JPS6035363B2 - 塩化ビニルを放出することなく乳化ポリ塩化ビニルを製造する方法 - Google Patents
塩化ビニルを放出することなく乳化ポリ塩化ビニルを製造する方法Info
- Publication number
- JPS6035363B2 JPS6035363B2 JP50107549A JP10754975A JPS6035363B2 JP S6035363 B2 JPS6035363 B2 JP S6035363B2 JP 50107549 A JP50107549 A JP 50107549A JP 10754975 A JP10754975 A JP 10754975A JP S6035363 B2 JPS6035363 B2 JP S6035363B2
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- pressure
- vessel
- vinyl chloride
- polymerization vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 16
- 229920000915 polyvinyl chloride Polymers 0.000 title claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 56
- 239000003995 emulsifying agent Substances 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000004815 dispersion polymer Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 description 16
- 238000004140 cleaning Methods 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000011017 operating method Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- -1 polyoxy Polymers 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VAXCXSDAWONRLI-UHFFFAOYSA-N 2,3-dihydroxypropyl hydrogen sulfate Chemical class OCC(O)COS(O)(=O)=O VAXCXSDAWONRLI-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- RZXUKBRHXFSGJL-UHFFFAOYSA-N [N].C(=C)Cl Chemical compound [N].C(=C)Cl RZXUKBRHXFSGJL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical group 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- 229950005425 sodium myristyl sulfate Drugs 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- HDRLZNWDSGYGBZ-KVVVOXFISA-M sodium;(z)-octadec-9-ene-1-sulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCCS([O-])(=O)=O HDRLZNWDSGYGBZ-KVVVOXFISA-M 0.000 description 1
- MWZFQMUXPSUDJQ-KVVVOXFISA-M sodium;[(z)-octadec-9-enyl] sulfate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCCOS([O-])(=O)=O MWZFQMUXPSUDJQ-KVVVOXFISA-M 0.000 description 1
- FIWQZURFGYXCEO-UHFFFAOYSA-M sodium;decanoate Chemical compound [Na+].CCCCCCCCCC([O-])=O FIWQZURFGYXCEO-UHFFFAOYSA-M 0.000 description 1
- KQFAFFYKLIBKDE-UHFFFAOYSA-M sodium;ethanesulfonate Chemical compound [Na+].CCS([O-])(=O)=O KQFAFFYKLIBKDE-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- KBAFDSIZQYCDPK-UHFFFAOYSA-M sodium;octadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCS([O-])(=O)=O KBAFDSIZQYCDPK-UHFFFAOYSA-M 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/04—Pressure vessels, e.g. autoclaves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2442575A DE2442575C3 (de) | 1974-09-05 | 1974-09-05 | Verfahren zur Herstellung von Emulsionspolyvinylchlorid unter Vermeiden von Vinylchlorid-Emissionen |
| DE2442575.0 | 1974-09-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5154683A JPS5154683A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-05-13 |
| JPS6035363B2 true JPS6035363B2 (ja) | 1985-08-14 |
Family
ID=5924969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50107549A Expired JPS6035363B2 (ja) | 1974-09-05 | 1975-09-04 | 塩化ビニルを放出することなく乳化ポリ塩化ビニルを製造する方法 |
Country Status (15)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5100988A (en) * | 1987-09-08 | 1992-03-31 | Shin-Etsu Chemical Co., Ltd. | Initiated scale-free formation of vinyl chloride polymers using washing liquid at temperature affecting initiator half-life |
| US4954595A (en) * | 1987-09-08 | 1990-09-04 | Shin-Etsu Chemical Co., Ltd. | Method for preparing vinyl chloride polymers |
| US5256758A (en) * | 1991-06-10 | 1993-10-26 | Eastman Kodak Company | Thermosetting coating compositions |
| US20030219363A1 (en) * | 2002-05-17 | 2003-11-27 | Kobylecki Ryszard J. | Examining chemical reactions |
| CN104028173B (zh) * | 2014-05-28 | 2016-06-29 | 新疆中泰化学股份有限公司 | 聚合釜入料装置及其使用方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2979492A (en) * | 1957-06-03 | 1961-04-11 | Ethyl Corp | Continuous polymerization process |
| US3317449A (en) * | 1966-04-19 | 1967-05-02 | Grace W R & Co | Polyvinylidene chloride latex and process |
| US3926931A (en) * | 1970-04-13 | 1975-12-16 | Shinetsu Chemical Co | Method for suspension-polymerizing vinyl chloride |
| DE91560C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1970-05-07 | |||
| DE2141770A1 (de) * | 1971-08-20 | 1973-03-08 | Huels Chemische Werke Ag | Verfahren und vorrichtung zur herstellung von polymerisaten oder copolymerisaten von vinylchlorid durch kontinuierliche polymerisation in masse |
| DE2239942C3 (de) * | 1972-08-14 | 1988-02-11 | Wacker-Chemie GmbH, 8000 München | Verfahren zur Polymerisation von Vinylchlorid |
-
1974
- 1974-09-05 DE DE2442575A patent/DE2442575C3/de not_active Expired
-
1975
- 1975-06-25 NO NO752267A patent/NO142351C/no unknown
- 1975-08-26 FR FR7526235A patent/FR2283911A1/fr active Granted
- 1975-08-28 CA CA234,418A patent/CA1052925A/en not_active Expired
- 1975-09-03 IT IT7551178A patent/IT1044466B/it active
- 1975-09-03 US US05/610,069 patent/US4020263A/en not_active Expired - Lifetime
- 1975-09-03 CH CH1142375A patent/CH597266A5/xx not_active IP Right Cessation
- 1975-09-04 JP JP50107549A patent/JPS6035363B2/ja not_active Expired
- 1975-09-04 BR BR7505680*A patent/BR7505680A/pt unknown
- 1975-09-04 ES ES440718A patent/ES440718A1/es not_active Expired
- 1975-09-04 AT AT683475A patent/AT339600B/de not_active IP Right Cessation
- 1975-09-04 GB GB36435/75A patent/GB1513404A/en not_active Expired
- 1975-09-04 SE SE7509853A patent/SE421801B/xx unknown
- 1975-09-04 NL NL7510448A patent/NL7510448A/xx not_active Application Discontinuation
- 1975-09-05 BE BE159801A patent/BE833140A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE2442575B2 (de) | 1979-05-31 |
| DE2442575A1 (de) | 1976-03-25 |
| NO752267L (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-03-08 |
| AT339600B (de) | 1977-10-25 |
| NO142351B (no) | 1980-04-28 |
| NO142351C (no) | 1983-08-03 |
| JPS5154683A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-05-13 |
| NL7510448A (nl) | 1976-03-09 |
| SE421801B (sv) | 1982-02-01 |
| BR7505680A (pt) | 1976-08-03 |
| CH597266A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-03-31 |
| BE833140A (fr) | 1975-12-31 |
| FR2283911A1 (fr) | 1976-04-02 |
| FR2283911B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1979-05-18 |
| SE7509853L (sv) | 1976-03-08 |
| GB1513404A (en) | 1978-06-07 |
| DE2442575C3 (de) | 1980-01-17 |
| ES440718A1 (es) | 1977-03-16 |
| ATA683475A (de) | 1977-02-15 |
| IT1044466B (it) | 1980-03-20 |
| US4020263A (en) | 1977-04-26 |
| CA1052925A (en) | 1979-04-17 |
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