 100 m / min, feed: 0.03 mm / blade, cutting A cutting test was performed under the conditions of: 5 mm, cutting oil: water-soluble, and the cutting length until the flank wear width of the cutting edge outer circumference reaches 0.3 mm was measured. The results are shown in Table 5.

【0025】[0025]

【表5】 [Table 5]

【0026】表5に示される結果から、本発明切削工具
22〜28は、従来切削工具と比較して工具寿命が一段
と改善されていることがわかる。
From the results shown in Table 5, it is understood that the cutting tools 22 to 28 of the present invention have a further improved tool life as compared with the conventional cutting tools.

【0027】[0027]

【発明の効果】上述のように、この発明の表面被覆切削
工具は、その表面に蒸着された硬質被覆層が従来表面被
覆切削工具を構成する硬質被覆層に比して一段とすぐれ
た耐摩耗性を有するので、長期に亘ってすぐれた切削性
能を発揮し、長い使用寿命を示すなど工業上有用な特性
を有するのである。
As described above, in the surface-coated cutting tool of the present invention, the hard coating layer vapor-deposited on the surface thereof has much higher wear resistance than the hard coating layer constituting the conventional surface-coated cutting tool. Therefore, it has industrially useful properties such as excellent cutting performance over a long period of time and long service life.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 炭化タングステン基超硬合金または炭窒
化チタン基サーメットを基体とし、その表面に硬質被覆
層を形成してなる表面被覆切削工具において、 上記硬質被覆層は、TiとAlとCrの複合炭化物固溶
体層、TiとAlとCrの複合窒化物固溶体層およびT
iとAlとCrの複合炭窒化物固溶体層のうちの少なく
とも1層からなることを特徴とする耐摩耗性に優れた表
面被覆切削工具。
1. A surface-coated cutting tool comprising a tungsten carbide-based cemented carbide or titanium carbonitride-based cermet as a substrate, and a hard coating layer formed on the surface thereof, wherein the hard coating layer comprises Ti, Al and Cr. Composite carbide solid solution layer, composite nitride solid solution layer of Ti, Al and Cr and T
A surface-coated cutting tool having excellent wear resistance, comprising at least one layer of a composite carbonitride solid solution layer of i, Al, and Cr.
【請求項2】 炭化タングステン基超硬合金または炭窒
化チタン基サーメットを基体とし、その表面に硬質被覆
層を形成してなる表面被覆切削工具において、 上記硬質被覆層は、TiとAlとCrの複合炭化物固溶
体層、TiとAlとCrの複合窒化物固溶体層およびT
iとAlとCrの複合炭窒化物固溶体層のうちの少なく
とも一層を必須構成層とし、さらに金属Ti層、Tiの
炭化物層、Tiの窒化物層およびTiの炭窒化物層のう
ちの少なくとも一層を含むことを特徴とする耐摩耗性に
優れた表面被覆切削工具。
2. A surface-coated cutting tool comprising a tungsten carbide-based cemented carbide or titanium carbonitride-based cermet as a substrate, and a hard coating layer formed on the surface thereof, wherein the hard coating layer comprises Ti, Al and Cr. Composite carbide solid solution layer, composite nitride solid solution layer of Ti, Al and Cr and T
At least one of the composite carbonitride solid solution layers of i, Al, and Cr is an essential constituent layer, and at least one layer of a metal Ti layer, a Ti carbide layer, a Ti nitride layer, and a Ti carbonitride layer. A surface-coated cutting tool having excellent wear resistance, which comprises:
JP5267394A 1994-02-25 1994-02-25 Surface coated cutting tool with excellent wear resistance Pending JPH07237010A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5267394A JPH07237010A (en) 1994-02-25 1994-02-25 Surface coated cutting tool with excellent wear resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5267394A JPH07237010A (en) 1994-02-25 1994-02-25 Surface coated cutting tool with excellent wear resistance

Publications (1)

Publication Number Publication Date
JPH07237010A true JPH07237010A (en) 1995-09-12

Family

ID=12921402

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5267394A Pending JPH07237010A (en) 1994-02-25 1994-02-25 Surface coated cutting tool with excellent wear resistance

Country Status (1)

Country Link
JP (1) JPH07237010A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
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JPH09256138A (en) * 1996-03-19 1997-09-30 Kobe Steel Ltd Titanium-base alloy member excellent in oxidation resistance and wear resistance
JP2000144378A (en) * 1998-11-05 2000-05-26 Yamaguchi Prefecture Formation of composite hard film with low coefficient of friction
EP1132498A1 (en) * 2000-03-09 2001-09-12 METAPLAS IONON Oberflächenveredelungstechnik GmbH Hard layer coated parts
JP2002513087A (en) * 1998-04-29 2002-05-08 ユナキス・トレーディング・アクチェンゲゼルシャフト Tools or mechanical parts and methods for increasing the wear resistance of such parts
EP1219723A2 (en) * 2000-12-28 2002-07-03 Kabushiki Kaisha Kobe Seiko Sho Hard film for cutting tools
US6794064B2 (en) * 2001-11-28 2004-09-21 Metaplas Ionon Oberflaechenveredelungstechnik Gmbh Hard coating coated parts
US6906295B2 (en) * 2003-02-20 2005-06-14 National Material L.P. Foodware with multilayer stick resistant ceramic coating and method of making
JP2008073821A (en) * 2006-09-22 2008-04-03 Mitsubishi Materials Corp Surface coated cutting tool with hard coating layer exhibiting excellent chipping resistance
US8021768B2 (en) 2009-04-07 2011-09-20 National Material, L.P. Plain copper foodware and metal articles with durable and tarnish free multiplayer ceramic coating and method of making
WO2012069475A1 (en) 2010-11-23 2012-05-31 Seco Tools Ab Coated cutting tool insert
RU2596527C1 (en) * 2015-03-13 2016-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Method for production of multi-layer coating for cutting tool
RU2596530C1 (en) * 2015-03-13 2016-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Method for production of multi-layer coating for cutting tool
RU2648962C1 (en) * 2017-03-10 2018-03-28 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method for producing wear-resistant coating for cutting tool
RU2648927C1 (en) * 2017-03-10 2018-03-28 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method for producing wear-resistant coating for cutting tool
RU2648964C1 (en) * 2017-03-10 2018-03-28 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method for producing wear-resistant coating for cutting tool
RU2696916C2 (en) * 2017-11-10 2019-08-07 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method of producing wear-resistant coating for cutting tool
RU2720012C1 (en) * 2019-10-01 2020-04-23 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method of producing a wear-resistant coating for a cutting tool

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JPH09256138A (en) * 1996-03-19 1997-09-30 Kobe Steel Ltd Titanium-base alloy member excellent in oxidation resistance and wear resistance
JP2002513087A (en) * 1998-04-29 2002-05-08 ユナキス・トレーディング・アクチェンゲゼルシャフト Tools or mechanical parts and methods for increasing the wear resistance of such parts
JP2000144378A (en) * 1998-11-05 2000-05-26 Yamaguchi Prefecture Formation of composite hard film with low coefficient of friction
US6730392B2 (en) 2000-03-09 2004-05-04 Metaplas Ionon Oberflächenveredelungstechnik GmbH Hard layer coated parts
EP1132498A1 (en) * 2000-03-09 2001-09-12 METAPLAS IONON Oberflächenveredelungstechnik GmbH Hard layer coated parts
AU2005202710B2 (en) * 2000-12-28 2007-02-22 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel Ltd) Hard film for cutting tools, cutting tool coated with hard film, process for forming hard film, and target used to form hard film
US6824601B2 (en) 2000-12-28 2004-11-30 Kobe Steel, Ltd. Hard film for cutting tools, cutting tool coated with hard film, process for forming hard film, and target used to form hard film
US6919288B2 (en) 2000-12-28 2005-07-19 Kobe Steel, Ltd. Hard film for cutting tools, cutting tool coated with hard film, process for forming hard film, and target used to form hard film
EP1702997A3 (en) * 2000-12-28 2006-11-29 Kabushiki Kaisha Kobe Seiko Sho Hard film for cutting tools
EP1219723A2 (en) * 2000-12-28 2002-07-03 Kabushiki Kaisha Kobe Seiko Sho Hard film for cutting tools
US7186324B2 (en) 2000-12-28 2007-03-06 Kabushiki Kaisha Kobe Seiko Sho Hard film cutting tools, cutting tool coated with hard film, process for forming hard film and target used to form hard film
EP1219723A3 (en) * 2000-12-28 2002-09-04 Kabushiki Kaisha Kobe Seiko Sho Hard film for cutting tools
US6794064B2 (en) * 2001-11-28 2004-09-21 Metaplas Ionon Oberflaechenveredelungstechnik Gmbh Hard coating coated parts
US7462375B2 (en) 2003-02-20 2008-12-09 National Material L.P. Method of making a stick resistant multi-layer ceramic coating
US6906295B2 (en) * 2003-02-20 2005-06-14 National Material L.P. Foodware with multilayer stick resistant ceramic coating and method of making
JP2008073821A (en) * 2006-09-22 2008-04-03 Mitsubishi Materials Corp Surface coated cutting tool with hard coating layer exhibiting excellent chipping resistance
US8021768B2 (en) 2009-04-07 2011-09-20 National Material, L.P. Plain copper foodware and metal articles with durable and tarnish free multiplayer ceramic coating and method of making
WO2012069475A1 (en) 2010-11-23 2012-05-31 Seco Tools Ab Coated cutting tool insert
RU2596527C1 (en) * 2015-03-13 2016-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Method for production of multi-layer coating for cutting tool
RU2596530C1 (en) * 2015-03-13 2016-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Method for production of multi-layer coating for cutting tool
RU2648962C1 (en) * 2017-03-10 2018-03-28 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method for producing wear-resistant coating for cutting tool
RU2648927C1 (en) * 2017-03-10 2018-03-28 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method for producing wear-resistant coating for cutting tool
RU2648964C1 (en) * 2017-03-10 2018-03-28 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method for producing wear-resistant coating for cutting tool
RU2696916C2 (en) * 2017-11-10 2019-08-07 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method of producing wear-resistant coating for cutting tool
RU2720012C1 (en) * 2019-10-01 2020-04-23 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Method of producing a wear-resistant coating for a cutting tool

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